• Tunnel and Underground Space
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• v.21 no.5
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• pp.394-405
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• 2011

In this paper, we applied coupled non-isothermal, multiphase fluid flow and geomechanical numerical modeling using TOUGH-FLAC coupled analysis to study the complex thermodynamic and geomechanical performance of underground lined rock caverns (LRC) for compressed air energy storage (CAES). Mechanical stress in concrete linings as well as pressure and temperature within a storage cavern were examined during initial and long-term operation of the storage cavern for CAES. Our geomechanical analysis showed that effective stresses could decrease due to air penetration pressure, and tangential tensile stress could develop in the linings as a result of the air pressure exerted on the inner surface of the lining, which would result in tensile fracturing. According to the simulation in which the tensile tangential stresses resulted in radial cracks, increment of linings' permeability and air leakage though the linings, tensile fracturing occurred at the top and at the side wall of the cavern, and the permeability could increase to $5.0{\times}10^{-13}m^2$ from initially prescribed $10{\times}10^{-20}m^2$. However, this air leakage was minor (about 0.02% of the daily air injection rate) and did not significantly impact the overall storage pressure that was kept constant thanks to sufficiently air tight surrounding rocks, which supports the validity of the concrete-lined underground caverns for CAES.

• Applied Chemistry for Engineering
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• v.32 no.6
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• pp.613-620
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• 2021

A flow channel shape of PEMFC has an influence on the internal flow uniformity. If the reactant distribution in a flow path is not uniform during operation, both catalyst deactivation and mechanical damage of membrane could occur resulting in decreasing the membrane electrode assembly (MEA) durability. Numerous studies concerning flow design have been conducted to make smooth supply and uniform distribution of reactants in fuel cells. The baffle of flow path could improve fuel cell performance through the forced convection effect. A sub-channel, as an additional air flow path, could increase the reactant concentration and reduce the mass transfer loss via a smooth water discharge. In this study, computational fluid dynamics (CFD) was used to analyze the effect of blocks and sub-channels on the current density and oxygen concentration of the fuel cell. As a result, the limit current density and oxygen concentration at a rear block increased when using blocks and sub-channels in a flow channel. In particular, the current density increased significantly when the sub-channel was placed between two blocks. Also, the sub-channel position was optimized by analyzing the oxygen concentration, and the oxygen concentration was recovered at a rear block in the fuel cell.

• Clean Technology
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• v.25 no.1
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• pp.19-32
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• 2019

As regional air pollution gets worse by the sulfur oxides emitted from various types of vessels passing through the many countries, the International Maritime Organization establishes the emission control areas and regulates sulfur dioxide in those areas. In order to satisfy these regional regulations, the fuel selection method and the exhaust gas post-treatment device are applied to the ships. Due to the economic reasons, the post-treatment method of exhaust gas for reducing the amount of sulfur oxides discharged is mainly preferred. The scrubber which is dominantly used in the ships are the spray type system where the sprayed liquid drops used for capturing the soluble sulfur dioxides in the exhaust gas. The performance of the spray type system depends on the size distribution of the sprayed droplets. In order to evaluate this performance, we designed counterflow type scrubber and cyclone scrubber and evaluated the desulfurization efficiency and the amount of droplet evaporation according to the size of each droplet by using computational fluid dynamics. The Eulerian-Eulerian analysis method was used because the scrubber had a gas-liquid two-phase flow inside the scrubber. When the diameter of the droplet was $100{\mu}m$, $300{\mu}m$, $500{\mu}m$ and $700{\mu}m$. As a result, both of scrubbers showed high desulfurization efficiency and low evaporation amount at $500{\mu}m$ and $700{\mu}m$.

• Journal of the Korean Chemical Society
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• v.64 no.6
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• pp.327-333
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• 2020

Performance of a portable GC that can be utilized for the real time determination of volatile organic compounds in air was evaluated. It employs purified/compressed ambient air as the carrier gas eliminating the need for high pressure gas tanks. The compact system with dimensions of 35 × 26 × 15 ㎤ and weight of 5 kg is powered by either a 24 V DC external adapter or battery pack. Chromatograms of the mixture sample including benzene, toluene, ethylbenzene, and oxylene at concentrations of 1 ppmv and 20 ppmv represent a good reproducibility: 3.79% and 0.48% relative standard deviations (RSDs) for peak area variations; 0.40% and 0.08% RSDs for retention times. The method detection limit was 0.09 ppmv. A 30 m long, 0.28 mm I.D. column operated at an optimal condition yielded a peak capacity of 61 with good resolution for a 10 min isothermal analysis. The relative standard deviations (RSD) of the peak area variations and retention times during consecutive measurements over 27 h were less than 2.4%RSD and 0.5%RSD, respectively. Thus, this instrument makes it suitable for continuous and field analysis of low-concentration VOC mixtures in the indoor/outdoor environment as well as the spillage accident of hazardous chemicals.

• Journal of the Korea Institute of Building Construction
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• v.21 no.1
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• pp.31-39
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• 2021

The aim of this paper is to improve durability of cement paste by imparting hydrophobicity to the surface and sphere of cement-based materials. A cement paste mixed with a silane/siloxane-based water repellent, and the initial hydration performance, flow performance, and age-specific compressive strength were measured. In addition, the water contact angle, SEM, and XRD before and after surface polishing were measured. When 0.5% of the silane/siloxane-based water repellent was mixed into the cement paste, the compressive strength increased, but the compressive strength decreased as the mixing amount increased by 1.5% and 3.0%. When a silane/siloxane water repellent was incorporated into the cement paste, the hydrophilicity was improved and the contact angle was increased due to hydrophobicity. In addition, the contact angle after surface polishing was found to be larger than the contact angle before surface polishing.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.6
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• pp.42-49
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• 2020

This paper is a basic study to improve durability by imparting hydrophobicity to the surface and sphere of cement-based materials. A cement mortar to which a silane/siloxane-based mixed water repellent was added was prepared, and its initial hydration performance, flow performance, and compressive strength were measured. In addition, after the surface was abraded, the water contact angle and water absorption were measured. The flow of cement mortar to which the water repellent was added was found to decrease up to 1.5% in the addition amount of the water repellent agent, and increased at 3.0% in the addition amount. It was found that the setting time of the cement paste was delayed in both the initial setting and the termination when the water repellent was added. It was found that the compressive strength decreased from 3.0% of the maximum added amount of the water repellent to a maximum of 30%. The contact angle was found to increase when the water repellent was added to the cement mortar, and the contact angle after surface polishing was found to be larger than before surface polishing. The addition of the water repellent showed hydrophobicity not only on the surface but also on the surface and cross section damaged by polishing. The water absorption rate was found to decrease when the water repellent was added to the cement mortar, and the water absorption rate after surface polishing was found to be greater than before surface polishing.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.300-307
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• 2022

Time-resolved serial femtosecond crystallography (TR-SFX) is a powerful technique for determining temporal variations in the structural properties of biomacromolecules on ultra-short time scales without causing structure damage by employing femtosecond X-ray laser pulses generated by an X-ray free electron laser (XFEL). The mixing rate of reactants and biomolecule samples, as well as the hit rate between crystal samples and x-ray pulses, are critical factors determining TR-SFX performance, such as accurate image acquisition and efficient sample consumption. We here develop two distinct sample delivery systems that enable ultra-fast mixing and on-demand droplet injecting via pneumatic application with a square pulse signal. The first strategy relies on inertial mixing, which is caused by the high-speed collision and subsequent coalescence of droplets ejected through a double nozzle, while the second relies on on-demand pneumatic jetting embedded with a 3D-printed micromixer. First, the colliding behaviors of the droplets ejected through the double nozzle, as well as the inertial mixing within the coalesced droplets, are investigated experimentally and numerically. The mixing performance of the pneumatic jetting system with an integrated micromixer is then evaluated by using similar approaches. The sample delivery system devised in this work is very valuable for three-dimensional biomolecular structure analysis, which is critical for elucidating the mechanisms by which certain proteins cause disease, as well as searching for antibody drugs and new drug candidates.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1059-1066
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• 2021

In Korea, the importance of marine activities is great, and automatic weather observation facilities are operating on land to investigate abnormal weather phenomena caused by industrialization; however, the number of facilities at sea is insufficient. Marine survey ships are operated to establish marine safety information, but there are many places where marine survey ships are difficult to access and operating costs are high. Therefore, a small, unmanned vessel capable of marine surveys must be developed. The sail has a significant impact on the sailing performance, so much research has been conducted. In this study, the camber effect, which is a design variable of the twin curvy sail known to have higher aerodynamic performance than existing airfoil shapes, was investigated. Flow analysis results for five cases with different camber sizes show that the lift coefficient is highest when the camber size is 9%. Curvy twin sails had the highest lift coefficient at an angle of attack of 23° because of the interaction of the port and starboard sails. The port sail had the highest lift coef icient at an angle of attack of 20°, and the starboard sail had the lowest lift coef icient at an angle of attack of 15°. In addition, the curvy twin sail had a higher lift coefficient than NACA 0018 at all angles of attack.

• Applied Chemistry for Engineering
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• v.34 no.4
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• pp.434-443
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• 2023

We have investigated the performance improvement of grease by synthesizing calcium sulfonate grease as an alternative to lithium grease, which is widely used globally. Since the composition ratio of the grease, when manufactured, is usually 50% base oil and 50% thickener, using grease as a lubricant in a cryogenic environment is not encouraged due to its inferior low-temperature performance. In this study, we have synthesized three types of calcium sulfonate grease with paraffin oil and PAO-based base oil and thickener. Furthermore, lithium grease was synthesized via saponification with PAO-based base oil, lithium hydroxide, 12-hydroxystearic acid, and sebacic acid. We have measured low-temperature characteristics using a rheometer and low-temperature torque meter, and tribology characteristics were obtained using a four-ball lubricant tester and schwingung reibung verschleiß (SRV). As a result, the flow point of the calcium sulfonate grease synthesized with a PAO-based base oil and thickener was found to be -40℃, overcoming the existing calcium sulfonate grease's low-temperature limitation. Moreover, the synthesized calcium sulfonate grease showed low-temperature performance similar to that of lithium grease synthesized with PAO base oil, but superior anti-wear, extreme pressure, coefficient of friction, heat resistance, adhesion, and corrosion resistance. It is thus expected to commercially replace the existing lithium grease.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.341-347
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• 2023

In PEMFC, PtCo/C alloy catalysts are widely used because of good performance and durability. However, few studies have been reported on the durability of carbon supports of PtCo/C evaluated at high voltages (1.0~1.5 V). In this study, the durability of PtCo/C catalysts and Pt/C catalysts were compared after applying the accelerated degradation protocol of catalyst support. After repeating the 1.0↔1.5V voltage change cycles, the mass activity, electrochemical surface area (ECSA), electric double layer capacitance (DLC), Pt dissolution and the particle growth were analyzed. After 2,000 cycles of voltage change, the current density per catalyst mass at 0.9V decreased by more than 1.5 times compared to the Pt/C catalyst. This result was because the degradation rate of the carbon support of the PtCo/C catalyst was higher than that of the Pt/C catalyst. The Pt/C catalyst showed more than 1.5 times higher ECSA reduction than the PtCo/C catalyst, but the corrosion of the carbon support of the Pt/C catalyst was small, resulting in a small decrease in I-V performance. In order to improve the high voltage durability of the PtCo/C catalyst, it was shown that improving the durability of the carbon support is essential.