• Title/Summary/Keyword: 요소 SCR

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A Study on the Injection Characteristics of Urea Solution to Improve deNOx Performance of Urea-SCR Catalyst in a Heavy Duty Diesel Engine (대형 디젤 엔진용 요소분사 SCR촉매의 deNOx 성능향상을 위한 요소수용액의 분사특성 연구)

  • Jeong, Soo-Jin;Lee, Chun-Hwan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.4
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    • pp.165-172
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    • 2008
  • Urea-SCR, the selective catalytic reduction using urea as reducing agent, has been investigated for about 10 years in detail and today is a well established technique for deNOx of stationary diesel engines. In the case of the SCR-catalyst a non-uniform velocity and $NH_3$ profile will cause an inhomogeneous conversion of the reducing agent $NH_3$, resulting in a local breakthrough of $NH_3$ or increasing NOx emissions. Therefore, this work investigates the effect of flow and $NH_3$ non-uniformities on the deNOx performance and $NH_3$ slip in a Urea-SCR exhaust system. From the results of this study, it is found that flow and $NH_3$ distribution within SCR monolith is strongly related with deNOx performance of SCR catalyst. It is also found that multi-hole injector shows better $NH_3$ uniformity at the face of SCR monolith face than one hole injector.

Preliminary Study on Factor Technology of Selective Catalytic Reduction System in Marine Diesel Engine (선박용 디젤엔진 SCR 시스템 요소 기술에 관한 기초 연구)

  • Park, Yoon-Yong;Song, Ha-Cheol;Ahn, Gi-Ju;Shim, Chun-Sik
    • Journal of Navigation and Port Research
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    • v.40 no.4
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    • pp.173-181
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    • 2016
  • From 2016, controls on reduction of NOx and SOx emissions from the vessels that are operated in the emission control area were tightened. The selectivity catalytic reduction system of the denitrification equipment which NOx among the above controlled materials is very effective and used commercially very much. But it has the disadvantage that CSR is activated at high temperatures. Therefore, the SCR and SCR activation instrument that can react even at low temperatures by using micro-nano bubbles so that the above problems can be minimized were developed. And the computational fluid dynamics technique was used by ANSYS-CFX package to prepare the plan that improves the SCR system's efficiency. Simulation for the viscous flow analysis of the SCR system was executed by applying the Navier-Stokes equation to it as a governing equation. For the SCR system's shape, 3D modeling was done by using CATIA V5. SCR jet nozzle's position was checked by changing it to the intervals of 1/3, 1/2, and 2/3 from the inlet of the vent pipe to compare the SCR system's efficiency. And the number of nozzles was compared and analyzed by simulating 4, 6, and 8 holes to check an effect of the number on the SCR system's efficiency. The simulation result has found that the closer nozzles are to the inlet of the vent pipe and the more nozzles are, the more efficiency is improved.

Experimental Study on Mixing Efficiency of Exhaust Gas and Reductant According to SCR Mixer Shape (SCR 믹서형상에 따른 배기가스와 환원제 혼합 효율에 관한 실험적 연구)

  • Choe, Munseok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.74-79
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    • 2021
  • This study examined the mixing efficiency of exhaust gas and urea according to the mixer shape in the SCR system. For the experiment, an SCR simulation system was manufactured, and a uniformity detector was attached to the catalyst location to measure the uniformity. The experiment was conducted by setting the exhaust-gas flow rate, temperature, mixer type, and catalyst distance as variables. The experimental results confirmed the swirl angle analysis, urea number distribution, and uniformity. The swirl angle experiment of Models A and B confirmed that the swirl angle of Model A was formed approximately 7 to 8 degrees higher over the entire RPM range. When there was no mixer in the SCR system, the urea and water were concentrated to one side. Mixer Model A showed an even distribution overall, and Model B showed a slightly concentrated tendency at the beginning but then showed a stable distribution of urea. The mixing efficiency of 90%, which was the uniformity target, could be satisfied in Model A and Model B. In particular, Model A showed excellent results that satisfied 90% efficiency at 10 cm of the catalyst position.

A study on Property of Emission Gas by the Content Variation of Urea (UREA의 함량 변화에 따른 배출가스 특성분석)

  • Kang, Hyungkyu;Doe, Jinwoo;Hwang, Inha;Im, Jaeheuk;Ha, Jonghan;Na, Byungki
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.24-32
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    • 2015
  • National and international regulations on the exhaust gases of diesel engines are being strengthened, and a study of the combutsion engine and the post-porcessing system are in progress as a variety of ways. There are many techniques for the removal of nitrogen oxide like HC-SCR, LNT, Urea-SCR. And the technical development on the Urea-SCR owing to high conversion efficiency and fuel economy characteristics has being processed. This study investigated the physical/chemical properties of urea according to the change of the urea content, and were analysed the characteristic of exhaust gas. According to the increase of urea content, the contests of biuret aldehyde, phosphate content was increased and the changes of emission quantity of carbon monoxide, hydrocarbons and particulate matter in the exhaust gas was very slight. The emission quantity of NOx was decreased in accordance with increasing the urea content and it was shown to be more than 80 % in the urea solution having more than 30 wt%.

A Study on the Urea-SCR System for NOx Reduction of a light-Duty Diesel Engine (소형 디젤엔진의 NOx 저감을 위한 Urea-SCR 시스템에 관한 연구)

  • Nam Jeong-Gil
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.5
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    • pp.57-63
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    • 2005
  • The effects of an urea injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine were investigated with the parameters such as urea-SCR(Selective Catalytic Reduction) and EGR system. The urea quantity was controlled by NOx quantity and MAF(Manifold Air Flow). The urea injection quantity can be controlled with the urea syringe pump, precisely. The effects of NOx reduction for the urea-SCR system were investigated with and without ECR engine, respectively. It was concluded that the SUF(Stoichiometric Urea Flow) is calculated and the NOx results are visualized with engine speed and load. Furthermore, the NOx map is made from this experimental results. It was suggested, therefore, that NOx reduction effects of the urea-SCR system without the EGR engine were better than that with the EGR engine except of low load and low speed.

선박배기가스 유해물질 저감을 위한 선박용 SCR 시스템 요소기술에 관한 소개

  • Park, Yun-Yong;Song, Ha-Cheol;Sim, Cheon-Sik;An, Gi-Ju;Park, Gi-Yeong
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2015.10a
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    • pp.77-78
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    • 2015
  • 산업화로 인하여 토지의 사막화, 물부족, 오존층 파괴, 지구 온난화 등 많은 환경문제가 발생되었으며 아직 진행 중에 있다. 이에 UN에서는 환경 규제를 강화하였으며 국제해사기구(IMO:International Maritime Organization)에서는 선박의 배기가스 규제 강화를 위하여 NOx(질소산화물) 및 SOx(황산화물)의 배기량을 줄이도록 하고 있으며 2016년부터는 본격적으로 규제하려 하고 있다. 상기의 규제 물질 중 NOx를 제거하는 선택적환원촉매(SCR:Selectivity Catalytic Reduction) 시스템은 선박의 배기가스가 지나가는 통로에 요소수(Urea)를 분무하여 $260^{\circ}C$ 이상의 높은 온도에서 요소수에 있는 암모니아가 배기가스에 있는 NOx와 반응, 결합함으로서 NOx를 질소와 산소로 분리, 제거하는 방식이다. 하지만 선박의 경우 대부분 엔진이 2행정으로 배기가스 온도가 일반적으로 $180^{\circ}C{\sim}220^{\circ}C$이기 때문에 요소수에 있는 암모니아가 배기가스에 있는 NOx와 반응하지 않아 환원률이 높지 않다. 이에 우리는 초미세기포를 이용하여 낮은 온도에서도 반응할 수 있는 요소수 및 요소수 활성화 기기를 개발하여 상기의 문제점들을 최소화 할 수 있도록 하였다. 또한 SCR 시스템의 점성유동해석을 통하여 보다 효율적인 SCR 시스템의 개발을 할 수 있도록 기여하였다.

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Numerical Study on Urea Spraying and Mixing Characteristics with Application of Static Mixer in Marine SCR System (박용 탈질 시스템의 혼합기 적용에 따른 요소수용액 분무 및 혼합특성 수치적 연구)

  • Jang, Jaehwan;Park, Hyunchul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.7
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    • pp.429-434
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    • 2016
  • Among various De-NOx technologies, Urea-based Selective Catalytic Reduction (SCR) systems are known to be the most effective in marine diesel applications. The spraying and mixing behavior of the urea-water solution has a decisive effect on the system's net efficiency. Therefore, in this study, the spray behavior and ammonia uniformity with and without a static mixer were analyzed by CFD in order to optimize the SCR system. The results showed that the static mixer significantly affected the uniformity of velocity and ammonia concentration. Static mixers may be especially suited for marine SCR systems with space constraints.

Study on the Flow Characteristics of Urea-SCR Swirl Injector according to the Needle Lift Profile (Urea-SCR용 스월 인젝터의 니들 리프트 형상에 따른 유동특성에 대한 연구)

  • Gwak, Eun-Jo;Park, Sung-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.6
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    • pp.650-655
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    • 2016
  • In this study, a computational simulation of the internal flow characteristics was carried out for a Urea-SCR Injector. A single hole swirl injector with a swirl disk and slanted nozzle was used in this simulation. The maximum needle lift and opening velocity were selected as the design parameters. To analyze the unsteady internal flow characteristics of the Urea-SCR injector, the moving grid technique was applied to simulate the delicate needle movement. According to the simulation results, the injected mass flow rate from the Urea-SCR injector decreased with increasing needle opening velocity and maximum needle lift. This is because the Urea-solution tends to fill the empty space that the needle previously occupied. The swirl flow is decreased as the flow goes through the injector nozzle, because of the friction with the nozzle wall. Also, during the maximum needle lift period, the swirl coefficient and mean swirl coefficient increase with increasing needle lift. The results of this study may be used as the basic design data of related injectors.

선박용 디젤엔진 SCR 시스템의 효율향상을 위한 점성유동해석

  • Song, Ha-Cheol;Sim, Cheon-Sik;Park, Yun-Yong
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2016.05a
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    • pp.88-89
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    • 2016
  • 선택적 환원 촉매(SCR : Selective Catalytic Reduction) 시스템은 대기오염을 예방하기 위한 배기가스 처리장치 중 하나이다. 본 연구에서는 전산유체역학(CFD : Computational Fluid Dynamics)를 사용하여 SCR 시스템 의 효율향상을 위하여 ANSYS-CFX package를 이용하여 점성 유동 해석을 수행하였다. SCR 시스템의 점성 유동 흐름의 전산 유체 역학을 이용하여 시뮬레이션하기 위하여 Navier-Stokes 방정식을 지배방정식으로 사용하였다. CATIA V5를 사용하여 SCR 시스템의 형상을 3D 모델링을 하였고, 암모니아와 배기가스의 혼합 비율을 확인하기 위해 요소수 분사 노즐의 위치를 변경하였다. 요소수 분사 노즐은 배기관의 입구로부터 1/3, 1/2, 2/3에 위치한다. 또한, 분사 노즐의 위치가 배기관 입구의 1/3에 위치할 때 노즐의 분사구수에 따른 효율을 확인하기 위하여 분사구수를 4Hole, 6Hole, 8Hole일 경우를 확인하여 비교하였다. 시뮬레이션의 결과로는 배기관 입구에 가까울수록, 분사구수가 많을수록 효율이 좋아짐을 확인하였다.

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Effect of the De-NOx Facility Operating Condition on NOx Emission in a 125 MW Wood Pellet Power Plant (125 MW급 우드펠릿 발전소에서 탈질설비 운전조건이 질소산화물 발생량에 미치는 영향)

  • Jeon, Moonsoo;Lee, Jae-Heon
    • Plant Journal
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    • v.18 no.3
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    • pp.52-61
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    • 2022
  • This study tested the effect of de-NOx Facility operating condition on Nox emisiion in a 125 MW wood pellet power plant in Yeongdong Eco Power Plant Unit 1, which is in operation. As SNCR urea flow rate increased, NOx emission gradually decreased, but ammonia slip after SCR increased. The boiler under test has a structure that is unfavorable to SNCR operation due to the high internal temperature, and the optimum location of the nozzle will be required. SCR dilution air temperature change did not affect the amount of NOx generated. Increasing SCR ammonia flow reduced the NOx emission at SCR outlet and also increased the NOx removal efficiency. However, the ammonia flow rate of 111 kg/h, which does not exceed the ammonia slip its own reference limit, is estimated to be the maximum operating standard. The increase in SCR mixer pressure reduced NOx emission and the removal efficiency was also measured to be the most effective variable to inhibit NOx production.

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