• Title/Summary/Keyword: 유리 전이

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키토산 및 칼슘 처리와 저장고 형태에 따른 청견의 저장 중 품질변화

  • 김성학;고정삼
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.04a
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    • pp.134.1-134
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    • 2003
  • 저장 전 키토산과 칼슘 처리와 저장고 형태에 따른 온주밀감의 저장 중 품질특성을 검토하였다. 항균제로서 베프란(iminoctadime-triacetate) 2,000배 희석액, 키토산 1.5%에 0.5% CaCl$_2$를 혼합한 용액에 감귤을 충분히 침지하였다. 풍건시킨 후 26L인 플라스틱 컨테이너에 감귤을 12kg 정도씩 담아 3$0^{\circ}C$에서 24시간동안 저장전 처리를 하고, 상온저장과 내부온도 4$^{\circ}C$, 상대습도 87%를 기준으로 저장하였다. 저장고내의 온습도 편차가 적은 저장고에서 낮은 부패율이 나타내어, 감귤저장 중 온도관리가 중요함을 알 수 있었다. 중량감소, 껍질과 과육의 수분 함량은 저장 중 서서히 감소하였으며, 저온저장에서 감소 폭이 적었다. 산 함량의 감소는 저장 4개월 동안 15-18%이었다. 비타민 C는 저장 중 감소가 많아 장기간 저장으로 감귤품질이 떨어짐을 알 수 있었다. 유리아미노산은 23종이 검출되었다. isoleucine, leucine은 저장감귤에서 검출이 되지 않았으며, 이와 반대로 alanine은 90일간 저장한 감귤에서만 검출되었다. 품질유지가 위한 청견의 저장은 3개월까지로 판단된다.

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Towards a Indexing Structure for Querying Product Information in Relational Databases (관계형 데이터베이스 상품 정보 질의 처리를 위한 인덱싱)

  • Lee, Hyu-Nja;Shim, Jun-Ho
    • The Journal of Society for e-Business Studies
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    • v.13 no.4
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    • pp.209-222
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    • 2008
  • The product information can be practically stored and managed, and also queried when we use a relational database. We need to develop a special indexing scheme in order to process the queries to ask for the semantic relationships of the product information. Such semantic relationships include ISA or taxonomy relationships that have the transitive properties. In this paper, we propose an index scheme to effectively process those queries with the transitive property. The proposed index scheme is based on a numbering scheme that has relatively low update cost.

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A Visual on Study on Nucleate Boiling Phenomena in a Closed Two-Phase Thermosyphon (밀폐형 2상 열사이폰내의 비등현상에 관한 가시화 연구)

  • 김철주;강환국;오광헌
    • Journal of Energy Engineering
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    • v.4 no.2
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    • pp.261-269
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    • 1995
  • 본 연구에서는 밀폐형 2상 열사이폰의 액체 Pool에서 발생하는 핵비등현상과 유동영역에 대해 가시화 방법으로 연구하였다. 실험용 열사이폰은 스텐레스와 유리관을 이용하여 제작하였으며, 열공급은 증발부 주위에 설치된 유도 가열용 코일에 고주파를 가함으로써 스텐레스 외면에 발열이 일어나도록 하였다. 이에 따른 결과는 다음과 같다. 실험용 열사이폰은 고주파 가열등 열사이폰의 작동성능을 저해하는 여러 요인들이 포함되어 있었으나, 실험결과 이러한 문제는 실험 내용에 영향을 미칠만큼 크게 나타나지 않았다. 열속과 상당압력의 범위는 각각2$m^2$, 0.1

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A Study on the Physical Property of Epoxy Resin Due to After-Curing Condition (후경화 조건에 따른 에폭시 수지의 물성에 관한 연구)

  • Han, Jeong-Young;Kim, Myung-Hun;Kang, Sung-Soo
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.6
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    • pp.976-981
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    • 2012
  • In this study, hardness, microstructure and temperature of glass transition are measured respectively by using SEM (Scanning electron microscope) and DSC (Differential scanning calorimeter) to analyze the effects on material properties by after-curing in the epoxy resin. As the result of hardness test according to the after-curing conditions, the higher the temperature of after-curing, hardness and heat resistance are, the higher hardness is. As a result of microstructure for each specimen by SEM, it could be confirmed that the specimen with after-curing has more dense fracture surface. It is also found that temperatures of glass transitions by DSC are comparatively higher in the specimens with after-curing, and the differences between after-curing conditions are negligible.

Effect of Fe and BO3 Substitution in Li1+xFexTi2-x(PO4)3-y(BO3)y Glass Electrolytes (Li1+xFexTi2-x(PO4)3-y(BO3)y 계 유리 전해질에서 Fe 및 BO3 치환 효과)

  • Choi, Byung-Hyun;Jun, Hyung Tak;Yi, Eun Jeong;Hwang, Haejin
    • Journal of the Korean Electrochemical Society
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    • v.24 no.3
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    • pp.52-64
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    • 2021
  • The effect of Fe and BO3 doping on structure, thermal, and electrical properties of Li1+xFexTi2-x(PO4)3-y(BO3)y (x = 0.2, 0.5)-based glass and glass ceramics was investigated. In addition, their crystallization behavior during sintering and ionic conductivity were also investigated in terms of sintering temperature. FT-IR and XPS results indicated that Fe2+ and Fe3+ ions in Li1+xFexTi2-x(PO4)3-y(BO3)y glass worked as a network modifier (FeO6 octahedra) and also as a network former (FeO4 tetrahedra). In the case of the glass with low substitution of BO3, boron formed (PB)O4 network structure, while boron preferred BO3 triangles or B3O3 boroxol rings with increasing the BO3 content owing to boic oxide anomaly, which can result in an increased non-bridging oxygen. The glass transition temperature (GTT) and crystallization temperature (CT) was lowered as the BO3 substitution was increased, while Fe2+ lowered the GTT and raised the CT. The ionic conductivity of Li1+xFexTi2-x(PO4)3-y(BO3)y glass ceramics were 8.85×10-4 and 1.38×10-4S/cm for x = 0.2 and 0.5, respectively. The oxidation state of doped Fe and boric oxide anomaly were due to the enhanced lithium ion conductivity of glass ceramics.

A Study on the Recovery of Lithium from Secondary Resources of Ceramic Glass Containing Li-Al-Si by Ca-based Salt Roasting and Water Leaching Process (Li-Al-Si 함유 유리세라믹 순환자원으로부터 Ca계열 염배소법 및 이에 따른 수침출 공정에 의한 리튬의 회수 연구)

  • Sung-Ho Joo;Dong Ju Shin;Dongseok Lee;Shun Myung Shin
    • Resources Recycling
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    • v.32 no.1
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    • pp.42-49
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    • 2023
  • The glass ceramic secondary resource containing Li-Al-Si is used in inductor, fireproof glass, and transparent cookware and accounts for 14% of the total consumption of Li, which is the second most widely used after Li-ion batteries. Therefore, new Li resources should be explored when the demand for Li is exploding, and extensive research on Li recovery is needed. Herein, we recovered Li from fireproof Li-Al-Si glass ceramic, which is a new secondary resource containing Li. The fireproof glass among all Li-Al-Si glass ceramics was used as raw material that contained 1.5% Li, 9.4% Al, and 28.9% Si. The process for recovering Li from the fireproof glass was divided into two parts: (1) calcium salt roasting and (2) water leaching. In calcium salt roasting, a sample of fireproof glass was crushed and ground below 325 mesh. The leaching efficiency was compared based on the presence or absence of heat treatment of the fireproof glass. Moreover, the leaching rates based on the input ratios of calcium salt, Li-Al-Si glass, and ceramics and the leaching process based on calcium salt roasting temperatures were compared. In water leaching, the leaching and recovery rates of Li based on different temperatures, times, solid-liquid ratios, and number of continuous leaching stages were compared. The results revealed that fireproof glass ceramics containing Li-Al-Si should be heat treated to change phase to beta-type spodumene. CaCO3 salt should be added at a ratio of 6:1 with glass ceramics containing Li-Al-Si, and then leached 4 times or more to achieve a recovery efficiency of Li over 98% from a solution containing 200 mg/L of Li.

A Study on Dry and Wet Wipe Test for Radioisotope Leakage Checking (방사성동위원소 누설 점검을 위한 건식 및 습식 문지름 시험법 연구)

  • Park, SangMin;Yoo, SeungHee;Choi, KyuSeok;Lee, HwaHyung;Hong, Sayong
    • Journal of the Korean Society of Radiology
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    • v.12 no.3
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    • pp.305-312
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    • 2018
  • A dry and wet wipe test for radioisotope leakage checking was conducted by fixing the radioisotope $^{14}C$ to the glass surface and used for observing the transfer factor and surface shape of the test paper through wipe test. The dry wipe test showed that transfer factor in the tissue paper was twice as high as in the paper filter, and the wet wipe test showed that transfer factor in the paper filter paper was three times higher than the tissue paper. Although paper filters are general choice for leakage checking, it has been shown that tissue paper can be an alternative in the dry wipe test.

전처리공정이 천연유기물질의 움집에 미치는 영향

  • 이주영;이석모
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1997.10a
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    • pp.67-67
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    • 1997
  • 정수공정은 "원수 -1 침사지 1 전염소 -1 전오존 -1 침전지 1 여과지 1 후오존 1 GAC 4 후염소 1 가정수"로 이루어져 있으며 전처리 공정으로 염 소와 오존을 주입하게 되는데, 여기서 전염소 처리 공정으로 인해 잔류 유리염 소가 수중의 유기물질과 반웅하여 유해성 유기염소 화합물 (i.e.. Trihalomethane, Haloacetonitriles, Chlorophenol 등)을 생성하는 것으로 알려져 있다. 이러한 이유로 고도 정수처리 공정에서는 강한 산화력을 지닌 대체 산화 제로서 오존을 이용하고 있다. 전오존 처리공정은 OOC와 탁도 제거에 있어 응 집제 주입량을 감소시키는 것과 더불어 전오존 효과 (산화, 생분해 증대, 살균 등)를 얻을 수 있는 것으로 알려져 왔다. 그러나 낙동강과 같이 유기물이 많은 원수에 과다한 오존이 주입되면 수중 의 유기물이 저분자화 또는 응집이 어려운 오존 산화물로 변화하여 응집제의 소비가 많아지게 된다. 실제, 오존을 응집 효과에 대해서 pilot plant로 운전한 결과 전오존에 의해 입자성 물질의 제거 효율은 향상된 반면에 유기물 제거는 뚜렷한 효과를 볼 수 없었다고 보고되었다 (류, 1997). 본 연구에서는 물금 지역의 원수와 응집-침전 공정까지 거치는 각각의 처 리수에 대해서 전처리가 응집에 미치는 영향을 천연유기물질 (NOM)의 조성 변화로 파악하였다. 그 방법으로 천연유기물질 (NOM)을 XAD-1, -4 수지를 이 용하여 소수성 물질 (hydrophobic components)과 친수성 물질 (hydrophilic components)로 분리 및 농축하여 용존 유기물이 처리 과정에서 어떻게 변화하 는지를 조사하여 개선된 상수 처리 시스템을 설계하는데 기초 자료를 제공하고 수질 관리 분야에서도 적용하고자 하였다. 상수원수인 물금 지역의 소수성 물질(hydrophobic components)은 75~80%, 친수성 물질(hydrophilic components)은 30~33%정도의 분포를 보였고, 전염소 및 전오존 공정을 거친 처리수에서는 각각 62.2-62.8%, 43.9~49.0% 및 50~ 55%, 40~57% 정도의 분포를 보였다. 그리고 웅집-침전을 거친 처리수에서는 그 분포가 77~82%, 24-48%였다. 전주리 공정을 통하여 소수성 물질(byoghobic components)의 분포가 감 소하는 것을 볼 때 전염소 및 전오존 처리가 용존유기물의 응집에는 오히려 역 효과를 나타내는 것으로 판단된다. 것으로 판단된다.

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Developing a General Recycling Method of FRP Boats (FRP선박의 범용 재활용을 위한 재처리시스템의 연구)

  • Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.1
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    • pp.29-34
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    • 2009
  • For several decades, many researchers have been involved in developing recycling methods for FRP boats. There are four basic classes of recycling covered in the literature. Despite of environmental problems(safety hazards), mechanical recycling of FRP boats, which involves shredding and grinding of the scrap FRP, is one of the simpler and more technically proven methods than incineration, reclamation or chemical ones. Because FRP is made up of reinforced fiber glass, it is very difficult to break into pieces. It also leads to secondary problem in recycling process, such as air pollution and unacceptable shredding noise level. Another serious problem of mechanical FRP recycling is very limited reusable applications for the residue. This study is to propose a new and efficient method which is more wide range applications and environment friendly waste FRP regenerating system. New system is added with the cyclone sorting machine for airborne pollutions and modified cutting system for several glass fiber chips sizes. It also has shown the FRP chip fiber-reinforced concrete and fiber-reinforced secondary concrete applications with the waste FRP boat to be more eligible than existing recycling method.

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