• Title/Summary/Keyword: 유화특성

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Synthesis and Characterization of Water Repellent Materials Containing 2-(Perfluorooctyl) Ethyl Acrylate and m-Isopropenyl-α, α-Dimethylbenzyl Isocyanate (2-(Perfluorooctyl) Ethyl Acrylate (PFOEA) 및 m-Isopropenyl-α, α-Dimethylbenzyl Isocyanate (TMI)가 함유된 발수체 합성 및 특성연구)

  • Kang, Young Taec;Kwak, Eun Mi;Chung, Ildoo
    • Journal of Adhesion and Interface
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    • v.15 no.4
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    • pp.151-160
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    • 2014
  • A series of terpolymers based on stearyl methacrylate (SMA), n-methyol acrylamide (n-MAM), and 2-(perfluorooctyl) ethyl acrylate (PFOEA) were synthesized by changing PFOEA contents up to 8 wt% in order to obtain optimal water-repellent properties. In addition, various contents of m-isopropenyl-${\alpha}$,${\alpha}^{\prime}$-dimethylbenzyl isocyanate (TMI) from 1 to 4 wt% were added to the above terpolymers with 4 wt% of PFOEA content. The emulsion polymerization was carried out using tridecyl alcohol (EO)7 (TDA-7) as a nonionic surfactant, alkyl dimethyl amine derivatives (ADAD) as a cationic surfactant, and 2,2'-azobis(2-amidinopropane dihydrochoride) (AAPDL) as an initiator. The synthesized copolymers were characterized by FT-IR spectroscopies, contact angle, surface energy, and water-repellency. Surface and thermal properties were analyzed by SEM, TGA, and DSC. It was found that water repellency increased with increasing the contents of PFOEA and TMI.

Innovative Technology for Removal of Dispersants used in Oil Spill Remediation Using the Magnetic Separation (자성 분리를 이용한 해상 유류오염제어에 사용되는 유화제를 제거하는 새로운 기술에 대한 연구)

  • Chun, Chan-Lan;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.679-688
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    • 2000
  • Dispersants, which are used to break water-in-oil emulsions and to remediate oil-spills, are another water pollutants. In this study, magnetic separation technology was applied to remove dispersants from the sea. Magnetite and maghemite were used as magnetic sorbents and SDDBS, an anionic surfactant and Triton X-100, a nonionic surfactant, were employed as dispersants. Batch experiments were undertaken to study the sorption capacity and sorption equilibrium, and water-bath experiments were conducted to simulate the real situation and to describe the recovery of magnetic particles by the permanent magnet or electromagnet. Maghemite has rather constant removal efficiency for dispersants, regardless of surfactant species. On the other hand, removal efficiency by magnetite is higher for anionic surfactant than maghemite and is higher in distilled water than in seawater which contains more ions. The sorption of dispersants to magnetite is explained by electrostatic attraction and that of maghemite is described not only by electrostatic attraction, but also by structural characteristics that provide high sorption ability and surface condition. Water bath experimental results showed that recovery efficiency of magnetic particle after sorption for dispersants is nearly 100%. It is suggested that this magnetic separation technology is an effective way of dispersant removal because of short operating time, high sorption capacity, and high recovery efficiency of sorbents.

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Effective of Extract Garlic, Spices of Emulsified with Egg-Yolk & Olive Oil (마늘과 향신료 첨가가 난황과 감람유 유화의 관능적 특성)

  • 장혁래
    • Proceedings of the Korea Hospitality Industry Research Society Conference
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    • 2002.11a
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    • pp.112-122
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    • 2002
  • This study was made to find the compound of it's taste and properties of texture and also it's color desired and optimal conditions when the natural spices garlic, celery, parsley, bay leaves, pepper com, nutmeg, shallot, onion, tarragon, lemon juice-are added to reduction of the spices in the liquid egg yolk and hot virgin olive oil. Extracted by white wine and vinegar and then baked on salamander and gas oven in emulsified properties of sabayon and hot virgin olive oil. It may be indicated the pasteurization that during that in all treatment of the liquid egg yolk was achieved with whisk holding water in double boiling pen 95$^{\circ}C$ for 1min with the object of removing salmonella possibly contained in the yolk.(lmai camd namba e2).

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Isolation and Characterization of a Crude oil-Degrading Strain, Nocardia sp. H 17-1 (원유 분해균주 Nocardis sp. Hl7-1의 분리 및 특성)

  • 이창호;권기석
    • KSBB Journal
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    • v.11 no.6
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    • pp.654-662
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    • 1996
  • Bacterial strains which degrade crude oil were isolated by liquid culture from oil-spilled soil, and four isolates were selected among them. The strain Hl7-1 was finally selected after testing emulsifying activity and oil conversion rate. The strain Hl7-1 was identified as a Nocardia sp. based on the test for morphological, biochemical and physiological characteristics. It appears to be highly specialized for growth on crude oil in minimal salts medium since it showed preference for oil or degradation products as substrates for growth. It was found that it could grow on at least fifteen different hydrocarbons. The optimum cultural and environmental conditions were seeked. Cell growth and emulsification activity as a function of time were also determined. Crude oil degradation and the reduction of product peak was identified by the analysis of remnant oil by gas chromatography after 3 days of cultivation. Approximately 83% of oil were converted into a form no longer extractable by organic solvents.

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Improvement of Emulsion Stability of Food Proteins by Microbial Transglutaminase (미생물유래 transglutaminase를 이용한 식품단백질의 유화안정성 향상에 관한 연구)

  • Lee, Deuk-Sik
    • Korean Journal of Food Science and Technology
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    • v.37 no.2
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    • pp.164-170
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    • 2005
  • To improve functional properties of food proteins, homologous or heterologous ${\beta}-casein$ and 11S globulin(glycinin) from animal and vegetable proteins, respectively, were bio-hybridized using transglutaminase(MTGase). Susceptibility was confirmed by SDS-PAGE, particle size analyzed, and emulsion stability tested using Reddy and Fogler method, To determine how bio-hybridized protein influences emulsion stability, protein bound on oil droplet was investigated using Scanning Electron Microscopy (SEM). formation of bio-hybridized protein band was detected among homologous and heterologous proteins, with heterologous protein forming weak band in oligomer form. Homologous ${\beta}-casein$ protein showed high emulsion stability, while homologous glycinin showed almost no stability. Stability of heterologous ${\beta}-casein$ and glycinin protein was higher than that of glycinin. SEM photographs showed even distribution of bio-hybridized proteins on oil droplet improved stability.

The Manufacturing Characteristics of Magnesium Chloride Emulsion by Different Rotational Speed of Homomixer as Soybean Curd Coagulant (두부응고제로서 Homomixer 회전속도를 달리한 염화마그네슘유화물의 제조특성)

  • Hong, Seung-Seok;Park, Won-Jong;Joung, Kyung-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.3
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    • pp.1252-1257
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    • 2013
  • This study was used homomixer as one of the manufacturing method to establish optimal manufacturing condition with magnesium chloride emulsion as coagulant. The more rotational speed of homomixer was fast, the more particle size of magnesium chloride emulsion was minute. The particle size was distributed between 1 and $5{\mu}m$. The more minute particle size of emulsion had an effect on increasing viscosity of emulsion and delay of oil phase separation during storage period, so the quality of magnesium chloride emulsion had correlation with dispersed phase particle size. After all the experiments, when manufacturing magnesium chloride emulsion, it used more than 10,000 rpm of rotational speed of homomixer, it showed the best result as coagulant according to the state of texture and the water separation ratio of soybean curd.

Evaluation of Characteristics of Tack Coat for Porous Pavement using Direct Shear Test (직접 전단 실험을 통한 배수성포장용 택코트 특성 평가)

  • Kim, Nak-Seok;Hong, Eun-Cheol;Jo, Shin-Haeng
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.27-32
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    • 2009
  • The main objective of this study is to develop a test for measuring the bond shear strength between pavement layers. The research is also conducted to evaluate tack coat materials and application rate in porous pavement. The experiment includes using two types of emulsions (RSC-4, Modified Emulsion) and a asphalt binder type (HM-1). HM-1 was developed to be applied in porous pavement. The bond shear strengths were measured by a direct shear type device under various test conditions. The shear strength may not be appropriate in the evaluation of the bond shear strength, while the toughness of the test may be useful. In case of the tack coat application rate in porous pavement, RSC-4 has to be used a minimum amount of $0.8l/m^2$ and modified emulsion asphalt has to be applied a volume of use $0.5{\sim}0.6l/m^2$. HM-1, asphalt cement type, is far stronger bond shear strength than emulsified asphalt tack coat and had showed the excellent trackless property.