• Title/Summary/Keyword: 용해 평형

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Development of Power Plant Simulator for Control System Verification & Validation (제어 검증용 발전소 시뮬레이터 개발)

  • Byun, Seung-Hyun;Hwang, Do-Hyun
    • Journal of the Korea Society for Simulation
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    • v.19 no.1
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    • pp.41-51
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    • 2010
  • A control system has been being developed by korean engineers for 500MW korean standard type fossil power plant with the advent of retrofit of old control system. Simulators have been used for digital I&C system pre-tests and validation tests in nuclear power plants. In this paper, the power plant simulator for control system V&V was developed in order to verify the developed control system prior to application to a power plant. The control models were developed using plant control system data, translator programs, and vendor manuals. The developed simulator was verified by steady-state test, load swing test, transient test and so on.

The annihilation of the flow pattern defects in CZ-silicon crystal by high temperature heat treatment (고온 열처리에 의한 결정결함의 재용해)

  • 서지욱;김영관
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.3
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    • pp.89-95
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    • 2001
  • The CZ-silicon crystal was annealed at $1350^{\circ}C$ to dissolve the vacancy type grown-in defects. A this temperature, the equilibrium concentration of the oxygen in the silicon crystal is around $1.7{\times}10^{18}$ which induces the oxygen undersaturation in the silicon crystal. This situation results in the faster dissolution of the grown-in defects in the bulk of the silicon wafer than near the surface. This indicates the possibility that the presence of the higher concentration of silicon interstitial hinders the dissolution of the grown-in defects, which were known to compose of the vacancy clusters with surrounding silicon oxide film. This expectation was confirmed by the observation that the slower dissolution of the grown-in defects near the surface of the silicon wafer in the oxygen atmosphere than in the argon atmosphere. This result is quite opposite to the previous argument hat presence of the excess silicon interstitial leads to faster dissolution of the vacancy type defects.

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Permeation Characteristics of Water Vapor Through PVA/PSSA_MA/THS-PSA Membranes (PVA/PSSA-MA/THS-PSA 막의 수증기 투과특성에 관한 연구)

  • Rhim, Ji-Won;Cho, Hyun-Il;Kim, Dae-Hoon;Ha, Seong-Yong;Nam, Sang-Yong
    • Membrane Journal
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    • v.17 no.2
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    • pp.140-145
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    • 2007
  • In this study, 3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA) was added to poly(vinyl alcohol) (PVA) membranes crosslinked with poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA) to improve the separation characteristics toward water vapors in the air. The prepared membranes varying both PSSA_MA and THS-PSA amounts were also synthesized at different cross linking temperatures. Then, in order to investigate the separation characteristics of the resulting membranes, the dynamic vapor sorption (DVS) and vapor permeation experiments were carried out. The increase of cross-linking temperature showed longer time to reach the equilibrium sorption state from the dynamic vapor sorption experiments. PVA/PSSA_MA (3%)/THA-PSA(7%) prepared at $120^{\circ}C$ gave the highest permeability of 480 barrer at $35^{\circ}C$.

Relationship between Hydrochemical Variation of Groundwater and Gas Tigtness in the Underground Oil Storage Caverns (지하원유비축기지 공동주변 지하수의 수질화학적 변화와 기밀성과의 관계)

  • Jeong Chan Ho
    • The Journal of Engineering Geology
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    • v.14 no.3 s.40
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    • pp.259-272
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    • 2004
  • The purpose of this study is to investigate the effect of hydrochemical variation of groundwater on the gas tigtness in an unlined oil storage cavern. The groundwater chemistry is greatly influenced by the seawater mixing, the water curtain and the dissolution of grounting cements. The chemical composition of groundwater greatly varies ac-cording to both the location of monitoring wells and the sampling period. Most of groundwater shows alkaline pH and high electrical conductivity. The chemical types of groundwater show the dominant order as follows : Na-Cl type > Ca-Cl type > $Ca-HCO_3(CO_3)$ type. Thermodynamic equilibrium state between chemical composition of groundwater and major minerals indicates that carbonate minerals except clay minerals can be precipitated as a secondary mineral. It means that the secondary precipitates can not greatly exerts the clogging effect into fracture aperture in rock mass around oil storage cavern. The content of total organic carbon (TOC) shows a slightly increasing trend from initial stage to late stage. The $EpCO_2$ was computed so as to assess the gas contribution on the $CO_2$ in groundwater. The $EpCO_2$ of 0$\~$41.3 indicates that the contribution of oil gas on $CO_2$ pressure in groundwater system can be neglected.

Operational Characteristics of Methanol Reformer for the Phosphoric Acid Fuel Cell System (인산형 연료전지용 메탄올 연료개질기의 운전 특성)

  • 정두환;신동열;임희천
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.200-207
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    • 1993
  • A methanol reformer was designed and fabricated using a CuO-ZnO low temperature shift catalyst, and its operation characteristics have been studied for the phosphoric acid fuel cell (PAFC) power generation system. The type of reactor was annular Methanol was consumed both for heating and for reforming fuel. Contents of carbon monoxide produced from the reformer increased as the reaction temperatures increased, but decreased as the mole ratios of water to methanol(H$_2$O/CH$_3$OH) increased. At steady state operating conditional, temperature profile of the catalytic reactor of the reformer was well coincide with the model equation, and it took 50 minutes from start to the rated condition of the reformer. When the system was operated at 4/4 and 1/4 of load, thermal efficiencies of the system were 72.3% and 77%, respectively. When the PAFC system was operated with reformed gas in the range of 62 V-37.6 V and 0-147 A, the trend of I-V curve showed a typical fuel tell characteristic. At steady state condition, the flow rates of reforming and combustion methanol were 88.1 mol/h and 50.1 mol/h, respectively.

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Aluminum Solubility of Andisols in Jeju Island, Korea (제주도 Andisol 토양의 Al-용해도 특성)

  • Lee, Gyoo-Ho;Song, Yun-Goo;Moon, Ji-Won;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.89-104
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    • 2012
  • The solubility of aluminum for two Andisol profiles formed on pyroclastic materials and basaltic rocks from Jeju Island, Korea was investigated. It is found that high organic carbon content and $Al_{pyrophosphate}/Al_{oxalate}$ ratios in the A horizons, suggesting the substantial amounts of reactive Al are associated with organic matter, whereas the low organic carbon content and the $Al_{pyrophosphate}/Al_{oxalate}$ ratios in the Bo horizons indicate that a major part of the reactive Al should be bound inorganically. The differential FT-IR spectra following acid-oxalate dissolution and heating up to 150 and $350^{\circ}C$, and transmission electron microscope (TEM) observation confirm that imogolite is in the Bo horizon. Our results of equilibration experiments demonstrate that the Al solubility in the Bo horizon for Andisols can be clarified by the congruent dissolution model for imogolite-type material (ITM), rather than by the simultaneous equilibrium with both ITM and Al hydroxy-interlayered aluminosilicate. With results from dialysis and aging procedures, it is noted that the formation of a proto imogolite sol showing its transformation to imogolite, which supports the congruent dissolution of ITM primarily controlling the Al solubility of Andisols in Jeju Island, Korea.

Relationship between Interfacial Tension and Solubility of Diesel Fuel in Surfactant Solutions (계면활성제용액-경유 간 계면장력과 용해도 상관관계 연구)

  • Jeong, Seung-Woo;Hur, Jeong-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.70-73
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    • 2013
  • Solubility of oil contaminants in surfactant solutions plays an important role in selecting a suitable surfactant type for soil remediation. Solubility measurement procedures consist of making an equilibrium between surfactant solution and oil, solvent extraction using dichloromethane, and condensation for gas chromatography analysis. Solubility measurement requires time consumption and lots of materials. Interfacial tension is the contracting force between two immiscible liquids, surfactant solution and oil, and also closely related to solubility of oil. This study established a relationship between the interfacial tension and solubility of diesel fuel in surfactant solution and suggested a quick method to estimate solubility of oil in a surfactant solution by measuring its interfacial tension. The results of this study showed that the solubility of diesel fuel in surfactant solution was exponentially increased by decreasing the interfacial tension between two immiscible liquids. The solubility of diesel fuel was significantly increased under the interfacial tension conditions below 1 dyne/cm, while the solubility change was not apparent under the interfacial tension conditions beyond 5 dyne/cm. Interfacial tension measurements may allow us to quickly select an efficient surfactant and its concentration for soil remediation.

Development of a diaphragm type actuator (다이어프램형 방식의 파일럿 액추에이터 개발)

  • Lee, Joongyoup;Jeong, Daeseong;Han, Sangyeop
    • Aerospace Engineering and Technology
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    • v.13 no.2
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    • pp.160-166
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    • 2014
  • The shutoff valve of a Liquid Rocket Engines (LRE) controls the flow of propellant between turbo-pump and combustion devices of LRE using pilot pressure and spring force. The shutoff valve is closed when the pilot pressure is removed from the diaphragm type actuator. During designing process of life cycle is when should be analyzed according to the characteristics of forces with respect to the opening and closing of diaphragm actuator. A valve has been designed to adjust the control pressure which is required to open a poppet and to determine the working fluid pressure at which a valve starts to close. During flow capacity test under room temperature as a part of life cycle tests, the leakage in diaphragm was occurred due to the leakage of sheet welding sections. The operating cycle of the diaphragm type actuator is about 61 times with 22 MPa of pilot pressure.

Fabrication of RFID Reader RF Transceiver for 900 MHz Bandwidth (900 MHz 대역 RFID 리더용 RF 트랜시버 설계 및 제작)

  • Kim Bo-Joon;Kim Chang-Woo;Kim Nam Yoon;Kim Young-Gi
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.1A
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    • pp.58-64
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    • 2006
  • A 900-MHz band transceiver has been developed for RFID reader applications. In the transmitter, a GaAs SPST switch is used for high speed switching and low power consumption. In the receiver, a double balanced mixer is used to compress even-harmonic products. The ASK demodulator which consists of an active filter and comparator is used to reject the unwanted in band interferers. The transceiver produces a maximum transmitting power of 30 dBm and exhibits an 5 m communication range with a 6-dBi gain antenna.

Recent Developments in High-Flux Heat Transfer Tubes (最近의 高性能傳熱管의 開發)

  • 서정윤
    • Journal of the KSME
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    • v.18 no.3
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    • pp.18-24
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    • 1978
  • 열고환기에는 boiler와 같이 다량의 열 energy를 취급하는 것을 비롯하여 가정용 냉장고, 냉방기 기와 같이 비교적 적은 양의 열 energy를 취급하는것, 가종 고온 gas-gas 열교환기, 초전도송전 등의 초저온기기에 부속되는 저온열교환기 혹은 배열회수, 태양열이용을 위한 장치에 포함되는 열교환기등이 있으며, 그 종류와 내용에 있어서 다양하다. 따라서 새 형식의 열교환기 혹은 우수 한 전열특성을 갖는 표면, 형상을 갖는 전열관의 연구, 개발은 한층더 절실하게 요망된다. 최근주 목을 받고 있는 열교환기용전열관중에는 관축방향을 따라 표면을 파상으로 가공한 것(corrugate 식)과 축과 평형이 되게 만든 좁은 흠을 갖는 관(fluted tube)등이 있는데 이들에 있어서는 다같 이 표면의 요철에 의한 면부근의 난동을 촉진시켜서 우수한 대류열전달의 특성을 갖도록 하고 있다. 한편 응축과 비등등의 상변화를 동반하는 열전달에 대해서는 세구, 기공질금속층, 세공등을 갖는 면에 관해서 새로운 관심이 집중되고 있다. 이 후자의 전열면은 유축열전달에서는 평활면보 다 약10배의 높은 열전달율을 가지며 불등열전달에서는 벽면과 액의 온도차는 평활면의 경우보다 약1/5의 값을 갖는다. 동시에 한계열유속은 5활이상으로 증가시킬 수 있음이 알려져 있다. 따라서 본론에서는 후자의 전열면중에서 최근에 알려진 비약적으로 높은 전열성능을 갖는 전열면에 관해 서 소개하기로 한다.

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