• Title/Summary/Keyword: 유리 전이

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MAS-NMR Studies in Mixed Alkali Silicate Glasses with low Fe2O3 Content (미소량의 Fe2O3를 첨가시킨 혼합 알칼리 Silicate 유리들의 MAS-NMR 연구)

  • Kang, Myoung-Jin;Shim, Moon-Sik
    • Journal of Korean Ophthalmic Optics Society
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    • v.1 no.1
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    • pp.1-14
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    • 1996
  • The mixed alkali silicate glasses doped 0.1 mol% $Fe_2O_3$ are fabricated for studying the effect of transition metal oxides, which is related to the $Li^-$ ion movement in Magic-Angle-Spinning NMR. We have investigated the spin-lattice relaxation times in the room temperature and measured the $^7Li$ MAS-NMR spectrum with temperature. When the $Fe_2O_3$ oxides are added in alkali silicate glasses, the width of spectrum is changed a little but the line shape is hardly varied. For this reason, we can think that the mixed alkali effects are shown sufficiently in the spin-spin relaxation processes. However, it is not mixed alkali effects in this case. The activation energy of $Li^-$ ions are diminished in mixed alkali glasses. From the analysis of $Li^-$ diffusion environment, spin-lattice relaxation time and the nuclear magnetization, it is confirmed that the alkali mixed effects are not shown in $^7Li$ spin-lattice relaxation processes.

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Study on the solution for the overflow of molten solder during the soldering of fuse cap through CFD analysis (전산유체해석을 통한 퓨즈캡 솔더링 시의 용융솔더 넘침 문제 해결방안 연구)

  • Jeong, Nam-Gyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.31-36
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    • 2018
  • Fuses are used to protect electric circuits or devices from excess current. Glass-tube fuses are typically used, but problems have arisen due to the mandated switch from conventional solder to lead-free solder. This study used CFD to simulate the phenomenon of molten solder being poured out of a fuse during the soldering process for a fuse cap and fuse element. In addition, a method is proposed to prevent solder from overflowing, and its effectiveness was verified based on the analysis results. The results show that a sufficient increase of the temperature inside the glass tube before soldering and gravity can help to prevent the solder from overflowing.

A study of transmittance and color change of various photochromic lenses by an UVA lamp (UVA광원에 의한 Photochromic lens의 색비율 제어에 관한 연구)

  • Lim, Yong-Moo;Jung, Ju Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.2
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    • pp.185-191
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    • 2003
  • In this study, We measured transmittance and color change of various photochromic lens as a function of temperature(6, 12, $28^{\circ}C$), irradiation time of UVA lamp and the types of materials(plastic and glass) and distribution of photochromic ingredients(coated and bulk type). The coated-type photochromic lens showed higher saturated value than bulk-type lens without regard to temperature. And darkening rate of smoke color lenses were higher compare to brown lens in case of glass photochromic lens. All of photochromic lens passed ANSI Z80.3 regulation in transmittance and color independent of temperature. The saturated values of plastic photochromic lens excluded coated-type and glass photochromic lens were ranked as cosmetic use. The saturated value of coated-type. Tbr and TMs were general applications in $6^{\circ}C$ and $12^{\circ}C$, but cosmetic purpose in $28^{\circ}C$. The darkening rate was increased with decreasing temperature, whereas the fading rate became higher with increasing temperature.

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Cell Immobilization of Zyrnornonas rnobilis by Entrapment (포괄담체에 의한 Zymomonas mobilis 균체의 고정화)

  • 한면수;정동효
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.459-469
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    • 1992
  • The immobilization characteristics of Zymomonas mobilis for ethanol production were examined. Four different strains of Zymomonas mobilis have been used for ethanol production. Among those, Zymomonas mobilis KCTC 1534 has been selected as the best strain for the highest ethanol productivity from glucose and sucrose. The optimum temperature and pH of the selected strain for ethanol production were $37^{\circ}C$ and 5.0 respectively for both free and immobilized cells. When the cells were immobilized by the gel entrapment method, the immobilized cells could produce ethanol at a little higher temperature than free cells. Calcium alginate was selected as the best gel for immobilizing cells. The immobilized cells could maintain the viability of 80% in 10 weeks storage at $4^{\circ}C$ in the medium with 2% calcium chloride. 20-25 hours of preincubation in 10% glucose solution was required for the activation of immobilized cells entrapped within calcium alginate gel.

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The design of the optical film for absorbent ARAS coating (흡수층을 이용한 무반사, 무정전용 광학박막의 설계)

  • Park, M.C.;Son, Y.B.;Jung, B.Y.;Lee, I.S.;Hwangbo, C.K.
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.1
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    • pp.7-11
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    • 2000
  • The anti-reflective anti-static (ARAS) optical film is designed using absorbent materials such as ITO, $TiN_xW_y$, Ag by Essential Macleod program. [air ${\mid}TiN_xW_y{\mid}SiO_2{\mid}$ glass] two layer shows wide-band AR coating in the wavelength range of 450~700 nm. The reflectivity, transmittance of this coating are below 0.5%, about 75%, respectively. [air $SiO_2{\mid}TiO_2{\mid}SiO_2{\mid}$, ITO glass] layer can adjust reflectance of below 0.5% with above 97% transmittance. In the [air ${\mid}SiO_2{\mid}TiO_2{\mid}SiO_2{\mid}$ Ag glass] layer, the transmission can be controlled at above 96% with reflectance of 1~2%.

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Reinforced Performance Evaluation of RC Slab Bridge Using Conclinic Advanced FiberWrep (유리섬유 복합재를 이용한 RC슬래브 교량의 보강성능평가)

  • Park, Soon-Eung;Park, Moon-Ho;Lee, Tack-Woo
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.5
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    • pp.35-40
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    • 2010
  • The present study proposes the strengthening method to use Conclinic Advanced FiberWrep(CAF) so as to improve Load Carrying Capacity of the RC slab bridge. In order to evaluate the strengthening performance, we strengthen 50cm per unit-width of CAF to the slab's bottom of the test bridge that designed with DB 18, then perform Static and Dynamic Field Load Test. As a result of this, 14.7% of the maximum displacement, 5.0% of the strain and 33.7% of the impact factor are reduced after strengthening. At the middle of the test spans, nominal resisting ratio is increased by 27% and Service Load Carrying Capacity is increased by 44.6%, 48.9% of each span 1 and 2. In conclusion, this study indicates that the strengthening method using CAF is very effective to improve the deteriorated RC slab bridge designed with DB 18, to the DB 24 of the first class bridge design load.

Microstructural analysis of coal bottom ash-${Na_2}O-{Li_2O}$ system glass-ceramics (석탄 바닥재-${Na_2}O-{Li_2O}$계 결정화 유리의 미세구조 분석)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.25-32
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    • 2009
  • The glass-ceramics composed of coal bottom ash produced from a thermal power plant, $Na_{2}O$ and $Li_{2}O$ as a flux agent and $TiO_2$ as a nucleation agent were fabricated and its microstructures were analyzed. The nepheline was a major crystal phase in the glass-ceramics fabricated and its amount increased with $TiO_2$ addition. The glass-ceramics without $TiO_2$ addition had the thick surface crystals induced by a surface-crystallization mechanism and no crystal in the interior matrix. The surface crystallization, however, was restrained and the interior matrix was completely crystallized showing dendrite shape spread with fine particles < $1{\mu}m$ when added with $TiO_2$ above 4 wt%. For the glass-ceramics containing 6 wt% $TiO_2$, the $5{\mu}m$-long dendrite crystal; were interlocked each other which could suppress the crack propagation effectively at the external loading applied.

Global Status of Korea's Media Firms and Their Future Strategies (한국 미디어 기업의 글로벌 위상과 미래 전략)

  • Kim, Dae-Ho
    • The Journal of the Korea Contents Association
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    • v.11 no.9
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    • pp.174-186
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    • 2011
  • This research addresses global status of Korean media firms and their future directions. Mapping of major international media firms all over the world is used in order to explain global status fully. In the four categories that classified media firms using Forbes Global 2000 mapping, all Korean media firms are included in the fourth group, which is the weakest in terms of global competitiveness. Therefore, it is essential to trace appropriate global strategy from the media industry value chain that has competence. This paper finds out that Korea has advantage in the contents, terminal, and next generation networks. That means alliance strategies of contents-terminal-next generation network have advantage to evolve into global media firms. Moreover, Korean media companies should adopt selection and concentration strategy in terms of geographical expansion. As Korea's broadcasting and game contents are already popular in Asian and Latin American regions, they would better to enter the emerging markets. In so doing, terrestrial broadcasters and game service providers should lead the way.

Study of Failure Mechanisms of Wafer Level Vacuum Packaging for MEMG Gyroscope Sensor (웨이퍼 레벨 진공 패키징된 MEMS 자이로스코프 센서의 파괴 인자에 관한 연구)

  • 좌성훈;김운배;최민석;김종석;송기무
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.3
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    • pp.57-65
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    • 2003
  • In this study, we carry out reliability tests and investigate the failure mechanisms of the anodically bonded wafer level vacuum packaging (WLVP) MEMS gyroscope sensor. There are three failure mechanisms of WLVP: leakage, permeation and out-gassing. The leakage is caused by small dimension of the leak channel through the bonding interface and internal defects. The larger bonding width and the use of single crystalline silicon can reduce the leak rate. Silicon and glass wafer itself generates a large amount of outgassing including $H_2O$, $C_3H_5$, $CO_2$, and organic gases. Epi-poly wafer generates 10 times larger amount of outgassing than SOI wafer. The sandblasting process in the glass increases outgassing substantially. Outgassing can be minimized by pre-baking of the wafer in the vacuum oven before bonding process. An optimum pre-baking temperature of the wafers would be between $400^{\circ}C$ and $500^{\circ}C$.

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The composition control of ITO/PET by Plasma Emission Monitors (PEM을 이용한 ITO/PET film 조성 제어)

  • 한세진;김용한;김영환;이택동
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.213-213
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    • 1999
  • 현재 LCD용 기판재료는 ITO/glass를 전극으로 사용하고 있다. 그러나 유리기판은 무겁고 깨지기 쉽기 때문에 사용상 곤란한 점이 많다. 최근 flexible하고 가공성 및 생산성이 우수한 플라스틱한 ITO를 성막하여 EL용, Touch panel, plastic LCD용 사용하려는 시도로, roll-to-roll 연속 스퍼터링에 의한 ITO성막공정에 대한 연구가 최근 활발하게 이루어지고 있다. 폴리머는 유리에 비해 Tg 온도가 낮고, 기판으로부터의 수분 및 여러 종류의 가스방출이 심하기 때문에 유리와는 달리 ITO막의 제조에 있어 큰 차이점이 있다. 따라서, 폴리머에 반응성 스퍼터링을 하기 위해서는 표면처리가 중요한 변수가 되며, roll to roll sputter로 ITO 필름을 얻기 위해서는 폭과 길이 방향으로 균일한 막을 얻는 것이 중요하다. 두께 75$\mu\textrm{m}$, 폭 190mm, 길이 400m로 권취된 광학용 Polyethylene terephthalate(PET:Tg:8$0^{\circ}C$)위에 In-10%Sn의 합금타겟과 Unipolar pulsed DC power supply를 사용하여 반응성 마그네트론 스퍼터링 방법으로 0.2m/min의 속도로 연속 스퍼터링 하였다. PET를 Ar/O2 혼합가스로 플라즈마 전처리를 한 후, AFM, XPS를 이용하여 효과를 분석을 하였고, 성막전에 가스방출을 막기 위해 TiO를 코팅하였다. Pilot 연속 생산공정에서 재현성을 위해 PEM(Plasma Emission Monitor)의 optical emission spectroscopy를 이용, 금속과 산화물의 천이구역에서 sprtter된 I/Sn 이온과 산소 이온의 반응에 의한 최적의 플라즈마의 강도값을 입력하여 플라즈마의 radiation을 검출하고, 스퍼터링 공정중 실질적인 in-situ 정보로 이용하였다. PEM을 통하여 In/Sn의 플라즈마 강도변화를 조사하였다. 초기 In/Sn의 플라즈마 강도(intensity)는 강도를 100하여, 산소를 주입한 결과, plasma intensity가 35 줄어들었고, 이때 우수한 ITO 박막을 얻을 수 있었다. Pulsed DC power를 사용하여 아크 현상을 방지하였다. PET 상에 coating 된 ITO 박막의 표면저항과 광투과도는 4-point prove와 spectrophotometer를 이용하여 분석하였고, AES로 박막의 두께에 따른 성분비를 확인하였다. ITO 박막의 광투과도는 산소의 유량과 sputter 된 In/Sn ion의 plasma emission peak에 따라 72%-92%까지 변화하였으며, 저항은 37$\Omega$/$\square$ 이상을 나타내었다. 박막의 Sn/In atomic ratio는 0.12, O/In의 비율은 In2O3의 화학양론적 비율인 1.5보다 작은 1.3을 나타내었다.

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