• Title/Summary/Keyword: 응결지연

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A Hydration Reaction and Strength Development Properties of Cement Using Pond Ash in Coal Fired Power Plant (화력 발전소 매립회를 치환한 시멘트의 수화반응 및 강도발현 특성)

  • Lee, Jae-Seung;Noh, Sang-Kyun;Shin, Hong-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.578-584
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    • 2021
  • This study comparatively analyzed the properties of hydration reaction and strength development of four types of pond ash(PA) and fly ash(FA), aiming for the effective use of PA. The PA whose chlorine content was highest due to the seawater movement method had a faster setting time, higher cumulative heat, and greater initial strength development than those of FA due to the acceleration of the cement hydration reaction. However, the activity factor increase rate decreased after seven days of curing due to the rapid generation of early hydrates. The PA that contained impurities, such as a large amount of unburned carbon, had a delayed setting time due to the lower hydration reaction. Moreover, the strength was degraded in all curing ages. The PA whose chlorine content was lower due to the freshwater movement method and the amorphous content exhibited similar hydration reactivity and strength development characteristics compared to that of FA. The thermogravimetric analysis results verified that it had a similar level of Ca(OH)2 consumption and pozzolanic reactivity with that of FA. Conclusively, it is necessary to expand the application of the freshwater movement method and manage the ignition loss to raise PA's usability.

A Study on the Fundamental Properties of Mortar Mixed with Converter Slag and Ferronickel Slag (전로슬래그 및 페로니켈슬래그를 혼입한 모르타르의 기초물성 연구)

  • Kim, Ji-Seok;Park, Eon-Sang;Ann, Ki-Yong;Cho, Won-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.152-160
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    • 2021
  • Converter steel slag(BOF slag) is a vast amount of solid waste generated in the steelmaking process which has very low utilization rate in Korea. Due to the presence of free CaO which can derive bad volume stability in BOF slag, it usually land filled. For recycling BOF and identify its applicability as fine aggregate, this study investigates the fundamental characteristics of mortar with cement replaced ferronickel slag(FNS), which has the potential to be used as a binder. The results suggest that the mineral phases of BOF slag mainly include larnite(CaSiO4), mayenite(Ca12Al14O33) and wuestite(FeO) while olivine crystallines are shown in FNS. The results of flow and setting time reveals that the flowability and process of hardening increased when the amount of FNS and BOF slag incorporated was increased. The length change shows that the amount of change in the length of the mortar was almost constant regardless of mix proportion while compressive strength was reduced. Micro structure test results revealed that FNS or/and BOF slag mix took a long time to react in the cement matrix to form a complete hydration products. To achieve the efficient utilization of B OF slag as construction materials, proper replacement rate is necessary.

Water Repellent Characteristics of Cement Paste Added Silane/siloxane-based Emulsion Water Repellent (실란/실록산계 에멀전 발수제를 혼입한 시멘트 페이스트의 발수특성)

  • Kang, Suk-Pyo;Hong, Seong-Uk;Kang, Hye-Ju;Yang, Seung Hyeon
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.1
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    • pp.31-39
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    • 2021
  • The aim of this paper is to improve durability of cement paste by imparting hydrophobicity to the surface and sphere of cement-based materials. A cement paste mixed with a silane/siloxane-based water repellent, and the initial hydration performance, flow performance, and age-specific compressive strength were measured. In addition, the water contact angle, SEM, and XRD before and after surface polishing were measured. When 0.5% of the silane/siloxane-based water repellent was mixed into the cement paste, the compressive strength increased, but the compressive strength decreased as the mixing amount increased by 1.5% and 3.0%. When a silane/siloxane water repellent was incorporated into the cement paste, the hydrophilicity was improved and the contact angle was increased due to hydrophobicity. In addition, the contact angle after surface polishing was found to be larger than the contact angle before surface polishing.

Material Properties of Concrete Produced with Limestone Blended Cement (석회석 혼합 시멘트로 제조된 콘크리트의 기초 물성)

  • Bang, Jin-Wook;Kwon, Seung-Jun;Shin, Kyung-Joon;Chung, Woo-Jung;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.2
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    • pp.125-132
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    • 2015
  • This paper presents an experimental investigation in order to evaluate fresh and hardened properties of LP (Limestone Powder) blended cement concrete. The cement contents of the mixtures are replaced by LP in the range of 10%, 15%, 25%, and 35%, while a control mixture is prepared with only OPC (Ordinary Portland Cement). The fresh concrete properties like slump and air content are similar to those of control mixture up to 35% of replacement ratio of LP, however a delay in setting time is evaluated. The hardened properties including compressive strength, flexural strength, and rapid freezing and thawing resistance shows similar results of control mixture up to 15% of replacement. Relatively lower strength development is evaluated over 25% replacement of LP. For accelerated carbonation test, resistance to carbonation rapidly decreases with increasing LP replacement ratio due to the limited amount of $Ca(OH)_2$. From the study, LP replacement under 15% can be adopted considering reduction of strength and resistance to carbonation.

Evaluating Early Age Shrinkage Behavior of Ultra High Performance Cementitious Composites (UHPCC) with CSA Expansive Admixture and Shrinkage Reducing Agent (CSA계 팽창재 및 수축 저감제의 혼입에 따른 UHPCC의 초기 수축 거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.23 no.4
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    • pp.441-448
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    • 2011
  • In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

Strength Development and Freeze-Thaw Resistance of Concrete Incorporating High Volume Blast-Furnace Slag Subjected to Initial Frost Damage (초기동해를 받은 고로슬래그 다량 혼입 콘크리트의 강도발현 및 동결융해 저항성)

  • Koh, Kyung-Taek;Ryu, Gum-Sung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.79-87
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    • 2011
  • Concrete incorporating high volume blast-furnace slag placed in cold weather regions might be in danger of initial frost damage because dependently on the mix proportions, the setting and the hardening would be remarkably delayed. Therefore, this study investigated to effect of the degree of frost on the strength development and the resistance to freezing and thawing of the concrete incorporating blast-furnace slag when being subjected to freeze at early age. As the experimental results, the concrete incorporating blast-furnace slag attacked by initial frost damage showed the remarkable reduction of both the compressive strength development and the resistance to freezing and thawing. Especially, the resistance to freezing-thawing of the concrete incorporating high volume blast-furnace slag became much lower than that of the normal concrete.

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Initial Performance Evaluation of Fine-size Exposed Aggregate PCC Pavement by Experimental Construction (시험시공을 통한 소입경 골재노출 콘크리트포장의 초기 공용성 평가)

  • Kim, Young-Kyu;Choi, Don-Hwa;Lee, Seung-Woo;Kim, Hyung-Bae
    • International Journal of Highway Engineering
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    • v.12 no.1
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    • pp.87-98
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    • 2010
  • Surface of fine-size exposed aggregate Portland cement concrete pavements is consists of exposed coarse aggregate by removing upper 2~3mm mortar of concrete slab. Fine-size exposed aggregate PCC pavements have advantages of maintaining low-noise and adequate skid-resistance level during the performance period. In order to provide the successful exposed concrete aggregate pavement, uniform distribution of the coarse aggregate on pavement surface through adequate the mix design and exposing method. In this study, evaluated initial performance of fine-size exposed aggregate PCC pavement by experimental construction. And it was known that fine-size exposed aggregate concrete pavement which can reduce the noise and maintain the adequate level of skid resistance and strength.

Effect of Carbon Amino Silica Black Contained Superplasticizer on the Engineering Properties and Chromaticity of Black Color Concrete (카본 아미노 실리카 블랙 기반 고성능 감수제가 블랙 컬러 콘크리트의 공학적 특성 및 발색도에 미치는 영향)

  • Han, Min-Cheol;Hong, Seok-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.181-188
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    • 2013
  • This paper is to investigate experimentally an effect of carbon amino silica black-superplasticizer(CASB-SP)on the engineering properties and chromaticity of black color concrete with 0.45 of W/C(water to cement). CASB-SP and carbon black were applied for pigment of the concrete. To prevent efflorescence of concrete, four different water repellent agents were also applied. As results, it was found that use of CASB-SP increased the slump and air contents. Furthermore, the use of CASB-SP increased the compressive strength. As CASB-SP dosages increased, chromaticity was well developed. For the effect of water repellent agent, the use of epoxy type was effective for protection from efflorescence. Based on test results, it was evaluated that 0.5% of CASB-SP effectively improve the concrete quality as well as enhance the chromaticity with proper dosage.

Effect of Ethanol Content on Fine Soot Particle Emission from a Diesel-Ethanol Blended Fuel Diesel Engine (디젤-에탄올 혼합연료의 에탄올 함량이 미세 그을음(Soot) 입자 배출특성에 미치는 영향)

  • Park, Su-Han;Cha, June-Pyo;Kwon, Seok-Ju;Park, Sung-Wook;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.12
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    • pp.1359-1365
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    • 2011
  • The purpose of this study is to investigate the effect of ethanol content on the emission of nanosized particles from a diesel-ethanol blended fuel engine. The engine combustion and exhaust emission characteristics of a singlecylinder diesel engine were analyzed using an emission analyzer and an SMPS(scanning mobility particle sizer). The analysis revealed that soot emission increased with the ignition delay. When the ignition delay was fixed, an increase in the ethanol content caused a decrease in the soot emission. With an increase in the ethanol blending ratio, the number concentration and mass distribution of nanosized particles generally decreased. However, for 30% ethanol blending, large particles were observed because of the agglomeration of soot particles, and consequently, the particle mass increased.

The Fundamental Properties of High-Strength Concrete Using Pre-mixed Cement Corresponding to Water Binder Ratio (물 결합재비 변화에 따른 프리믹스 시멘트를 사용한 고강도 콘크리트의 기초적 특성)

  • Jin, Cheong-Ri;Han, Dong-Yeop;Kim, Ki-Hoon;Hwang, Yin-Seong;Kim, Sung-Su;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.369-372
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    • 2008
  • This study analysis fundamental properties of high-strength concrete corresponding to W/B ratio for suggested table of high strength concrete, mixed with premixed cement. As a result of this study, the amount of using air entraining and high-range water reducing agent for intended slump flow and air content decreased as W/B increased, and the setting time corresponding to the W/B ratio delayed as W/B ratio increased except 20% W/B ratio. The compressive strength according to W/B ratio decreased as W/B ratio increased, and there was no great deferent as the intended slump flow. Also it could possible to use this study at work as the correlation coefficient is high enough as 0.9646 substituting B/W and compressive strength for the regression formula.

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