• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.1
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• pp.66-72
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• 2010

This study was done to analyze the condition of combustion exhaust gas that is produced according to incinerator operating condition in A area Kyonggido. The boiler exhaust gas temperature, the oxygen concentration of boiler, the outgassing temperature of Semi Drying Sorber(SDS), the temperature of catalytic reactor, the concentration of NOx, SOx, CO, Hcl and Dust were investigated by change the temperature of incinerator. The concentration of SOx, CO, HCL and DUST were below 5 ppm as increase the temperature of incinerator however the concentration of NOx was increased from 40 ppm to 70 ppm as increase the temperature of incinerator. The boiler exhaust gas temperature and the temperature of catalytic reactor were not changed however the oxygen concentration of boiler was decreased gradually as increase the temperature of incinerator.

• Korean Journal of Agricultural and Forest Meteorology
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• v.17 no.4
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• pp.306-316
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• 2015

An experiment in a controlled environment was conducted to evaluate the genotypic differences of grain yield and yield-related elements of rice under elevated air temperature. Eight rice genotypes included in three maturing group (early, medium, and medium-late maturing group) were grown with 1/5,000 a Wagner pots at four plastic houses that were controlled to the temperature regimes of ambient temperature (AT), $AT+1.5^{\circ}C$, $AT+3.0^{\circ}C$, and $AT+5.0^{\circ}C$ throughout the rice growing season in 2011. Ripened grain ratio and 1000 grain weight showed the most susceptible and tolerant responses to elevated air temperature, respectively. The grain yield reduction was attributable to the sharp decrease of ripened grain ratio. Grain yield was significantly decreased above the treatment of $AT+1.5^{\circ}C$ and $AT+3.0^{\circ}C$ in early maturing group and the others, respectively. Highly correlation to average temperature from heading to 20 days was revealed in yield (r = -0.69), ripened grain ratio (r = -82), fully-filled grain (r = -70), and 1000 grain weight (r = -0.31). The responses of yield and yield-related elements except number of spikelets and panicle to elevated air temperature were fitted to a logistic function. The parameters of logistic function for each elements except grain yield could not be applied to the other varieties. In conclusion, yield and yield-related elements responded differentially to elevated air temperature according to maturity groups and rice varieties. Ongoing global warming is expected to decrease the grain yield not only by decreasing the grain weight but also decreasing the ripened grain ratio in the future. However, the yield reduction would be mitigated by adopting and/or breeding the less sensitive varieties to high temperature.

• Journal of Energy Engineering
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• v.20 no.4
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• pp.346-352
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• 2011

The experiment was designed to study the char oxidation kinetics of pulverized coals commonly utilized in Korean power plants. The kinetics has been estimated using the Semenov's thermal spontaneous ignition theory adapted to coal char particle ignition temperature. The ignition temperature of coal char particle is obtained by a direct measurement of the particle temperature with photo detector as well as by means of a solid thermocouple which is used as both a heating and a measuring element. The ignition temperatures for subbituminous coal, Wira, and bituminous coal, Yakutugol, have been measured for 4 sizes in the range of 0.52-1.09 mm. The ignition temperature of the particle increases with the increasing diameter. The results were used to calculate the activation energy and the pre-exponential factor. As a result, the kinetic parameters are in an agreement with ones reported from other investigations.

• Aerospace Engineering and Technology
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• v.9 no.1
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• pp.143-150
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• 2010

This study examined the effect of cold water finger immersion at various water temperature on cold-induced vasodilation (CIVD) and its reproducibility to the cold stress. Ten healthy collegiate men ($21.4{\pm}2.5$ yrs, $175.8{\pm}4.1$ cm, $69.6{\pm}7.6$ kg, $11.2{\pm}3.7$ %fat) underwent two tests. At the first test (1ST), subjects immersed their middle fingers at $43^{\circ}C$ water for 5 min followed by a resting at an ambient air for 25 min. Then they immersed the finger at one of the five water temperatures (Tw: 5, 8, 11, 14, or $17^{\circ}C$) at random order for 20 min. Once a testing at one Tw was completed, they immediately repeated the testing procedure for another Tw. The second test(2ND) was performed within a week after 1ST with having an identical procedure of 1ST except the order of Tw. During the test, rectal temperature, finger temperature from middle finger nail bed, and heart rate were measured every six second. In conclusion, maximal finger temperature(Tfmax), and Tfmax minus Tw was highly reproducible in this experiment. Minimal finger temperature (Tfmin) and Tfmax were higher as Tw decreased. And Tfdiff was higher as the colds tress decreased. No differences were found in time variables of temperature responses.

• Journal of the Korea Organic Resources Recycling Association
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• v.6 no.1
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• pp.67-73
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• 1998

This study was to experiment, through sewage sludge treatment by Vacuum Drying Method, variation of water content with reaction pressure, reaction time, reaction temperature. The result are as follows; The water content decreased with the same reaction temperature and reaction time at lower pressure and 360~40 mmHg (a close vacuum) showed lower water content at low reaction temperature and short reaction time. The water content rapidly decreased with the same reaction pressure and time at low reaction temperature (above $120^{\circ}C$).

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.243-249
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• 1998

상용 핵연료 피복관 재료로 사용되고 있는 Zircaloy-2와 Zircaloy-4 및 ZIRLO$^{TM}$에 대한 수소와의 반응거동 및 속도론적(kinetic) 자료를 얻기 위하여 electro-microbalance가 장착된 TGA (thermogravimetric analysis) 장치를 이용하여 30$0^{\circ}C$~50$0^{\circ}C$의 온도범위에서 1기압 수소와의 반응에 따른 무게증가를 in-situ로 측정하였다. Zircaloy와 수소와의 반응거동은 chamber내 온도상승시 생성되는 산화막에 의해 초기에는 느린 반응이 진행되는 영역이 존재하고 온도가 낮은 35$0^{\circ}C$ 이하에서는 이것이 잠복기 형태로 나타난 후 직선속도법칙(linear rate law)을 따르며 반응이 가속화되는 것으로 나타났고 40$0^{\circ}C$ 이하의 저온에서는 직선속도법칙에서 반응이 지연되는 방향으로 약간의 편차(deviation)가 관찰되었다. 그 결과 Zircaloy-2와 ZIRLO$^{TM}$가 Zircaloy-4보다 수소와의 반응속도가 빠르고 활성화에너지가 낮은 것으로 나타났으며 직선속도법칙을 근거로 하여 각각 1.1x$10^{7}$ exp(-20,800/RT)와 1.5x$10^{6}$exp(-18,000/RT) 및 6.9x$10^{7}$ exp(-23,800/RT) (mg/dm$^2$/min) 의 속도상수를 도출하였다. 또한, 열구배가 존재하지 않는 out-of-pile 조건하에서도 'sunburst' 형태의 국부적 수소침투가 발생할 수 있음이 ～l,000 ppm이상의 수소침투 시편에서 확인되었다. ～3,000ppm이상 침투하게 되면 표면에 수소화물이 농축되어 있는 hydride layer가 형성됨을 관찰하였으며 ～5,000ppm 이상의 경우에는 수소화물의 방향성이 random하였으며 특히, ZIRLO$^{TM}$ 시편의 경우에서는 원주방향으로 길게 이어진 수소화물과 기계적 성질에 치명적인 반경방향의 수소화물이 평행하게 배열된 것을 관찰하였다.

• Resources Recycling
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• v.12 no.4
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• pp.30-37
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• 2003

A kinetics study on the dissolution reaction of zinc-ferrite has been made with aqueous sulfuric acid in various temperature and concentration. Fraction reacted(R) and apparent rate constant(K) increased with increasing temperature and concentration of sulfuric acid solution. The rate of dissolution is shown by $1-(1-K)^{1/3}=Kt$ for the initial stage of the reaction in aqueous sulfuric acid, where K is apparent rate constant, R is fraction reacted and t is reaction time, respectively. Activation energy associated with reaction was determined to be 16.3 kcal/mole. The dissolution of zinc-ferrite in sulfuric acid solution is dissolved by sto-ichiometric composition, but Fe and Zn did not dissolved, respectively.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.532-535
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• 2009

In this study, the fatty acid methyl ester was prepared from the vegetable oil by inducing ultrasound energy. The ultrasound energy was applied to the esterification reaction for heating and stirring effects. Ultrasonic induction results in the shortened reaction time and brings the increase of the methyl ester yield. However, the continuous introduction of ultrasound during the esterification reaction results in temperature increase, then the over-heating of reaction temperature was ineffective. Therefore, the system temperature was controlled at constant temperature state with the cooling circulation. The ultrasound induction reaction had the fatty acid methyl ester yield of 93% at the reaction time was 30 minutes, faster than the traditional esterification process.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.620-629
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• 2022

By varying various experimental conditions such as heating rate, molar hourly space velocity (MHSV), and nitridation reaction temperature, vanadium oxynitride was prepared through temperature programmed reduction/nitridation reaction (TPRN) of vanadium pentoxide and ammonia, and characterization were performed. In order to investigate the physico-chemical properties of the prepared catalyst, N₂ adsorption-desorption analysis, X-ray diffraction analysis (XRD), hydrogen temperature programmed reduction (H₂-TPR), temperature programmed oxidation (TPO), ammonia temperature programmed desorption (NH₃-TPD), transmission electron microscopy (TEM) was performed. Transformation of V₂O₅ with 5 m² g^-1 low specific surface area by reduction at 340 ℃ to V₂O₃ showed a high specific surface area value of 115 m² g^-1 by micropore formation. As the nitridation temperature increased beyond that, the specific surface area continued to decrease due to sintering. The nitridation reaction variable that had the greatest influence on the specific surface area was the reaction temperature, and the x + y value of VN_xO_y of a single phase approached from 1.5 to 1.0 as the nitridation reaction temperature increased. At a high reaction temperature of 680 ℃, the cubic lattice constant a was VN. close to the value. At 680 ℃, the highest nitridation temperature among the experimental conditions, the ammonia conversion rate was 93%, and no deactivation was observed.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1998.05a
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• pp.253-258
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• 1998

연료 전지 시스템에서의 스택은 화학 공장의 반응기에 해당한다. 화학 공장에서 반응 생성물의 생산성을 최적화하기 위해 반응기 해석이 매우 중요한 것과 마찬가지로, 연료 전지 스택의 특성을 해석하고 최적 조건으로 설계 및 운전하는 것은 필수적이다. 스택에서 전기를 생산하는 과정에서 중요한 두 가지 운전 변수는 기체의 조성과 온도이며, 이론적인 해석을 위해서는 유체의 이동시에 열전달 및 각 성분별 물질 수지식과 전기 화학 반응식이 사용될 수 있다.(중략)