• Title/Summary/Keyword: 유기물화

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A Study on the Influence of the Organic Matter Contents in Soil Deposited of Chlorine Gas (염소의 토양 침적특성에 미치는 토양 내 유기물 함량의 영향)

  • Song, Bo Hee;Lee, Kyung Eun;Yim, Sang Sik;Lee, Jin Han;Jo, Young Do
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.1-5
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    • 2017
  • In the event of toxic gas accidents, soil deposition is a main factor which has an effect on extent of the damage. In this study, it presents the influence of soil deposition properties according to the change of soil depth and the organic matter contents in soil. In this experimentation, the soil deposition device developed in Air Force Research Laboratory in USA is recreated. The tested samples of mixing soil have each value of the organic matter contents. After a variety of synthetic soil were exposed to constant Cl2 concentration, the chlorinity is measured using an anion exchange chromatography(ICS-1100) to quantify the mount of deposition. As the results, the increase of soil depth causes an decreased soil deposition and the increase of exposure time causes an increased soil deposition in surface. Also, the increase of soil deposition mainly depended on the organic matter contents in surface.

Evaluation of pure oxygen with MBR(Membrane Bio Reactor) process for anaerobic digester effluent treatment from food waste (순산소의 MBR(Membrane Bio Reactor) 공정 적용을 통한 음식물류 폐기물 혐기성소화 유출수 처리 평가)

  • Park, Seyong;Kim, Moonil;Park, Seonghyuk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.3
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    • pp.5-16
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    • 2021
  • In this study, the applicability of the MBR(Membrane Bio Reactor) process of oxygen dissolve was evaluated through comparison and evaluation of the efficiency of oxygen dissolve device and conventional aeration device in the explosive tank within the MBR process. The organic matter and ammonia oxidation by oxygen dissolve device were evaluated, and the efficiency of persaturation was evaluated by applying real waste water (anaerobic digester effluent treatement from food waste). SCOD and ammonia removal rates for oxygen dissolve device and conventional aeration device methods were similar. However, it was determined that the excess sludge treatment cost could be reduced as the yield of microorganisms by oxygen dissolve device is about 0.03 g MLSS-produced/g SCOD-removed lower than that of microorganisms by conventional aeration device. The removal rates of high concentrations of organic matter (4,000 mg/L) and ammonia (1,400 mg/L) in anaerobic digester effluent treatment from food waste were compared to the conventional aeration device and the oxygen dissolve device organic matter removal rate was approximately 13% higher than that of the conventional aeration device. In addition, for MLSS, the conventional aeration device was 0.3 times higher than for oxygen dissolve device. This is believed to be due to the high progress of sludge autooxidation because the dissolved oxygen is sufficiently maintained and supplied in the explosive tank for oxygen dissolve device. Therefore, it was determined that the use of oxygen dissolve device will be more economical than conventional aeration device as a way to treat wastewater containing high concentrations of organic matter.

Changes of the Substances during Composting of Industrial Wastewater Sludge (공단폐수슬러지의 퇴비화과정 중 물질변환)

  • Lee, Hong-Jae;Cho, Ju-Sik;Lee, Sung-Tae;Heo, Jong-Su
    • Journal of the Korea Organic Resources Recycling Association
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    • v.5 no.2
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    • pp.17-28
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    • 1997
  • To study the possibility of agricultural utilization of industrial wastewater sludge, the changes of the substances, such as temperature, pH, inorganic and organic matter, the form of nitrogen, fatty acid and the population number of microorganisms during composting periods were investigated. Temperature and $CO_2$ generation were the highest in the second day of composting peroids, and then were gradually fallen. And they were similar to room temperature after the sixth day of composting periods. C/N ratio was a little increased as time went by. pH value was not changed in early composting periods and then pH had been gradually decreased since it was rapidly increased. It was in the range of 8.7~8.8 in late composting periods. The contents of $P_2O_5$, $K_2O$, CaO, MgO and Fe were a little increased and that of ${SO_4}^{2-}$ was increased with 62~67% in late in comparing with early composting periods. The contents of ether extracted materials, water soluble polysaccharides, hemicellulose and cellulose were decreased but that of resins and lignin were not changed during composting periods. The contents of total and organic nitrogen were decreased but that of inorganic nitrogen was increased during composting periods. The population number of microorganism during composting periods was too much changed according to the kinds of bulking agents and microorganisms, and the composting periods.

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Preliminary Study on Arsenic Speciation Changes Induced by Biodegradation of Organic Pollutants in the Soil Contaminated with Mixed Wastes (유기물분해에 따른 유류${\cdot}$중금속 복합오염토양내 비소화학종 변화의 기초연구)

  • 이상훈;천찬란;심지애
    • Economic and Environmental Geology
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    • v.36 no.5
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    • pp.349-356
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    • 2003
  • As industrial activities are growing, pollutants found in the contaminated land are getting diverse. Some contaminated areas are subject to mixed wastes containing both organic and inorganic wastes such as hydrocarbon and heavy metals. This study concerns with the influence of the degradation of organic pollutants on the coexisting heavy metals, expecially for As. As mainly exists as two different oxidation state; As(III) and As(V) and the conversion between the two chemical forms may be induced by organic degradation in the soil contaminated by mixed wastes. We operated microcosm in an anaerobic chamber for 60 days, using sandy loam. The soils in the microcosm are artificially contaminated both by tetradecane and As, with different combination of As(III) and As(V); As(III):As(V) 1:1, As(III) only and As(V) only. Although not systematic, ratio of As(III)/As(Total) increase slightly at the later stage of experiment. Considering complicated geochemical reactions involving oxidation/reduction of organic materials, Mn/Fe oxides and As, the findings in the study seem to indicate the degradation of the organics is connected with the As speciation. That is to say, the As(V) can be reduced to As(III) either by direct or indirect influence induced by the organic degradation. Although Fe and Mn are good oxidising agent for the oxidation of As(III) to As(V), organic degradation may have suppressed reductive dissolution of the Fe and Mn oxides, causing the organic pollutants to retard the oxidation of As(III) to As(V) until the organic degradation ceases. The possible influence of organic degradation on the As speciation implies that the As in mixed wastes may be have elevated toxicity and mobility by partial conversion from As(V) to As(III).

The Effect of Application Adjusted C/N Ratio of Orgaic Matter Resources on Soil Chemical Properties and Growth of Watermelon in Plastic Film Houses (시설재배지 유기물자원 C/N율 조절 시용시 토양화학성 및 수박의 생육에 미치는 영향)

  • Kang, Bo-Goo;Lim, Sang-Cheol;Lee, Joung-Won
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.304-305
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    • 2009
  • 시설재배지의 토양화학성 변화는 작물재배 기간 시비한 화학비료에서 유래된 무기성분 뿐만아니라, 가축분퇴비의 질소성분의 토양잔류량이 요소비료 보다 9.4배 많아 염류집적 주 요인이라는 보고('05 경기도)가 시사하는 봐와 같이 유기자원으로 시용하는 가축분 등의 부산물비료의 무기화에서 유래된 비료성분이 토양염류집적 및 토양환경악화에 더 큰 영향을 미칠 수 있다. 시설재배지의 유기물자원 시용기준이 토양의 특성에 관계 없이 작물에 따라 양적인 시험성적이 주로되어 있으며, 토양검정에 의한 시용기준도 유기물함량에 따라 볏짚, 우분, 돈분 및 계분으로 돠어 있다. 일반노지와 달리 시설재배지에서는 유기물함량이 토양의 비옥도 및 작물생육에 영향을 미치는 것 보다는 토양의 전기전도도(EC)가 더 중요한 작물생육 조건이 될 수 있다. 따라서 토양의 특성에 따라 물질순환에 의한 유기자원 시용기준으로 개선할 필요성이 있다. 시설재배지의 장기적인 토양관리를 위하여 유기물자원에 의한 토양환경 개선 효과를 구명하고자. 무처리, 가축분부산 물비료 관행 시용 기준 대비 볏짚 등 5개의 유기자원을 토양의 무기태질소 함량 대비 유기자원의 탄소함량을 C/N율 10 조절량을 시용하여 시험하였고, 또한 토양의 전기전도도(EC)가 상이한 3개( <2.0 dS/m, 2.0~6.0 dS/m, 6.0 dS/m<)토양에 유기물자원(우드칩)을 C/N율 10, 20, 30 조절하여 수박을 시험작물로 비닐하우스에서 재배하여 수행하였다. 시험 후 토양의 전기전도도(EC)는 시험 전에 비하여 시험 후 토양에서 가축분부산물비료는7% 증가되었으나 유기물자원 처리는 26~33% 경감되는 효과가 있었다. 수박의 과중은 무처리를 제외하고 처리간에 차이가 없었다. 유기물자원 C/N율 조절간에는 시험전 토양의 EC에 따라 차이가 있어 C/N 10 조절에서는 26~44%, C/N 20 조절에서는 30~51%, C/N 30 조절에서는 27~48% 경감효과가 있었으며, 3토양의 평균 토양EC 경감율은 C/N 10, 20, 30 조절에서 각각 34, 39 및 38 % 이었다. 수박의 생육 및 과중은 토양의 C/N율 조절간에는 차이가 없었으나, 토양의 EC 간에는 토양의 EC가 6.0dS/m 이상 토양에서 가장 낮았다. 따라서 탄소원의 유기자원을 C/N율 조절에 의한 시용기준 개선으로 토양의 무기태질소와 토양의 전기전도도(EC)를 경감시켜 친환경적 토양관리와 수박의 수량과 품질을 향상시킬 수 있을 것으로 평가되었다.

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UV Effects on Production and Photoreactivity of Chromophoric Dissolved Organic Matter in Media of Polar Marine Phytoplanktons (극지 식물플랑크톤의 유색 용존 유기물의 생산과 광반응성에 대한 자외선 영향)

  • Park, Mi Ok;Ha, Sun-Yong
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.5
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    • pp.712-720
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    • 2022
  • In this study, we evaluated the production and photoreactivity of CDOM of two polar phytoplanktons - Phaeocystis antarctica and Phaeocystis pouchetii, in order to find out UV effects on phytoplanktons. In visible region, CDOM in media of both phytoplanktons under UV-R decreased during 48hrs incubation period. However, in UV region CDOM decreased 30 % in the media of P. antarctica, but increased 10% in media of P. pouchetii, compared to CDOM concentrations of control after 48 hr incubation. This result indicates that biota in polar environment would not well protected from UV-R harmful effect when P. antarctica is dominant because of loss of CDOM, but when P. pouchetii is dominant species, production of UV absorbing organic matter could play more efficiently for UV screening for marine biota. Also we confirmed that FDOM of humic substance (C-peak) produced by these phtoplanktons under UV-R stress were well matched with fluorescence characteristics of the UV-protecting compound, MAAs. This finding shows that Phaeocystis pouchetti with low photoreactivity would contribute to DOM pool of polar marine environment under stratification by global warming.

Refractory Textile Wastewater Treatment Using Cell-Immobilized Polyethylene glycol Media (PEG 포괄고정화담체를 이용한 난분해성 염색폐수 처리)

  • Han, Duk-Gyu;Cho, Young-Jin;Bae, Woo-Keun;Hwang, Byung-Ho;Lee, Yong-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.345-350
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    • 2006
  • This study investigated the removal of recalcitrant organics in dyeing wastewater using a fluidized bed reactor(FBR) that contained cell-immobilized pellets. The pellets were manufactured and condensing the gel phase by mixing PEG-polymer and cells to form micro-porous PEG-polymer pellets whose size were ${\Phi}\;4mm{\times}H\;4mm$ on average. An industrial activated sludge without any pre-adaptation was used for the cell immobilization because it gave an equivalent removal efficiency to a pre-adapted sludges. The feed was obtained from an effluent of a biological treatment plant, which contained $SCOD_{Cr}$ of 330 mg/L and $SBOD_5$ of 20 mg/L. The $SCOD_{Cr}$ removal efficiency was over 45% and the effluent $COD_{Mn}$ concentration was less than 100 mg/L at HRTs from 6 to 24 hrs. The optimum HRT in the FBR was determined as 12 hrs considering the removal efficiency and cost. When a raw wastewater containing 768 mg/L of $COD_{Cr}$ was fed to the FBR, the effluent $COD_{Cr}$ concentration increased only slightly, giving a 70% of $COD_{Cr}$ removal or a 97% of $BCOD_5$ removal. This indicated that the FBR had an excellent capability of biodegradable organics removal also. In conclusion, the FBR could be applied to textile wastewater treatment in place of an activated sludge process.

A Study on Biomass Utilization Strategies of Hokkaido Prefecture in Japan (일본 북해도지역 바이오매스 이용에 관한 사례 연구)

  • Yook, Hye-Young;Lee, Myung-Gyu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.2
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    • pp.37-50
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    • 2009
  • This study was carried out to investigate the integrated biomass strategies for utilization and application characteristics in Hokkaido prefecture, japan. From the results, to achieve a successful operation of biomass recycling facilities, it previously needs the effective byproduct supplying construction system for field demander as well as the advanced environmental technology introduction. Especially, the value-promotion recycling technology were requested as follows; (1) production of functional solid composting for protection soil acidification, (2) the addition of soil microorganism to the production of liquid fermentation fertilizer, (3) construction of diverse energy supply system, (4) mixed organic material fermentation process concerning on heavy metal concentration, (5) introduction of incentive garbage collection system for contaminants prevention.

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