• Title/Summary/Keyword: 운모편암

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Interpretation of the Manufacturing Characteristics and the Mineral and Chemical Composition of Neolithic Pottery Excavated from the Jungsandong Site, Yeongjong Island, South Korea (영종도 중산동 신석기시대 토기의 광물 및 화학조성과 제작특성 해석)

  • Lee, Chan Hee;Kim, Ran Hee;Shin, Sook Chung
    • Korean Journal of Heritage: History & Science
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    • v.51 no.1
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    • pp.4-31
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    • 2018
  • The Neolithic pottery excavated from the Jungsandong site has been classified into four types of pottery (I: feldspar type, II: mica type, III: talc type and IV: asbestos type) according to their mineral composition. These four types of potteries generally appear to have undergone incomplete firing, while the level of oxidation in the type I pottery objects, which have a relatively higher clay content, was found to be particularly low. The type III objects, which have a high talc content, are judged to have been somewhat slow in removing carbon because they contain saponite belonging to the smectite group. Of the four types of pottery, type IV showed the highest redness and the most uniform characteristics, thus indicating a good level of oxidation. In particular, fixed carbide (C; 33.7 wt.%) with a thickness of about 1mm, and originating from organic substances, was detected inside the walls of the type I pottery, while the deep radial cracks in the outer surfaces of the pottery are thought to have been caused by repeated thermal shocks. Given that all of the pottery except for the type I artifacts are considered to be have been made for storage purposes, those containing talc and tremolite are easy to done liquid storing vessels based on an analysis of their material characteristics. As for the type II relics, which are composed of various minerals and exhibit poor physical properties, they seem to have been used for simple storage purposes. As domestic talc and asbestos mines were concentrated in the areas of Gyeonggi, Gangwon, Chungbuk, and Chungnam, it seems likely that talc and tremolite were produced as contiguous minerals. Considering the distance between the remains in Jungsandong and these mines and their geographical distribution, there is a possibility - albeit somewhat slight - that these mines were developed for the mining of various minerals. Although ultramafic rock masses - such as serpentine capable of generating talc and tremolite - have not been found in the Jungsandong area, limestone and biotite granite containing mica schist have been identified in the northwestern part of Yeongjong Island, indicating that small rock masses might have formed there in the past. Therefore, it is judged necessary to accumulate data on pottery containing talc and tremolite, other than the remains in Jungsandong, and to investigate the rocks and soils in the surrounding area with greater precision. The firing temperatures of the pottery found at the Jungsandong site were interpreted by analyzing the stability ranges of the mineral composition of each type. As a result, they have been estimated to range from 550 to $800^{\circ}C$ for the type I artifacts, and from 550 to $700^{\circ}C$ for the type I, II and IV artifacts. However, these temperatures are not the only factors to have affected their physical properties and firing temperature, and the types, particle sizes, and firing time of the clay should all be taken into consideration.

Phase equilibria between coexisting minerals in the talc ores and process of talc formation in the Daeheung Talc Deposits, Korea (대흥활석광상에 있어서 공존하는 광물의 상평형과 활석화 과정)

  • 이상헌
    • The Journal of the Petrological Society of Korea
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    • v.3 no.2
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    • pp.156-170
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    • 1994
  • The talc ore deposits can be divided into chloritic and dolomitic ores according to mineral assemblages. The former is mainly composed of chlorite and talc accompanied with dolomite, muscovite and opaque mineral, and the latter of dolomite and talc with serpentine, calcite and magnesite in places. Talc was originated from chlorite and serpentine. Carbonate minerals were formed either directly from the introduced hydrothermal solution or secondarily as a by-product of steatitization of chlorite and serpentine. The process of talc formation may be governed by the chemical composition of the host rocks and the amount and/or chemical composition of the hydrothermal solution which may be different in places. However, the representative reactions producing talc from chlorite and serpentine are as follows : (1) chlorite+$Mg^{++}+Si^{4+}+H_2O$=talc, (2) chlorite+$Mg^{++}+Si^{4+}+Ca^{++}+CO_2+O_2+H_2O$=talc+ dolomite+ magnesite, and (3) serpentine +$Mg^{++}+Fe^{++}+Si^{4+}+Ca^{++}+CO_2+H_2O$=talc+dolomite. The reactions indicate that the carbonate minerals can be formed when the hydrothermal solution have high $fO_2$ and $fCO_2$. The steatitization might be proceeded by the hydrothermally metasomatic reaction between chlorite schist or chlorite gneiss intercalated in the granitic gneiss and hydrothermal solution accompanied to the wet granitization.

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Metamorphism of gneiss complex in the Paju-Gimpo area, northwestern Gyeonggi massif, Korea (경기육괴 북서부의 파주-김포지역에 분포하는 편마암복합체의 변성작용)

  • Ahn, Kun-Sang;Park, Young-Seog;Kim, Cheong-Bin;Chen, Jiangfeng
    • The Journal of the Petrological Society of Korea
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    • v.7 no.3
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    • pp.177-189
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    • 1998
  • Proterozoic gneisss complex of the Paju-Gimpo area, Northwestern Gyeonggi Massif, consists of mainly gneiss and schist with locally intercalated quartzite and metamorphic calcareous rocks. Mineral assemblages of the gneiss and schist are classified into two type: sillimanite free (garnet zone) and sillimanite bearing (sillimanite zone) assemblages. In the Goyang area, Kyanite occurs as metastable relict grain in two gneiss samples, in which sillimanite, garnet, biotite, K-feldspar and plagioclase occur. Cordierite bearing mineral assemblages of gneiss are biotite+garnet+sillimanite+cordierite+plagioclase+quartz ($\pm$K-feldspar, muscovite), and represent the upper amphibolite or granulite facies metamorphism. The metamorphic complex has experienced two different regional metamorphism. The prograde metamorphism is a medium-pressure type characteries by kyanite. The peak metamorphic P-T condition of the prograde metamorphism calculated from the kyanite bearing rock is 7.0~9.4 kb and $718~778^{\circ}C$. The retrograde metamorphism, after the prograde metamorphism, is the low-pressure type characteries by occurrence of cordierite. The peak metamorphic P-T condition of later calculated from the cordierite bearing rock is 3.6~5.5 kb and $750~889^{\circ}C$. Together with the occurrence of relict kyanite, garnet+biotite+plagioclase assemblage as relict in the cordierite, and the result of estimated P-T metamorphic conditions indicate a clockwise P-T path.

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Granulite-facies metamorphism and P-T evolutionary path of cordierite gneisses in the Cheongpyeong-Yangpyeong area (청평-양평 지역에 분포하는 근청석 편마암의 백립암상 변성작용과 P-T 진화 경로)

  • 조윤호;조문섭;이승렬
    • The Journal of the Petrological Society of Korea
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    • v.5 no.1
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    • pp.52-65
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    • 1996
  • Precambrian metamorphic rocks of the Cheongpyeong-Yangpyeong area, central Gyeonggi massif, comprise gneiss, schist, quartzite and amphibolite. Mineral, assemblages of pelitic gneisses are characterized by biotite + cordierite + garnet + sillimanite + K-feldspar + plagioclase + quartz together with minor muscovite, spinel and corundum, and represent the granulite facies metamorphism. In particular, kyanite occurs as fine-grained relict phase inside plagioclase of three gneiss samples. Metamorphic conditions are estimated from garnet-biotite and garnet-cordierite geothermometers in conjunction with garnet-$Al_2SiO_5$-quartz-plagioclase (GASP) and garnet-rutile-$Al_2SiO_5$-ilmenite (GRAIL) geobarometers. They are 700-$850^{\circ}C$ and 3.2-8.3 kbar, and 580-$690^{\circ}C$ and 2.1-3.2 kbar, respectively, when the core and rim compositions of garnet are use. Garnet of the GASP assemblage increases rimward in the Fe and Mn contents but decreases in the Mg content, whereas its Ca content does not vary significantly. Together with the occurrence of relict kyanite and the result of P-T estimates, compositional zoning patterns of garnet indicate a clockwise P-T history. Moreover, the preservation of high-pressure minerals such as kyanite in plagiocalse, even after the medium-pressure granulite facies metamorphis, suggests a rapid change in P-T conditions.

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Chemistry of Chlorite and Its Genetic Significance in the Talc Deposits in the Yesan-Gongju-Cheongyang Area, Chungnam, Korea (충남 예산-공주-청양지역의 활석 광산에서 산출되는 녹니석의 화학적 특징과 광상 성인과의 관계)

  • 김건영;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.8 no.2
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    • pp.91-107
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    • 1995
  • 충남 예산-공주-청양지역의 대흥, 평안, 신양(청당)광산에서 산출되는 녹니석에 관하여 화학적 및 성인적 연구를 하였다. 이들 광상은 초염기성암기원의 사문암이 열수변질작용을 받아 생성되었다. 활석 광석의 주 구성 광물은 활석, 녹니석, 금운모, 각섬석류, 사문석, 탄산염광물 등이고 이밖에 감람석, 휘석류, 크롬철석, 스멕타이트, 녹니석/스멕타이트의 혼합층상광물들과 같은 팽윤성 광물들이 소량 산출된다. 이 중 감람석과 크롬철석은 광상의 초염기성암 기원을 지시하는 중요한 광물이다.녹니석은 활석 광석의 불순 광물 중 가장 많은 양을 차지하는 광물이다. 이들 녹니석은 성인적으로 활석과 밀접하게 연관된 녹니석과 그렇지 않은 녹니석의 두 가지 뚜렷한 타입으로 나뉘어지며 이들은 화학적으로 명확한 차이를 보인다. 전자의 녹니석은 Mg/(Mg+Fe)비가 높으며 매우 일정한 범위의 Mg/(Mg+Fe)qkl (0.784∼0.951/산소수 14 기준)를 보여주고, 높은 8면체 치환양 (0.892 (-0.200∼0.692)/산소수 14, 이상적인 클리노클로어/차모사이트 성분 기준)과 넓은 범위의 Al 함량 변화 (2.975 (1.085∼3.160)/산소수 14 기준), 높은 Cr, Ni 함량을 갖는다. 이들은 매우 제한되고 높은 Mg/(Mg+Fe)비를 갖는 환경에서 생성되었으며 따라서,활석과 밀접하게 연관된 녹니석은 생성시, 주변암에 둘러싸여 있는, 초염기성암 기원의 사문암에 의해 주로영향을 받았다. 후자의 녹니석은 전자의 녹니석에 비하여 Fe 함량이 더 놓으며 광범한 범위의 Mg/(Mg+Fe)비 (0.378∼0.852/산소수 14 기준)를 보여주고, 더 적은 범위의 8면체 치환양 (0.560 (-0.035∼0.525)/산소수 14, 이상적인 클리오클로어/차모사이트 성분 기준)과, 전반적으로는 더 높은 값을 가지면서 더 좁은 범위의 Al 함량 변화 (1.491 (1.468∼2.959)/산소수 14 기준)를 보여주며, 낮은 Cr, Ni 함량을 갖는다. 이들은 낮은 Mg/(Mg+Fe)비를 갖고 전자에 비해 Al이 풍부한 환경에서 생성되었으며, 따라서 활석과 연관되지 않은 녹니석은 생성시 광체와 인접한 화강아질 편마암에 의해 주로영향을 받았을 것으로 생각된다. 녹니석의 이러한 2가지 화학조성상의 경향은 녹니석과 공존하는 운모류나 각섬석류들의 화학분석결과와도 잘 일치한다. 이러한 결과는 이 지역의 활석 광상이 초염기성암 기원의 사문암이 열수변질작용을 받아 생성되었음을 명확하게 지시하며, 따라서 활석 광석내에 존재하는 녹니석은 활석의 근원 광물로서 녹니석편암 및 녹니석 편마암 매의 녹니석이 활석화되고 남은 잔존광물이 아니라, 주변암에 의해 성분상의 영향을 받은 열수와 사문암과의 변질교대작용에 의한 활석화과정 중에 주로 생성된 것으로 추정된다. 이러한 결과는 연구지역의 활석광상이 초염기성암의 사문암화 작용과 활석화 작용의 두 가지 변질작용에 의해 형성되어졌음을 알려준다.

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Application of Yeongdong Illite to Remove Radiocesium for Severe Nuclear Accidents (원자력 중대 사고에 대비한 영동 지역 일라이트의 방사성 세슘 흡착 특성 평가)

  • Hwang, Jeonghwan;Choung, Sungwook;Park, Chan-Soo;Han, Jeong-Hee;Jeon, Sodam
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.4
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    • pp.229-238
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    • 2016
  • This study evaluated potential application of illite, which is produced at Yeongdong area in Korea, to remove radiocesium released to environmental system through severe nuclear accidents. The Yeongdong illite was formed by metamorphose of micaceous schist in hydrothermal condition, and composed of quartz, illite, and albite. Sorption distribution coefficient ($K_d$) of cesium by the Yeongdong illite was higher than the $K_d$ values for other clay minerals. It may be affected by preferential adsorption of cesium to Frayed Edge Sites (FES) on illite. Nonlinear isotherm models were suitable to describe the sorption processes for the Yeongdong illite. Its max. single layer capacity was $250,000{\mu}g\;kg^{-1}$ for cesium. Therefore, the Yeongdong illite could be an efficient and economic sorbent to prevent dispersion of radiocesium, and apply for remediation.

Text integration processing based on connectives in Aphasics (실어증 환자의 접속사 정보처리에 관한 연구)

  • Kim, Soo-Jeong;Moon, Young-Sun;Kim, Mi-Ra;Kim, Yoo-Jeong;Nam, Ki-Chun
    • Annual Conference on Human and Language Technology
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    • 1999.10e
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    • pp.441-446
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    • 1999
  • 본 연구는 접속사를 통한 텍스트 통합 과정이 논리적 추론 종류에 따라 다른 정보처리 과정 혹은 다른 종류의 단원적 구조(modular structure in language processing)에 의해 처리되는지를 조사하기 위해 실시되었다. 또한, 접속사를 통한 추론 과정이 실어증의 증상 종류에 따라 다른 종류의 언어정보처리 손상이 있는지를 평가하기 위해 실시되었다. 실험에 참가한 환자는 이해성 실어증환자(Wernicke aphasic), 전반성 실어증 환자(Global aphasic), 표현성 실어증 환자(Broca aphasic) 등이었다. en 종류의 과제를 이용하였다. 한 과제는 앞 뒤 문장을 논리적 관계성을 표현하는 접속사를 채워 넣는 과제였고 다른 과제는 접속사가 포함된 텍스트가 옳은지를 판단하는 정오 판단 과제였다. 실험재료 문장에 사용된 접속사는 추가적인 정보를 제공하는 '그리고'와 대등 관계를 나타내는 '그러나' 및 인과 관계를 표현하는 '그래서' 였다. 이 세 종류의 접속사는 각기 다른 논리적 관계성을 나타낸다. 실험 결과는 실어증 환자가 전반적으로 채워 넣기 과제에서 보다는 정오 판단 과제에서 더 많은 실수를 보였으며, 표현성 실어증 환자보다는 이해성 실어증 환자가 더 많은 오류를 보였다. 또한, 세 종류의 접속사 중에 '그리고'가 표함된 텍스트에서 더 많은 실수를 보였다. 이 연구에서 나타난 흥미 있는 결과는 표현성 실어증 환자는 '그러나' 접속사가 포함된 텍스트에서의 수행이 '그래서'가 포함된 경우에서보다 좋은 반면에 전반성 실어증 환자는 '그래서'를 포함하는 텍스트에서의 수행이 '그러나'를 포함하는 텍스트에서의 수행이 더 우수해서 이중해리(double dissociation)가 나타난다는 사실이다. 이 결과는 선후 문장이 어떤 종류의 논리적 관계성을 지니는가에 따라 다른 종류의 정보처리가 진행된다는 것을 암시하는 결과이다.>$\textrm{cm}^2$.。C로 비교적 양호한 초전박막의 전기적 특성을 나타내었다.(Mg+Fe)비를 갖고 전자에 비해 Al이 풍부한 환경에서 생성되었으며, 따라서 활석과 연관되지 않은 녹니석은 생성시 광체와 인접한 화강아질 편마암에 의해 주로영향을 받았을 것으로 생각된다. 녹니석의 이러한 2가지 화학조성상의 경향은 녹니석과 공존하는 운모류나 각섬석류들의 화학분석결과와도 잘 일치한다. 이러한 결과는 이 지역의 활석 광상이 초염기성암 기원의 사문암이 열수변질작용을 받아 생성되었음을 명확하게 지시하며, 따라서 활석 광석내에 존재하는 녹니석은 활석의 근원 광물로서 녹니석편암 및 녹니석 편마암 매의 녹니석이 활석화되고 남은 잔존광물이 아니라, 주변암에 의해 성분상의 영향을 받은 열수와 사문암과의 변질교대작용에 의한 활석화과정 중에 주로 생성된 것으로 추정된다. 이러한 결과는 연구지역의 활석광상이 초염기성암의 사문암화 작용과 활석화 작용의 두 가지 변질작용에 의해 형성되어졌음을 알려준다.농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회로의 복귀가 빠르며, 고위험군에 적용할 수 있고, 무엇보다도 미용상의 이점이 크다는 면에서 자연기흉에 대해 유용한 치료방법임에는 틀림이 없으나 개흉술에 비해 재발율이 높고 비용이 비싸다는 문제가 제기되고 있는 만큼

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Lithological Characteristics and Provenance Consideration on the Jade Investiture Books of Joseon Dynasty in National Palace Museum of Korea (국립고궁박물관 소장 조선왕조 옥책의 암석학적 특징과 산지검토)

  • Lee, Chan Hee;Park, Jun Hyoung
    • Economic and Environmental Geology
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    • v.52 no.5
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    • pp.485-497
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    • 2019
  • The Jade Investiture Books in Joseon Dynasty shows diverse facies with various petrographic characteristics to green and white based on color. In lithologically, the green rocks are jade composed of calcite and serpentine, and the white ones are marbles consisting mainly in crystalline calcite. As a result of X-ray diffraction of jade rocks, the more green in color, the more increased intensity of serpentine appears. Therefore, the grade of jade is correlated with contents of serpentine. The Jade Investiture Books owned by the National Palace Museum of Korea are subdivided with 104 (41.3%) books made by only jade rocks, 98 (38.9%) books made by only marbles, and 50 (19.8%) books mixed with jade rocks and marbles. Among the mixed ones, 47 (18.6%) books consisted mainly of the marbles. This result shows the superior marble books occupy more than half of the total books. The Jade Investiture Books made in early Joseon Dynasty are composed of high grade jade. However, the grade of jade had decreased as the kings changed in process of time, and the composition of marble had increased in reverse proportion of jade. The quality of letter pigments, metal accessories and fabrics also had decreased with jade. These trends are reflected in the aspect of society such as weakening royal authority, national power and finance with the course of time. The jade of the books has different mineralogical characteristics from some modern jade produced in Chuncheon nephrite and Buyeo precious serpentine in Korea. Meanwhile, there is ancient literature that described quarries from Namyang in Hwaseong of Gyeonggi province. This area has a wide distribution of gneiss, limestone and limesilicate rocks are interbedded between muscovite schist. The limesilicate rocks contain diopside, which produced serpentine through alteration. It has possibility to make the Jade Investiture Books using these small amounts of jade through mining activity.

A Review on the Depositional Age and Provenance of the Taean Formation in the Western Gyeonggi Massif (서부 경기육괴에 분포하는 태안층의 퇴적시기와 기원지에 대한 고찰)

  • Choi, Taejin;Park, Seung-Ik
    • Economic and Environmental Geology
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    • v.52 no.5
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    • pp.347-356
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    • 2019
  • Various studies regarding the sedimentary environment, depositional age, provenance, and metamorphic history have been carried out on the Taean Formation in the western part of Gyeonggi Massif, since the unique detrital zircon age pattern was revealed. This review paper introduces the previous researches on the Taean Formation and discusses the depositional age and provenance. The Taean Formation was traditionally regarded as a Precambrian stratigraphic unit, but recently it is interpreted to be a middle or upper Paleozoic formation due to the occurrence of large amounts of Early to Middle Paleozoic detrital zircons. The Taean Formation consists of metasandstone, argillaceous schist, and phyllite which are mainly made up of quartz and mica. The protoliths are interpreted as turbidites deposited in deep sea fan environment. The Taean Formation has been interpreted to be deposited between the Devonian to Triassic ages given the age differences between detrital zircons and intrusive rocks. There are two opinions that the deposition age is close to the Devonian or the Permian period. The provenance of this formation is supposed to be South China block, Chinese collisional belt, or Gyeonggi Massif. Given the available detrital zircon ages of the Taean Formation and other Korean (meta)sedimentary rocks, the Taean Formation shares major source rocks with Yeoncheon Group and Pibanryeong Unit of the Okcheon Supergroup, but their source regions are not entirely consistent. Considering the existing hypotheses about the depositional timing and provenance, we put weight on the possibility that the Taean Formation was deposited between Permian and Early Triassic periods. However, further studies on the stratigraphy and sedimentary petrology are needed to clarify its definition and to elucidate the provenance.

Metamorphism of the Gyeonggi Massif in the Gapyeong-Cheongpyeong area (가평-청평 지역 경기육괴의 변성작용)

  • Lee Kwang Jin;Cho Moonsup
    • The Journal of the Petrological Society of Korea
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    • v.1 no.1
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    • pp.1-24
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    • 1992
  • Precambrian metamorphic rocks of the Gapyeong-Cheongpyeong area consist of banded gneiss, augen gneiss, leucocratic gneiss, quartz schist and quartzite, together with minor intercalations of serpentinite, amphibolite and marble. Mineral assemblages of meta-sedimentary rocks are classified into three types: sillimanite-free; sillimanite-bearing; and sillimanite+K-feldspar-bearing assemblages. Compositions of metamorphic phases depend on the type of mineral assemblages. In particular, the Ca contents of plagioclase and garnet are high in sillimanite-free assemblges. Kyanite occurs in three samples, and coexists with sillimanite in one sample. The presence of kyanite indicates that metamorphic rocks of the study area have experienced the Barrovian type metamorphism. Peak metamorphic conditions estimated from various geothermobarometers and phase equilibria are 618-674$^{\circ}C$ and 6.5${\pm}$2.0 kbar for sillimanite-free assemblages, and 701-740$^{\circ}C$ and 4.4${\pm}$0.8 kbar for sillimanite-bearing assemblages, respectively. Furthermore, a clockwise P-T-time path is deduced for the study area, based on the following observations: (1) the polymorphic transition of kyanite to sillimanite, (2) the occurrence of sillimanite and K-feldspar belonging to the upper amphibolite facies, and finally (3) the retrograde metamorphism characterized by muscovite-, chlorite-, and actinolite-bearing assemblages.

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