• Journal of Korean Society of Water and Wastewater
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• v.30 no.6
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• pp.683-690
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• 2016

Modified coagulants were investigated for the removal of phosphorus from secondary effluent of wastewater treatment. The modified coagulants were prepared by mixing alkali earth metal ions such as calcium and magnesium. The basicity of a coagulant influenced on the removal of phosphorus, and coagulants with basicity of 5.9% showed a better removal of total phosphorus than that of 38.5%. Also, coagulants with alkali earth metals enhanced the performance of coagulation by 10% and resulted in 67.1% for total phosphorus removal. Moreover, the removal of suspended solids and chemical oxygen demand was improved using coagulants with low basicity and earth metal ions. Results of this study demonstrated that the use of coagulants with low basicity, and calcium and magnesium ions is recommended to improve wastewater effluent quality.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.5
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• pp.630-638
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• 2021

In this study, we investigated the effects of dissolved inorganic and organic nutrient on the growth of dinoflagellate Alexandrium affine (LIMS-PS-2345). The maximum uptake rates (ρ_max) and half saturation constants (Ks) calculated from the uptake kinetics experiment were 77.0 pmol/cell/hr, 17.6 μM for nitrate and 15.5 pmol/cell/hr, 3.88 μM for phosphate, respectively. These results suggested that this species has high inorganic nutrient demand and a low affinity for inorganic nutrients. During the utilization of organic nutrients for A. affine, growth rates of experimental groups added by organic nitrogen (urea and glycine) and phosphorus (adenosine triphosphate and glycerol phosphate) were above 70 %, compared to the experimental groups added by inorganic nutrients. Thus, A. affine may need to utilize organic nutrients to understand the dominant strategy and advantageous position in the interspecific competition within low inorganic nutrient environments.

• Analytical Science and Technology
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• v.24 no.5
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• pp.378-386
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• 2011

The goal of this study is to understand the influence of temperature on phosphorus release rate from soil into water. As the temperature increases, $PO_4$-P reaches equilibrium more quickly and the equilibrium concentration increases, and thus the $PO_4$-P concentration increases, and pH decreases. The $PO_4$-P concentration affects pH. $PO_4$-P released from turbidity is not adsorbed onto the turbidity. $PO_4$-P was independent on the turbidity and yet $PO_4$-P was steadily increasing. However, $PO_4$-P was dependent upon the turbidity concentration as the turbidity releases $PO_4$-P. The total phosphorous (T-P) and turbidity were directly linked because T-P changed with the turbidity. T-P includes the $PO_4$-P content of water and the phosphorus content of the turbidity. As the temperature decreases, density of water increases, and the precipitation of turbidity decreases, resulting in an increases in T-P concentration. As the temperature increases, the T-P concentration decreases, but the PO4-P release rate from turbidity increases. At the same time, even at different temperatures, the T-P concentrations of the samples were about the same. When the lake gets deepened, the water temperature decreases, hence, the phosphorus release rate from soil into water was decreased. This mechanism is of great interest because phosphorus is released from soil sediment into the lake water.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.19-19
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• 2011

수중방전은 다양한 라디칼을 직접 물 속에서 발생시키기 때문에 수처리 공정에 다양한 응용이 가능하다. 특히, 최근에 선박평형수 등의 살균이 국제적인 이슈가 되고 있고, 2017년까지는 모든 선박에 살균을 위한 수처리 설비가 의무화된다. 본 연구에서는 염분이 있는 수체에서의 방전공정을 연구하고 이를 수처리공정에 적용할 수 있는 방법에 대해 연구하였다. 해수의 경우 전도도가 53mS로 자유로운 전하의 이동이 가능하기 때문에 일반적인 민물방전의 전원과 전극 등으로는 방전을 할 수 없다. 이에 세라믹과 금속의 이중구조로 되어 있는 모세관전극을 개발하여 전도성이 있는 수체에서의 방전을 이루었다. 전원장치로는 60 Hz, 380 V를 1차측에 인가하여 2차측에서 약 3 kV, 10 kW의 파워가 발생하는 12위상차 교류전원장치를 개발하여 사용하였다. 모세관 내부에 전압이 인가되면 전류가 발생하여 joule heating에 의하여 모세관 내부에 기포가 형성된다. 이 때, 전류의 단락이 이루어지면서 고전압쪽에 전하가 축적되며 기포내부의 E-field가 상승한다. 이후 기포 내에서 방전이 개시되며 각종 라디칼을 생성한다. 방전에 의해 생성되는 산화제로는 오존, OH라디칼, 과산화수소 등이 있으며, 해수에서는 Cl-의 결합에 의하여 Cl2 가스가 발생한다. 약 30,000 J/L의 체적에너지에 대하여 생성되는 총염소의 농도는 2.5 mg/L이다. 수중방전의 적용대상으로 선박평형수, 멤브레인과의 결합, 용존기포부상법을 선정하여 적용가능성을 연구하였다. 먼저 선박평형수 살균처리를 위해 해수의 처리유량을 20 lpm으로 유지하고 대장균, 바실러스, 조류(테트라셀미스) 등을 투입하여 전극 12개가 삽입된 12위상차 플라즈마 반응기를 통과시켰더니, 약 30,000 J/L의 체적에너지에 대하여 1일 후의 살균력이 각각 99.99, 99.99, 99.9%의 살균력을 나타내었다. 이는 국제해사기구에서 권장하는 살균수준인 99.9%를 초과하는 수치이다. 플라즈마를 이용한 해수살균공정의 안정적 운전을 위해 후단에 UF멤브레인을 추가하여 잔류생존 미생물을 제거할 수 있다. 이를 위해 플라즈마가 후단의 멤브레인 운전에 미치는 영향을 평가하였다. 카올린과 탄산칼슘을 오염원으로 각각 투입하여 멤브레인으로 처리를 하였을 때, 방전 직후 멤브레인에 걸리는 막간압력차가 약 30% 감소하였는데, 이는 막에 형성된 파울링이 방전에 의해 제거된 것으로 평가할 수 있다. 수중방전은 다양한 산화제를 생성함과 동시에 미세기포를 발생시키는데 이는 수중유기물의 부상분리에 적용될 수 있다. 방전모세관전극의 내부직경을 1 mm로 유지하고, 60 Hz, 교류전원으로 방전한 결과 평균입경 44 um의 기포를 발생시켰고, 이는 일반적으로 용존공기부상법에 사용되는 기포의 크기와 일치한다.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.4
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• pp.241-248
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• 2009

A farming area located near an abandoned copper mine in GuPo-ri, Choongchung province is heavily contaminated with heavy metals such as As, Pb, Cd, Cu and Zn of which concentrations are higher than the values typically detected in Korean soil environment. In this work, laboratory and field studies were conducted to examine feasibility of using Ca-citrate-phosphate solution in stabilizing heavy metals in the polluted soils. In laboratory batch experiments with field soil, the addition of Ca-citrate-phosphate solution resulted in decrease of aqueous phase concentration of phosphate and improvement of heavy metal stabilization, compared to those for sterilized soil samples. This indicates that microbial uptake of phosphate may have provided positive effects on availability of phosphate toward heavy metal stabilization. According to microbial community analysis for the field experiment, the use of Ca-citrate-phosphate led to increased diversity of microbial populations, and strict anaerobic microorganisms such as Anaerofilum and Treponema became the most dominant populations in the solution-amended field experiments. These findings suggest that, when Ca-citrate-phosphate is used for heavy metal stabilization in soils, microbial processes may have important roles in improving the stabilization of heavy metals by providing reducing conditions to the treatment locations or/and by making phosphate available to heavy metal stabilization.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.24 no.1
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• pp.21-30
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• 1991

In Summer, oxygen-deficient water masses were developed extensively in the closed eutrophic bays such as Chinhae Bay which results in mass mortality of marine organisms and severe decrease the production of the bay every year. Under the circumstances, this study was performed to investigate the oxygen depletion relating to eutrophication, and also to evaluate self-purfication capacity of Buk Bay by dissolved oxygen mass balance in 1988. The mean concentration of total inorganic nitrogen, phosphate phosphorus and chlorophyll-a were $11.06{\mu}g-at/l,\;0.80{\mu}g-at/l\;and\;1.11mg/m^3$ respectively, which were over eutrophication criteria. Oxygen-deficient water mass was formed in July with the minimum concentration of 2.08ml/l(mean) at the bottom of all stations and recovered slowly in August. The decay and reaeration coefficient calculated from dissloved oxygen sag curve were 0.222/day and 0.018ml/l/day, respectively. To maintain above 4ml/l of oxygen to prevent oxygen-deficient water mass, it is recommendable to supply as much as 0.856ml/l/day of dissolved oxygen or should be reduced the same mass loading of BOD from watershed by the construction of wastewater treatment plant.

• Journal of Korea Water Resources Association
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• v.48 no.1
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• pp.9-21
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• 2015

This study examined pollution level of sediment in Sookchun lake, and studied dredging validity by examining phosphorous release characteristics on surface polluted soil. Total phosphorous, the principal cause of algal blooms, exceeded dredging assessment standards regarding Daechung lake (1.5 mg/g) at all points. Also at all points, total nitrogen exceeded the dredging assessment standard regarding Paldang Lake (1.1 mg/g), but fell short of the standard regarding Daechung lake (3.0 mg/g). Dredging zone was suggested in this study is Chuso water body (WS-6~WS-12) in Sookchun lake. In relation to sediment pollution levels measured at different depths, LOI tended to decrease as it became deeper. The concentrations of T-N varied depending upon the depth as well as points, but no regular pattern was observed. The depth and site did not significantly influence T-P. From the results of phosphorous release tests, it was shown that total phosphorous release flux was calculated to be $7.2{\sim}15.4mg/m^2/d$ for anaerobic condition, $0.5{\sim}2.0mg/m^2/d$ for aerobic condition and $2.0{\sim}4.1mg/m^2/d$ for facultative condition. Release flux and T-P concentration of surface sediments had positive correlation ($R^2$ 0.7871). And The corelation between release flux and DO condition in reactor had strong negative correlation ($R^2$ 0.8824).

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.290-290
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• 2019

최근 우리나라 수자원 오염의 심각성에 관한 인식이 커지고 있으며, 수질 및 조류 관리의 필요성이 다양한 분야에서 증가하고 있다. 우리나라의 경우 초여름부터 장마 이전과 장마 이후부터 10월까지 호소의 영양 단계가 조류의 성장에 충분한 상태이기 때문에 남조류가 대량으로 증식된다. 하지만 기상 조건에 따라 조류의 발생 시기와 발생 정도는 매년 다르게 나타날 수 있다. 한편, 조류를 포함한 수질 모의 모형은 현재의 상태에 대한 정확한 모사를 통해 수질 관리와 미래의 예측 등 다양한 방면으로 활용된다. 따라서 복잡한 현상을 모형을 통해 재현하는 것은 중요하다. 본 연구에서는 대청호 지역을 대상으로 CE-QUAL-W2 모형을 이용하여 2016년 1월부터 2018년 7월까지 수질 및 조류의 거동을 모의하였다. 금강의 지류 하천인 소옥천에 위치한 옥천천 측정소부터 대청호 내부의 대청댐5 구간을 상류 및 하류 경계로 설정하였고, 수질 및 조류의 모의를 위해 물환경 정보시스템과 실시간 수질 정보시스템의 관측자료 및 대청댐의 운영 자료, 기상청의 기상관측 자료를 수집하였다. 모형의 안정화(warm up) 기간을 고려하여 2015년 1월부터 2018년 7월까지 주요 수질 항목인 수온, 용존산소, 총 인, 총 질소, 클로로필-a에 대한 분석을 수행하였고, 연구대상 지역 내의 대청댐6 지점의 관측값과 모의 결과를 비교 분석하였다. 수온과 용존산소, 클로로필-a의 경우 모의 결과가 관측 값을 비교적 잘 모사하였지만, 총 인과 총 질소의 경우 자동 수질 측정지점의 값과 일반수질 측정 지점의 측정 방법의 차이로 인해 오차가 다소 발생하는 것을 확인할 수 있었다. 본 연구는 CE-QUAL-W2 모형을 이용한 수질 및 조류 모의에 관한 연구로서, CE-QUAL-W2 모형을 이용한 수질 및 조류 관리에 활용될 수 있을 것으로 판단된다.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.24 no.4
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• pp.519-534
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• 2019

When the fresh water from the artificial lakes (Ganwolho and Bunamho) were discharged to Cheonsu Bay in summer to prevent the flood over the reclaimed farmland near the lakes, the impact on water qualities (nutrients, organic matters, trace metals) within the bay was investigated through four surveys (June, July, August and October, 2011). Dissolved inorganic nitrogen (DIN) increased about as much as 3-4 times over the whole water column when the freshwater was discharged. And the main species composition of DIN changed from ammonia to nitrate. Dissolved inorganic phosphorus (DIP) decreased as much as 2 times in surface waters, but increased as much as 1.5 times in deep waters, and also silicate concentrations increased as much as 3-4 times in deep waters of the inner bay. The N/P ratios in Chunsu bay seawaters were much higher (2 to 7 times) than the Redfield ratio when the freshwaters were discharged, which indicated the phosphorus limiting in the phytoplankton growth. Dissolved organic carbon (DOC) and nitrogen (DON) increased as much as about 2 times. In addition, particulate organic matters (POC, PON, POP, Bio-Si) increased as much as above 2 times in the surface waters of the inner bay. Trace metals (Fe, Mn, Co, Ni, Cu) increased in the surface waters of the inner bay, but dissolved Cd concentrations decreased as much as 2 times. Therefore, when the contaminated fresh waters from the artificial lakes were discharged into the bay, nutrients, organic matters and trace metals generally increased compared to normal period. Since the phytoplankton bloom occurred in the surface waters of the inner bay, dissolved oxygens at the surface waters were oversaturated and hence hypoxic in the deep waters. Highly enriched nutrients concentrations were found in deep waters of the inner bay, which was accompanied with the hypoxic condition. Finally, the water quality in the inner bay of the Chunsu bay was deteriorated from less than grade 3 in normal periods to grade 5 when the freshwaters from the artificial lakes were discharged in summer.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.26 no.4
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• pp.392-400
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• 1993

The present study was accomplished to understand the occurrence and time serial variations of oxygen-deficient watermass in wonmun Bay from 1989 to 1991. From the results of this work, oxygen-deficient water was periodically observed in bottom layer and in Summer in this region. The stratification of water began to develop in Spring and the strong formation of oxygen-deficient water showed in Summer but it gradually disappeared in Autumn. It seems that the occurring and continuing period of very low dissolved oxygen watermass is intensively controlled by meteorological conditions and vortical stratification of water column. On formation of oxygen-deficient watermass, high nutrient concentrations in the bottom layer appear to be due to release of nutrients from bottom sediment. The dissolved inorganic phosphate versus AOU shows two linear curves according to the level of AOU. In the relationships between phosphate and AOU, the gradient of a linear curve over approximately 5mg-AOU/l was significantly large, presumably indicating dissolution of phosphate from the sediment.