• Title/Summary/Keyword: 용융금속

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Surface Study on the Supported Molten Salt Catalyst (담지된 금속염 혼합물 촉매의 표면 연구)

  • Kim, Jong Pal;Lee, Kwang Hyun
    • Applied Chemistry for Engineering
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    • v.20 no.4
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    • pp.381-385
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    • 2009
  • A basic objective is the preparation and surface studies of supported molten salt catalysts because molten salts can stay as the liquid phase in the range of the ordinary reaction temperature. Many kinds of metal salt mixtures for the formation of molten salt phase are appliable but CuCl and KCl were selected in this study because Cu is considered catalytically reactive in many reactons. The loading of the molten salt was selected as 25 vol% of the total pore volume of ${\gamma}-alumina$ to provide reasonable exposed surface area. The surface structure of catalysts containing molten salts in the ${\gamma}-alumina$ was studied using scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). CuCl and KCl were added into the ${\gamma}-alumina$ using concentrated hydrochloric acid solution by the impregnation technique. The surfaces of the prepared catalysts before and after heat treatments were compared and they suggested that the heat treatment of catalysts helped the formation of molten-salt although the surface compositions of CuCl and KCl were not uniform.

Wettability of Zn and Zn-Al alloy (Zn와 Zn-Al 합금의 젖음성)

  • Kim, Su-Yeong;Bae, Dae-Cheol;Jin, Yeong-Sul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.122-122
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    • 2009
  • 금속기판과 액체금속의 젖음성은 일반적으로 액적법 (sessile drop)에 의해 고체와 액체간의 접촉각 측정을 통해서 알 수 있다. 이러한 방법에 의한 젖음성 실험결과는 고체와 액체계면에서의 반응이 무시될 수 있는 경우에 적용가는 하지만 연속용용도금공정과 같이 용융된 금속내부로 강판이 인입되는 과정에서 계면반응이 동적으로 진행되는 과정에서의 젖음성을 모사하기에는 이러한 방법의 신뢰성이 떨어지는 문제점이 있다. 따라서 본 연구에서는 실제 용융도금공정과 유사하게 소둔열처리된 저탄소강판이 환원성분위기내에서 Zn 및 Zn-Al 용융도금욕 내부로 연속적으로 인입되는 과정에서의 젖음력 및 접촉각 등의 측정을 통해 실제 도금공정상의 도금성과 젖음성의 연관성을 규명하고자하였다. 연구결과 일반적인 Zn 도금욕의 경우 젖음성이 양호하지만 Al함량이 높은 경우에는 젖음성이 좋지 못한 것으로 나타났다.

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An Experimental and Numerical Analysis of Flow of Electromagnetic Pump for Molted Metal Transport (용융금속 이송용 전자기 펌프의 유동해석 및 실험)

  • Choi, Jae-Ho;Lim, Hyo-Jae;Kim, Chang-Eob;Kwon, Jung-Tae
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2621-2625
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    • 2007
  • This study aims at analyzing the flow characteristics of the electromagnetic pump using a linear induction motor (LIM) for transferring molten metals. The flow characteristics of the pump are simulated by magnetohydrodynamic(MHD) program. In this system, the LIM is used for transferring molten metal by electromagnetic force. The molten metal is treated as the secondary part of the LIM. Since the LIM produces an electromagnetic force in the duct, the molten metal can flow from the furnace to the reservoir. The flow characteristics of the pump are analyzed using MHD program for magnetic field of 0.1[T] in duct. In order to prove the analysis, we made a prototype electromagnetic pump using LIM.

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A Fundamental Study on the Gas Atomization of Liquid Metal (용융금속 미립화에 관한 기초적 연구)

  • Kang, Min-Sung;Choi, Jong-Youn;Kim, Heuy-Dong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2777-2781
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    • 2008
  • Gas atomization of liquid metal using nozzle technology has more advantages over other methods. Previous study shows that high-velocity gas is important for effective liquid metal atomization. An important first step towards understanding the gas atomization using nozzle is complete evaluation of the flow fields. This will provide a basis for understanding how well high velocity gas is brought to bear on the liquid metal. Present work is a fundamental study of liquid metal atomization for various pressure ratio, different gas and temperature. A two-dimension, axisymmetry compressible Navier-Stokes equations are considered. Two-equation k-epsilon turbulence model is selected.

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Preparation of Magnesium from Magnesite using Fused Salt Electrolysis (마그네사이트 광석으로부터 용융염전해법에 의한 마그네슘 제조)

  • Park, Hyungkyu;Kang, Jungshin;Lee, Jinyoung
    • Resources Recycling
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    • v.26 no.3
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    • pp.69-78
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    • 2017
  • Magnesium has been used as parts of vehicles, case materials of notebook PC and mobile phone, and its demand has been increasing recently. Its extraction technologies were classified according to the two major reduction methods: the fused salt electrolysis and the thermal reduction method. A research on the extraction of magnesium from magnesite which has been being carried out at KIGAM was briefly introduced here. Magnesium was prepared using a fused salt electrolysis method through preparation of anhydrous magnesium chloride with lab scale experiments.

Options Manageing for Radioactive Metallic Waste From the Decommissioning of Kori Unit 1 (고리1호기 해체시 발생할 방사성금속폐기물 관리 옵션 연구)

  • Kessel, David S.;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.2
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    • pp.181-189
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    • 2017
  • The purpose of this paper is to evaluate several leading options for the management of radioactive metallic waste against a set of general criteria including safety, cost effectiveness, radiological dose to workers and volume reduction. Several options for managing metallic waste generated from decommissioning are evaluated in this paper. These options include free release, controlled reuse, and direct disposal of radioactive metallic waste. Each of these options may involve treatment of the metal waste for volume reduction by physical cutting or melting. A multi-criteria decision analysis was performed using the Analytic Hierarchy Process (AHP) to rank the options. Melting radioactive metallic waste to produce metal ingots with controlled reuse or free release is found to be the most effective option.