• Title/Summary/Keyword: 유기폐액

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방사성폐액 처리를 위한 유.무기 이온교환수지 성능 비교 분석

  • 박세문;김종빈
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.415-420
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    • 1998
  • 시판중인 대표적 유·무기이온교환수지를 이용하여 방사성폐액의 주 방사성핵종인 코발트와 세슘에 대하여 방사성패액에 함유되어 있는 대표적 일반이온인 나트륨이온이 이들의 이온교환에 미치는 영향을 분석하였다. 나트륨 존재 하에서 세슘이온에 대한 선택도와 수지단위 부피당 폐액 처리 부피는 무기이온교환수지인 DT 30과 Durasil 230이 가장 높으며 반면에 유기이온교환수지는 두 수치 모두 낮아서 유기이온교환수지는 저농도의 나트륨 이온을 갖는 증발기 응축수의 처리에는 적합하나 나트륨이온의 농도가 비교적 높은 폐액처리에는 적합하지 않으며, 또한 코발트 제거 면에서는 무기이온교환수지인 DT 10 보다 유기이온교환수지인 Amberlite IRN 77이 바람직하다는 결론을 얻었다.

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Recovery of Copper from Spent Copper Solution of Printed Circuit Board Process by Solvent Extraction Method (인쇄회로기판 제조과정에서 발생되는 동폐액의 용매추출에 의한 재활용)

  • Moon, Young-Hwan
    • Clean Technology
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    • v.2 no.1
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    • pp.47-52
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    • 1996
  • The solvent extraction method was applied on a spent solution containing copper, which was produced in a printed circuit board process, to recover copper and to reuse the etching solution. Lix 64 N ($\alpha$-Hydroxyoxime + $\beta$-Hydroxybenzophenone Oxime) was used as a solvent. The acidic spent copper solution was mixed with and alkaline copper solution to pH=2. The solvent including 30 volume% of Lix 64 N extracted 17.1gr/l of copper from the mixed spent copper solution. In the continuous bench scale experiment, 4 stages for extraction, 2 stages for stripping and 4 stages for washing were used. Recovered copper was recycled as copper sulfate and the raffinate was reused as copper etchant. The percentage of copper recovery and the purity of copper sulfate were higher than 99.9%, respectively.

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