• Title/Summary/Keyword: 유기물화

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An Experimental Study on Wastewater Treatment by Modified Activated Sludge Process (변형된 활성슬러지공법의 폐수처리에 관한 실험적 연구)

  • 채수권;연기석
    • Water for future
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    • v.22 no.1
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    • pp.117-125
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    • 1989
  • This study deals with the performance of an acivated sludge system which is modified by the researcher to function without any additional chemical or internal recyle in removing organics, nitrogen, and phosphorus from synthetic wastewater. To improve the nutrient removal efficiency, the researcher utilized the anoxic, anaerobic, and aerobic reactor sequences with a single sludge return, whiched to nitrification/denitrification and phosphorus release/overplus accumulation. A bench scale system was operated with a view to investigating the reaction characteristics of each reactor, and to measuring the biological kinetic coefficients(Y, $K_d$, k, $K_s$) for theremoval of COD in relation to the mean cell residence time at five different MLSS concentrations, 5000, 4200, 3300, 2600, and 1900 mg/l. The results of the research showed that organic substance and nutrient were removed simultaneously by this modified activated sludge process. And the process kad 66%-99% ortho-p removal efficiency.

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Analysis of Organic Impurities in Terephthalic Acid Manufacturing Process (테레프탈산 제조공정 중의 유기불순물 분석)

  • Kim, Dong Bum;Cha, Woonou;Kwak, Kyu Dae
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1204-1208
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    • 1996
  • The organic impurities are formed in the p-xylene oxidation process to terephthalic acid(TPA) and they are present in the filtrate(mother liquor) solution or the TPA particles. The organic impurities present in the p-xylene oxidation are formed through side reactions or incomplete reaction. In this study, the main organic impurities, such as benzoic acid, p-toluic acid, p-tolualdehyde, 4-carboxybenzaldehyde, phthalic acid, isophthalic acid, trimellitic acid, and 4-hydroxymethyl benzoic acid were identified simultaneously by gas chromatograghy. The above impurities were reacted with bis(trimethylsilyl)trifluoroacetamide in the mixture of internal standard solution and pyridine solution by trimethylsilylation, where the internal standard solution was made by 99% bis (trimethylsilyl)trifluoroacetamide and 1% trimethylchlorosilane. The main organic impurities above mentioned can be analyzed quantitatively within 50 min.

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Characteristic Reactions in Anaerobic Nitrogen Removal from Piggery Waste (돈사폐수의 혐기성 질소제거공정에서 일어나는 특이반응)

  • Hwang, In-Su;Min, Kyung-Sok
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.300-307
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    • 2006
  • Anaerobic ammonium oxidation(ANAMMOX) is a novel process fur treatment of piggery waste with strong nitrogen. In this study, we investigated acid fermentation of organic matter, denitrificatiot reduction of sulfur compounds and P crystalization by hydroxyapatite during the treatment of wastewater with high strength of ammonium and organic matters by ANAMMOX process. Also, functions of hydroxylamine and hydrazine as intermedeates of ANAMMOX process were tested. This study reveals that various complex-reactions with anaerobic ammonium oxidation of piggery waste are happened and hydroxylamine and hydrazine play an important role in ANAMMOX reaction.

A Gas Chromatographic Detector using Glow Discharge (글로우 방전을 이용한 기체크로마토그라피 검출기)

  • Han Chong Soo;Song, Seung Ho
    • Journal of the Korean Chemical Society
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    • v.35 no.4
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    • pp.350-354
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    • 1991
  • Characteristics of a gas chromatographic detector using glow discharge as the ionization source was studied in helium flow. Discharge current greater than 10$_6$ A was observed from the electric field 400 V/mm for the electrode distance 1 mm. The discharge current of 0.1~0.3 mA could be used for the detection of organic compounds. Discharge current was almost constant for the helium flow rate greater than 10 ml/min, but the discharge was easily disappeared by an injection of a small amount of organic compound in the flow rate of 0~30 ml/min. From the decrement of the discharge current depend on several compounds, it was suggested that the sensitivity of the glow discharge ionization chromatographic detector is strongly influenced by the molecular weight of the compounds.

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Hydrocarbon-Organic Composite Membranes for Improved Oxidative Stability for PEMFC Applications (연료전지용 탄화수소 전해질 막의 산화안정성 향상을 위한 유기물 복합막의 제조 및 특성 분석)

  • Park, Satbyul;Lee, Hyejin;Bae, Byungchan
    • Journal of the Korean Electrochemical Society
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    • v.19 no.2
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    • pp.45-49
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    • 2016
  • In order to mitigate oxidative degradation of polymer membrane during fuel cell operation, an organic radical quencher was introduced. Rutin was selected as a radical quencher and mixed with sulfonated poly(arylene ether sulfone) to prepare composite membrane. Physicochemical properties of the composite membranes such as water uptake and proton conductivity were characterized. Hydrogen peroxide exposure experiment, which can mimic accelerated oxidative stability test during fuel cell operation, was adopted to evaluate the oxidative stability of the membranes. The composite membranes containing Rutin showed similar proton conductivity and enhanced oxidative stability compared to pristine ones.

A study on The Effect of Antibiotics Usage too The Efficiency of Biological Piggery Wastewater Treatment (축산물에 사용되는 항생제가 축산폐수의 처리효율에 미치는 영향)

  • Cho, Mi Kyeong;Tran, Hung Thuan;Kim, Dae Hee;Jia, Yu Hong;Oh, Se Jin;Ann, Dae Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.1
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    • pp.123-133
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    • 2007
  • The presence of antibiotics in the wastewater from livestock farm due to its over-application should be concerned because they could change microbial ecology, increase the proliferation of antibiotic resistant pathogens, provoke toxic effect on aquatic species. In addition, these antibiotics can cause negative effect on the performance of biological wastewater treatment due to its antibacterial properties. In this study, our aim is to evaluate the effect of some common used antibiotic in Korea piggery farm such as oxytetracycline (OTC) to nitrification efficiency as well as organic compounds removal rate in biological system for treating piggery wastwater. The experiment was conducted in aeration batch reactor and lab-scale $A_2/O$(Anoxic-Anoxic-Oxic) system. From this study, it would be suggested that the piggery wastewater characterization should be examined in order to assess the fraction of common used antibiotics. The alternative treatment processes for piggery wastewater having high-strength antibiotics might be suggested in the future work.

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Isolation and Enzymatic Characterization of Bacteria from Livestock Manure (축산분뇨에서 분리한 세균의 동정 및 효소학적 특성)

  • 김진선;정소선;이준석;최미영;서승염
    • Korean Journal of Microbiology
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    • v.37 no.3
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    • pp.214-220
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    • 2001
  • To develop the effective composting system, we isolated bacteria that have the abilities to degrade organic matters such as cellulose, carbohydrate, protein and lipid during the compositing of livestock manureAmong 24 strains, 6 bacteria have all the enzymatic activities of protease, amylase, cellulase and lipase.These microorganisms were identified as Corynebacterium varibilis, Bacillus spp., Pseudomonas spinosa,Acetobacter calcoaceticus and Athrobacter cumminsii All the enzymes produced by the bacteria showedactivities at the broad pH range and the maximal activities were obtained at $60^{\circ}C$. It seemed that after theincrease of temperature caused by fermentation of livestock manure, the enzymes started to degrade the rawmaterials, which are added for the control of humidity. However cellulase activity was maximum at $37^{\circ}C$,suggesting that the cellulase-producing bacteria work at an early stage of livestock manure fermentation toprovide the organic material for the growth of other bacteria. The production of the enzymes were growth-associated and maximal activities appeared at the early stationary phase of growth.

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Evaluation of Biological Organic and Nutrient Removal Performance in Intermittent MBR Systems by Computer Simulation (컴퓨터 시뮬레이션을 이용한 간헐폭기 MBR시스템에서의 유기물 및 영양염류 처리 성능 평가)

  • Yoo, Hosik;Rhee, Seung-Whee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.3
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    • pp.82-92
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    • 2013
  • The Intermittent Aeration MBR systems have the advantage of controlling reaction time by changing aeration period and are one of economic BNR systems since these processes do not require MLSS recirculation that demands capital and operation costs. In this study, two intermittent aeration MBR systems were studied by computer simulation: an intermittent aeration MBR system that had both 1hr/1hr and 4hr/4hr aeration/unaeration periods at intermittent reactor and NEW INTERMITTENT-process that was an energy saving process and certified as a new process by Korean government. Since DO concentration reached only at 0.23mg/L at intermittent reactor when it was aerated, the Intermittent aeration MBR system having 1hr/1hr aeration/unaeration period showed simultaneous nitrification/denitrification and had the highest nitrogen and phosphorus removal efficiencies that were 57% and 55%, respectively. Since this study was based on the constant influent flow and characteristics, more studies are needed to define the operational characteristics of intermittent aeration MBR systems under dynamic influent conditions.

Changes of the Soil Physic-Chemical Properties and Rice Productions with Organic Materials used in Organic Culture (벼 유기재배에 있어서 유기자재처리에 따른 토양 및 수량 특성 변화)

  • Kim, Hyun-Woo;Kim, Sun-Kook;Seo, Youn-Won;Kim, Hong-Jae;Son, Bo-Gyon;Chung, Doug-Young
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.286-286
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    • 2009
  • 벼 유기재배시 토양양분공급용으로 이용되고 있는 유기자재(금수강산골드)를 대조로 하고 식물성유기 자재(쌀겨팰렛), 동물성유기자재, 식물성과 동물성이 혼합된 유기자재를 질소 성분량(7kg/10a)을 기준으로 하여 이앙 20일전에 전량 기비로 시비하고 경운한 다음 동진1호를 시험품종으로 하여 2년연속 유기 자재와 벼를 재배하면서 일어나는 토양의 이화학적 특성과 벼 생육 및 특성의 변화를 시기별로 조사하였다. 시험 전 토양의 화학성은 전반적으로 유기물은 높고 인산함량은 매우 낮은 조건의 토양이었다. 관행유기자재(금수강산골드)는 20일경에 50% 무기화율을 보였으나, 식물성자재 40~60일경, 동물성자재와 혼합자재(식물성+동물성)는 60~80일경에 47~52% 무기화 정도를 나타내 식물성 자재의 무기화 속도가약 20일정도 빨랐다. 토양 중의 유기물 잔존함량은 식물성자재 > 혼합자재 > 동물성자재 > 관행 순이었으며, 토양 중의 전 질소 잔존함량의 경우 관행유기자재는 처리초기부터 빠르게 감소하는 특성을 보이나, 식물성자재와 혼합 자재는 시비초기와 거의 비슷한 수준을 유지하였고, 동물성 자재는 서서히 감소되는 경향이었다. 토양 물리성은 액상과 공극율 다소 증가되는 경향이었으며 식물성과 혼합유기자재처리구가 컸으며, 토양 유효 입단 형성력에 있어서도 유사한 경향이었다. 벼 수량 특성은 관행유기자재보다 1년차에는 3~9%의 낮았으나, 2년 연속처리를 할 경우 관행유기자재를 처리할 때와 동일한 생산성을 기대할 수 있었다. PME와 $\beta$-Glucosidase의 효소활성은 관행유기자재 < 식물성자재 < 동물성자재 < 혼합유기자재의 순으로 높은 경향을 볼 수 있었다.

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Rejection Behavior of 2-MIB and Geosmin Using Polyethersulfone Nanofiltration Membrane and Surface Hydrophilicity Effect Using $TiO_2$ Particles (2-MIB와 Geosmin의 Polyethersulfone 나노 분리막 배제율 거동 및 $TiO_2$ 적용 표면 친수화 효과 관찰)

  • Nam, Dowoo;Kim, Mooin;Kim, Jeonghwan
    • Membrane Journal
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    • v.22 no.5
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    • pp.326-331
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    • 2012
  • In this study, rejection behavior of 2-MIB (methylisoborneal) and geosmin which are known as taste-and-odor (T & O) causing micropollutants in drinking water source was investigated using hydrophobic polyethersulfone (PES) nanofiltration "loose" membrane (MWCO : 400 Da). It was found that the rejection of the geosmin was higher than that of the 2-MIB in all experimental conditions tested. This study also showed that the rejections of 2-MIB and geosmin were increased by increasing solution pH due to enhancing electrostatic repulsions between micropollutants and membrane surface. The presence of natural organic matter led to increase the rejection of the hydrophobic 2-MIB and geosmin and the effectiveness was more pronounced at higher solution pH. Increasing hydrophilicity of the hydrophobic membrane surface by coating with $TiO_2$ particles resulted in the significant increase in the rejection of 2-MIB and geosmin. In addition to the charge repulsion, this result suggests that hydrophobic-hydrophobic interaction should be one of main rejection mechanisms of T & O compounds by NF membrane.