• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.52-52
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• 2011

PLA 섬유는 폴리머의 주성분이 옥수수에서 추출한 모노머를 중합한 화학섬유가 아닌 인체친화적인 식물성 소재이며 생분해성이 좋은 친환경 소재로 최근 주목받고 있는 섬유소재이다. 본 연구에서는 아토피완화용 여러 섬유 구조체 개발에서 사용되는 섬유소재중 PLA 원사에 항균성 물질을 혼입하여 PLA 항균사 제조를 위한 연구를 수행하였다. PLA Grade의 점도가 낮아질수록 Grade별 용융 지수값은 차이를 나타내지만 방사온도 $230^{\circ}C$를 변곡점으로 하여 용융점도가 급격히 변하였으며, 특히 방사온도 $240^{\circ}C$의 경우 용융지수가 100을 넘어가고 폴리머의 색깔이 황갈색을 띄어 폴리머의 열분해가 많이 일어났을 것으로 판단되었다. PLA의 적정 방사온도 구간은 $210{\sim}225^{\circ}C$ 구간이 최적이며 그 이상에서는 Color 변화 및 물성 저하가 나타나는 것으로 판단되었다. 항균성 PLA 섬유를 제조하기 위하여 피톤치드계 유기항균제를 이용하였으며, 피톤치드에 기능성 엘라스토머를 사용하여 Capsulation을 진행하였다. 이러한 유기항균제 Powder의 경우 비중이 낮아 표면적로 인하여 마스터배치 칩을 만드는 공정에서 잘 혼합되지 않는 문제점이 발생하였으나, 피톤치드의 함량을 조절하여 PLA와의 마스터배치 칩 제조를 시험하였다. 압출온도와 토출량, Screw 조건(Mixing, Zone)을 시험하여 적정 조건을 설정하였다. 항균사 PLA 섬유는 Sheath/Core 복합방사 형태와 단독사 형태의 2가지 Type을 제조하였다. Sheath/Core 복합방사 폴리머 구성은 Sheath부에 PLA항균사, Core부에 PLA 또는 저융점 PET를 사용하였다. Core부의 폴리머는 제사성에 큰 영향을 미치지 않았으나, 항균 마스터배치의 함량이 증가할수록 Pack압 상승이 급격히 일어나는 단점이 나타났다. 항균제 5% 정도가 혼입되어 있는 경우에 2.1 이상의 정균활성치와 99.8% 정도의 정균감소율 성능을 나타내었다. PLA 단독사의 경우, 항균제 최적 함량은 3% 이상으로 정균활성치 5.5 이상, 정균감소율 99.9%의 우수한 항균특성을 나타내었다.

• Korean Journal of Materials Research
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• v.6 no.8
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• pp.786-795
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• 1996

The fiber reinforced thermoplastics(FRTP) were prepared with polypropylene fiber(PP) as matrix and polyvinyl alchol(VF), aramid(KF) or polyamide fiber(PAF) as the reinforcing materials using the integrated fiber mixing apparatus. The reinforced thermoplastic sheets were prepared by com¬pression molding and their morphology, rheological and mechanical properties were characterized. In the morphological properties of composites, the wettability of the reinforced thermoplastics were decreased in proportion to the content of fibers. At low angular frequency, the viscosity of PAF /PP and VF/PP composite was increased with the content of reinforced fiber. However at high frequency the viscosity of composite reinforced with 5~20wt% fiber, was shown the reduced values which approaches that of the neat matrix. The mechanical properties of the composite were changed with the content of reinforecd fiber, and VF/PP and KF/PP composite had better properties than PAF/PP system.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.358-359
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• 2003

Organic light-emitting device have attracted much interest due to their potential application in large area, full color, flat panel displays. Poly(p-phenylene)(PPP), as a blue light-emitting materials, have studied in our previous report. Thus, we selected poly(p-phenylene) (PPP) to fabricate the organic light-emitting filaments(OLEF) [1-2]. In this paper, we fabricated an organic light-emitting filaments(OLEF), which can be woven into fabric. The key concept was flexibility in one-dimensional structures. (omitted)

• Proceedings of the Korean Fiber Society Conference
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• 2007.11a
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• pp.389-390
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• 2007

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• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2000.11a
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• pp.307-312
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• 2000

최근 고분자 화학의 급속한 발전에 따라 우수한 특성을 가진 다양한 절연재료가 개발되어 왔으며, 이러한 유기고분자 재료의 용도와 수요가 매년 급증하고 있다. 이들 고분자 재료 중 유리섬유 강화 복합재료(FRP; fiber reinforced plastics)는 전기$\cdot$화학적으로 우수한 특성을 갖는 에폭시 수지에 기계적 강도를 보강하기 위해 유리섬유를 복합시틴 hybrid 재료로서 애자, PCB 기판 및 우주항공 산업분야에 이르기까지 그 응용분야를 확대시키고 있다.(중략)

• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.219-220
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• 2003

나일론 6의 열변형온도와 탄성률을 증가시키는 동시에 높은 기체 차단성을 얻기 위하여 Na-montmorillonite (Na-MMT) 또는 유기화제로 개질된 MMT (organo-MMT)를 나일론 6과 melt-compounding함으로써 나일론 6 분자쇄가 MMT 층 내로 intercalation하거나 MMT의 각 층을 완전히 exfoliation시켜 나일론 6/MMT 나노복합체를 제조하는 방법과 Na-MMT 또는 organo-MMT의 존재하에서 $\varepsilon$-caprolactam (CL)을 in situ 중합함으로써 대부분의 MMT가 각각의 층으로 exfoliation 되도록하여 나일론 6/MMT 나노복합체를 제조하는 방법이 널리 쓰이고 있다 [1-2]. (중략)

• Applied Chemistry for Engineering
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• v.4 no.3
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• pp.437-446
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• 1993

• Journal of the Korea Institute of Building Construction
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• v.14 no.6
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• pp.639-645
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• 2014

For the construction materials, concrete, as the most widely used material, is focused on its improvement of performance. Although concrete has many advantages of easiness of handling, economical benefits, and high compressive strength, low tensile strength, brittleness and drying shrinkage are reported as the drawbacks of concrete. Hence, to solve these drawbacks of concrete, many research has conducted especially using fiber-reinforced concrete technology. Especially, HPFRCC which has high volume of fiber reinforcement was suggested as a solution of these drawbacks of normal concrete with increased ductility while it has the possibility of workability loss with fiber clumping which can cause low performance of concrete. Therefore, in this paper, optimized fiber combination with either or both metal and organic fibers is suggested to provide better performance of HPFRCC in tensile strength and ductility. As the results of experiment, better workability was achieved with 1 % of single fiber rather than multiple fibers combinations, espeically, short steel fiber showed the best workability result. Furthermore, in the case of organic fibers which showed higher air content than steel fibers, higher compressive strength was achieved while lower tensile and flexural strength were shown.

• Journal of the Korea institute for structural maintenance and inspection
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• v.13 no.3 s.55
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• pp.127-134
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• 2009

This study investigated their properties of spalling resistance and residual compressive strength after fire test corresponding to various ISO, RABT heating curves, and contents of hybrid organic fiber of high strength concrete. The results were summarized as following. As fundamental characters of concrete with hybrid organic fiber, the flowability was directly declined as the increase of fiber contents, and air contents were decreased or increased a little bit, but there was not big difference. The compressive strength was gradually declined sluggishly at 28 days. As properties of fire resistance, in case of RABT heating curves, compare with ISO heating curves a spalling aspect showed till range that has much contents of hybrid organic fiber, but they are mostly peeling spalling, which means spalling aspect didn't happen to inside. In conclusion, in case of W/B 25% high strength concrete, the spalling was prevented over 0.04% of contents of fiber at ISO heating curve and over 0.10% of contents of fiber at the RABT heating curve. In case of spalling was prevented, mass reduction rate according to the change of heating temperature curves showed around 7% at ISO heating curves and around 9% at RABT heating curves. The residual compressive strength rate corresponding to the change of heating temperature curves showed 50%~60% at ISO heating temperature curves and 30%~35% at RABT heating temperature curves in case of spalling was prevented.

• Fire Science and Engineering
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• v.28 no.5
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• pp.71-79
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• 2014

This study was performed to test the combustive properties of Medium Density Fibreboards (MDFs) treated with chemicals of the bis-(dimethylaminomethyl) phosphinic acid (DMDAP), N,N-dimethylethylenediaminomethyl-bis-phosphonic acid (DMDEDAP), piperazinomethyl-bis-phosphonic acid (PIPEABP), and methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP). MDFs were painted in three times with 15 wt% solution of the bis-(dimethylaminomethyl) phosphinic acid and alkylenediaminoalkyl-bis-phosphonic acids at the room temperature, respectively. After drying MDF treated with chemicals, combustive properties and volatile organic compounds (VOCs) contents were examined by the cone calorimeter (ISO 5660-1), test for flame retardant (NEMA Notice No. 2012034), and gas chromatography (KS M ISO 11890-2), respectively. It was indicated that the MDFs treated with chemicals showed the longer time to combustion time (CT) = (442~492) s than that of virgin plate by reducing the burning rate except for CT treated with DMDAP. In adition, the MDFs treated with chemicals showed both of the higher char area (44.33~61.33) kg/kg and char length (10.33~11.67) cm than those of virgin plate. Especially, the MDFs treated with chemicals showed the higher mean volatile organic compounds (VOCs) (0.188~0.333) g/L than that of virgin plate within the prescribed limits. Thus, It is supposed that the combustion- retardation properties were improved by the partial due to the treated chemicals in the virgin MDF.