• Title/Summary/Keyword: 유기물질 단량체

Search Result 4, Processing Time 0.021 seconds

Role of Polymers as Sound and Vibration Damping Materials (소음 진동 제어의 고분자 재료의 기능)

  • 여종기
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 1994.04a
    • /
    • pp.5-8
    • /
    • 1994
  • 고분자 물질은 저분자량의 유기 단량체들이 화학 공유 결합으로 연속적으로 연결된 거대 분자 구조를 갖는다. 고분자 사슬로 연결된 단량체들은 힘의 장 의 지배하에 열에너지에 따라 지속적으로 운동을 한다. 이와같은 단량체들의 운동은 국부적으로 제한되나 온도가 증가되어 유리 전이온도 이상이 되면 분자전체에 상당하는 운동으로 발전하게 된다. 이때 소음 및 진동 에너지는 효과적으로 흡수되어 열에너지로 발산된다. 본고에서는 유리 전이온도에서의 고분자 재료의 특성가 실제 소음 및 진도제어시 고려해야할 고분자 재료의 특성에 관해 알아본다.

  • PDF

The Change of Properties of reverse Osmosis Thin Film Composite Membrane according to Preparation Conditions (계면중합조건에 따른 복합막의 물성 변화)

  • Lee, Dong-Jin;Min, Byung-Ryul
    • Applied Chemistry for Engineering
    • /
    • v.8 no.2
    • /
    • pp.276-285
    • /
    • 1997
  • The theoretical and experimental analysis on polyamide used for reverse osmosis thin-film composite membrane had been conducted. The physicochemical properties of polyamide had been varied by preparation recipes which depends on kinds of monomer, solvents and polymerization time. These properties and performance as a reverse osmosis membrane had been calculated by group contribution method. The experimental results has the same trends with theoretical preview.

  • PDF

Effects of Additives on Soil Washing Efficiency for Mixed Surfactants (혼합 계면활성제에 적용된 각종 첨가제가 토양세척 효율에 미치는 영향)

  • Choi, Sang-Il;Jang, Min;Hwang, Kyung-Yub;Ryoo, Doo-Hyun
    • Journal of Korea Soil Environment Society
    • /
    • v.3 no.1
    • /
    • pp.65-74
    • /
    • 1998
  • To enhance the washing efficiency of soil polluted by hydrophobic organic compounds, the effects of electrolytes and monomeric organic additives on micelle formation and washing efficiency of mixed surfactant solutions were investigated in this study. The surface tensions and critical micelle concentrations(CMCs) of the single and mixed surfactant solutions[$POE_5$/SDS] supplemented by NaCl were measured to investigate the effects on washing efficiency, and the composition ratios of surfactants and NaCl were optimized for the efficient soil washing system. As the mixing ratio of $POE_5$/SDS was increased to 80%, the mixed surfactant with 0.01M NaCl showed more proportional increase of washing efficiency than the mixed surfactant without any salts. The 3% solution of $POE_5$ and SDS(80%/2o%) with 0.01M NaCl showed the washing efficiency of 90%. However, the washing efficiency was not enhanced by NaCl addition to the single surfactant solution of $POE_5$. The CMC of SDS(0.049%) was higher than that of $POE_5$(0.016%), but the CMCs of mixed surfactants were decreased as the mixing ratio of $POE_5$ was increased. Alcohols having longer chain and branched carbon chain were found to be desirable for the soil washing additives.

  • PDF

A Study on the Permeation Properties of Permanent Gases and condensable Vapors through Hexamethyldisiloxane Plasma-Polymerized Membranes (Hexamethyldisiloxane 플라즈마 중합막을 통한 영구기체 및 응축성 증기의 투과특성에 관한 연구)

  • Oh, Sae-Joong
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.3
    • /
    • pp.699-706
    • /
    • 2018
  • The permeation properties of plasma polymer membranes were studied for permanent gases such as He, $H_2$, $O_2$, $N_2$, $CH_4$ and condensable vapors such as $CO_2$, $C_2H_4$, $C_3H_8$. The plasma polymers were prepared by the discharge of microwave or radiofrequency(RF) wave. Hexamethyldisiloxane (HMDS) vapor was used as a monomer for plasma polymerization. In HMDS plasma-polymerized membranes prepared under microwave discharge, the permeability coefficient was dependent of the kinetic molecular diameter of the permeate gases. Additionally the membranes showed higher $O_2/N_2$ permselectivity compared to the plasma polymers from radiofrequency discharge. On the contrary, in the HMDS plasma-polymerized membranes prepared under radiofrequency discharge, the permeability coefficient was dependent of the critical temperature of the permeant gases. The membranes showed high selectivities of $C_2H_4$ and $C_3H_8$ over $N_2$. The permeability coefficient of plasma polymerized membranes prepared under microwave discharge was dependent of the molecular diameter of permeant gases because of high crosslinking density of the membrane. However, the crosslinking density of the plasma polymerized membranes prepared under RF discharge was lower because the energy density of RF wave is weaker than that of microwave. Hence, the permeability of RF plasma polymerized membranes became dependent of the critical temperature rather than molecular diameter of the gases.