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Adsorption of Mn on iron minerals and calcium compounds to reduce Mn(II) toxicity (2가 망간의 독성 저감을 위해 철산화물과 칼슘화합물을 이용한 망간 흡착)

  • Hyo Kyung Jee;Jin Hee Park
    • Journal of Applied Biological Chemistry
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    • v.65 no.4
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    • pp.457-462
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    • 2022
  • Manganese (Mn) exists in various oxidation states and Mn(II) is the most mobile species of Mn, which is toxic to plants and limits their growth. Therefore, the purpose of this study was to reduce Mn toxicity by immobilizing Mn using various adsorbents including iron oxides and calcium compounds. Ferrihydrite, schwertmannite, goethite were synthesized, which was confirmed by X-ray diffraction. Hematite was purchased and used as Mn adsorbent. Calcium compounds such as CaNO3, CaSO4, and CaCO3 were used to increase pH and oxidize Mn. For Mn adsorption, Mn(II) solution was reacted with four iron oxides, CaNO3, CaSO4, and CaCO3 for 24 hours, filtered, and the remaining Mn concentrations in the solution were analyzed by inductively coupled plasma optical emission spectroscopy. The adsorption rate and adsorption isotherm were calculated. Among iron oxides, the adsorption rate was highest for hematite followed by ferrihyrite, but goethite and schwertmannite did not adsorb Mn. In the case of calcium compounds, the adsorption rate was high in the order of CaCO3>CaNO3>CaSO4. In conclusion, treatment of CaCO3 was the most effective in reducing Mn toxicity by increasing pH.

Flash Lamp Annealing of Ag Organometallic Ink for High-Performance Flexible Electrode (플래시 기반 유기금속화합물 열처리를 통한 고성능 유연 전극 제조)

  • Yu Mi Woo;Dong Gyu Lee;Yun Sik Hwang;Jae Chan Heo;SeongMin Jeong;Yong Jun Cho;Kwi-Il Park;Jung Hwan Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.5
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    • pp.454-462
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    • 2023
  • Flash lamp annealing (FLA) of metal nanoparticle (NP) ink has provided powerful strategies to fabricate high-performance electrodes on a flexible substrate because of its rapid processing capability (in milliseconds), low-temperature process, and compatibility with to roll-to-roll process. However, metal NPs [e.g., gold (Au), silver (Ag), copper (Cu), etc.] have limitations such as difficulty in synthesizing fine metal NPs (diameter less than 10 nm), high price, and degradation during ink storage and FLA processing. In this regard, organometallic ink has been proposed as a material that can replace metal NPs due to their low-cost (usually 1/100 times cheaper than metal nano inks), low-temperature processability, and high material stability. Despite these advantages, the fabrication of flexible electrodes through FLA treatment of organometallic compounds has not been extensively researched. In this paper, we experimentally guide how to determine the optimal conditions for forming electrodes on flexible substrates by considering material parameters, and flashlight processing parameters (energy density, pulse duration, etc) to minimize the difficulties that may arise during the FLA of organometallic ink.

A Study on Transport Robot for Autonomous Driving to a Destination Based on QR Code in an Indoor Environment (실내 환경에서 QR 코드 기반 목적지 자율주행을 위한 운반 로봇에 관한 연구)

  • Se-Jun Park
    • Journal of Platform Technology
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    • v.11 no.2
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    • pp.26-38
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    • 2023
  • This paper is a study on a transport robot capable of autonomously driving to a destination using a QR code in an indoor environment. The transport robot was designed and manufactured by attaching a lidar sensor so that the robot can maintain a certain distance during movement by detecting the distance between the camera for recognizing the QR code and the left and right walls. For the location information of the delivery robot, the QR code image was enlarged with Lanczos resampling interpolation, then binarized with Otsu Algorithm, and detection and analysis were performed using the Zbar library. The QR code recognition experiment was performed while changing the size of the QR code and the traveling speed of the transport robot while the camera position of the transport robot and the height of the QR code were fixed at 192cm. When the QR code size was 9cm × 9cm The recognition rate was 99.7% and almost 100% when the traveling speed of the transport robot was less than about 0.5m/s. Based on the QR code recognition rate, an experiment was conducted on the case where the destination is only going straight and the destination is going straight and turning in the absence of obstacles for autonomous driving to the destination. When the destination was only going straight, it was possible to reach the destination quickly because there was little need for position correction. However, when the destination included a turn, the time to arrive at the destination was relatively delayed due to the need for position correction. As a result of the experiment, it was found that the delivery robot arrived at the destination relatively accurately, although a slight positional error occurred while driving, and the applicability of the QR code-based destination self-driving delivery robot was confirmed.

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A Study On Artifacts Analysis In Portable Software (무 설치 프로그램에서의 사용자 행위 아티팩트 분석)

  • Taeyeong Heo;Taeshik Shon
    • Journal of Platform Technology
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    • v.11 no.2
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    • pp.39-53
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    • 2023
  • Non-installation program (hereinafter referred to as "portable program") is a program that can be used without an installation process, unlike general software. Since there is no separate installation process, portable programs have high mobility and are used in various ways. For example, when initial setup of multiple PCs is required, a portable program can be stored on one USB drive to perform initial setup. Alternatively, when a problem occurs with the PC and it is difficult to boot normally, Windows PE can be configured on the USB drive and portable programs can be stored for PC recovery. And the portable program does not directly affect PC settings, such as changing registry values, and does not leave a trace. This means that the portable program has high security. If a portable program is deleted after using it, it is difficult to analyze behavior in a general way. If a user used a portable program for malicious behavior, analysis in a general way has limitations in collecting evidence. Therefore, portable programs must have a new way of behavioral analysis that is different from ordinary installation software. In this paper, after installing the Windows 10 operating system on a virtual machine, we proceed with the scenario with a portable program of Opera and Notepad++. And we analyze this in various ways such as file analysis of the operating system and memory forensics, collect information such as program execution time and frequency, and conduct specific behavioral analysis of user.

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Effect of Operating Variables on the Morphology of Precipitated Calcium Carbonate in a Slurry Bubble Reactor (슬러리 기포탑 반응기에서 침강성 탄산칼슘의 모폴로지에 대한 조업변수들의 영향)

  • Hwang, Jung-Woo;Lee, Yoong;Lee, Dong-Hyun
    • Clean Technology
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    • v.16 no.2
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    • pp.124-131
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    • 2010
  • Effects of $Ca(OH)_2$ concentration (0.16~0.64 wt%), surfactant concentration (2~16 wt%), total volumetric flow rate (3~6 L/min) and $CO_2$ volume fraction $(0.3{\sim}0.6)$ on morphology, crystal structure, mean particle diameter, aggregation and specific surface area of the precipitated $CaCO_3$ were investigated in the slurry bubble column reactor. Experiments were carried out in acrylic reactor ($0.11\;m-ID{\times}1.0\;m-high$) with a internal tube ($0.04\;m-ID{\times}1.0\;m-high$h). The reaction time of $CaCO_3$ synthesis decreased with adding Dispex N40 of the anionic surfactant. The reaction rate of $Ca(OH)_2$ increased with increasing the volumetric flow rate of $CO_2$. From SEM images, the single crystal of $CaCO_3$ increased with increasing the reaction rate in the saturated concentration of $Ca(OH)_2$ (0.16 wt %) and the concentration of Dispex N40 (2 wt%). The mean particle size of $CaCO_3$ varied with adding Dispex N40. In addition, the specific surface area of $CaCO_3$ increased with adding of surfactant (2 wt%) from $35m^2/g$ to $44m^2/g$ at the volumetric flow rate of $CO_2$ (0.9 L/min) and the concentration of $Ca(OH)_2$(0.64 wt %).

Prediction of Dormant Customer in the Card Industry (카드산업에서 휴면 고객 예측)

  • DongKyu Lee;Minsoo Shin
    • Journal of Service Research and Studies
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    • v.13 no.2
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    • pp.99-113
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    • 2023
  • In a customer-based industry, customer retention is the competitiveness of a company, and improving customer retention improves the competitiveness of the company. Therefore, accurate prediction and management of potential dormant customers is paramount to increasing the competitiveness of the enterprise. In particular, there are numerous competitors in the domestic card industry, and the government is introducing an automatic closing system for dormant card management. As a result of these social changes, the card industry must focus on better predicting and managing potential dormant cards, and better predicting dormant customers is emerging as an important challenge. In this study, the Recurrent Neural Network (RNN) methodology was used to predict potential dormant customers in the card industry, and in particular, Long-Short Term Memory (LSTM) was used to efficiently learn data for a long time. In addition, to redefine the variables needed to predict dormant customers in the card industry, Unified Theory of Technology (UTAUT), an integrated technology acceptance theory, was applied to redefine and group the variables used in the model. As a result, stable model accuracy and F-1 score were obtained, and Hit-Ratio proved that models using LSTM can produce stable results compared to other algorithms. It was also found that there was no moderating effect of demographic information that could occur in UTAUT, which was pointed out in previous studies. Therefore, among variable selection models using UTAUT, dormant customer prediction models using LSTM are proven to have non-biased stable results. This study revealed that there may be academic contributions to the prediction of dormant customers using LSTM algorithms that can learn well from previously untried time series data. In addition, it is a good example to show that it is possible to respond to customers who are preemptively dormant in terms of customer management because it is predicted at a time difference with the actual dormant capture, and it is expected to contribute greatly to the industry.

Blade Type Field Vs Probe for Evaluation of Soft Soils (연약지반 평가를 위한 블레이드 타입 현장 전단파 속도 프로브)

  • Yoon, Hyung-Koo;Lee, Chang-Ho;Eom, Yong-Hun;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.23 no.12
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    • pp.33-42
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    • 2007
  • The assessment of shear wave velocity($V_s$) in soft soils is extremely difficult due to the soil disturbances during sampling and field access. After a ring type field $V_s$ probe(FVP) has been developed, it has been applied at the southern coastal area of the Korean peninsular. This study presents the upgraded FVP "blade type FVP", which minimizes soil disturbance during penetration. Design concerns of the blade type FVP include the tip shape, soil disturbance, transducers, protection of the cables, and the electromagnetic coupling between transducers and cables. The cross-talking between cables is removed by grouping and extra grounding of the cables. The shear wave velocity of the FVP is simply calculated by using the travel distance and the first arrival time. The large calibration chamber tests are carried out to investigate the disturbance effect due to the penetration of FVP blade and the validity of the shear waves measured by the FVP. The blade type FVP is tested in soils up to 30m in depth. The shear wave velocity is measured every 10cm. This study suggests that the upgraded blade type FVP may be an effective device for measuring the shear wave velocity with minimized soil disturbance in the field.

Geophysical Techniques for Underwater Landslide Monitoring (수중 산사태 모니터링을 위한 지반물리탐사기술)

  • Truong, Q. Hung;Lee, Chang-Ho;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.23 no.7
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    • pp.5-16
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    • 2007
  • The monitoring and investigation of underwater landslide help to understand its mechanism, increase the usefuless of design and construction and reduce the losses. This paper presents three high resolution geophysical techniques electrical resisitance, ultrasonic wave reflection imaging, and shear wave tomography conducted to determine the lab-scaled submerged landslide. Electrical resistance profiles of a soil mass obtained by an electrical resistance probe provide detailed information to assess the spatial distribution of the soil mass with milimetric resolution. An ultrasonic wave image obtained by recording the reflections from interfaces of different impedance materials permits detecting layers and landslide with submilimetric resolution. The pixel based image of immersed landslides is created by the inversion of the boundary information achieved from the traveling time of shear waves. The experimental results show that the ultrasonic wave imaging and the electrical resistance can provide complementary information; and their association with S-wave tomography image can produce a 3-D view of the underwater landslide. This study suggests that geophysical techniques may be effective tools for the detection of the underwater landslides and spatial distribution offshore.

Anti-cancer activity of the ethylacetate fraction from Orostachys japonicus in A549 human lung cancer cells by induction of apoptosis and cell cycle arrest (인체 폐암 세포에 대한 와송 유래 에틸아세테이트 분획 생리 활성 물질의 세포사멸 유도 및 세포주기 억제 항암활성)

  • Kwon, Ji-Hye;Lee, Dong-Seok;Jung, Eun-Cheol;Kim, Hyeon-Mi;Kim, Su-Bin;Ryu, Deok-Seon
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.1
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    • pp.395-405
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    • 2017
  • To confirm potential anti-cancer activities of ethylacetate (EtOAc) fraction from Orostachys japonicus on the A549 human lung cancer cells, this study examined. As a result of conducting MTS assay for measuring cell viability, the EtOAc fraction inhibited the proliferation of A549 cells in a dose-dependent manner. To investigate whether the inhibiting A549 cell viability was caused by apoptosis, this study analyzed chromatin condensation in A549 cells using DAPI staining. The morphological changes such as the formation of nuclear condensation were formed in a dose-dependent manner. Also, this study performed Annexin V-FITC staining for detecting phosphatidylinositol (PS). As a result of Annexin V-FITC staining to investigate level of early and late apoptosis, the apoptosis level treated with EtOAc fraction was higher than that of control. RT-PCR was performed to study the correlation between G2/M cell cycle arrest and cell cycle control genes. The anti-cancer activity of EtOAc fraction was accompanied by inhibition of CDK1, 4, cyclin B1 and D1 mRNA. This study also examined the expression of various marker proteins: p53, Bax, Bcl-2 and pro-caspase 3. Western blotting revealed that p53 and Bax proteins were up-regulated, and Bcl-2 and pro-caspase 3 proteins down-regulated in a time and dose-dependent manner.

Study for Manufacturing of Zinc Sulfate from Electric Arc Furnace Dust by Hydrometallrugical Process (제강분진으로부터 습식제련공정에 의한 황산아연의 제조 연구)

  • Dong Ju Shin;Sung-Ho Joo;Dongseok Lee;Shun Myung Shin
    • Resources Recycling
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    • v.32 no.1
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    • pp.33-41
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    • 2023
  • Herein, we selectively recovered Zn and produced ZnSO4 from electric arc furnace dust using a hydrometallurgical process. The analysis of the properties of the electric arc furnace dust revealed that the Fe content (9.9%) was relatively low while the Mn content (19%) was high as compared to the composition of general dust. Therefore, an appropriate hydrometallurgical process was designed based on the properties of the raw materials. In the leaching process involving the use of 1.6 M sulfuric acid and 20% solid-liquid ratio at 60℃ for 1 h, 85% of the Zn and Mn got dissolved while the Fe was not leached. To selectively recover Zn, a solvent extraction process using D2EHPA as the extractant was chosen, and 99% of the Zn was extracted using 0.8 M D2EHPA with 32% saponification and an O/A ratio of 2 using counter-current 3-stage extraction. Mn was entirely scrubbed with an aqueous sulfuric acid solution of pH 1.5. Finally, Zn was concentrated and stripped using 1.5 M sulfuric acid at an O/A ratio of 4 using counter-current 4-stage stripping. The stripping solution contained 40 g/L of Zn, and 99.9% of ZnSO4∙H2O was obtained by vacuum distillation.