• Analytical Science and Technology
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• v.23 no.5
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• pp.429-436
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• 2010

The present research evaluates the efficiency of mixed resins between anion exchange resin and active carbon. We expected synergic effect from advantages of both adsorbents. Especially, this research focused on the removal of high cencentrated perchlorate ion from demilitarization solution. The total amount of the adsorbed perchlorate ion is increased considerably with mixed resins between mono functional anion exchange resin and granular active carbon from a single adsorbent. Results demonstated that this process not only improve the efficiency of adsorbing perchlorate, but save the time, space and cost for treating perchlotrate waste solution, because of reducing organic contaminant removing process. The interference effects from coexisting anions are not significant and can successfully applied to real demilitarization sample.

• 대한방사선방어학회:학술대회논문집
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• 2010.04a
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• pp.84-85
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• 2010

• Nuclear Engineering and Technology
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• v.13 no.4
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• pp.237-244
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• 1981

The preliminary concentration of trace elements in uranium dioxide using an anion exchange resin is presented for neutron activation analysis. The uranyl solution in sulfuric acid is adjusted to the acidity of about pH 2.7 and loaded on a column of the anion exchange resin. An appropriate volume of eluates obtained from the column shows good recoveries of trace elements. By combining this preconcentration with a radiochemical separation scheme, which was developed for the determinations of impurities in aluminum, it is possible to determine 21 trace elements in reactor grade uranium dioxide.

• Journal of the Korean Chemical Society
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• v.23 no.3
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• pp.141-151
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• 1979

The selective absorption of metal ions by chelating agent-loaded resins was studied in aqueous media. The resins were prepared by loading the conventional anion exchange resin, Dowex 1-X8 (50 to 100 mesh) with chelating agents containing sulfonic group, such as 8-hydroxy-quinoline-5-sulfonic acid (HQS) and 7-nitroso-8-hydroxyquinoline-5-sulfonic acid (NHQS). The stability of the resin was markedly influenced by the following factors; (1) the affinity and concentration of anions in the external solution, (2) the pH of the media. The optimum conditions for the absorption of metal ions were determined with respect to the pH, shaking time, and the effect of anion concentration in the medium. Under the optimum condition the order of the absorption of metal ions such as Fe(Ⅲ), Cu(Ⅱ), Pb(Ⅱ), and Zn(Ⅱ) was in accord with that of the stability constants of the chelates. The total capacities of the resins were found in the range of 0.6∼1.6 mmole metal per gram.

• Applied Chemistry for Engineering
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• v.1 no.1
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• pp.23-29
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• 1990

The effect of a rapid freeze pretreatment of organic ion exchange resins on their grinding properties was studied. It was found that the structure of ion exchange resins was defected by freezing pressure formed in the process of rapid freezing. The defected resins didn't recover their own structure after thawing and those could be easy to be broken at room temperature by small force. Therefore, organic ion exchange resins could be ground readily at room temperature after rapid-freezing the fully swelled resins using by solid carbon dioxide, or liquid nitrogen. The rapid freeze pretreatment of cation exchange resins was very effective on grinding in particular. However, the effect of the pretreatment of anion exchange resins on grinding was less than that of cation exchange resins. In case of anion exchange resins, the ionic form of affected the grindability remarkably.

• Journal of the Korean Chemical Society
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• v.29 no.3
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• pp.233-238
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• 1985

The non-porous and porous polystyrene divinylbenzene copolymers were prepared by the suspension polymerization method. The non-porous aminated polystyrene divinylbenzene, N-APSTDVB and the porous aminated polystyrene divinylbenzene, P-APSTDVB of 50∼100mesh size weakly basic anion exchanger were synthesized by chloromethylation followed by amination with methylamine. The functional groups of these synthesized anion exchangers were confirmed by their infrared spectra. The maximum capacity of these exchangers was 4.86meq/g. Pore volume and pore spectra were determined with a mercury porosimeter. The pore volume of P-PSTDVB increased with increasing X$_{diluent}$ at 30% of divinylbenzene. However, the pore volume of P-PSTDVB increased with increasing volume percent of divinylbenzene at constant mole fraction of diluent, X$_{diluent}$ of 0.5. The pore volume of synthesized copolymer and anion exchanger at 8% divinylbenzene and 0.5X$_{heptane}$ decreased as follows; P-PSTDVB 〉P-APSTDVB 〉N-PSTDVB. This result was attributed to the possibility that the pore volume were reduced by amination reactions. The distribution coefficients of boric acid on the N-APSTDVB anion exchanger in various concentrations of alcohol water solutions showed that as alcohol concentration increased, the distribution coefficients values decreased due to the reduced concentration of H$_2$BO$_3^-$.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.1
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• pp.41-47
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• 2005

Preparation of ferrocyanide-anion exchange resin and adsorption test of the prepared resin on the Cs$^{+}$$ion were performed. Adsorption capability of the prepared resin on the Cs$^{+}$ion in the simulated citric acid based soil decontamination waste solution was 4 times greater than that of the commercial cation exchange resin. Adsorption equilibrium of the prepared resin on the Cs$^{+}$ion reached within 360 minutes. Adsorption capability on the Cs$^{+}$ion became to decrease above the necessary Co$^{2+}$ion concentration in the experimental range. Recycling test of the spent ion exchange resin by the successive application of hydrogen peroxide and hydrazine was also performed. It was found that desorption of Cs$^{+}$ion from the resin occurred to satisfy the electroneutrality condition without any degradation of the resin.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.2
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• pp.146-154
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• 2017

Recently, self-healing concrete has been researched as maintenance and repair of concrete structures are important challenges we face. This paper focused on possibility of ion exchange resin as a novelty material directly and actively controlling harmful ions of concrete, whereas most self-healing concrete researches have been focused on methods to automatically filling and repairing internal crack of concrete. Because equilibrium properties between ion exchange resin and harmful ion is important before design of cement mixing proportion, it was conducted to remove chloride or sulfate in saturated $Ca(OH)_2$ solutions containing NaCl or $Na_2SO_4$. The removal performance was analyzed using kinetic equation and isothermal equation. Consequently, the removal properties of anion exchange resin were relatively more dependent on pseudo second reaction equation and Langmuir equation than pseudo first reaction equation and Freundlich equation. And it was concluded that each chloride and sulfate can be removed to the maximum 1068 ppm and 1314 ppm.

• Korean Journal of Food Science and Technology
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• v.27 no.3
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• pp.313-317
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• 1995

Ion exchange process was optimized to purify ultrafiltrated bean cooking water(BCW) for the production of soy-oligosaccharides. The ultrafiltrated BCW with cutoff MW(COMW) 20,000 membrane was treated with various ion exchange resins. Protein and ash were mostly removed by anion and cation exchange resins, respectively. Based upon removing capabilities for ash and protein, a cation exchange resin(SK1B) and an anion exchange resin(WA30) were selected. Protein and ash were more efficiently removed at low extract/resin ratios(ERR), but part of the oligosaccharides were concomitantly lost. When 2-step-ultrafiltrated BCW first with COMW 20,000 membrane and successively with COMW 5,000 membrane was treated with a mixed resin(SK1B : WA30 =1 : 2) at ERR 5.0, most oligosaccharides were recovered in a clear protein- and ash-free liquid.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.11
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• pp.804-811
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• 2011

The aim of this study is to evaluate the applicability of adsorption models for understanding adsorption properties of adsorbents. For this study, the adsorption charateristics of $NO_3^-$ by commercial anion exchange resin, PA-308, were investigated in bach process. The adsorption kinetic data for $NO_3^-$ by anion exchange resin showed two stage process comprising a fast initial adsorption process and a slower second adsorption process. Both the pseudo-first-order kinetic model and the pseudo-second-order kinetic model could not be used to predict the adsorption kinetics of $NO_3^-$ onto anion exchange resin for the entire sorption period. Only the fast initial portion ($t{\leq}20min$) of adsorption kinetics was found to follow pseudo-first-order kinetic model and controlled mainly by external diffusion that is very fast and high, whereas, the slower second portion (t > 20 min) of adsorption kinetics seems to be controlled by a second-order chemical reaction and by intraparticle diffusion.