• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.78-78
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• 2000

다결정 실리콘-게르마늄 (poly-SiGe)은 태양전지 개발에 있어서 중요한 물질이다. 우리는 소량의 Ge(x=0.05)으로부터 다량의 Ge(x=0.67)을 함유한 수소화된 비정질 실리콘-게르마늄 (a-SiGe:H) 박막의 고상결정화 과정을 ESR (electron spin resonance)방법으로 조사해보았다. 먼저 PECVD 방법으로 Corning 1737 glass 위에 a-Si1-xGex:H 박막을 증착시켰다. 증착가스는 SiH4, GeH4 가스를 썼으며, 기판온도는 20$0^{\circ}C$, r.f. 전력은 3W, 증착시 가스압력은 0.6 Torr 정도이었다. 증착된 a-SiGe:H 박막은 $600^{\circ}C$ N2 분위기에서 다시 가열되어 고상결정화 되었고, 결정화 정도는 XRD (111) peak의 세기로부터 구해졌다. ESR 측정은 상온 x-band 영역에서 수행되었다. 측정된 ESR스팩트럼은 두 개의 Gaussian 함수로써 Si dangling-bond와 Ge dangling-bond 신호로 분리되었다. 가열 초기의 a-SiGe:H 박막 결함들의 스핀밀도의 증가는 수소 이탈에 기인하고, 또 고상결정화 과정에서 결정화된 정도와 Ge-db 스핀밀도의 변화는 서로 깊은 상관관계가 있음을 알 수 있었다. 특히 Ge 함유량이 큰 박막 (x=0.21, 0.67)에서 뿐만 아니라 소량의 Ge이 함유된 박막(x=0.05)에서도 Ge dangling-bond가 Si dangliong-bond 보다 고상결정화 과정에서 더 중요한 역할을 한다는 것을 알수 있었다. 또한 초기 열처리시 Si-H, Ge-H 결합에서 H의 이탈로 인하여 나타나는 Si-dangling bond, Ge-dangling bond 스핀밀도의 최대 증가 시간은 x 값에 의존하였는데 이러한 결과는 x값에 의존하는 Si-H, Ge-H 해리에너리지로 설명되어 질 수 있다. 층의 두께가 500 미만인 커패시터의 경우에 TiN과 Si3N4 의 계면에서 형성되는 슬릿형 공동(slit-like void)에 의해 커패시터의 유전특성이 파괴된다는 사실을 알게 되었으며, 이러한 슬릿형 공동은 제조 공정 중 재료에 따른 열팽창 계수와 탄성 계수 등의 차이에 의해 형성된 잔류응력 상태가 유전막을 기준으로 압축응력에서 인장 응력으로 바뀌는 분포에 기인하였다는 사실을 확인하였다.SiO2 막을 약화시켜 절연막의 두께가 두꺼워졌음에도 기존의 SiO2 절연막의 절연 파괴 전압 및 누설 전류오 비교되는 특성을 가졌다. 이중막을 구성하고 있는 안티퓨즈의 ON-저항이 단일막과 비교해 비슷한 것을 볼 수 잇는데, 그 이유는 TiO2에 포함된 Ti가 필라멘트에 포함되어 있어 필라멘트의 저항을 감소시켰기 때문으로 사료된다. 결국 이중막을 구성시 ON-저항 증가에 의한 속도 저하 요인은 없다고 할 수 있다. 5V의 절연파괴 시간을 측정한느 TDDB 테스트 결과 1.1$\times$103 year로 기대수치인 수십 년보다 높아 제안된 안티퓨즈의 신뢰성을 확보 할 수 있었다. 제안된 안티퓨즈의 이중 절연막의 두께는 250 이고 프로그래밍 전압은 9.0V이고, 약 65$\Omega$의 on 저항을 얻을수 있었다.보았다.다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품 개발에 따른 새로운 수요 창출과 수익률 향상, 기존의 기능성 안료를 나노(nano)화하여 나노 입자를 제조, 기존의 기능성 안료에 대한 비용 절감 효과등을 유도 할 수 있다. 역시 기술적인 측면에서도 특수소재 개발에 있어 최적의 나노 입자 제어기술 개발 및 나노입자를 기능성 소재로 사용하여 새로운 제품의 제조와 고압 기상 분사기술의 최적화에 의한 기능성 나노 입자 제조 기술을 확립하고 2차 오염 발생원인 유기계 항균제를 무기계 항균제로 대체할 수 있다. 이와 더불

• Journal of Wetlands Research
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• v.20 no.1
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• pp.72-79
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• 2018

Two planter boxes were monitored during their initial year of operation to be able to assess their stormwater runoff and pollutant reduction capabilities and investigate on the design factors affecting their performance. One of the planter boxes provided 85-100% runoff volume reduction for rainfall less than 15 mm and rainfall intensities lower than 5 mm/hr. This reduced to 50-64% during higher rainfall intensities and depths of up to 50 mm. Suspended solids, organics, nutrients, and heavy metals were satisfactorily removed at a range of 40-95%. The other planter box, however, did not produce outflow in all the events and allowed total capture of stormwater. The uncertainty regarding the fate of the runoff in that case required an investigation of the planter box's actual drainage and underground conditions which was deemed outside the scope of the study. Nonetheless, several design improvements and retrofits were suggested based on the provisions of current design guidelines to ensure that the hydraulic and water quality goals are achieved without potential damage to nearby structures. Moreover, continuous monitoring data is required to provide more accurate design evaluation and can serve as a guide in the construction of similar facilities in the future.

• Journal of the Korean Society of Food Science and Nutrition
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• v.22 no.2
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• pp.190-195
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• 1993

In order to investigate the changes of some chemical components during the maturation of Vitis vinifera red grapes, brix, total sugar, organic acids, total acid, pH and free amino acids were analyzed by HPLC etc. Brix, pH and total sugar content during the maturation of red grapes were increased rapidly but total acidity was decreased between 12~14 days after the formation of sugars. Its compositions were 16.5~17.9 of brix, 14.8~16.4g/100ml of total sugar, 3.24~3.25 of pH and 0.81~0.92g/100ml of total acidity. The ratio of brix/acid was increased gradually during the maturation. Glucose and fructose were contained more than 99% of total sugar and the content of sucrose were 0.03~0.04g/100ml in three varieties (Cabernet sauvignon, Cabernet franc and Malbec). The ratio of fructose/glucose in maturated three red grapes was ranged 1.04~1.06. Organic acids during the maturation, when sugars increased, were decreased rapidly and the ratio of tartaric/malic acid showed 0.83~1.00. Free amino acids during the maturation were increased and these content were 256.8mg~290.9mg/100ml in three varieties. The content of proline was the highest content of free amino acids in three red grapes, the next ones were arginine, alanine and glutamic acid in the other with 73.2~77.2% of total free amino acids. Especially, content of arginine was higher than others in Malbec variety.

• Polymer(Korea)
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• v.36 no.1
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• pp.47-52
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• 2012

Abstract: In this study, PAN/$TiO_2$ fiber mats were fabricated from polyacrylonitrile (PAN) and titanium(IV) butoxide ($Ti(OBu)_4$) by an electrospinning method with various solution concentrations, applied voltages and solution flow rates. The fiber mats were irradiated with an electron beam to induce structural crosslinking and enhance photocatalytic activity. As a result, uniform and bead-free fibers without pits or cracks on surface were obtained at 5 wt% of $Ti(OBu)_4$ solution with 15 kV and 0.02 mL/min flow rate. The PAN/$TiO_2$ fiber mats were irradiated with an electron beam of 1.14 MeV acceleration voltage, 4 mA of current and $1{\times}10^4kGy$. Electron beam irradiation was enhanced the photocatalytic activity of PAN/$TiO_2$ nano fiber mat. The photocatalytic activity of the PAN/$TiO_2$ fiber mat was analyzed by degradation of methylene blue and volatile organic compounds.

• Journal of the Korea Organic Resources Recycling Association
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• v.29 no.3
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• pp.5-16
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• 2021

In this study, the applicability of the MBR(Membrane Bio Reactor) process of oxygen dissolve was evaluated through comparison and evaluation of the efficiency of oxygen dissolve device and conventional aeration device in the explosive tank within the MBR process. The organic matter and ammonia oxidation by oxygen dissolve device were evaluated, and the efficiency of persaturation was evaluated by applying real waste water (anaerobic digester effluent treatement from food waste). SCOD and ammonia removal rates for oxygen dissolve device and conventional aeration device methods were similar. However, it was determined that the excess sludge treatment cost could be reduced as the yield of microorganisms by oxygen dissolve device is about 0.03 g MLSS-produced/g SCOD-removed lower than that of microorganisms by conventional aeration device. The removal rates of high concentrations of organic matter (4,000 mg/L) and ammonia (1,400 mg/L) in anaerobic digester effluent treatment from food waste were compared to the conventional aeration device and the oxygen dissolve device organic matter removal rate was approximately 13% higher than that of the conventional aeration device. In addition, for MLSS, the conventional aeration device was 0.3 times higher than for oxygen dissolve device. This is believed to be due to the high progress of sludge autooxidation because the dissolved oxygen is sufficiently maintained and supplied in the explosive tank for oxygen dissolve device. Therefore, it was determined that the use of oxygen dissolve device will be more economical than conventional aeration device as a way to treat wastewater containing high concentrations of organic matter.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.2
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• pp.13-18
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• 2019

Sewage sludge treatment is increasing every year due to improvement of living and urbanization. However, interest in anaerobic digestion which is one of the recycling technology. There is anaerobic digestion of increasing due to limitations of ocean dumping and final disposal. But, the limit of anaerobic digestion efficiency due to the advanced treatment of sewage has been limited, and studies for solubilization technology have been actively conducted. Therefore, in this study, we aimed to investigate the variation of generation of scum and the solubilization efficiency in the application of pre-treatment of ozone reaction and the change of properties of digested sludge with wet milling. There are results of VS/TS increased by 4.4% and $SCOD_{cr}/TCOD_{cr}$ increased by 9.4% by wet milling alone. In addition, the increase of the specific surface area due to which the reduction of the particle size of the solid content of the sludge in the ozone reaction caused by wet milling decreased the generation rate of scum at 14.3% and increased VS/TS at 2.1%, compared with the ozone reaction alone. From these results, it is expected that the application of wet milling can be increased the contact efficiency with solids in the sludge during ozone reaction with suppress scum and increase the efficiency of the subsequent process in anaerobic digestion.

• Clean Technology
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• v.27 no.2
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• pp.152-159
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• 2021

Volatile organic compounds (VOCs) occur in indoor and outdoor industrial and urban areas and cause environmental problems. Malodorous VOCs, along with aesthetic discomfort, can have a serious effect on the human body. Compared with the existing method of reducing malodorous VOCs, a wet scrubbing method using an electrolytic oxidant has the advantage of reducing pollutants and regenerating oxidants. This study investigated the optimal conditions for producing OCl^-, a chlorine-oxidant. Experiments were conducted by changing the type of anode and cathode electrode, the type of electrolyte, the concentration of electrolytes, and the current density. With Ti/IrO₂ as the anode electrode and Ti as the cathode electrode, OClproduction was highest and most stable. Although OCl^- production was similar with the use of KCl or NaCl, NaCl is preferable because it is cheap and easy to obtain. The effect of NaCl concentration and current density was examined, and the OCl^- production rate and concentration were highest at 0.75 M NaCl and 0.03 A cm^-2. However, considering the cost of electric power, OCl^- production under the conditions of 1.00 M NaCl and 0.01 A cm^-2 was most effective among the conditions examined. It is desirable to produce OCl^- by adjusting the current density in accordance with the concentration and characteristics of pollutants.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.4
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• pp.23-33
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• 2020

Marine algae(Macro algae) are easily bio-degradable, and by-products are available as feed and fertilizer. The biomass of marine algae has higher CO2 absorption capacity than the wood system, and is highly valuable in use due to its fast growth speed and wide cultivation area without special cost for raw material production. In 2018, Marine algae production was 1,722,486ton, such as Saccharina japonica, Undaria pinnatifida and Porphyra tenera, the large amounts of by-products have been generated in the food processing facilities for commercialization. In this study, Saccharina japonica, Undaria pinnatifida were collected in the south coast region and Porphyra tenera was collected in the west coast region. The theoretical methane potential and biochemical methane potential(BMP) were analyzed, and Modified Gompertz model and Parallel first order kinetics model were adopted for the interpretation of the cumulative methane production curves. The theoretical methane potential of Saccharina japonica, Undaria pinnatifida and Porphyra tenera were 0.393, 0.373 and 0.435 N㎥/kg-VS, respectively. BMP obtained by the Modified gompertz model 0.226, 0.227, and 0.241 N㎥/kg-VS for Saccharina japonica, Undaria pinnatifida and Porphyra tenera, respectively. And BMP obtained by the Parallel first order kinetics model were 0.220, 0.243, and 0.240 N㎥/kg-VS for Saccharina japonica, Undaria pinnatifida and Porphyra tenera, respectively.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.15-25
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• 2022

In this study, the efficiency of treatment of moisture and organic matter in food waste was analyzed according to the air blast volume and preheating using the bio-drying method. Te mount of air blast volume and preheating were determined by the evaluation of temperature and CO2 during food waste treatment using the bio-drying method. As a results, the increase in the air blast volume increased the moisture removal efficiency and removal rate, but, lowered the temperature inside the bio-drying by the decease in microbial activity. In order to maintain the activity of microorganisms, it was estimated that it was necessary to inject an appropriate air blast rate according th the properties of the food waste. In this study, the injection of air blast volume at 15L/min was optimal. It was evaluated that the organic matter and water removal rates according to the presence or absence of air preheating, the organic matter removal rate and water removal rate increased by 3-5% when air preheating was not performed. Also, there was no internal aggregation caused by the generation of condensate inside the bio-drying. Therefore, for effective bio-drying of food waste, it is necessary to maintain an appropriate air blast volume to maintain microbial activity, and it is considered that injection through preheating of air is required.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.27-40
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• 2022

In this study, the anaerobic digestion potential and thermo-chemical pre-treatment were evaluated for efficient anaerobic co-digestion of dewatered sludge(DS) and food waste(FW). As a result, the degradable organic matter concentration and methane yield of FW were evaluated to 2.2 and 1.3 times higher than that of DS, respectively. In order to increase the amount of biogas production, it was determined that it is desirable to increase the mixing ratio of FW. The efficiency of thermo-chemical pre-treatment was evaluated for the reaction temperature, NaOH concentration, reaction time and mixture ratio. As a result of evaluation through pre-treatment efficiency and dehydration capacity, the optimum pre-treatment conditions were evaluated as follows: reaction temperature 140℃, NaOH concentration 60 meq/L, reaction time 60 min, mixture ratio 1:5(DS:FW). The gas production rate and methane yield increased 1.6 and 1.5 times, respectively, compared to before and after applying the optimum pre-treatment. Therefore, it is necessary to increase the mixing ratio of food waste for efficient anaerobic co-digestion of DS and FW. and it is necessary to increase the solubilization efficiency of waste by application of pre-treatment.