• Title/Summary/Keyword: 은 이온

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The Optimal Combination of Major Nutrients Computed by the Homés Systematic Variation Technique -III. Determination of the Optimal Combination of Σ Anion : Σ Cation and the Optimal Application Rate of Total Ions on the Various Grassland Soils (Homés방법(方法)에 의(依)한 다량요소(多量要素)의 적정(適正) 시비비율(施肥比率) 결정(決定)에 관한 연구 -III. 초지토양별(草地土壤別) 음(陰)이온 성분총량(成分總量) : 양(陽)이온 성분총량(成分總量) 적정(適正) 시비비율(施肥比率) 및 적정(適正) 총시비량(總施肥量))

  • Jung, Yeun-Kyu;Kim, Sang-Chul;Weinberger, P.
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.3
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    • pp.178-187
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    • 1982
  • This pot experiment was undertaken to find out the optimum fertilization ratios of total anions to total cations, ${\Sigma}A/{\Sigma}C$, and the optimum application rates of total macro-nutrients in various soil conditions. Soil samples were collected from uncultivated mountains and hills where grassland development was under consideration. 1. The optimum application ratios of ${\Sigma}A/{\Sigma}C$ and the optimum application rates of total macro-nutrients for the high yields of mixed grass-clover sward in various grassland soils were computed by the Hom$\acute{e}$s systematic variation techniqu.e. 2. With respect to the optimum application ratios of ${\Sigma}A/{\Sigma}C$ in fertilization in a mixed grass-clover sward, the grass yield and botanical composition were distinctly proportional to ${\Sigma}A$ wheras the regume yield and botanical composition were proportional to ${\Sigma}C$. 3. The optimum fertilization rates of total macro-nutrients for the high legume yields were depended upon ${\Sigma}A/{\Sigma}C$ ratios. These optimum rates were in proportional to ${\Sigma}C$ ratios and were inversely proportional to ${\Sigma}A$ ratios. 4. The efficiencies of ${\Sigma}A$ and ${\Sigma}C$ in relation to the grass and grass plus legume yields were highest with the low ratios of each other and the low fertilization rates of total macronutrients. The ${\Sigma}A$ effieiency in the legume yield tended to be similar to that of ${\Sigma}A$ related to the grass yield noted above except Daegu soil. The ${\Sigma}C$ efficiency, however, was proportional to the ${\Sigma}C$ ratio, although that was varied with the fertilization rates of total macro-nutrients and with the kinds of soils. 5. The yield of mixed forages, yield component, and botanical composition in a mixed sward were greatly influenced by the ${\Sigma}A/{\Sigma}C$ ratios, the fertilization rates of total macronutrients, and the interactions of ratio and rate noted above. In addition, these effects were generally different and opposite according to grass and legume.

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Antimicrobial polyurethane film manufacturing complex Apatite, and the characteristics (아파타이트를 복합한 항균 폴리우레탄 필름제조 및 특성)

  • Kwon, Oh-Kyung;Kim, Seok-Hoon;Park, Sun-Hwa;Min, Byung-Gil
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.14-14
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    • 2011
  • 폴리우레탄 필름을 이용하여 등산복, 스포츠 웨어, 보호복 등 많은 의복이 제조되고 있으며, 현재 폴리우레탄 필름에 항균성을 부여하여 메디컬 소재에 적용되고 있다. 항균성을 부여하는 물질은 제올라이트. 수산화아파타이트, 실리카 겔을 이용한 많은 무기 항균제가 사용되고 있다. 이들중 특히 수산화아파타이트는 생체친화력 및 이온교환 능력이 우수하여 인공뼈 또는 인공치아로 사용되고, 환경분야에서는 이온교환수지로 중금속 제거를 위하여 사용되기도 한다. 본 연구에서는 폴리우레탄 필름 내부의 비드 간극 및 크기를 제어하여 비드콘 구조를 가지는 폴리우레탄 필름을 제조하였고 수산화아파타이트에 다양한 조건으로 은이온을 흡착시켜 은의 최적 흡착 조건을 설정하고 은이 흡착된 수산화아파타이트의 입자를 제어하여 다양한 종류의 입자를 제조하고 입자별 항균성을 평가하였다. 최종적으로 개발된 비드콘 폴리우레탄 필름과 은담지 수산화아파타이트를 여러가지 조건으로 복합화하여 항균성을 가지는 아파타이트복합 폴리우레탄필름을 제조하고 개발된 필름의 항균성 및 그 특성을 분석하여 보았다.

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Characterization of Cellulase Gene (MsGHF45) from Monochamus saltuarius Expressed in Yeast (효모에 발현된 북방수염하늘소(Monochamus saltuarius) Cellulase gene MsGHF45의 특성에 관한 연구)

  • Ko, Hyeon-Jin;Ko, Hyunjun;Hong, Soon-Kwan;Park, Yong Chul
    • Journal of Korean Society of Forest Science
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    • v.105 no.2
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    • pp.261-267
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    • 2016
  • In this study, the cellulase of Monochamus saltuarius (MsGHF45) gene was introduced in Kluyveromyces lactis, successfully. The molecular weight of recombinant enzyme was determined by SDS-PAGE and western blotting. The enzymatic activity was confirmed by native-PAGE containing carboxymethyl cellulose as a substrate. The optimul pH and temperature of recombinant MsGHF45 was pH5 and $40^{\circ}C$. The barium ($Ba^{2+}$) and ferrous ($Fe^{2+}$) enhanced enzyme activity, and the mercuty ($Hg^{2+}$) inhibited its activity.

Photo-sensitized oxidation of benzene in water under UV irradition (자외선 조사에 의한 벤젠의 광증감 산화처리에 관한 연구)

  • Lee, Chun Sik;Lee, Dong-Keun
    • Clean Technology
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    • v.4 no.2
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    • pp.11-22
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    • 1998
  • The photo-sensitized oxidation of benzene in water was investigated under various reaction conditions using persulfate, sulfate, nitrate, nitrite and chloride ions as sensitizers. Persulfate ion was proved to be the most effective sensitizer, while sulfate and nitrite could not play any sensitizing role on the benzene photooxidation. When exited together with other ions, the nitrite ion inhibited the photooxidation of benzene by quenching the produced hydroxyl radicals.

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LC/ESI/MS 와 기능성 화장품 관련 분석에의 응용

  • 이명희
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.3
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    • pp.23-46
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    • 1999
  • LC/MS는 HPLC의 분리능과 질량분석기의 화합물의 확인 능력을 결합시킨 기기이다. 여기서 사용되는 이온화 방법은 GCJMS에서 사용되어지는 전자이온화법(electron ionization, EI)이나, 화학이온화법(chemical ionization, CI)은 부적당하기 때문에 최근 개발되어진 연성 이온화법의 대표적인 고속원자폭격식(Fast atom bombardment, FAB)이나 전기분무이온화식 (electrospray ionization, ESI) 등이 사용되고 있다. 이중 전기분무이온화법은 고속원자폭격법에서 사용되는 매트릭스를 사용하지 않기 때문에 매트릭스 이온의 부재로 인한 낮은 바탕 신호, 오래 지속되면서 안정된 초기 이온 전류, 샘플링의 용이성, HPLC와의 더 좋은 호환성 등의 장점을 제공한다. 이러한 전기분무이온화 방법은 극성이 매우 크거나 휘발성이 낮은 물질로 보통의 EI나 CI 이온화 방법으로 분석이 어려운 물질들을 분석할 수 있다. 또한 열에 불안정하거나 분자의 분자량이 다른 단백질 등의 분석도 가능하다. 이러한 LC/ESI/MS 방법을 이용하여 열에 불안정하고 극성이면서 분자량이 커서 GC/MS 펄의 분석이 어려운 기능성 화장품 원료로 주목받고 있고 생체에 존재하는 지질 성분으로 알려진 레시틴과 세라마이드의 분석이 가능함을 소개하고 분리와 동시에 그 분자량과 구조에 대한 정보를 빠르게 얻을 수 있음을 소개하였다.

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Effects of Silver lon Exchanged Water Treatment Agent upon E. Coli RB 797 and Bacillus sp. (수처리제 은이온이 E. Coli RB 797과 Bacillus sp. 에 미치는 영향)

  • 신혜자;신춘환
    • Journal of Life Science
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    • v.7 no.4
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    • pp.316-321
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    • 1997
  • The effects of the silver ion-exchanged water treatment agent (Ag-Os) upon E. coli RB 797 and Bacillus sp. have been discussed in this study. Silver ion causes a number of toxic effects with no known biological function. Silver ion-exchanged water treatment agent (Ag-Os) using oyster shell here showed antimicrobial activities. the soluble form of silver ion in water is more toxic to the growth of Bacillus sp. than that of E. Coli RB 797. The minium amount of Ag-Os needed for growth inhibition is 0.2 mg/ml for E. Coli RB 797 and 0.02 mg/ml for Bacillus sp., which is consistant with the data of the survival cell fraction. Binding studies suggested that binding of silver to the cell surface was a rapid, metabolic-independent process and different from active transport. Bacillus sp. showed more binding than E. Coli RB 797. Reducing substances of the cell cultures in the presence of Ag-Os was detected using Methylen blue as an indicator. From these results, we suggest that Ag-Os is effective as an antimicrobial agent on E. Coli RB 797 and Bacillus sp. and silver binds to the cells through rapid, metabolic-independent process and might complex to sulfur group in the cells for its toxicity.

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Membrane Potential across Porous Anion-Exchange Membranes in Electrolyte Solution (전해질용액에서의 다공성 음이온교환막을 통한 막전위)

  • ;;Kiyono, Ryotaro;Tasaka, Masayasu
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.04b
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    • pp.21-22
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    • 1997
  • 최근의 이온교환막은 종래의 양이온교환막의 표면에 polycation 등의 얇은 층을 덧붙인 다층막(multi-layer membrane)의 형태가 많이 이용되고 있으며, 정전기적 반발력의 차 등을 이용하여 원자가가 다른 이온들간의 투과성에 차를 부여하기 위하여 이용되고 있다. 이 때문에 polycation막을 통한 1가 이온과 2가 이온의 투과성을 연구하는 것은 우수한 이온교환막을 제작하는것 이상으로 중요하다. 본 연구에서는 고정전하농도(fixed charge density, $\Phi$ X)가 낮은 다공성 저전하음이온교환막을 제작하여, 양측에 대이온(counterion)은 같고 복이온(co-ion)이 다른 전해질용액을 두었을 경우에 관찰되는 막전위를 측정하였다. 이를 토대로 음이온교환막을 통한 막전위의 농도의존성에 관하여 검토하였으며, 비평형열역학(non-equilibrium thermodynamies)에 기초한 이론적 모델을 도입하여 실험치와 비교, 해석하였다.

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Electrical Conductance and Electrode Reaction of $RbAg_4I_5$ Single Crystals (고체전해질 $RbAg_4I_5$ 단결정의 전기전도성과 전극반응)

  • Jong Hee Park;Woon-Kie Paik
    • Journal of the Korean Chemical Society
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    • v.24 no.4
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    • pp.295-301
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    • 1980
  • The electrical conductivity of solid electrolyte $RbAg_4I_5$ single crystal was studied at various temperatures. The four-probe method was used in measuring the conductance with an ac signal imposed on the specimen. The ionic conductivity was $0.284 ohm^{-1} cm^{-1}\;at\;25^{\circ}C$, and the activation energy for $Ag^+$ ion migration was calulated to be 1.70 kcal/mole. These values agree well with those reported for polycrystalline samples. Reactions at $Ag/RbAg_4I_5$ interface were studied by cyclic voltammetry with a silver reference electrode. It was found that silver ion is reversibly reduced at silver surfaces below zero volt, and iodide was oxidized above +0.67 volt.The anodic current arising from the oxidation of the electrode was small in magnitude initially over a wide range of potential, but, after silver was cathodically deposited on the electrode, reversing the potential sweep to the anodic direction resulted in a sharp peak of anodic current.

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Effect of Nitrate-Ammonium Ratio on Ionic Balance in Mulberry(Morus alba L.) Leaves (질산태(窒酸態) 및 암모니아태(態) 질소비율(窒素比率)과 상엽중(桑葉中)이온의 균형(均衡))

  • Lee, Won-Chu;Yoo, Sun-Ho;Lim, Sun-Uk
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.2
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    • pp.110-116
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    • 1982
  • A water culture was conducted with 5 levels of nitrate-ammonium ratio (NAR: 10:0, 7:3, 5:5, 3:7, 0:10) to study the ionic balance, cation-anion (C-A) in mulberry leaves and to determine the optimum NAR for the greatest leaf yields. The results were as follows: 1. The growth rate of mulberry plants was the greatest at 7:3 NAR. 2. Magesium in the mulberry leaves was not affected by NAR. By lowering NAR, calcium content decreased more than potassium content increased, consequently lowering the sum of cation content (${\sum}C$). However, the sum of anion (${\sum}A$) increased because of increments of sulphate, chloride and especially phosphate. 3. Ionic balance in the mulberry leaves deceased from 727 to 116 me/Kg dry matter with increasing ammonium levels of 0 to 100% in the nutrient solution.

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