• Title/Summary/Keyword: 유연소재

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유연소재 천 기반의 슈퍼캐패시터 저장체의 전기화학적 성능 향상

  • Yun, Tae-Gwang;O, Min-Seop;Hu, Liangbing;Hyeon, Seung-Min;Han, Seung-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.697-698
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    • 2013
  • 최근에 유연한 성질을 갖는 전자기기들의 수요가 증가하면서, 그에 따라서 유연 전자기기를 뒷받침 해줄 수 있는 에너지 저장체의 유연한 성질도 중요성이 점점 부각되고 있으며 많은 연구가 진행되고 있다. 유연한 에너지 저장체의 많은 연구들이 유연한 금속 박막이나 특수 공정처리가 필요한 고분자를 이용하고 있으나, 대부분의 유연 에너지 소자들은 에너지 저장체의 성능에 비해 고온과 산 약품과 같은 환경이 필요하며, 비용과 시간이 많이 소모되고 있다. 그에 반해 섬유는 앞에서와 같이 특수 공정 처리가 따로 필요하지 않으며 상온에서도 손 쉽게 이용 가능하며, 신축성이 뛰어난 장점이 있기 때문에 효율적, 비용적으로 유연한 에너지 저장체에 유리한 소재이다. 몸에 해로운 산과 같은 약품처리의 필요도 없으며, 용매를 흡수하는 능력이 뛰어나기 때문에 용매를 이용한 도포 방법을 사용하면 다양한 물질을 폭넓게 적용 가능하다. 그리고 적용 분야에 맞춰서 섬유의 종류를 조절하면 다양한 성질을 갖는 천 기반의 에너지 저장체가 형성되며, 면 섬유가 수소 결합과 높은 반데르 발스 결합에 의해 탄소나노튜브와 결합하여 높은 에너지 밀도를 갖는 에너지 저장체를 형성하는 것을 분석한 논문들도 보고되고 있다. 면 섬유의 특수한 성질을 이용하여 에너지 저장체를 제작하고 이를 확인하기 위해서 일반 합성 섬유인 polyester와 면 섬유를 비교 제작하였으며, 용매의 형태로 손쉽게 도포 가능한 물질은 탄소 계열의 활물질들이며, 탄소 나노 튜브나 그래핀 등이 분산된 용액을 이용해 천에 도포 가능하다. 탄소 계열의 활물질들은 대표적인 슈퍼캐패시터 물질이며, 천에 도포를 함으로써 천 기반의 슈퍼캐패시터를 제작하였다. 일반 합성 섬유 polyester와 CNT를 결합한 형태의 전극은 최대 에너지 축전 용량(Maximum specific capacitance)이 53.6 F/g으로 나타났으며, 면 섬유와 CNT를 결합한 형태의 전극은 최대 에너지 축전 용량이 122.1 F/g으로 나타났다. 따라서 면 섬유에서 높은 에너지 저장 능력을 보이는 것을 실험적으로 확인하였으며, 에너지 저장 능력이 뛰어난 면 섬유를 다음 전극 디자인에서도 일률적으로 적용하였다. 슈도캐패시터의 대표적 물질인 금속 산화물인 망간 산화물(MnO2)을 3전극 도금 시스템을 이용하여 에너지 축전 용량과 에너지 밀도를 올리는 전극을 제작하였다. 특히 망간 산화물의 형태는 표면적을 극대화하기 위해서 평균 지름은 200~300 nm 정도 되는 나노 입자의 형태로 제작하였다. 그 결과, 확연하게 에너지 축전 용량이 향상되었으며, 최대 에너지 축전 용량은 282.0 F/g, 에너지전력 밀도는 14.2 Wh/kg으로 나타나서 금속 산화물의 형태가 주는 효과를 확인할 수 있었다. 하지만 나노 입자의 형태로 제작된 금속 산화물은 문제점이 발생하였다. 금속 산화물의 전기 전도성이 매우 낮기 때문에, 전기 전도성에 비례해서 전력 밀도의 값이 표현되는데, 전기 전도성이 급격히 감소하기 때문에 전력 밀도도 급격한 감소가 나타난다. 다음과 같이 전기 전도성 물질을 첨가하는 방법은 추가의 공정이 필요한 단점이 있지만 오직 기계적인 인장응력만을 가해서 에너지 밀도와 전력 밀도를 증가시키는 전극을 제작하였다. 인장응력을 섬유 기반의 전극에 가했을 시에 가닥들간의 접촉 증가와 CNT가 정렬되면서 특정 변형률(strain) 이전에서는 전기 전도성이 최대 50% 이상 증가하는 것을 확인할 수 있었으며, 선행 연구에서 보고되었다. 이를 이용해서 전기 전도성과 직결되는 전력 밀도의 양도 증가시키고 에너지 밀도의 증가 여부까지 확인한 결과 인장을 가하기 전 면 섬유의 전력 밀도와 에너지 밀도는 6.4 kW/kg and 6.1 Wh/kg으로 나타났으나 30% 변형 인장 후에는11.4 kW/kg과 7.1 Wh/kg으로 나타났다. 그리고 망간 산화물을 첨가한 전극 역시 4.9 kW/kg과 14.2 Wh/kg으로 나타났었으나 인장 이후 전력 밀도는 14.2 kW/kg, 에너지 밀도는 17.6 Wh/kg으로 확연하게 증가한 것을 확인하였다.

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A Comparative Study on the Subjective Sensation and Tactile Preferences for Casual Shirt Fabrics Compared by the Nationality of Female University Students (여대생의 국적에 따른 캐주얼 셔츠 소재의 주관적 감각과 촉감 선호도 비교)

  • Meng, Yu;Choi, Jongmyoung
    • Science of Emotion and Sensibility
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    • v.24 no.1
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    • pp.105-114
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    • 2021
  • This study determines the differences between Korean female university students and their Chinese counterparts residing in Korea by evaluating the subjective sensation and tactile preference in fabrics for casual shirts. Seven types of white causal shirt fabrics were selected as specimens from those available in spring and autumn shirt collection. The fabrics were made from various fibers (cotton 100%, polyester 100%, flax 100%, polyester 80%/cotton 20%, polyester 65%/cotton 35%, polyester 50%/cotton 45%/spandex 5%, and polyester 50%/modal 50%). Forty Korean and Chinese female university students subjectively assessed the subjective sensation of fabrics used for casual shirts. Participants were asked to observe the seven types of fabrics and complete the questionnaire. The subjective sensation to be assessed for white casual shirt fabrics was classified into the following four factors: smoothness, lightness, softness, and stretchiness. Subjective sensation factors showed partially significant differences by nationality. Korean female students evaluated cotton fabric as being light, whereas their Chinese counterparts evaluated the polyester/cotton/spandex blended fabric as light. Korean female students evaluated polyester/modal blended fabric as being stretchable. The tactile preference for fiber composition of the fabrics showed partially significant differences by nationality. Korean female students preferred cotton 80%/polyester 20% blended fabric, polyester 50%/cotton 45%/spandex 5% blended fabric, and flax 100% fabric. The subjective sensation of the fabrics had different effects on preferences by nationality. Smoothness and softness had positive effects on preferences for the fabrics of Korean students. However, smoothness, softness, and stretchiness had positive effects on the preferences of Chinese students. The subjective sensation and tactile preference for casual shirt fabrics showed a difference between Korean female students and their Chinese counterparts. Therefore, when planning casual shirt fabrics for female university students, it is necessary to reflect on these differences in subjective sensation and tactile preference.

ZnO/PMMA 나노복합소재와 $C_{60}$ 층과 결합하여 제작한 유기 쌍 안정성 소자의 메모리 성능 향상

  • Yu, Chan-Ho;Jeong, Jae-Hun;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.82-82
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    • 2010
  • 유기 쌍안정성 소자는 비휘발성 기억 소자 중에서 구조가 간단하고 제작비용이 저렴하며 유연성을 가지기 때문에 많은 연구가 진행되고 있다. 현재 유기물/무기물 나노복합소재를 사용하여 소자 성능 향상이 기억소자의 성능 향상을 위하여 여러 가지 유기물/무기물 나노복합소재를 사용하여 제작한 유기 쌍안정성 소자가 유연성을 가진 비휘발성 기억소자로 대두되고 있다. 본 연구에서는 ZnO 나노입자를 포함한 PMMA 복합층을 사용하여 제작한 유기 쌍안정성 기억소자를 제작하여 메모리 특성을 조사하였다. 이와 더불어 활성층에 효과적인 전하주입을 위하여 전극과 PMMA/ZnO 층 사이에 $C_{60}$ 층을 삽입한 구조를 가진 메모리 소자의 성능 향상에 대하여 연구하였다. Indium tin oxide 가 증착된 유리 기판위에 $C_{60}$ 층을 스핀코팅 방법으로 적층하였다. 1 wt% ZnO 나노입자와 1 wt% PMMA를 혼합하여 스핀코팅 방법으로 $C_{60}$ 층 위에 박막을 형성하였다. 그리고, 전극으로 Al을 열증착으로 형성하였다. $C_{60}$ 층이 있는 유기 쌍안정성 기억 소자와 $C_{60}$ 층이 없는 두 가지의 소자에 대하여 전류-전압 (I-V) 특성을 측정하여 각각의 소자에서의 전류 히스테리시스 현상이 발생하는 원인을 규명하였다. I-V 특성 결과와 전자적 구조를 사용하여 유기 쌍안정성 소자에서의 쓰기, 지우기 및 읽기 동작에 대한 과정을 설명하였다. 두 소자의 I-V 특성을 비교하므로 $C_{60}$ 층을 사용하여 유기 쌍안정성 소자의 성능이 향상됨을 알 수 있었다. 또한 $C_{60}$ 층을 사용하여 제작된 유기 쌍안정성 소자의 성능이 향상된 원인을 규명하였다.

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Dimensional Stability of Poly(ethylene/propylene naphthalate) as a Flexible Substrate Application (유연 기판 소재로 응용을 위한 폴리(에틸렌/프로필렌 나프탈레이트)의 치수안정성 연구)

  • Kim, Jae-Hyun;Heo, Hye-Young;Jung, Tae-Houng;Han, Joon-Hee;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.371-376
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    • 2009
  • The 1,3-propane diol has been introduced as a co-monomer with ethylene glycol to polymerize the poly(ethylene/propylene naphthalate) in order to improve the dimensional stability of poly(ethylene naphthalate) for a possible flexible substrate material. Based on $^1H$-NMR results, it was found that poly (ethylene/propylene naphthalate) has been synthesised successfully. Introducing 1,3-propane diol resulted in the amorphous state in polyester as well as lowering of glass transition and thermal degradation temperature. Coexisting relatively longer propylene segment compared with ethylene in synthesized polyester caused less orientation behavior and reducing thermal expansion coefficient. This is a promising result for poly (ethylene/propylene naphthalate) to apply a flexible substrate.

A Basic Study on the Design of the Flexible Keel in the Energy-Storage Prosthetic Foot for the Improvement of the Walking Performance of the Below Knee Amputees (하지 절단환자의 보행 능력 향상을 위한 에너지 저장형 의족의 유연 용골 설계를 위한 기초연구)

  • 장태성;이정주;윤용산;임정옥
    • Journal of Biomedical Engineering Research
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    • v.19 no.5
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    • pp.519-530
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    • 1998
  • In this paper, the basic study on the design of the flexible keel of the energy-storage prosthetic foot was performed in order to Improve the walking performance and Increase the activities of the below knee amputees. Based on the analysis of the anthropometric data and the normal gait on two dimensional sagittal plane available In the literature, we presented a model of the basic structure of the flexible keel of the prosthetic foot. The model of the basic structure was composed of the simple beams, and linear rotational spring and damper. Laminated carbon fiber-reinforced composites were selected as the material of the basic structure model of the flexible keel In order to apply the high strength and light weight materials to the basic structure of the flexible keel of the prosthetic foot. The recoverable strain energy In response to the change of beam shape was calculated bur the finite element analysis and it was suggested that the change of beam shape could be the design variable in flexible keel design. The simulation process was systematically designed by using orthogonal array table in order to design the flexible keel structure which could store the more recoverable strain energy. finite element analysis was carried but according to the design of simulations by using the finite element program ABAQUS and the flexible keel structure of the energy-storage prosthetic foot was obtained from the analysis of variance(ANOVA). The dynamic simulation model of the prosthetic walking using the flexible keel structure was made and the dynamic analysis was carried but during one walk cycle. Based on the above results, an effective design process was presented for the development of the prosthetic fool system.

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Stress Analysis of Tractor Front-End Loader against Impact Load Using Flexible Multi-Body Dynamic Simulation (유연 다물체 동역학 해석을 이용한 충격 하중에 따른 트랙터 프론트 로더의 응력 분석)

  • Shin, Chang-Seop;Kim, Beom-Soo;Han, Hyun-Woo;Chung, Woo-Jin;Cho, Seung-Je;Park, Young-Jun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.3
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    • pp.26-32
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    • 2019
  • This study was conducted to analyze the stresses by impact loads on front-end loaders attached to tractors using flexible multi-body dynamics. The model was designed and validated by comparing previous experimental data with the simulation data obtained in this study. Nine sets of conditions were designed using three weights (500, 300, and 100 kg) loaded inside a bucket and three heights (1700, 1350, and 1000 mm) of the bucket from ground level. A parametric study was carried out at five locations for two types of parts of a front-end loader. All the safety factors for the five locations under all conditions were calculated and were greater than 1. Thus, the designs of the front-end loaders were structurally safe. Based on this study, front-end loaders attached to tractors can be designed effectively in terms of cost and safety.

Silica Aerogel Blanket Processing Technologies for Use as a Widespread Thermal Insulation Material (범용 단열재로 활용하기 위한 실리카 에어로젤 블랭킷의 처리 기술)

  • Jae-Wook Choi;Young Su Cho;Dong Jin Suh
    • Clean Technology
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    • v.29 no.4
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    • pp.237-243
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    • 2023
  • Aerogel is the most excellent insulation material known to date, but it is inflexible and has very low strength. A blanket containing aerogel in a nonwoven fabric or fiber is currently the most practical form. However, aerogel blankets are not yet widely used because they cannot avoid dust generation when handled, lack flexibility, and can possibly deform. In this study, vacuum treatment, surface treatment, and composite materialization technology were applied to solve this problem, and some prototypes were also made. If an aerogel blanket is wrapped in an aluminum sheet, sealed at the four ends, and vacuumed, it can become a material with better insulation than the blanket itself. An aerogel molded body can be made by coating the aerogel blanket with resin and treating the surface. If the aerogel blanket is multi-packed and laminated with resin or fiber in multiple layers to make it a composite material, it can be used as a flexible insulation material. In particular, this composite material, which utilizes a Teflon membrane with controlled pores, is breathable and waterproof, so it can be used for clothing. Prototypes of insoles for winter boots and outdoor roll mats were also produced using aerogel blanket resin and fiber composites. These prototypes showed low thermal conductivity of less than 20 mW m-1K-1, with good flexibility and durability.

Analysis on the development trend of flexible materials and platforms for wearable devices based on fiber - Based on domestic & international patent data - (섬유기반의 웨어러블 디바이스용 유연소재 및 플랫폼 개발동향 분석 -국내외 특허분석을 중심으로-)

  • Han, Hyunjung;Jang, Myoungjin;Lee, Yongsung
    • Journal of the Korea Fashion and Costume Design Association
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    • v.22 no.1
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    • pp.33-44
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    • 2020
  • The purpose of this study is to guide the research direction for securing the competitiveness of the textile industry by analyzing the trends of patent technology development for flexible materials and platform technologies of domestic and overseas textiles used for wearable devices. The study is based on patents from Korea (KIPO), USA (USPTO), Japan (JPO), Europe (EPO), PCT (WO), and China (SIPO), which were registered as of December 31, 2017. The analysis utilized 3,643 patents acquired from the WINTELIPS search DB. The technology classification system for patent analysis was divided into evangelist-based textile technology developments: human body (AA), fiber attachment patch development (AB), and service platform development (AC). The analysis findings are as follows: 1. The development of flexible materials and platform technologies for textile-based wearable devices has increased since 2000. In particular, China (SIPO) had the most patents. 2. In China, Japan, and Korea, most patent applicants are applied for by natives, but the US has a high proportion of foreigners applying for patents. 3. As for the amount of development of the evangelist-based textile technology (AA) was the most common with 1,203 (33%) cases. As a result of the above IP historical analysis, it can be seen that as a result of the global competition, domestic companies need to acquire IRP and standard technology, and promote commercialization by applying their products to smart wearables devices and other products.

Development of harmful ultraviolet blocking transparent flexible device using TiO2-x thin film process (TiO2-x 산화물 박막공정을 이용한 유해자외선차단 투명유연소재개발)

  • Kim, Geug Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.3
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    • pp.123-131
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    • 2019
  • In this study, the development of transparent UV blocking material using $TiO_{2-x}$ oxide thin film process was developed. A process technology is related to a process technology for making a sample with ultraviolet-shielding property of visible light transmittance of 78 % or more (total light transmittance at 550 nm) and of a UV cut-off characteristic of more than 95 % at 315 nm in ultraviolet wavelength band. In this study, it is possible to establish a flexible device process condition of high performance ultraviolet (UV) shielding thin film, to design mixed type of transparent flexible device with heterogeneous characteristics and to formulate composite deposition technology, according to various market demands. Establishment of actual roll-to-roll continuous process and equipment and process technology will affect related industries greatly.