• Analytical Science and Technology
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• v.22 no.4
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• pp.313-318
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• 2009

Liquid chromatographic enantiomer separation of amino alcohols was performed on several chiral columns based on polysaccharide derivatives under the mobile phase conditions containing acid or base additive. The chromatographic parameters were greatly influenced by the nature of the mobile phase containing acid or base additive as well as the used chiral columns. Compared to chromatographic results obtained in the mobile phase containing base additive (0.1% triethylamine), especially, Chiralcel OD showed dramatically enhanced separation factors and resolution factors with reduced capacity factors under the mobile phase condition containing acidic additive (0.1% trifluoroacetic acid). When the mobile phase containing 0.05% trifluoroacetic acid and 0.05% triethylamine was used on Chiralcel OD, the greatest separation factors and resolution factors among all other mobile phase conditions in this study were observed.

• Journal of Korea Spatial Information System Society
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• v.9 no.3
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• pp.51-65
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• 2007

In order to analyze moving object trajectories on road networks, its representation needs to be defined correctly. The most previous methods representing moving object trajectories on road networks defined moving object trajectories as a set of passed location and its time. It is required much time in processing analysis such as retrieval for moving object trajectories. In this paper, we focus on POI(Points of Interest) on road networks and propose methods simplifying moving object trajectories based on it. Our method simplifies moving object trajectories by reducing the number of POIs that moving object trajectories passed and maintains its form after moving object trajectories were simplified.

• Journal of the Korean Chemical Society
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• v.43 no.6
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• pp.656-662
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• 1999

We have obtained retention data of benzene, toluene, ethylbenzene, phenol, and acetophenone at 25, 30, 35, 40, 45 and 50 $^{\circ}C$ in 30/70, 40/60, 50/50, 60/40, 70/30, and 80/20 (v/v %) methanol/water eluents using a $C_18$ phase with a high ligand density. We drew van't Hoff plots from the data, and computed enthalpies and entropies of solute transfer from the mobile to the stationary phase. The cavity formation effect was found the major factor that governs the solute distribution between the mobile and stationary phases. The hydrophobic effect became significant in highly aqueous mobile phases. We also concluded that the Shodex C18-5B stationary phase was a polymer-like phase with a high ligand density, and followed a partially adsorption-like mechanism.

• Korean Journal of Food Science and Technology
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• v.34 no.5
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• pp.762-769
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• 2002

As a preliminary test for defining intact yellow croaker pigment, the pigment was analyzed by column chromatography and UV-vis spectrophotometry. All maximum absorbance wavelengths commonly showed three maximum absorbance ranges, similar to those of carotenoid, suggesting that the tested pigment may be carotenoid. We detected total six peak RT values in the chromatogram through PDA-HPLC under gradient mode (behavior A at 10% for initial 2 min and changed to behavior B for 60 min). Most pigments were detected at the peak with 3.27 RT value. Because seven peaks were detected under gradient mode and three under isocratic mode [methanol : methylene chloride (90 : 10, v/v)], gradient mode was determined to be more appropriate for quantitative analysis. By the comparison test of RT values among yellow pigment in croakers and reference pigments, such as zeaxanthine, ${\beta}-cryptoxanthine$, ${\beta}-carotene$, and astaxanthin, only ${\beta}-cryptoxanthine$ was detected in the white croaker, whereas such pigment of yellow croaker having RT value of 31.02 was not detected. Therefore, RT value was found to be applicable for detecting adulterated croaker.

• Journal of the Korean Chemical Society
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• v.53 no.2
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• pp.137-143
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• 2009

Liquid chromatographic enantiomer separation of N-tert-butoxycarbonyl (BOC) $\alpha$-amino acids and their ethyl esters was performed on covalently immobilized chiral column (Chiralpak IC) derived from polysaccharide derivative. The solvent versatility of the covalently immobilized Chiralpak IC in enantiomer separation of N-BOC $\alpha$-amino acid ethyl ester derivatives was shown and the chromatographic parameters of their enantioselectivities and resolution factors were greatly influenced by the nature of the mobile phase. Also the effect on the dissolving solvent for these analytes on the enantiomer separation using the same mobile phase and the examples of preparative enantiomer separation on analytical column were shown.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.3
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• pp.805-812
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• 2014

This study investigates the impact of morphological change on the physical habitat simulation. For this, CCHE2D model is used for the hydraulic analysis including the morphological change, and the physical habitat suitability is assessed with habitat suitability curves. The model is applied to a 2.5km long reach downstream of the Goesan Dam, from Sujeon Bridge to Daesu Weir. Flow data of discharge and stage in July, 2006 are used in the computation. The numerical model is verified by means of comparison with the measured water surface elevation data, and the variation of the river bed is not verified in this study. Adult Zacco platypus is chosen for the dominant species. Physical habitat simulations result in composite habitat suitability and weighted usable area for drought, low, normal, and averaged-wet flows. The simulation results indicate that the composite suitability index increased at reaches right downstream of the Sujeon Bridge and around the bend. This also increased weighted usable area by 5.4-11.3%.

• Proceedings of the Korean Information Science Society Conference
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• 2003.04d
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• pp.121-123
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• 2003

무선 이동 통신은 눈에 띄는 성장을 해왔고 이에 발맞춰 새롭게 네트워크와 그에 따른 기술에 접근하고 있다 이러한 성향에 따라 사용자의 이동성을 지원하고 투명하게 서비스의 이동성을 지원하는 새로운 기술이 요구되어지고 있다 본 논문에서는 무선통신 네트워크상에서의 효율적인 서비스의 이동을 보장하는 새로운 메커니즘을 제안한다. 이러한 메커니즘은 서비스 이동성을 위한 컴포넌트 기반의 서버측 모델과 사용자의 이동성을 제공하는 센서 네트워크 상에서의 모바일 IP 기술로 구성된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.1679-1683
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• 2007

최근 우리나라에서 하천 및 유역 환경의 급격한 변화로 인하여 하천 형태가 많이 변하고 있는 추세이다. 특히 사행하는 모래 하천에서 만곡부 사주의 형태 변화가 커지고 있다. 이 연구에서는 이와 같은 모래 하천의 만곡부에서 사주의 변화 특성을 평가하고 그 원인을 파악하기 위하여 이동상 수리모형 실험을 실시하였다. 실험에서 하천 및 유역의 여러 상황 변화를 감안하여 유량, 유사 공급량, 공급 시간, 하천 변형 등 다양한 조건을 상정하였다. 연구 대상하천은 낙동강 본류이며, 중점 수리모형 실험대상 구간은 우리나라의 전통민속마을인 안동 하회마을을 태극형으로 감싸면서 사행하는 만곡부이다. 이동상 실험규모는 수평축적 1/110, 수직축적 1/50로 왜곡도가 2.2로써 비교적 대규모이다. 모형 하상재료는 입경 0.29 mm의 석탄분(anthracite)을 채택하였으며, 현장에서 하상재료조사와 상사해석을 통해 결정하였다. 실험 결과, 유량과 유사 공급량 변화에 따른 사주 변화가 밀접한 관계가 있는 것으로 나타났다. 특히 유사 공급이 이루어지지 않을 때 국지적 퇴적양상을 보였다. 이는 사주 내 식생활착으로 이어지는 계기가 될 수 있음을 확인할 수 있었다. 그리고 설계홍수량 규모에서 구하도와 과거 사주가 재현되었는데, 이는 지역주민을 통해 입증되었다. 또한 천연기념물인 만송정 주변의 모래둔덕의 형성과정이 입증되었다.

• Journal of the KSME
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• v.24 no.4
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• pp.275-283
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• 1984

유한요소기법은 원만한 온도변화를 갖는 이동경계문제에 대해 적용할 수 있음을 설명하였다. 상변화가 일어나는 요소에서 어느 한 시간 단계에 변화할 수 있는 온도의 범위는 상변화 온도 구간 보다 적어야 원만한 수치해를 얻을 수 있음을 소개하였다. 잠열의 효과를 엔탈피의 온도에 대한 변화율로 처리하여 열용량 행렬을 계산할 수 있음을 설명하였다. 급격한 변화를 갖는 온 도분포를 수치적으로 근사해를 구할 때 나타나는 파동형상은 연속적인 변수를 부분적으로 근사 해를 가정 하는데서 포함되는 오차에 기인한다. 따라서 이러한 급격한 변화의 변수를 취급하는 기법이 요구된다. 상변화를 수반하는 이동경계문제는 물의 결빙금속의 열처리, 용접, 고체연료의 연소 등에서 많이 접하게 되나 전문적인 프로그램이 없으므로(저자가 조사한 바에 의하면) 온 도분포를 요구하는 문제에서는 이의 선결이 요망되고 있다. 특히 구조해석문제에서 시간에 따라 온도조건이 변화는 경우가 많아 온도분포에 대해 따로 계산하고 그 후 구조해석을 하는 방법이 있으나, 이는 상변화와 같은 물성의 큰 변화가 없는 경우에만 가능하다. 따라서 상변화가 있는 문제에서 열탄성(thermo-elasticity)이나 열탄소성(thermoelasto-plasticity)해석을 하기 위해서는 이동경계와 구조해석을 동시에 하여야 한다.

• Journal of Korea Water Resources Association
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• v.48 no.11
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• pp.879-889
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• 2015

The pattern of headward erosion at tributary and the separation zone formation in a loosed bed at confluence according to the confluence angle, discharge ratio, and dredging depth ratio have been analyzed. The separation zone is defined the inside of zero velocity boundary at downstream of confluence. The limit of separation zone occurrence is presented with dredging depth ratio. The propagation length of knickpoint increases as the confluence angle, discharge ratio, and dredging depth ratio increase in general and its regression equation has been suggested. The length and width ratios of separation zone in a loosed bed increase as discharge ratio and confluence angle increase as well as in a fixed bed. The length ratio decreases and the width ratio increases as dredging depth ratio increases results in great increase of shape factor and backwater rise by the conveyance reduction at confluence. The regression equation of shape factor with confluence angle, discharge ratio, and dredging depth ratio has been suggested.