• 제목/요약/키워드: 왕기(汪機)

검색결과 114건 처리시간 0.026초

벽 비등모델을 이용한 과냉비등 유동에 대한 CFD 모의계산에서 벽 인접격자의 영향 (NEAR-WALL GRID DEPENDENCY OF CFD SIMULATION FOR A SUBCOOLED BOILING FLOW USING WALL BOILING MODEL)

  • 인왕기;신창환;전태현
    • 한국전산유체공학회지
    • /
    • 제15권3호
    • /
    • pp.24-31
    • /
    • 2010
  • boiling flow in vertical tube. The multiphase flow model used in this CFD analysis is the two-fluid model in which liquid(water) and gas(vapour) are considered as continuous and dispersed fluids, respectively. A wall boiling model is also used to simulate the subcooled boiling heat transfer at the heated wall boundary. The diameter and heated length of tube are 0.0154 m and 2 m, respectively. The system pressure in tube is 4.5 MPa and the inlet subcooling is 60 K. The near-wall grid size in the non-dimensional wall unit for lqiuid phase ($y^+_{w,l}$) was examined from 101 to 313 at the outlet boundary. The CFD calculations predicted the void distributions as well as the liquid and wall temperatures in tube. The predicted axial variations of the void fraction and the wall temperature are compared with the measured ones. The CFD prediction of the wall temperature is shown to slightly depend on the near-wall grid size but the axial void prediction has somewhat large dependency. The CFD prediction was found to show a better agreement with the measured one for the large near-wall grid, e.g., $y^+_{w,l}$ > 300 at the tube exit.

저칼륨혈증성 주기성 사지마비로 진단된 위증(痿證)환자 3례 (Three Cases of Wei symtom diagnosed Hypokalemic Periodic Paralysis)

  • 송왕기;이성환;김나연;강재희;이현
    • 혜화의학회지
    • /
    • 제17권1호
    • /
    • pp.105-112
    • /
    • 2008
  • Objective : This is the clinical report about the Wei symptom patient diagnosed as Hypokalemic periodic Paralysis. Methods and Results : Three Wei symtom patients diagnosed Hypokalemic Periodic Paralysisat at Cheonan oriental medical hospital were treated with Oriental-Western therapies. Conclusion : Hypokalemic Periodic Paralysis is regarded as wei symtom in Oriental Medicine. The treatment of Hypokalemic Periodic Paralysis regarded as wei symtom of Oriental Medicine had favorable effect. Parallel treatment showed favorable effect on other symptoms caused by Hypokalemic Periodic Paralysis such as nausea, chest discomfort, leg pain besides main symptoms such as weakness and numbness.

  • PDF

아세토니트릴-메탄올 혼합용매계에서 질산벤질과 아닐린의 친핵성 치환반응 (Kinetic Studies on the Nucleophilic Reactions of Substituted Benzylnitrates with Anilines in $CH_3CN-CH_3OH$)

  • 손창국;김왕기;이수정;양기열
    • 대한화학회지
    • /
    • 제34권3호
    • /
    • pp.227-231
    • /
    • 1990
  • 50-100% $CH_3CN-CH_3OH$ 혼합용매계에서 파라-치환된 질산벤질과 아닐린과의 친핵성 치환반응에 대한 2차 속도상수를 전기전도도법으로 구하였다. 속도자료를 이용하여 Hammett ${\rho}_N$${\rho}_C$값, Bronsted $\beta$값 및 용매화 파라미터 계수들을 구하였으며 이들을 PES및 양자역학 모형에 적용하여 구조 변화를 논의하였다. 연구 결과 결합형성보다 결합절단이 비교적 많이 진행된 상태에서 치환기 변화에 따라 결합절단의 진척이 결합형성을 촉진하는 동시적 $S_N2$ 반응메카니즘으로 진행됨을 알았다.

  • PDF

효율적 4D 시스템을 위한 화염 검출 알고리즘 연구 (A Study of Fire Detection Algorithm for Efficient 4D System)

  • 조경우;왕기초;오창헌
    • 한국정보통신학회:학술대회논문집
    • /
    • 한국정보통신학회 2013년도 추계학술대회
    • /
    • pp.1003-1005
    • /
    • 2013
  • 4D 기술이란 3D 혹은 일반영상과 함께 물리적 효과를 제공하는 것을 말한다. 이를 구현하기 위해선 영상의 재생 시간 및 프레임 데이터에 따른 4D용 메타데이터 제작이 필요하다. 본 논문은 영상의 컬러 정보에 따라 영상의 온도 상황을 판단하여 물리적 효과를 제공할 수 있는 방안을 제안한다. 제안하는 방안은 화재와 같은 영상의 컬러 정보를 파악하여 해당 상황에 맞게 물리적 효과를 제공할 수 있도록 한다. 제안하는 방안을 사용할 경우, 히터 장치와 같은 촉각체험을 위한 4D 메타데이터를 프로그래머의 개입 없이 자동으로 제작할 수 있을 것으로 기대된다.

  • PDF

Nature와 Science 저널에 실린 2006-2010년 논문의 경향 분석

  • 김상철;김승리;경재만;이재우;임왕기;전성현
    • 천문학회보
    • /
    • 제37권2호
    • /
    • pp.150.1-150.1
    • /
    • 2012
  • 학자의 연구능력과 성과를 질적인 면을 포함하여 제대로 가늠하지 못하는 사회에서는 대신 몇몇 평가지표가 등장하는데, 한국에서는 영향력지수(Impact Factor)와 함께 많이 사용되는 것이 Nature와 Science 저널에 실린 논문이다. 두 저널은 과학의 전 분야를 대상으로 하며, 영향력지수가 25-35점으로 다른 저널(예: Astrophysical Journal ~6점)보다 월등히 높아 세간에서 '매우 좋은' 저널로 불리며, 여기에 실리는 논문이 '뛰어난' 논문으로 평가되고 있다. 우리는 2006-2010년의 5년간 두 저널에 실린 논문의 통계를 분석하였다. 전체 논문의 수는 7788편이며 생명과학 논문이 62.4%, 물리과학 논문이 37.0%를 차지한다. 천문학 논문의 수는 544편인데, 이는 전체 논문 중에는 7.0%를 차지하고 물리과학 논문 중에는 18.9%를 차지한다. 평균적으로 매년 Nature에는 약 64편, Science에는 약 45편의 천문학 논문이 실렸다. 천문학 논문들의 경우 세부 분야별 논문의 비율과 사용한 장비의 분포를 조사하였다. 전체 논문 중 국내의 한국인 저자가 포함된 논문은 86편인데 이는 전체 논문 중 1.10%에 해당한다. 이들의 물리(25.6%), 화학(16.3%), 생명과학(29.1%), 지구과학(12.8%), 공학(16.3%) 분야별 비율을 구했다. 천문학 분야의 국내 한국인 저자 논문은 7편에 해당한다. 본 발표에서는 우리가 구한 여러 가지 통계치와 시사점을 제시하고자 한다.

  • PDF

Amide류에서 형태안정화와 C-N결합의 회전장벽에 관한 분자궤도론적 연구 (MO Studies on the Conformational Stabilities and the Rotational Barriers about C-N Bond in Amides)

  • 김왕기;손창국;이익춘
    • 대한화학회지
    • /
    • 제32권3호
    • /
    • pp.163-170
    • /
    • 1988
  • N-methyl formamide, N,N-dimethyl formamide, N-methyl acetamide, 및 N,N-dimethyl acetamide의 여러 형태에 대한 상대에너지를 MNDO법으로 구하여 C-N결합 및 메틸기 회전에 대한 회전장벽에 미치는 1-전자 및 입체 반발에너지의 영향을 논의하였다. 그 결과 formamide의 형태안정화는 주로 1-전자 에너지항에 의하여 결정되고, acetamide의 형태안정화는 주로 입체인자항에 의하여 결정됨을 알았다. C-N 결합에 대한 회전장벽을 구한 결과 N-methyl formamide와 N-methyl acetamide에서 입체 장애 효과는 바닥상태에서 보다 전이상태에서 크게 작용하지만 N,N-dimethyl formamide와 N,N-dimethyl acetamide에서 입체장애 효과는 전이상태에서 보다 바닥상태에서 더 크게 작용함을 알았다.

  • PDF

모발 염색에 따른 광택도의 변화 (Hair dyeing and the consequential change in luster)

  • 박재정;문효승;김종협;김왕기;한상훈
    • 한국염색가공학회:학술대회논문집
    • /
    • 한국염색가공학회 2011년도 제45차 학술발표회
    • /
    • pp.13-13
    • /
    • 2011
  • Hair luster is a key objective for consumers in the hair care market. Recently, as consumers using hair coloring or bleaching product increase, measurement and quantification of hair luster become more important. A hair visual appearance measurement system called SAMBA can quantitate the luster and effectively separate specular and diffuse light. SAMBA usually has been employed to measure, mainly with the change of shine value, effects of cosmetic treatments on hair shine and surface smothness. We conducted a study on the effect of dyeing and bleaching on the luster, as a result, a strong bleaching caused large decline of the luster. But the large decline of luster was caused by increasing intensity of diffusion and width of chroma peak, not the shine value. The system of dye toning for higher luster can be developed on reference to the peak type of chroma and diffusion depends on kinds and combination of dye.

  • PDF

명대(明代) 왕기(王圻)의 《삼재도회(三才圖會)》 장부도(臟腑圖)에 대한 고찰(考察) (A Study on the Figures of Viscera (臟腑圖) in Sancaituhui (《三才圖會》 encyclopaedia illustrations about the all things in nature) by Wang Qi (王圻) of Ming-Dynasty)

  • 이명철;박경남;맹웅재
    • 한국의사학회지
    • /
    • 제20권2호
    • /
    • pp.149-168
    • /
    • 2007
  • This study compared the figures of viscera (臟腑圖) in the seventh volume titled "Body" of Sancaituhui (三才圖會), the illustrated Encyclopedia published in the Ming Dynasty (明代), and the figures of viscera in Leijingtuyi (類經圖翼). One hundred and six volume Sancaituhui was compiled by Wang Qi (王圻) and his son Wang Siyi (王思義) in the Ming Dynasty. It was first published in 1607 and republished in 1609. Sancaituhui is somewhat different from other existing medical books in terms of form and content. Thus, this study examined the difference. Another comprehensive medical book, Leijingtuyi, was written by Zhang Jing-yue (張景岳) in 1624. Both Sancaituhui and Leijingtuyi were published in China before Terrenz's Taixirenshenshuogai (泰西人身說槪), the book which first introduced Western anatomy. Therefore, this study accessed the two medical books to examine the development of figures of viscera before the instruction of Western medicine.

  • PDF

Theoretical Studies on the Nucleophilic Substitution Reactions of 1-Phenylethyl Chlorides

  • 김왕기;류왕선;박형연;한인석;김창곤;이익준
    • Bulletin of the Korean Chemical Society
    • /
    • 제18권8호
    • /
    • pp.868-873
    • /
    • 1997
  • Nucleophilic substitution reactions of 1-phenylethyl chlorides (1-PEC; YC6H4CH(CH3)Cl) with phenoxides (XC6H4O-) and thiophenoxides (XC6H4S-) are investigated theoretically using the PM3 method. The Bronsted α and β values are greater for the phenoxides indicating a more advanced reaction in the transition state (TS) than for the thiophenoxides. This is supported by a greater magnitude of ρX (- 6.4 ∼ - 7.4) and ρXY (- 0.76) for the phenoxides than for the thiophenoxides (ρX = - 3.6 ∼ - 4.4 and ρXY = - 0.60). The percentage bond order changes, %Δn≠, suggest that the extents of bond making and breaking are similar for the phenoxides and hence the TS is symmetrical, but bond making is somewhat greater than bond cleavage for the thiophenoxides indicating an unsymmetrical TS. The reactions in the gas phase for both nucleophile series proceed by a SN2 mechanism with a tight TS and negative charge development on the reaction center carbon, Cα. The reactions in water investigated with model systems of benzyl and 1-phenylethyl chlorides using the Cramer-Truhlar solvation model (PM3-SM3) indicate that the reactions of 1-PEC are far more complex due to enhanced stabilization of the carbocation by the methyl substitution for a benzylic hydrogen.

Density Functional Theory Studies on the Electrophilic versus Electron Transfer Mechanisms of Aryl Vinyl Ethers

  • 김왕기;손창국;임선희;이순기;김창곤;이익춘
    • Bulletin of the Korean Chemical Society
    • /
    • 제20권10호
    • /
    • pp.1177-1180
    • /
    • 1999
  • The ab initio SCF MO and density functional theory (DFT) studies are carried out on the electrophilic (1a) and electron transfer (1b) addition reactions to the vinyl double bond of aryl vinyl sulfides and ethers. In the electrophilic addition processes, a double bond shift from C3 = C4 to X = C3 occurs with occupation number (1.97) close to the normal two. Due to this shift direct conjugation between the cationic center, X = S or O, and the para electron-donor substituent becomes impossible so that the reaction energies (or log K) are correlated with σ rather than σ+. By contrast, radical cation formation leads to delocalization of the SOMO, a lone-pair πorbital on X, with four major resonance structures in which cationic charge as well as spin density is delocalized over C4 , X and C7 atoms. As a result, partial πbonds are formed over C1 -X and C3 - C4 with occupation numbers (0.82) lower than one. In two of the cannonical structures, III(Ⅹ) and III(X+), direct conjugation between the cationic center, X, and the para substituent is achieved so that a better correlation with σ+ rather than σis obtained. The SCF MO energies at the HF/3-21G* and HF/6-31G* levels lead to very much inferior Hammett correlations in the σ/ σ+ diagnostic criterion. In contrast, the ρvalues evaluated with the DFT energies can give reliable diagnostic distinction between the two addition mechanisms.