• Title/Summary/Keyword: 유해성분

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Co-incineration Characteristics of Sewage Sludge and Industrial Waste Using the Rotary Kiln Incinerator (로타리킬른 소각로를 이용한 하수슬러지와 사업장폐기물의 혼합소각 특성)

  • Yang, Dong-Jib;Ko, Jae-Cheol;Kim, Jeong-Keun;Park, Hui-Jae;Park, Joon-Seok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.3
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    • pp.91-99
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    • 2009
  • This research were performed to evaluate co-incineration characteristics of sewage sludge and industrial waste in rotary kiln incinerator, and provide the fundamental data. Plastic portion (42.55%) in this industrial waste showed over 3 times higher than that (11.92%) of paper. Korean proximate analysis of the waste mixed with sewage sludge and industrial waste (3 : 7, volumetric basis) showed 16.3% of moisture, 70.5% of volatile solids, and 13.2% of ash, respectively. Low heating value of the mixed waste was 4,513kcal/kg. So it was thought that the mixed waste of sewage sludge and industrial waste (containing 43% of plastics and 12% papers) has enough heating value for co-incineration. The incineration of mixed waste showed the lowest SOx and NOx concentrations at $700^{\circ}C$. However, the operation at $950^{\circ}C$ was feasible in considering dioxin and the other hazardous gases. It was concluded that use of $Ca(OH)_2$ should be under investigation for the operation at $950^{\circ}C$.

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A Study of Frangibility of 9MM Bullet Related to Material Composition and Sinter Condition (합금 조성 및 소결 조건에 따른 9MM 탄자의 파쇄성에 관한 연구)

  • Kim, Bo-Ram;Seo, Jung-Hwa;Jung, Hee-Chur;Kim, Kyu-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.5
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    • pp.615-622
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    • 2020
  • Frangible bullets, which are shredded after impact on a target, reduce the possibility of both ricochet and unexpected injury in shooting training and in mission acts in dams, nuclear power plants, and cultural properties. Reducing the levels of hazardous materials in shooting ranges, such as lead, has become an important agenda for the government and environmental groups. In this study, the shape of a frangible bullet was designed for efficient shredding, and the safety and reliability were confirmed by actual firing under different process conditions. In addition, the physical characteristics, such as compaction pressure, density, and frangibility of each process, were compared by analyzing the microstructure of the sintered frangible bullet. The experiment revealed the smallest fragmentation after impact on the target under the following conditions: Cu-Sn 85:15; sintering temperature, 600℃; sintering time, one hour. Further development of the process conditions and experimental methods will contribute to the performance and environmental improvement of a frangible bullet.

Development of Antifreeze Concentration Control device for Solar Heat Energy System (태양열에너지 시스템용 부동액 농도 제어 장치의 개발)

  • Seo, Choong-Kil;Won, Joung Wun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.1-7
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    • 2018
  • The gases emitted from internal combustion engines using fossil fuels are causing many social problems, such as environmental pollution, global warming, and adverse health effects on the human body. In recent years, the demand for renewable energy has increased, and government policy support and research and development are also active. In the collecting part of a solar energy system, which is widely used at home, propylene glycol (PG) (anti-freeze), as a heating medium, is mixed with water at a fixed value of 50%, and the heat is transferred to the collecting part at subzero temperatures. On the other hand, when leakage occurs in the heat medium in the heat collecting part, supplemental water is supplied to the solar heat collecting part due to the characteristics of the solar heat system, so that the concentration of antifreeze in the replenishing water becomes low. As a result, the temperature of the solar heat collecting part is lowered resulting in a frost wave, which causes economic damage. The purpose of this study was to develop a device capable of controlling the antifreeze concentration automatically in response to a temperature drop to prevent freezing of the heat collecting part generated in the solar energy system. The electrical conductivity of the H2O component was larger than that of PG, and the resistance increased with decreasing temperature. The PG concentration control values of 40, 50, and 60% should be controlled through calibration with a PG concentration of 39.6, 50.7, and 60.1%.

Effectiveness of an Environment-friendly Fumigator for Microorganisms that Can Cause Biological Damage to Records in Japan, Malaysia, and Oman (일본, 말레이시아, 오만의 기록물에서 분리한 유해미생물에 대한 친환경 기록물 소독장비 효과검증)

  • Kim, Min Ji;Lee, Eon Sook;Choi, Young Nam;Choi, Young Sin
    • Journal of Korean Society of Archives and Records Management
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    • v.15 no.2
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    • pp.165-179
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    • 2015
  • Archives have historical and academic values. That is why the study of preservation conditions and the environment for the effective management of various records progress. However, materials such as paper and adhesives will inevitably cause biological damages. These damages spread into the inner side of archives, which would make it impossible to recover. For example, archival records from Malaysia and Oman are easily exposed to biological damage because of these countries' hot and humid climate. As such, once records are damaged, disinfection operations are customary in these areas. Methyl bromide (MeBr) and ethylene oxide (EtO) were used in the disinfection process as they showed good insecticidal effect. However their antibacterial effect are negligible. As such, the need for an environmental-friendly fumigator was evident. An environmental-friendly fumigator is designed to improve storage stability. Such equipment is expected to contribute to prevention of damages to cultural heritages through its use of vaporization technology, maintenance of a disinfection space (chamber), and self-generation of nitrogen.

Treatment of Textile Wastewater by Membrane-Bioreactor Process (막-생물반응조 공정을 이용한 염색폐수의 처리)

  • 강민수;김성수;황규대;강종림
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.60-61
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    • 1996
  • 염색폐수를 처리하기 위하여, 일반적으로 물리.화학적 공정과 호기성 생물학적 공정을 조합한 방법들을 사용하고 있다. 하지만 호기성 생물학적 공정은 난분해성 물질의 제거능력이 낮고, 염색폐수의 주된 오염원인 염료분자가 호기성 미생물에 대한 에너지원으로 적합하지 않아 분해되기 어려우며, 물리.화학적 공정을 이용한 처리방법으로도 높은 처리효율을 얻을 수가 없다. 이러한 문제점을 극복하기 위하여 염색폐수 처리에 혐기-호기공정을 이용하며, 혐기성 공정에서 생물학적으로 분해되기 어려운 고분자 물질들을 가수분해하여 생물학적으로 분해가능한 저분자물질로 전환시키고, 호기성 공정에서 저분자 물질을 효과적으로 처라할 수 있기때문에 기존의 염색폐수 처리공정에 비하여 훨씬 높은 처리효율을 얻을 수 있다. 특히, 혐기성 미생물은 호기성 미생물에 비하여 난분해성 물질에 대한 분해력이 높고, 생물독성 물질에 대한 내성이 강하기 때문에 수중생물에 유해한 염료를 함유한 염색폐수의 색도제거에 효과적인 것으로 기대된다. 또한, 막분리 공정은 유기물 및 미생물이 막표면에 축적, 증식함으로써 막세공에 막힘현상을 초래하여 역세척 등의 물리적인 방법이나 화학약품을 이용한 화학적 세척 방법으로도 투과플럭스의 회복이 불가능한 상태를 유발함으로 막의 수명을 단축시키는 원인이 된다. 따라서, 혐기-호기공정과 조합하면 색도성분 제거 및 막 오염의 원인이 되는 유기물 및 용존성 고형물을 제거하고, 막 오염의 억제를 통한 후 수염의 연장은 물론, 처리수의 수질향상에 활용될 수 있을 것으로 사료된다.1로 강구와 함께 공구강 vial에 장입 후, Spex mixer/mill을 이용하여 기계적 합금화 하였다. 기계적 합금화 공정으로 제조한 분말에 대한 X-선 회절분석과 시차 열분석으로 합금화 정도를 분석하였다. (Bi1-xSbx)2Te3 및 Bi2(Te1-ySey)3 합금분말을 10-5 torr의 진공중에서 300℃∼550℃의 온도로 30분간 가압소결하였다. 가압소결체의 파단면에서의 미세구조를 주사전자현미경으로 관찰하였으며, 상온에서 가압소결체의 열전특성을 측정하였다. (Bi1-xSbx)2Te3의 기계적 합금화에 요구되는 공정시간은 Sb2Te3 함량에 따라 증가하여 x=0.5 조성에서는 4 시간 45분, x=0.75 조성에서는 5 시간, x=1 조성에서는 6 시간 45분의 vibro 밀링이 요구되었다. n형 Bi2(Te1-ySey)3 합금분말의 제조에 요구되는 밀링시간 역시 Bi2Se3 함량 증가에 따라 증가하였으며 Bi2(Te0.95Se0.05)3 합금분말의 제조에는 2시간, Bi2(Te0.9Se0.1)3 및 Bi2(Te0.85Se0.15)3 합금분말의 형성에는 3시간의 bivro 밀링이 요구되었다. 기계적 합금화로 제조한 p형 (Bi0.2Sb0.8)2Te3 및 n형 Bi2(Te0.9Se0.1)3 가압 소결체는 각기 2.9x10-3/K 및 2.1x10-3/K 의 우수한 성능지수를 나타내었다.ering)가 필수적이다. 그러나 침전법에서 얻게 되는 분말은 매우 미세하여 colloid를 형성하게 되며, 이러한 colloid 상태의 미세한 침전입자가 filte

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High-resolution Seismic Imaging of Shallow Geology Offshore of the Korean Peninsula: Offshore Uljin (신기 지구조운동의 해석을 위한 한반도 근해 천부지질의 고해상 탄성파 탐사: 울진 주변해역)

  • Kim, Han-Joon;Jou, Hyeong-Tae;Yoo, Hai-Soo;Kim, Kwang-Hee;You, Lee-Sun
    • Geophysics and Geophysical Exploration
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    • v.14 no.2
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    • pp.127-132
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    • 2011
  • We acquired and interpreted more than 650 km of high-resolution seismic reflection profiles in the Hupo Basin, offshore east coast of Korea at $37^{\circ}N$ in the East Sea (Japan Sea) to image shallow and basement deformation. The seismic profiles reveal that the main depocenter of the Hupo Basin in the study area is bounded by the large offset Hupo Fault on the east and an antithetic fault on the west; however, the antithetic fault is much smaller both in horizontal extension and in vertical displacement than the Hupo Fault. Sediment infill in the Hupo Basin consists of syn-rift (late Oligocene. early Miocene) and post-rift (middle Miocene.Holocene) units. The Hupo Fault and other faults newly defined in the Hupo Basin strike dominantly north and show a sense of normal displacement. Considering that the East Sea has been subjected to compression since the middle Miocene, we interpret that these normal faults were created during continental rifting in late Oligocene to early Miocene times. We suggest that the current ENE direction of maximum principal compressive stress observed in and around the Korean peninsula associated with the motion of the Amurian Plate induces the faults in the Hupo Basin to have reverse and right-lateral, strike-slip motion, when reactivated. A recent earthquake positioned on the Hupo Fault indicates that in the study area and possibly further in the eastern Korean margin, earthquakes would occur on the faults created during continental rifting in the Tertiary.

Synthesis of Electroactive PAAc/PVA/PEG Hydrogel Soft Actuator by Radiation Processing and Their Dynamic Characteristics (방사선을 이용한 전기 활성 PAAc/PVA/PEG 하이드로겔 소프트 액추에이터의 제조 및 구동 특성 분석)

  • Shin, Yerin;Kim, So Yeon
    • Applied Chemistry for Engineering
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    • v.30 no.6
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    • pp.698-706
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    • 2019
  • Over the last few decades, there have been a lot of efforts to develop soft actuators, which can be external stimuli-responsive and applied to the human body. In order to fabricate medical soft actuators with a dynamic precision control, the 3D crosslinked poly(acrylic acid) (PAAc)/poly(vinyl alcohol) (PVA)/poly(ethylene glycol) (PEG) hydrogels were synthesized in this study by using a radiation technique without noxious chemical additives or initiators. After irradiation, all hydrogels showed high gel fraction over 75% and the ATR-FTIR spectra indicated that PAAc/PVA/PEG hydrogels were successfully synthesized. In addition, the gel fraction, equilibrium water content, and compressive strength were measured to determine the change in physical properties of PAAc/PVA/PEG hydrogels according to the irradiation dose and content ratio of constituents. As the irradiation dose and amount of poly(ethylene glycol) diacrylate (PEGDA) increased, the PAAc/PVA/PEG hydrogels showed a high crosslinking density and mechanical strength. It was also confirmed that PAAc/PVA/PEG hydrogels responded to electrical stimulation even at a low voltage of 3 V. The bending behavior of hydrogels under an electric field can be controlled by changing the crosslinking density, ionic group content, applied voltage, and ionic strength of swelling solution.

Effect of Highly Pressurized Hydrogen Gas on Tensile Properties of a Low-Alloy Steel Used for Manufacturing CNG Storage Vessels (CNG 저장용기용 저합금강의 인장 특성에 미치는 고압 수소가스의 영향)

  • Lee, H.M.;Jeong, I.H.;Park, J.S.;Nahm, S.H.;Han, J.O.;Lee, Y.C.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.8
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    • pp.829-833
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    • 2012
  • SNG (synthetic natural gas or substitute natural gas) could contribute greatly toward energy security. In addition, HCNG (or $H_2CNG$) is expected to be used as a fuel gas for internal combustion engines and home appliances because it has extremely low emissions and high thermal efficiency. However, the hydrogen contained in SNG or HCNG can deteriorate the mechanical properties of the materials used in existing natural gas infrastructure. Therefore, it is necessary to investigate the effect of hydrogen on the mechanical properties of such materials so that SNG or HCNG can be transported and distributed safely and reliably. In this study, the effect of highly pressurized hydrogen gas on the tensile properties of a low-alloy steel used for manufacturing CNG storage vessels was investigated using the so-called hollow tensile specimen technique.

Fabrication of Electrospun PAN/FA Nanocomposites and Their Adsorption Effects for Reducing Volatile Organic Compounds (전기방사에 의한 PAN/FA 나노 복합재의 제조 및 휘발성 유기 화합물에 대한 흡착효과)

  • Ge, Jun Cong;Wang, Zi Jian;Yoon, Sam Ki;Choi, Nag Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.702-708
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    • 2018
  • Volatile organic compounds (VOCs), as a significant air pollutant, is generated mainly from the burning of fossil fuels, building materials using painting, etc. The inhalation of a certain amount of VOCs can be deleterious to human health, e.g., headaches, nausea and vomiting. In addition, it can also cause memory loss and even increase the rate of leukemia. Therefore, as one of the methods for reducing VOCs in air, polyacrylonitrile/fly ash (PAN/FA) composite nanofibrous membranes were fabricated by electrospinning. To observe their VOCs adsorption capacity, the morphological structure of PAN/FA nanofibrous mats was investigated by field emission scanning electron microscopy (FE-SEM), and the VOCs (chloroform, benzene, toluene, and xylene) adsorption capacity of PAN/FA membranes were tested by gas chromatography/mass spectrometry (GC/MS). The results indicated that the PAN nanofiber containing 40 wt. % FA powder had the smallest fiber diameter of 283 nm; they also showed the highest VOCs adsorption capacity compared to other composite membranes.

Current Status on the Pyrometallurgical Process for Recovering Precious and Valuable Metals from Waste Electrical and Electronic Equipment(WEEE) Scrap (폐전기전자기기(廢電氣電子機器) 스크랩으로부터 귀금속(貴金屬) 및 유가금속(有價金屬) 회수(回收)를 위한 건식공정(乾式工程) 기술(技術) 현황(現況))

  • Kim, Byung-Su;Lee, Jae-Chun;Jeong, Jin-Ki
    • Resources Recycling
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    • v.18 no.4
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    • pp.14-23
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    • 2009
  • In terms of resources recycling and resolving waste disposal problems, it is very important to recover precious metals like Au, Ag and Pd and valuable metals like Cu, Sn and Ni from the scraps of waste electrical and electronic equipment(WEEE) that consists of detective electrical and electronic parts discarded during manufacturing electrical and electronic equipments and waste electrical and electronic parts generated during disassembling them. In general, the scraps of WEEE are composed of various metals and alloys as well as refractory oxides and plastic components. Precious and valuable metals from the scraps of WEEE can be recovered by gas-phase-volatilization, hydrometallurgical, or pyrometallurgical processes. However, the gas-phase-volatilization and hydrometallurgical processes have been suggested but not yet commercialized. At the present time, most of the commercial plants for recovering precious and valuable metals from the scraps of WEEE adopt pyrometallurgical processes. Therefore, in this paper, the technical and environmental aspects on the important pyrometallurgical processes through literature survey are reviewed, and the scale-up result of a new pyrometallurgical process for recovering the precious and valuable metals contained in the scraps of WEEE using waste copper slag is presented.