• Journal of the Korean Chemical Society
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• v.37 no.12
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• pp.1035-1046
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• 1993

Some iron(III)porphyrin complexes were prepared, and identified by the spectroscopic methods. Elution behavior of iron(III)porphyrin complexes was investigated by reversed-phase HPLC. The optimum conditions for the separation of iron(III)porphyrin complexes were examined with respect to flow rate and mobile phase strength. These complexes were successfully separated on NOVA-PAK $C_{18}$ column using methanol / water(95/5) for $[T_pCF_3PP)Fe(R)]$ and methanol / water (98/2) for $[(P)Fe(C_6F_5)]$ as a mobile phase. It was found that these complexes were largely eluted in an acceptable range of capacity factor value ($0{\leq}logk'{\leq}1$). The dependence of the capacity factor (k') on the volume fraction of water in the binary mobile phase as well as the dependence of k' on the liquid-liquid extraction distribution ratio$(D_c)$ in methanol-water / n-pentadecane extraction system showed a good linearity. It means that the retention of iron(III)porphyrin complexes on NOVA-PAK $C_{18}$ column is largely due to the solvophobic effect. Also, there was a good linear dependence of the capacity factor(k') on the column temperature and enthalpy calculated by van't Hoff plot. From these results, it was confirmed that the retention mechanism of iron(III)porphyrin complexes in reversed-phase liquid chromatography was invariant under the condition of various temperature, and the solvophobic binding process exhibited isoequilibrium behavior.

• Journal of Broadcast Engineering
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• v.16 no.5
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• pp.834-845
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• 2011

Massive broadcasting contents such as UHD(Ultra High Definition) TV which requires multi-channel capacity for transmission has been introduced in recent years. A transmission scheme with channel bonding has been considered for transmission of massive broadcasting contents. In HFC(Hybrid Fiber Coaxial) networks, DOCSIS 3.0(Data Over Cable Service Interface Specification 3.0) has already applied channel bonding schemes for up/downstream of data service. A method unlike DOCSIS 3.0 is required to introduce a channel bonding scheme in the broadcasting service having unidirectional transmission with a downstream. Since a massive broadcasting content requires several channels for transmission, VBR(Variable Bit Rate) transmission has been emerging for the bandwidth efficiency. In addition, research on channel allocation and resource scheduling is required to guarantee QoS(Quality of Service) for the broadcasting service based on VBR. In this paper, we propose a transmission method for mass broadcasting service in HFC network and show the UHD transmission simulator developed to evaluate the performance. In order to evaluate the performance, we define various scenarios. Using the simulator, we assess the possibility of channel bonding and VBR transmission for UHD broadcasting system to provide mass broadcasting service efficiently. The developed simulator is expected to contribute to the efficient transmission system development of mass broadcasting service.

• Korean Journal of Environmental Agriculture
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• v.35 no.2
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• pp.152-157
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• 2016

BACKGROUND: Since bottom ash (BA) contains considerable amounts of CaO and MgO, it could be a useful amendment to increase soil pH and to immobilize cadmium (Cd). This study was conducted to evaluate effect of BA application in reducing Cd phytoavailability.METHODS AND RESULTS: Bottom ash was applied at the rate of 0, 20, 40, and 80 Mg/ha to Cd contaminated soil, and then lettuce was cultivated under field condition. soil pH and net negative charge increased slightly with increasing BA application; however, there was no statistical difference among the rates. Water soluble, exchangeable+acidic, reducible, and oxidizable fraction of Cd decreased with increasing bottom ash application rate, whereas residual fraction of Cd increased with increasing bottom ash application rate. Lettuce yield increased with rate of bottom ash up to 40 kg/ha. Visual evidences of cadmium toxicity and growth inhibition were not found during lettuce cultivation.CONCLUSION: Bottom ash was effective to reduce phytoextractability of Cd and to increase lettuce yield. Conclusively, BA could be a good soil amendment to reduce Cd phytoavailability in contaminated arable soil.

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.689-693
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• 2010

When natural rubber dissolved in toluene comes into use as a binder of carbon powder, the volatilization of solvent just after the construction of biosensor brought the mechanical robustness on the paste. This characteristic satisfied the pre-requisite condition for the practical use of carbon paste electrode and a biosensor for the determination of hydrogen peroxide was designed. In order to evaluate its electrochemical qualitative and quantitative behaviors, various electrochemical kinetic parameters of the electrode, e.g. the symmetry factor (${\alpha}$, 0.37), the exchange current density ($i_0$, $0.075mAcm^{-2}$), the capacitance of double layer ($C_d$, $9.7{\times}10^{-3}F$), the time constant (${\tau}_A$, 0.92 s), the maximum current ($i_{max}$, $5.92{\times}10^{-7}Acm^{-2}$), the Michaelis constant ($K_M$, $1.99{\times}10^{-3}M$) and others were investigated. Results show that natural rubber is a promising binder of carbon powder.

• Journal of Astronomy and Space Sciences
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• v.24 no.4
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• pp.397-408
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• 2007

Diplexer is one of core devices needed to communicate with satellite using single ground antenna by separating uplink and downlink signal. This paper presents the design of the S-band diplexer for LEO TT&C application, especially for KOMPSAT (KOrea Multi-Purpose SATellite). To cope with requirements such as high handling power, low insertion loss, air-cavity resonator with high quality factor was considered as one of design drivers. Design was started with predicting unloaded Q and equivalent circuit from the structure of air-cavity resonator. For the convenience of adjustment, the coupling factor placed between resonators was estimated from COTSEM (Electro-Magnetic) simulator, EESOF $ADS^{TM}$, and expressed with 2-order polynomial regression. To improve the isolation between transmitting part (Tx) and receiving part (Rx), the inductive and capacitive attenuation poles were inserted between $4^{th}\;and\;6^{th}$ resonator respectively. The fabricated diplexer consists of two bandpass filters and each filter has eight resonants. From the measurement, it was shown that major requirements such as 0.5dB of insertion loss, 20dB of return loss and 100dB of isolation were fully satisfied within passband.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1995.04a
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• pp.344-349
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• 1995

셀구조물은 선박, 항공기, 우주선 등의 산업분야에 자주 사용되는 중요한 구조요소로서, 이에 대한 연구도 공학적 필요성에 의해 많은 연구가 진행되어 왔다. Maddox등의 Rayleigh-Ritz법, Srinivasan and Bobby의 적분방정식 기법, Petyt의 유한요소법, Irie, Henderson등의 전달매트릭스법, 그 외 Webster, Petyt and Deb Nath, Blevins, Srinivasan and Krishnan등에 의해 여러가지 해석방법의 진동해석이 행해져 왔다. 현재 주로 사용되고 있는 매트릭스 구조해석 및 진동해석 방법으로는 유한요소법과 전달매트릭스법을 들 수 있다. 유한요소법은 범용적인 해석 프로그램의 개발은 수월하지만 대규모의 선형 연립방정식의 해법에 귀착되므로, 기억용량이 큰 대형컴퓨터가 필요하고, 반면 전달매트릭스법은 기억용량이 적은 퍼스널컴퓨터로도 계산수행이 가능하나 고차의 고유진동수를 구할 경우나, 중간에 단단한 경탄성지지가 존재할 경우 등에는 수치계산상의 문제점이 지적되고 있다. 이에 대한 대책으로, 상태변수를 바꾸어 넣은 Riccati방법, 각 절점의 기지의 상태변수를 제거하는 Frontal법, 전달매트릭스와 강성매트릭스를 결합시키는 방법 등이 보고 되고 있다. 이에 자자들은 퍼스널컴퓨터 이용에 적합한 고속, 고정도의 구조해석 및 진동해석 기법으로 전달영향계수법을 제안하여, 원판구조물, 사각판구조물, 원통형 셀구조물 등의 여러가지 형상구조물의 자유진동 해석에 적용해서, 종래의 전달매트릭스법에 비해 계산정도 및 계산속도의 양면에서 매우 우수함을 보고한바 있다. 본 연구에서는 동적영향계수의 축차전달에 그 개념을 두고 있는 전달영향계수법을 좀 더 일반화시키고 체계화시키기 위하여 탄성지지를 갖는 셀구조물에 적용하여 자유진동 해석 알고리즘을 정식화한 후, 간단한 모델에 대한 수치실험을 통해서 전달 영향계수법으로 구한 해를 전달매트릭스법의 결과와 비교.검토하여 본 방법의 유용성을 확인하였다.

• The Korean Journal of Pharmacology
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• v.26 no.2
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• pp.167-176
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• 1990

In the present study, we examined the effects of tamoxifen and LY117018 on various parameters for the estrogenic actions in order to understand the mechanism by which tamoxifen and LY117018 act on the uterine cells in 21-23 day old immature rats. Tamoxifen and LY117018 stimulated uterine weight and uterine contents of DNA, protein, and peroxidase activity in the absence of estradiol while inhibited above parameters in the presence of estradiol. Both cytosolic and nuclear progesterone receptors were increased by the treatment of tamoxifen and LY117018 as well as estradiol, but estradiol-induced increase in the progesterone receptors were reduced by the treatment of antiestrogens. These effects were enhanced by the multiple injections of antiestrogens. It seemed that tamoxifen was more agonistic than LY117018 but less antagonistic than LY117018, judged by their effects on various parameters for the estrogenic action. The affinities of estradiol, tamoxifen, and LY117018 for the estrogen receptor were $0.17{\pm}0.01nM(100%)$, $1.10{\pm}0.01nM(6.3%)$, and $0.23{\pm}0.01nM(77%)$, respectively. Furthermore, LY117018 was the competitive ligand for the estrogen receptor in dose-related manner but tamoxifen was not. Following estradiol treatment, nuclear estrogen receptor was sharply increased by 1 h, reaching the maximum by 16 h, while tamoxifen and LY117018 slightly increased nuclear estrogen receptor by 1 h and then decreased thereafter. It is therefore concluded that LY117018 is a competitive antagonist for the estrogen receptor with less estrogenic activity, compared to tamoxifen with low affinity to the estrogen receptor, and tamoxifen may act through other binding site than the estrogen receptor.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.218.1-218.1
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• 2010

천연가스를 대체하며 21세기 신 에너지원으로 기대되고 있는 메탄 하이드레이트가 주목을 받게된 것은 1930년대 시베리아의 화학 플랜트에서 고압의 천연가스 수송용 파이프라인이 막히는 사고가 빈번하게 발생하여 그 원인을 조사한 결과, 파이프 내에서 가스와 물이 결합하여 하이드레이트를 형성하고, 그것이 파이프의 내벽에 부착되어 파이프를 막고 있다는 것으로 밝혀지면서 천연가스 하이드레이트가 주목을 받게 되었다. 또한 메탄 하이드레이트의 경우 46개의 물분자에 8개의 메탄가스 분자가 포획된 구조로, 그 분자식은 $CH_4{\cdot}5.75H_2O$이다. 따라서 메탄가스와 물의 이론적 용량비가 216:1로써, 표준상태에서 $1m^3$의 메탄 하이드레이트는 $172m^3$의 메탄가스와 $0.8m^3$의 물로 분해된다. 만약 이와 같은 특징을 역으로 이용할 경우 메탄을 주성분으로 하는 천연가스를 물에 포집시켜 인공적으로 하이드레이트를 제조할 수 있기 때문에 천연가스 수송 및 저장의 수단으로써 그 중요성이 커지고 있으며, 액화수송보다 18-24%의 비용절감이 이루어진다고 보고하였다. 그러나 인공적으로 메탄 하이드레이트를 제조할 경우 가스 포집율의 예측이 매우 어려운 것으로 알려져 있다. 따라서 본 연구에서는 동일한 조건에서 메탄 하이드레이트 형성의 반복성 실험을 10회 수행한 결과 과냉도가 클수록 최대최소차이가 줄었고 또한 교반을 시킬 경우도 최대최소차이가 줄어 들었다.

• Prospectives of Industrial Chemistry
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• v.24 no.6
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• pp.19-31
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• 2021

자극응답성 액정 엘라스토머(liquid crystal elastomer)는 하이드로겔(hydrogel), 형상 기억 고분자(shape memory polymer)와 더불어 생체 특성을 모방한 인공 근육, 소프트 액추에이터 및 소프트 로봇을 위한 스마트 소재로 최근 높은 관심을 받고 있다. 특히, 액정 엘라스토머는 고무 탄성과 액정 이방성이 결합된 비등방성 탄성 고분자로, 열, 빛, 전기 및 수분과 같은 외부자극에 반응하여 가역적이며, 액정 분자들의 배향조절을 통한 프로그램된 변형이 가능하다. 액정 엘라스토머가 개념 증명을 하는 수준을 넘어 실제로 유용한 소프트 액추에이터 및 로봇 시스템에 적용되기 위해서는 우수한 구동력 및 작업 용량, 높은 구동 변형률, 빠른 응답 시간, 낮은 구동 온도, 다양한 외부 자극반응성 및 높은 에너지 전환 효율 등을 확보하는 것이 중요하다. 본 기고문에서는 액정 엘라스토머의 개념에 대해 소개하고, 이러한 소재가 소프트 액추에이터로써 광범위하게 활용될 수 있도록 다양한 성능들을 향상시킬 수 있는 방법에 대해 소개하고자 한다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.10
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• pp.206-211
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• 2020

Tungsten alloys are used widely in general industrial fields, but they are difficult to cast, so products are manufactured using powder metallurgy. In this study, a mixed powder of tungsten, nickel, and iron homogenized using a ball mill was added to pure water as a solvent, and PVA as a binder was added to prepare a spray drying mixture. The mixed liquid was prepared using a spraying machine. A study was carried out to produce a granular powder that can reduce the variations between products during the molding and sintering process of the powder metallurgy method. A preliminary experiment was conducted to confirm the influence of the variables in the granulation process. Through the preliminary test results, this experiment was performed with the volume of solvent of the spray drying the mixture as an independent variable, and granular powder having a mean particle size similar to that of the existing mass-production conditions and an increased apparent density was prepared. In addition, a pilot test was conducted for the molding and sintering process. The improved granular powder reduced the characteristic variation (weight variation) of the mass-produced product.