• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.94-101
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• 2011

In this study, in order to develop organic-inorganic hybrid packaging materials(PM) of bike paths using blast furnace slag(BS) as industrial by-products, fundamental properties of organic-inorganic hybrid packaging materials were performed. Test result, the increase of Acryl emulsion polymer(AEP)/binder(B) ratios tends to delay the setting time, to increase the table flow, to decrease the strength by material segregation and to increase the length change. The optimal mix proportion of AEP decides on 40%(AEP/B) due to workability and high strength. The increase of BS replacement ratios also tends to delay the setting time, to separate AEP from B and to decrease the strength by material segregation. When BS replacement ratios were lower than 40%, they are satisfied with goal properties.

• Magazine of the Korea Concrete Institute
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• v.10 no.6
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• pp.223-231
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• 1998

Existing cast in place piles made by grouting cement mortar have many problems that cracks by autogeneous and drying shrinkage bring about the deterioration of force for piles, segregations by the submersion of ground water occur and also, high cement contents lead to rise the manufacturing cost. Therefore, this study is intended to investigate the mechanical properties of high performance mortar, incorporating expansive additives and fly ash. for cast in place piles. According to the experimental results, as the contents of expansive additives increase in mortar mixture, fluidity decrease and air contents shows inverse tendency. Setting time is delayed. Although compressive strength at 7days shows a decline tendency. compressive strength at 28days and 91days increase slightly with 5% of expansive additives. As fly ash increase in mortar mixture, high fluidity is shown, air contents increase and setting time is delayed at fresh state, and additives are, the larger length change is, whereas shrinkage decrease with the increase of fly ash.

• Journal of the Korea Institute of Building Construction
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• v.8 no.1
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• pp.91-96
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• 2008

This study is to investigate the influence of the over-added chemical agents, such as water reducing agent(WRA) and AE water reducing agent(AEWRA), on the physical properties of concrete to estimate the degree of damage due to over-added chemical agents. For the fresh concrete, slump and slump flow increased with the increase of WRA and AEWRA as expected. Material segregation phenomenon was observed with the over dosage of lignin based AEWRA about 4 times larger than recommended dosage. The over dosage of AE water reducing agent about 4 times larger than recommended dosage resulted in an increase of air contents remarkably. The set retardation occurred greatly with the increase of AEWRA and WRA. For the properties of the hardened concrete corresponding to the over dosage of AEWRA, it is found that compressive strength of over added AEWRA and WRA concrete are much smaller than those of base and recommended dosage concrete proportionally due to associated increasing air content.

• Journal of the Korea Concrete Institute
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• v.21 no.4
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• pp.481-488
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• 2009

It has been reported that the magnitude and the development rate of autogenous shrinkage of cement paste, mortar and concrete were affected by history and magnitude of inner temperature at an early age. But it was not enough to explain the relation between hydration heat and autogenous shrinkage at an early age, because there was no certain analysis on histories of hydration heat and autogenous shrinkage in previous studies. In our prior study, to understand the relationship between hydration heat and autogenous shrinkage of concrete at an early age, the analysis method for histories of hydration heat and autogenous shrinkage was suggested. Based on this method, early age properties of hydration heat and autogenous shrinkage of high strength concrete with different sizes and hydration retardation were investigated in this study. As a result of the study, properties of hydration temperature and autogenous shrinkage were different according to specimen size and hydration retardation. However, there was a close relationship between hydration temperature and autogenous shrinkage at an early age, especially between HHV and ASV as linear slopes of the sections where hydration temperature and autogenous shrinkage increase rapidly; the higher HHV, the higher ASV and the greater ultimate autogenous shrinkage. And it was found that, among the setting time, bend point and temperature increasing point, they were close relationship each other on cement hydration process.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.3
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• pp.237-243
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• 2015

In this research, isothermal conduction calorimetry analysis has been conducted to investigate the reactivity of alkali activated slag binders. In order to secure the reactivity and workability of alkali activated slag binders, experiences with various types and concentrations of alkali activators were performed. Isothermal conduction calorimetry were measured with different alkali activators and mass ratio of $SO_3$ to binders as variables, and sodium tripolyphosphate ($Na_2P_3O_{10}$) and hydrated sodium borate ($Na_2B_4O_710H_2O$) were used to control setting time. As a results, alkali activated slag binders required alkali activators with 4 to 5 percent of concentration to accelerate the formation of calcium silicate hydrate(C-S-H) by alkali-activation, and overall heat generation rate delayed as accumulated heat decreased due to the high $SO_3$ contents. Moreover, the use of hydrated sodium borate as setting retarder causes elongated setting time due to delaying heat generation, so it can be considered that setting retarder played an important role in delaying total heat generation rate.

• Journal of the Korea Institute of Building Construction
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• v.14 no.2
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• pp.135-142
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• 2014

The heat of hydration can be reduced through the use of retarding agents. Typical retarding agents include sugar and glucose. However, these significantly delay the setting of cement paste. For the efficient use of sugar and glucose for mass concrete construction, it is necessary to develop a technique that can provide a setting behavior equivalent to that of plain concrete. In this work, the temperature rise of cement paste was monitored with the addition of various retarders including sugar and glucose. Hydrated cement powder was made with a water to cement ratio of 5 in order to accelerate the retarded cement pastes. It was found that the addition of hydrated cement powder in retarded pastes reduced the maximum temperature of cement paste. The use of hydrated cement powder could also successfully reduce the time to reach the maximum temperature.

• Journal of Conservation Science
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• v.36 no.6
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• pp.456-474
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• 2020

This study investigated the initial behavior (flowability and setting properties) and shrinkage characteristics of lime mortar, based on the mixing ratio of hydrated lime (lump, powder) and commercial lime, which is primarily used for repairing and restoring cultural assets. The flowability showed that the optimum mixing water contents of the masonry lime mortar were 8-10% for the lump hydrated lime, 10-18% for the powdered hydrated lime, and 17-40% for the commercial hydrated lime. The results of the setting and shrinkage analysis showed that the average final setting time ratio compared to the standard of cultural asset repair was in the increasing order of commercial hydrated lime(0.4) < powder hydrated lime(5.6) < lump hydrated lime(5.7). Moreover, the average shrinkage ratio was ordered as lump hydrated lime(1.1) < powder hydrated lime(1.2) < commercial hydrated lime(3.0). The analysis of the physical and chemical characteristics of hydrated lime showed that the optimum mixing water content was reduced as the particle size of the lime increased, thus delaying the setting time and decreasing the length change rate (shrinkage). These results are expected to contribute to the prediction of the initial behavior and shrinkage characteristics of mortars using handmade and commercial lime during repair and restoration work on cultural, heritage buildings.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.173-174
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• 2014

In this research, the effect of the amount of retarder and the washing timing on the quality of aggregate-exposed concrete produced by water-jet washing method is evaluated as a series of test to develop the aggregate-exposed concrete as a concrete finishing method. As a result, the amount of losing aggregate and surface mortar was increased as the dosage of retarder was increased because of the hydration retarding effect of the retarder. Furthermore, as the washing timing was extended, the mortar on the surface of the concrete was not blown by water jet with 8 to 24 ml of retarder because of hydration of cement, hence the surface quality was poor. Therefore, washing timing of one day after concrete placement showed 90 % of aggregate exposed rate and 24 ml of retarder showed the most favorable result of aggregate exposure.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.9
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• pp.4602-4609
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• 2013

In summer and winter, the difference between the temperature during the day and that during the night is high, which leads to various problems during concrete placement, such as cracks and defects in the concrete as well as low durability and strength. Although nuclear power plant concrete is widely used for placement in all seasons, particular attention must be paid to its quality during the summer. Therefore, we evaluated the effects of a cooling method for mixing water, which is a commonly used hot weather precooling method, and the use of a retarder, on the characteristics of Nuclear Power Plant concrete. In the cooling method for mixing water, cold water at 5 was used, with 50% of the water content consisting of ice flakes. The effects of using a retarder were evaluated by reviewing the characteristics of the cement at the unset stage and after hardening. To evaluate the characteristics of the unset cement, we measured the slump, air volumes, setting times, and pressure strengths after hardening. Furthermore, we measured the heat of hydration at different temperatures; the loss of heat was minimized using insulation. Both the slump time and the complete ageing time of the air volume were found to be 120 min at $20^{\circ}C$ and 40 min at $40^{\circ}C$. In the case when the cooling method for mixing water was used and in the case when a retarder was used, the initial and final sets by penetration resistance were delayed, and the delay decreased with increasing air temperature. For the heat of hydration, the cooling method for mixing water not only lowered the maximum temperature but also delayed its attainment. However, the use of a retarder had no effect on the maximum temperature. Moreover, in the early ages (e.g., 3 and 7 days), the pressure strength of the concrete was lower than that of plain cement. However, the strength of 28-day concrete met the standard construction specifications.

• Journal of the Korean Ceramic Society
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• v.34 no.2
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• pp.163-170
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• 1997

The retarding effects of MgSiF6.6H2O on the hydration of portland cement were studied. The setting time, flow value and compressive strength of mortar were measured and the mechanism of retardation was also studied by ion concentration in solution, SEM, BET, and X-ray diffraction. The results are as follows ; 1. Setting time was delayed by the addition of MgSiF6.6H2O. 2. The flow value of mortar decreases depending upon the amount of MgSiF6.6H2O. 3. The compressive strength was almost same or some increase on 28 days hydration. 4. The main retardation mechanism of MgSiF6 on the hydration of portland cement may be explained by the following hypothesis. MgSiF6 depressing the Ca++ and K+ ion concentration of cement paste solution be-cause of the recrystalization of K2SiF6 and CaF2 phase. The new products of K2SiF6 and CaF2 deposit on the surface of unhydrated cement powder and harzard the mass transfer through these layer. The low con-centration of Ca++, K+ ion in solution was decreasing the hydration rate of portland cement.