• Title/Summary/Keyword: 유기물 특성

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ZnO Nanostructures for Photovoltaic Applications

  • Im, Dong-Chan;Lee, Gyu-Hwan;Jeong, Yong-Su;Park, Mi-Yeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.6.1-6.1
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    • 2009
  • 최근 신 재생 에너지에 대한 관심이 고조되고 있으며 특히 태양전지는 차세대 대체에너지로 많은 연구 개발이 이루어지고 있다. 현재 태양전지 시장은 벌크실리콘 태양전지가 주를 이루고 있으나, 박막형, 유기물, 염료감응형 등 다양한 차세대 태양전지가 개발되고 있다. 차세대 태양전지는 글래스나 폴리머 기판위에 형성된 전극을 바탕으로 하여 다양한 형태의 태양전지가 형성되기 때문에 태양전지용 투명도전성 산화물 전극에 대한 중요성이 증가하고 있다. 예를 들어 실리콘 박막형 태양전지의 경우 수소 플라즈마 분위기 안정성 때문에 ZnO:Al 전극이 개발, 적용되고 있다. 이밖에도 ZnO는 나노입자, 나노로드 등의 다양한 형태를 기반으로 유기물 및 염료감응형 태양전지 전극으로 적용되고 있다. 본 연구에서는 전기화학적 방법을 이용해 나노입자, 나노로드, 나노 sheet 등 다양한 형태의 ZnO 나노구조를 형성한 후, 태양전지 적용을 위한 전기적, 광학적 특성을 분석하였다. 3차원 형태의 ZnO sheet 전극은 90% @ 550 nm 가 넘는 우수한 광특성 (Haze value)을 보였으며, 염료감응형 태양전지에 적용되었을 경우 2차원 형태의 ZnO 전극에 비해 Jsc 값이 2.5배 이상 향상되었다.

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The Spatio-temporal Distribution of Organic Matter on the Surface Sediment and Its Origin in Gamak Bay, Korea (가막만 표층퇴적물중 유기물량의 시.공간적 분포 특성)

  • Noh Il-Hyeon;Yoon Yang-Ho;Kim Dae-Il;Park Jong-Sick
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.1
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    • pp.1-13
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    • 2006
  • A field survey on the spatio-temporal distribution characteristics and origins of organic matter in surface sediments was carried out monthly at six stations in Gamak Bay, South Korea from April 2000 to March 2002. The range of ignition loss(IL) was $4.6{\sim}11.6%(7.1{\pm}1.6%)$, while chemical oxygen demand(CODs) ranged from $12.25{\sim}99.26mgO_2/g-dry(30.98{\pm}19.09mgO_2/g-dry)$, acid volatile sulfide(AVS) went from no detection(ND)${\sim}10.29mgS/g-dry(1.02{\pm}0.58mgS/g-dry)$, and phaeopigment was $6.84{\sim}116.18{\mu}g/g-dry(23.72{\pm}21.16{\mu}g/g-dry)$. The ranges of particulate organic carbon(POC) and particulate organic nitrogen(PON) were $5.45{\sim}23.24 mgC/g-dty(10.34{\pm}4.40C\;mgC/g-dry)$ and $0.71{\sim}2.99mgN/g-dry(1.37{\pm}0.58mgN/g-dry)$, respectively. Water content was in the range of $43.1{\sim}77.6%(55.8{\pm}5.6%)$, and mud content(silt+clay) was higher than 95% at all stations. The spatial distribution of organic matter in surface sediments was greatly divided between the northwestern, central and eastern areas, southern entrance area from the distribution characteristic of their organic matters. The concentrations of almost all items were greater at the northwestern and southern entrance area than at the other areas in Gamak Bay. In particular, sedimentary pollution was very serious at the northwestern area, because the area had an excessive supply of organic matter due to aquaculture activity and the inflow of sewage from the land. These materials stayed longer because of the topographical characteristics of such as basin and the anoxic conditions in the bottom seawater environment caused by thermocline in the summer. The tendency of temporal change was most prominently in the period of high-water temperatures than low-water ones at the northwestern and southern entrance areas. On the other hand, the central and eastern areas did not show a regular trend for changing the concentrations of each item but mainly showed a higher tendency during the low-water temperatures. This was observed for all but AVS concentrations which were higher during the period of high-water temperature at all stations. Especially, the central and eastern areas showed a large temporal increase of AVS concentration during those periods of high-water temperature where the concentration of CODs was in excess of $20mgO_2/g-dry$. The results show that the organic matters in surface sediments in Gamak Bay actually originated from autochthonous organic matters with eight or less in average C/N ratio including the organic matters generated by the use of ocean, rather than terrigenous organic matters. However, the formation of autochthonous organic matter was mainly derived from detritus than living phytoplankton, indicated the results of the POC/phaeopigment ratio. In addition, the CODs/IL ratio results demonstrate that the detritus was the product of artificial activities such as dregs feeding and fecal pellets of farm organisms caused by aquaculture activities rather than the dynamic of natural ocean activities.

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Octadecyltrichlorosilane Self-Assembled Monolayers에 따른 FTIR 분석

  • Kim, Jong-Uk;Kim, Heung-Bae
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2007.06a
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    • pp.43-46
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    • 2007
  • 기존 사용되어온 절연막의 $SiO_2$의 절연특성이 신호의 간섭 등의 문제가 있어서 절연특성을 좋게 하기 위해 낮은 유전상수와 비결정질의 절연막을 요구하고 있다. 본 연구에서는 OTS를 이용하여 액상 상태에서 SAMs를 형성하였으며 FTIR을 이용한 결합구조의 변화를 살펴보았다. OTS 유기물의 함량을 0.1%에서부터 0.9%까지 다르게 혼합하여 희석시킨 유기화합물 용액에 따른 $650\;cm^{-1}$에서 $4000\;cm^{-1}$까지 전구간에 대한 FTIR 스펙트라를 보았다.

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가막만 표층 퇴적물의 금속 물질 분포 및 지화학적 특성

  • 이재성;김성수;정래흥;김귀영;박승윤;박종수
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2000.10a
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    • pp.165-166
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    • 2000
  • 가막만은 반폐쇄성 해역으로 해수의 유통이 잘 되지 않고 주변에 여수시의 생활하수가 유입되는 곳이다. 또한 양식어장 증가 및 화학공장의 건설 등 다양한 오염원의 증가로 만 북부에서는 하계에 빈산소 현상이 주년 나타나고 있어 수산피해가 우려된다. 본 연구의 목적은 표층퇴적물과 주상 퇴적물에 함유된 유기물과 금속성분을 분석하여 각 성분의 지화학적 특성을 이해하고 이들 물질의 오염원 분포 및 강도를 추정하는데 있다. (중략)

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고속 및 광전자응용을 위한 반도체 첨단연구의 동향과 미래의 전망

  • Lee, Il-Hang
    • Electronics and Telecommunications Trends
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    • v.3 no.4
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    • pp.25-44
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    • 1988
  • 고속 및 광전자응용에 기반이 될 반도체들과 그 architecture 에 대한 연구 경향과 미래적 전망에 대하여 개괄적으로 살펴보았다. 주요점은 무기물 반도체에 두었고, 유기물 반도체 및 기타 반도체들은 필요한대로 언급할 뿐 넓게 다루지는 않았다. 우선 현대가 처한 정보처리의 전환기적 특성을 살핀뒤, 미래에 다가올 고속 및 광전자 정보처리의 필요성을 논하였다. 다음 전자와 광자의 특성을 비교해 보고, 이들의 매개체가 되는 반도체 재료와 소자들, 이들의 2차원적 집적과 3차원적 집적에 따른 제반문제, 해결점, 전망 등을 살펴 보았다. 결론적으로 점진적연구보다는 선진적연구의 필요성을 이야기하였다.

Change In Soil Properties After Cucumber Cultivation Under Plastic Film House At Gunwi-Gun Area (군위지역 오이 시설 재배지의 토양특성 변화)

  • Lee, Dong-Hoon;Choi, Choong-Lyeal;Kim, Kwang-Seop;Kim, Pyoung-Yeol;Seo, Jeong-Woo;Park, Man
    • Current Research on Agriculture and Life Sciences
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    • v.24
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    • pp.43-47
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    • 2006
  • The soils of plastic film houses in which intensive cultivation takes place suffer from the serious problems such as severe salinity and accumulation of heavy metals etc. The objective of this research was to examine the change in soil properties with repeated cucumber cultivation under plastic film house at Gunwi-Gun area. The soils were classified mainly to Danbuk and SinJung series. Clay content is lower in the soils of plastic film house than in the field soil. Available $P_2O_5$ and exchangeable cations were accumulated at the level higher than the optimum range. The content of extractable heavy metals were higher in the soils of plastic film house than in those of the field. For optimum yield, much attention should be paied to the management of soils by the pre-soil survey.

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Aluminum Solubility of Andisols in Jeju Island, Korea (제주도 Andisol 토양의 Al-용해도 특성)

  • Lee, Gyoo-Ho;Song, Yun-Goo;Moon, Ji-Won;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.89-104
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    • 2012
  • The solubility of aluminum for two Andisol profiles formed on pyroclastic materials and basaltic rocks from Jeju Island, Korea was investigated. It is found that high organic carbon content and $Al_{pyrophosphate}/Al_{oxalate}$ ratios in the A horizons, suggesting the substantial amounts of reactive Al are associated with organic matter, whereas the low organic carbon content and the $Al_{pyrophosphate}/Al_{oxalate}$ ratios in the Bo horizons indicate that a major part of the reactive Al should be bound inorganically. The differential FT-IR spectra following acid-oxalate dissolution and heating up to 150 and $350^{\circ}C$, and transmission electron microscope (TEM) observation confirm that imogolite is in the Bo horizon. Our results of equilibration experiments demonstrate that the Al solubility in the Bo horizon for Andisols can be clarified by the congruent dissolution model for imogolite-type material (ITM), rather than by the simultaneous equilibrium with both ITM and Al hydroxy-interlayered aluminosilicate. With results from dialysis and aging procedures, it is noted that the formation of a proto imogolite sol showing its transformation to imogolite, which supports the congruent dissolution of ITM primarily controlling the Al solubility of Andisols in Jeju Island, Korea.

Soil Properties in Quercus mongolica Communities (신갈나무림의 군집별 토양특성)

  • 박관수;장규관
    • Korean Journal of Environment and Ecology
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    • v.12 no.3
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    • pp.236-241
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    • 1998
  • This study was to compare soil characteristics among Quercus mongolica communities that characterize the boreal-temperate deciduous forest in Korea. The classification of Quercus mongolica community and soil sampling were carried in Mt. Odae and Mt. Jungwang in Kangwondo from April of 1991 to October of 1994. The study area was classified as 5 Quercus mongolica communities with Braun-Blanquet method as follows; Quercus mongolica - Abies nephrolepis, Quercus mongolica - Acer pseudosieboldianum, Quercus mongolica - Lindera obtusiloba, Quercus mongolica - Acer mandshuricum, and Quercus mongolica - Carpinus cordata communities. Quercus mongolica - Abies nephorolepis community had the most shallow depth of A horizon(5cm) among communities, and root penetration was mainly from 0 to 10cm soil depth, and they had a dry soil moisture condition. Depth of A horizon of Quercus mongolica - Lindera obtusiloba and Quercus mongolica - Acer mandshuricum communities was about 20cm, and root penetration was mainly from 0 to 20cm soil depth, and they had a slightly dry soil moisture condition. Quercus mongolica - Acer mandshuricum, and Quercus mongolica -Carpinus cordata communities had the deepest depth of A horizon(35cm) and root was well developed over 45cm, and they had a moderately-slight dry soil condition. The soil organic matter, total N, exchangeable Ca, Mg and K concentration and CEC was the greatest in Quercus mongolica-Acer mandshuricum community and Quercus mongolica-Carpinus cordata community among communities. Quercus mongolica - Abies nephyolepis community had the smallest soil organic matter, total N, and CEC among communities. There were large differences among Quercus mongolica communities by soil properties and the result may be due to different habitat positions in the landscape among communities.

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Comparison of Ocean Optical Properties Between the Micronesia and the Korean Peninsula (남태평양 마이크로네시아와 한반도 주변 해역의 해수 광학특성 비교)

  • Moon, Jeong-Eon;Choi, Jong-Kuk
    • Korean Journal of Remote Sensing
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    • v.37 no.5_1
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    • pp.1125-1133
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    • 2021
  • This study attempted to understand seawater characteristics like chlorophyll concentration (CHL), total suspended matter concentration (TSM), absorption characteristics, and remote sensing reflectance around Weno Island, Micronesia, located in the South Pacific Ocean near the equator. 50 in-situ measurement from May to June 2013 were analyzed and compared with data from around Korean peninsula. CHL around Weno Island was 0.11-0.49 mg/m3 (average 0.26 mg/m3), and TSM was 0.03-0.31 g/m3, (average 0.16 g/m3), showing typical clear water characteristics. Absorption coefficient of total suspended matters at 443 nm showed over 0.5 times less than that from East Sea and the slope of absorption coefficient spectrum of dissolved organic matter showed much larger than that of Korean peninsula, indicating the concentration of organic matter is very low and dissolved organic matter of marine origin is considered to be the main component in the study area. As a result of comparing the remote sensing reflectance spectrum with that of coastal waters around the Korean peninsula, coastal waters around Weno Island showed typical CASE-1 water properties. It was possible to understand the marine optical characteristics of coral reef habitats in tropical waters, and it can be used to develop seawater algorithms specialized in the study area.

Changes of the Soil Physic-Chemical Properties and Rice Productions with Organic Materials used in Organic Culture (벼 유기재배에 있어서 유기자재처리에 따른 토양 및 수량 특성 변화)

  • Kim, Hyun-Woo;Kim, Sun-Kook;Seo, Youn-Won;Kim, Hong-Jae;Son, Bo-Gyon;Chung, Doug-Young
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.286-286
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    • 2009
  • 벼 유기재배시 토양양분공급용으로 이용되고 있는 유기자재(금수강산골드)를 대조로 하고 식물성유기 자재(쌀겨팰렛), 동물성유기자재, 식물성과 동물성이 혼합된 유기자재를 질소 성분량(7kg/10a)을 기준으로 하여 이앙 20일전에 전량 기비로 시비하고 경운한 다음 동진1호를 시험품종으로 하여 2년연속 유기 자재와 벼를 재배하면서 일어나는 토양의 이화학적 특성과 벼 생육 및 특성의 변화를 시기별로 조사하였다. 시험 전 토양의 화학성은 전반적으로 유기물은 높고 인산함량은 매우 낮은 조건의 토양이었다. 관행유기자재(금수강산골드)는 20일경에 50% 무기화율을 보였으나, 식물성자재 40~60일경, 동물성자재와 혼합자재(식물성+동물성)는 60~80일경에 47~52% 무기화 정도를 나타내 식물성 자재의 무기화 속도가약 20일정도 빨랐다. 토양 중의 유기물 잔존함량은 식물성자재 > 혼합자재 > 동물성자재 > 관행 순이었으며, 토양 중의 전 질소 잔존함량의 경우 관행유기자재는 처리초기부터 빠르게 감소하는 특성을 보이나, 식물성자재와 혼합 자재는 시비초기와 거의 비슷한 수준을 유지하였고, 동물성 자재는 서서히 감소되는 경향이었다. 토양 물리성은 액상과 공극율 다소 증가되는 경향이었으며 식물성과 혼합유기자재처리구가 컸으며, 토양 유효 입단 형성력에 있어서도 유사한 경향이었다. 벼 수량 특성은 관행유기자재보다 1년차에는 3~9%의 낮았으나, 2년 연속처리를 할 경우 관행유기자재를 처리할 때와 동일한 생산성을 기대할 수 있었다. PME와 $\beta$-Glucosidase의 효소활성은 관행유기자재 < 식물성자재 < 동물성자재 < 혼합유기자재의 순으로 높은 경향을 볼 수 있었다.

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