• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.1
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• pp.1-9
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• 2009

Distribution characteristics of organophosphorous pesticides (OPs) were studied over the period from May to September, 2006 in Asan Bay, Korea. During the study period, 28 kinds of organophosphorous pesticides dissolved in surface water and adsorbed on suspended particle were measured. In the surface water, the dominant OPs were IBP and DDVP, and the concentration were in the ranges from not detected to 2014.4 ng/L for IBP and 3.2 to 696.3 ng/L for DDVP. The highest concentrations of OPs in the surface waters in Asan Bay appeared in July and August showing that seasonal distributions of OPs depend on application time and precipitation. The concentrations of OPs generally decreased with the increase of distance from the mouth of Asan Bay, implying progressive dilution of pesticides in the estuarine system. OPs residue in Asan Bay was relatively higher than in other area of Korea. The concentrations of the observed OPs concentrations did not exceed the seawater quality standard of Korea. DDVP, IBP, Diazinon, Phorate, Azinphos ethyl and Chlorfenvinfos had higher adsorption capacity onto suspended particle than the other OPs. In the study area, adsorption coefficients $(K_d)$ of OPs were closely related to the Log $K_ow$ of each compound.

• Journal of the Korean Society for Marine Environment & Energy
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• v.9 no.3
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• pp.176-186
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• 2006

Distribution characteristics of organophosphorous pesticides(OPs) in water and suspended particles were studied in Asan Bay, Korea, from June 2004 to October 2005. 28 organophosphorous pesticides could be detected in Asan Bay during this study. The most commonly and abundantly measured OPs in the surface waters were IBP (max=$6,343.7ng\;l^{-1}$). DDVP, diazionon, ethoprophos and methidathion were also observed at relatively high concentrations. Their maximum concentrations exceeded $100ng\;l^{-1}$ in almost every month. Malathion, mevinphos, ph orate and chlorfenvinphos were also detected at relatively high concentrations. Many OPs more frequently appeared in summer than in winter due to the intensive application of pesticides in summer months. The concentration of OPs generally decreased with increasing distance from the mouth of Asan Bay. This result implies progressive dilution of these pesticides in the marine environment. Measured concentrations of diazinon were well below $20,000ng\;l^{-1}$ which is a limit set by the seawater quality standard of Korea. The concentrations of malathion and parathion in the surface waters of Asan Bay did not exceed the seawater quality standard of Korea($250,000\;and\;60,000ng\;l^{-1}$ respectively). OPs adsorbed on suspended particles were also studied. DDVP, phorate, stirofos, EPN, azinphos-methyl and IBP had higher adsorption capacity onto suspended particles than other pesticides. Calculated pesticide-particle adsorption coefficient($K_d-particle$) for samples collected in Asan Bay were closely related to the reported pesticides-soil adsorption coefficient ($K_d-soil$).

• The Korean Journal of Pesticide Science
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• v.2 no.1
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• pp.12-17
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• 1998

Salicylic acid and 3-hydroxy benzoic acid are nitrated and esterified with some alcohols. Five phosphate and six carbamate compounds of alkyl-5-nitrosalicylate and alkyl-3-hydroxy-4-nitrobenzoate are synthesized by reacting alkyl-5-nitrosalicylate and alkyl-3-hydroxy-4-nitrobenzoate with diethyl-chlorophosphate and methyl isocyanate. As the bioassay results of synthesized compounds on five insects and six pathogens, the brown planthopper (BPH, Nilaparvata lugens) mortality of O-(2-carbomethoxy-4-nitrophenyl) O,O-diethylphosphate and O-(2-nitro-5-carbo methoxyphenyl) O,O-diethylphosphate was 96%, while four compounds including O-(2-carbo-(2-chloroethoxy)-4-nitrophenyl) O,O-diethylphosphate showed more than 95% of fungicidal activity on rice blast.

• Journal of the Korean Society for Marine Environment & Energy
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• v.5 no.1
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• pp.38-50
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• 2002

To study the distribution of organophosphorus pesticides which are extensively used for agriculture in Korea. Surface sea water samples were taken from 2 coastal areas during July and :;eptember of 1999 and sediment samples were collected from Kyeonggi bay in July of 1999. These samples were analyzed using a Gas Chromatography/Nitrogen Phosphorus Detector(GC/NPD). In coastal waters of the study areas IBP was commonly found the most compound. Traces of Diazinon, DDVP, Ethoprouhos and Chlorpyrifos were also encountered. Concentration of the other major organophosphorus pesticides(Disulfoton, Parathion Methyl, Fenchlorfos, Prothiofos, EDDP) were generally be below the detection limit of the employed analytical method. Tn sediment of the study areas Chlorpyrifos w3s found the most compound. Temporal and geographical distribution of individual organophosphorus pesticides is likely to be affected by types of agricultural practices in the watershed.

• Korean Journal of Ecology and Environment
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• v.40 no.2
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• pp.318-326
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• 2007

Characteristics of organophoshhorus pesticides (OPs) distribution were investigated in Shingu Reservoir, as a shallow eutrophic agriculture reservoir in Korea. In August 2006, IBP, DDVP and dyfonate were detected in the water column of Singu Reservoir, ranging from 1340.7 to 16030.1 ng $L^{-1}$, 58.7 to 127.6 ng $L^{-1}$ and N.D. to 20.3 ng $L^{-1}$, respectively, However, in September 2006, mevinfos, ethoprofos, phorate, chlorfenvinfos, and methidathion were also found in addition to IBP (202.5${\sim}$213.2 ng $L^{-1}$), DDVP (100.7${\sim}$340.6 ng $L^{-1}$) and dyfonate (N.D.${\sim}$25.0 ng $L^{-1})$. Maximum concentrations of OPs were observed at the middle depth in August, which might be related with photo-oxidation. On the other hand, IBP and DDVP among the OPs were detected in suspended particles, suggesting the relatively active adsorption reactivity. The composition of OPs varied temporally on account of the influence of inflow water from its surrounding areas. In the present study, the observed OPs concentrations seem to be not acute toBic levels to aquatic organisms in Shingu Reservoir, considering the standard monitoring levels of U.S. Environmental Protection Agency and Japan Ministry of Environment.

• Environmental Analysis Health and Toxicology
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• v.17 no.4
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• pp.341-346
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• 2002

To investigate the residue of organophosphorus pesticides such as Monocrotophos［Dimethyl-1-methyl-2-methyl carbamoylvinylphosphate］and EPN［O-ethyl-O-4-nitrophenyl phenylphosphonothioate］in the coastal environment of Cheju island, samples of sea organism, water and sediment were collected at the Sackdaldong and Daepodong near the Jungmoon golf course in July and Aug. 1997. The qualified detection limit of mono-crotophos and EPN by GC -FPD were 0.024 ng/g and 0.020 ng/g in the sea organism, respectively Neither Monocrotophos nor EPN was detected in seaweed cava (Ecklonia cava), Agar (Gelidium amansii), turban sell (Batillus cornutus) and sea urchin (Anthocidaris Crassispina). They were not detected in seawater and sediment, either. These results showed that the coastal area near the Jungmoon golf course in the Cheju island was not polluted by the organophosphorus pesticides such as Monocrotophos and EPN.

• Korean Journal of Environmental Agriculture
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• v.26 no.4
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• pp.337-342
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• 2007

To obtain the data on the risk assessment of residue levels of organophosphorus and organochlorine pesticides in fresh ginseng and red ginseng extract, the residual pesticides in samples are surveyed with GC-NPD and GC-ECD for quantitative analysis and GC-MSD for qualitative analysis. The residual organophosphorus pesticides, such as diazinon, pyrimethanil, tolclofos-methyl, metalaxyl, diethofencarb, parathion, cyprodinil, tolylfluanid and kresoxim-methyl, are not detected in fresh ginseng from Punggi. The residual organophosphorus pesticides except tolclofos-methyl are not detected in fresh ginseng from Sangju. Average amount of tolclofos-methyl in fresh ginseng from Sangju are $0.054{\pm}0.008\;mg/kg$, representing $18{\pm}2%$ of MRL of 0.03 mg/kg on fresh ginseng in Korea. The residual organochlorine pesticides, such as BHC isomer, DDT isomer, aldrin, azoxystrobin, captan, cypermethrin, deltamethrin, dieldrin, difenoconazole, endosulfan-sulfate, endrin, fenhexamid, quintozene, ${\alpha}$-endosulfan and ${\beta}$-endosulfan, are not detected in fresh ginseng from Punggi and Sangju. The residual organophosphorus and organochlorine pesticides in red ginseng extract from Punggi and Sangju are not detected.

• Korean Journal of Environmental Agriculture
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• v.15 no.2
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• pp.246-261
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• 1996

Organophosphorus pesticides, which are an important part of synthetic pesticides in current use contain sulfur atom in their molecules and can be activated or detoxified by environmental and/or biological metabolism. Among the related metabolic reactions, oxidative processes are particularly important with their final products and the study on the reactive intermediates formed in those reactions is essential to elucidate the metabolic pathways and mechanisms and to understand the toxicological properties. This review dealt with the reactive intermediates formed in various reactions from the structural and mechanistic point of view for organophosphorus pesticides and related compounds.

• The Korean Journal of Pesticide Science
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• v.18 no.1
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• pp.41-47
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• 2014

This study was performed to evaluate the exposure level of organophosphorus and pyrethroid pesticide to floriculture workers and florists. The urinary dialkylphosphates, metabolites of organophosphorus insecticides, including dimethylphosphate (DMP), diethylphosphate (DEP), dimethylthiophosphate (DMTP), diethylthiophosphate(DETP) and pyrethroids of metabolites, cis/trans DCCA, DBCA, and 3-PBA were analysed to evaluate the exposure of organophosphorus and pyrethroid pesticide to floriculture workers and florists. The concentration of DMP is highest in floriculture workers. but the concentration of DETP is highest in retail florist. The concentration of 3-PBA is highest in floriculture workers. The amount of organophosphorus and pyrethroid pesticide expusure is highest in flower workers, wholesale florist and retail florists are followed. The management for reducing pesticide exposure to floriculture workers and wholesale florist is required.

• Journal of Food Hygiene and Safety
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• v.36 no.1
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• pp.1-8
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• 2021

The inverted Y-shaped strip detection method based on acetylcholinesterase (AChE) was developed for the rapid detection of organophosphorus and carbamate pesticides. The inactivation of AChE by organophosphorus and carbamate pesticides has been well known. The AChE catalyzes acetylthiocholine into thiocholine having (-) and (+) charges, and the (+) charge results in aggregation of gold nanoparticle (GNP). Malaoxon and carbofuran were used as standard organophosphorus and carbamate for the development of the inverted Y-shaped strip, respectively. In order to optimize the method, various angles of the Y-shaped strip, different types of nitrocellulose membrane, and concentration of AChE were tested as key parameters. The detection limit of the method was 10 ng/mL for both malaoxon and carbofuran pesticides. No cross-reaction was observed to other pesticides such as atrazine, cyanazine, simazine, bifenthrin, boscalid, metalaxyl, and chlorobenzilate. Recoveries from lettuce spiked when known concentrations of malaoxon and carbofuran were found ranging from 96.4 to 100.7% and 81 to 112.7%, respectively. This study suggests that the inverted Y-shaped strip method based on AChE may be a useful tool for the sensitive, specific, rapid detection of organophosphorus and carbamate pesticides in agricultural products.