• Title/Summary/Keyword: 오염 세척

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유류오염토양 세척유출수내 미세토사의 효율적 제거방안에 관한 연구

  • 윤세영;최상일;서용식;류두현;이재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.227-230
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    • 2004
  • 본 연구에서는 유류오염토양 세척유출수내 미세토사의 효율적 제거를 위한 최적의 방안 및 적용 운전 조건을 도출하고자 하였다. 응집제를 주입하지 않은 blank 실험결과, 광운대학교 토양 세척유출수는 pH 7~12의 범위에서 65~75%의 효율을 나타내었고, 우이천 하천퇴적 토양 세척유출수는 pH 7~11의 범위에서 30% 안팎의, pH 12에서는 70% 정도의 낮은 효율을 나타내었다. pH 13에서는 두 가지 세척유출수에서 각각 91%, 85%의 효율을 나타내었다. 응집ㆍ침전 실험 결과, 광운대학교 토양 세척유출수는 FeC13, alum, PAC을 적용하였을 때 대체로 99% 이상의 효율을 보였으나, PAM을 적용하였을 때는 pH 13에서만 약 95%의 효율을 보였을 뿐 pH 7~12의 범위에서는 50~70%의 낮은 효율을 보였다. 우이천 하천퇴적 토양 세척유출수는 alum과 PAC을 적용하였을 때 대체로 90% 이상의 효율을 나타내었으나, FeC13와 PAM을 적용하였을 때는 pH 13일 경우에서만 98%이상의 효율을 보였을 뿐 다른 pH조건에서는 대체로 60%이하의 효율을 보였다. 두 가지 세척유출수에 대하여 높은 효율을 보인 alum과 PAC의 경제성을 비교해본 결과 같은 양의 세척유출수를 응집처리 할 경우 PAC에 비하여 alum을 적용하였을 때 적은 비용이 소요되었다. 따라서 alum이 효율성과 경제성에서 가장 우수함을 알 수 있었다.

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The Sterilization Effectiveness for Bacterial Contamination by Cleaning Methods in the Glasses for Vision Correction (시력교정용 안경의 세척 법에 따른 오염 균의 제균 효과)

  • Back, Seung-Sun;Kim, Hyun-Kyung;Lee, Kyu-Byung;Lee, Hyun-Joo;Kim, Heung-Soo
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.2
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    • pp.101-106
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    • 2013
  • Purpose: This research was to evaluate the sterilization effectiveness for bacterial contamination by general cleaning method of glasses for vision correction. Methods: From 82 eyeglass wearers the number of bacteria before and after cleaning was counted to check the status of the eradication. Results: The results after ultrasonic cleaning by using the tap water did not showed change of bacterial species. Ultrasonic cleaning using the 70% rubbing alcohol showed cleaning of 46.2% of bacteria. Ultrasonic cleaning using the 70% rubbing alcohol after brushing with general detergent showed clearing of 85.7% of bacteria. Conclusions: When glasses were brushed with a detergent, opportunities infectious bacteria in glasses for vision correction were removed effectively. These results can be suggested as a guideline for management of clean glasses.

Remediation of Heavy Metal Contaminated Soil by Washing Process (세척을 통한 중금속(Cd, Zn)으로 오염된 토양의 정화)

  • 백정선;현재혁;조미영;김수정
    • Journal of Korea Soil Environment Society
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    • v.5 no.1
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    • pp.45-54
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    • 2000
  • Several chemical washing procedures were applied to Zn and Cd contaminated soil. Batch and column tests were performed to determine the metal extraction efficiency as a function of pH and concentration. Washing efficiencies by water and NaOH are very low but those by HCI, EDTA and Oxalic acid are high. The most efficient washing occurs in case of using HCI because heavy metal is ionized easily at the condition of low pH. EDTA and Oxalic acid are also effective to extract Zn and Cd because they have a high complexation affinity for heavy metals forming active surface complexes. More Zn is released than Cd is and release trend is increased as pH is decreased and concentration of washing solution is increased. When heavy metal contaminated soil is remediated, HCI and EDTA are more effective to remove Zn than others are. Meanwhile HCI and Oxalic acid are more effective to remove Cd than others are.

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Applicability of Washing Techniques Coupled with High-Pressure Air Jet for Petroleum-contaminated Soils (고압공기분사를 이용한 유류오염토양 세척기법의 적용성 연구)

  • Choi, Sang-Il;Kim, Kang-Hong
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.61-68
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    • 2006
  • Soil washing techniques coupled with high pressure air jet were applied for diesel-contaminated soils sampled by an underground oil reservoir of which the initial total petroleum hydrocarbon (TPH) ($2,828{\pm}206\;mg/kg$) exceeded 5 times of current standard level (500 mg/kg) regulated by the Soil-Environment Conservation Law. Through several tests, we found that the position of impeller has a critical impact for washing efficiencies. The highest washing efficiency was obtained at an oblique angle (30 degree) for the impeller and optimized mixing speed (300 rpm) that could have high shearing forces. Considered economical and feasible aspects, the optimum mixing time was 10 min. Rate constants of TPH removal derived from the first-order equation were not linearly increased as mixing speed increased, indicating that mechanical mixing has some limits to enhance the washing efficiencies. Application of high-pressure air jet in washing process increased the washing efficiency. This increase might be caused by the fact that the surface of micro-air bubbles strongly attached hydrophobic matters of soil particles. As the pressure of air jet increased, the separation efficiencies of TPH-contaminated soil particles increased. In the combined process of high-pressure air jet and mixing by impeller, the optimum mixing speed and air flow-rate were determined to be 60 rpm and $2\;kg/cm^2$, respectively. Consequently, the washing technique coupled with high-pressure air jet could be considered as a feasible application for remediating petroleum-contaminated soils.

Remediation Design Using Soil Washing and Soil Improvement Method for As Contaminated Soils and Stream Deposits Around an Abandoned Mine (토양 세척법과 석회를 첨가한 토양 안정화 공법을 이용한 폐광산 주변 비소 오염 토양 및 하천 퇴적토 복원)

  • 이민희;이정산;차종철;최정찬;이정민
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.121-131
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    • 2004
  • Removal efficiencies of soil washing and soil improvement processes to remediate farmland soils and stream deposits around Goro abandoned mine were investigated with batch and column experiments. For As-contaminated farm-land soils around Goro mine, batch tests to quantify As extraction rate from contaminated soils and lime treated contaminated soils were performed. The contaminated soil mixed with lime decreased As extraction rate less than one fourth, suggesting that the soil improvement method mixed with lime dramatically decrease As extraction rate. A storage dam will be constructed in the lower part of the main stream connected to Goro abandoned mine and the amount of As extracted from the bottom soils of reservoir could be the main source to contaminate water of reservoir. The decrease of As extraction amount from the bottom in reservoir, caused by the application of the soil improvement method was investigated from the physically simulated column experiment and results showed that As extraction rate decreased to one forty when 1% lime mixed soil improvement was applied to contaminated soils. For contaminated stream deposits connected Goro mine, the removal efficiency of the soil washing method was investigated with batch experiments. Hydrochloric acid, citric acid, acetic acid and distilled water were used as soil washing solution and 0.01, 0.05, 0.1, 0.5, 1.0 N of washing solution were applied to extract As. When washing with 0.05 N of hydrochloric acid or citric acid, more than 99.9% of As was removed from stream deposits, suggesting that As contaminated stream deposits around Goro mine be successfully remediated with the soil washing process. Total volumes of contaminated soils and deposits needed for remediation were calculated based on three different reme-diation target concentrations and the operation cost of soil washing for calculated soil volumes was estimated. Results from this research could be directly used to make a comprehensive countermeasure to remediate contaminated area around Goro mine and also many contaminated areas similar to this research area.

Remediation of Pb-Contaminated Soil by Soil Washing using Hdrochloric Acid (염산을 사용한 납 오염 토양의 토양 세척에 의한 정화)

  • Baek, Ki-Tae;Kim, Do-Hyung;Seo, Chang-Il;Yang, Jung-Seok;Lee, Jae-Young
    • Journal of Soil and Groundwater Environment
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    • v.12 no.3
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    • pp.17-22
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    • 2007
  • The feasibility of soil washing was investigated to remediate Pb-contaminated field soil. Hydrochloric acid was used as a washing agent. As mixing time increased from 5 min to 120 min, removal efficiency of Pb from contaminated soil increased from 69.3% to 81.9%. Two times washing with 0.2 M HCl showed 96% removal efficiency even at mixing time of 10 min. The Pb content in soil increased sharply as particle size of soil decreased, and removal efficiency was highly dependent on mixing time and temperature. Based on this result, acid washing technologies can be applied to remediate the Pb-contaminated soil used in this study.

Analysis of Surface Contaminants and Removal Techniques on Three-story Stone Pagoda at the West of Gameunsaji Site (감은사지서삼층석탑의 표면오염물 분석과 제거기술)

  • Kim, Sa-Dug;Lee, Tae-Jong;Kim, Da-Ram;Han, Min-Su
    • Journal of Conservation Science
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    • v.26 no.2
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    • pp.203-211
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    • 2010
  • Analytic research on the surface pollutant of the three storied-pagoda at the west of Gameunsaji site as well as studies of previous wet cleaning cases was undertaken in order to decide cleaning method for removing inorganic pollutants. The status of pollutant was examined by naked eye observation, SEM-EDS, XRD. Then it was compared and categorized through qualitive and quantitative analysis. The result showed that the surface pollutants consisted of iron compounds or sulfur compounds and it was crystallized in the form of circle, oval, needle, etc. Result, Low-pressure rotating vortex process cleaning, with which particular matters are sprayed in swirl, is considered to be the best method to remove the pollutants.

A Study on Characteristics of Pollutant by Automobile in Highway Road Runoff (고속도로 강우유출수 내 차량 기인 오염물질 특성 연구)

  • Yong Bin An;Eun Mi Hong;Hyuck Su Kim
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.232-232
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    • 2023
  • 고속도로 및 편의시설 건설로 불투수층의 면적이 증가하여 강우 시 고속도로 및 편의시설에서 발생하는 오염원에 의한 하천의 수질 영향도 커지고 있다. 특히 휴게소에서는 자동차의 급가속, 급감속으로 더욱 많은 분진과 오염물질이 발생할 수 있으며 타이어 마모 입자, 자동차 배기가스, 중금속 및 오일류 등이 휴게소나 도로 지표에 집적되어 있다. 이렇게 발생한 오염물질은 우기에 강우와 함께 불투수면을 침투하지 못하고 배수로를 통해 유출되어 인근 하천의 수생태 및 토양의 주요 오염원으로 작용하고 있다. 이에 따라 고속도로 및 인근 휴게소의 비점오염 저감대책이 필요하며 효율적인 비점오염원 저감을 위해 장기적인 모니터링, 지속적인 자료 수집 및 분석이 필요하다. 본 연구에서는 강원지역 고속도로 및 인근 휴게소에서 강우 시 강우유출수 모니터링을 통해 강우유출수 유량가중평균농도 (Event Mean Concentration) 산정하고 강우유출수 수문곡선 (hydrograph)을 작성하였다. 또한 강우사상에 따른 분석항목별 초기세척효과(First Flush Effects)와 오염부하량을 산정하였다. 추가적으로 차량 기인 입자를 확인하기 위해 μ-FT-IR 현미경 분석 실험을 하였다. 모니터링 장소는 휴게소 및 고속도로 일원이며, 모니터링은 선행무강우일수 2일 이상, 강우량 10mm 이상일 때 실시하였으며 2022년 6월부터 10월까지 총 4회 실시하였다. 모니터링 결과 타이어 및 브레이크 패드 마모와 관련된 중금속인 Zn, Cu, Pb 등의 중금속이 높게 분석되었으며 이러한 중금속의 오염부하량 역시 높게 산정되었다. 강우유출수 수문곡선에서 강우 초기 오염물질의 세척효과가 나타났다. MFFn 산정 결과 강우 30% 구간에서 초기세척효과를 보였다. μ-FT-IR 현미경 분석 결과 PE (Polyethylene)가 가장 많이 검출되었고 PP (Polypropylene), PS (Polystyrene) 순으로 검출되었다. 이러한 강우유출수 모니터링 데이터는 향후 고속도로 휴게소 및 고속도로 주변 오염저감 시설 설치 및 사회적 동참을 위한 타당한 근거 확보를 위한 기초자료로서 제공될 수 있을 것이다.

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Comparison of Bonding Strength by Cleaning Method of Pediatric Zirconia Crown Contaminated with Saliva or Blood (타액 및 혈액오염 시 유치 지르코니아 기성관 내면의 세척 방법에 따른 결합강도의 비교)

  • Kim, Jaeyong;Park, Howon;Lee, Juhyun;Seo, Hyunwoo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.45 no.2
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    • pp.185-194
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    • 2018
  • The objective of this study was to compare the shear bonding strength of zirconia after cleaning the crown contaminated by saliva or blood and determine the effect of thermocycling. 180 specimens were embedded in acrylic resin. 20 Specimens in the positive control group were bonded with resin cement without contamination. 20 Specimens in the negative control group were washed with water for 20 seconds and then dried for 10 seconds. 120 Specimens contaminated by saliva or blood were cleaned by using three cleaning methods: 37% phosphoric acid gel, commercial cleanse, and 2.5% NaOCl. All samples were bonded with resin cement and divided into two subgroups: One was not aged, and the other was tested with 30,000 thermocycling. In both groups contamination by saliva and blood, no statistically significant difference was not found in control, groups cleansed by commercial cleanser and 2.5% NaOCl. When the groups cleansed with water and 37% phosphate gel were compared with the control, significantly low shear bond strength was shown. Thermocycling group showed statistically significantly low shear bond stress compared to the groups without thermocycling. When zirconia was contaminated by saliva or blood, its original shear bond strength could be obtained if it was cleaned with commercial cleanser or 2.5% NaOCl.

A Study on the In-Situ Soil Vapor Extraction and Soil Flushing for the Remediation of the Petroleum Contaminated Site (유류로 오염된 토양 복원을 위한 토양가스추출 및 세척공정의 현장적용 연구)

  • Ko, Seok-Oh;Kwon, Soo-Youl;Yoo, Hee-Chan;Kang, Hee-Man;Lee, Ju-Goang
    • Journal of the Korean Society of Hazard Mitigation
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    • v.1 no.3 s.3
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    • pp.83-92
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    • 2001
  • Field investigations for subsurface soil and groundwater at a gas station showed that the site was severely contaminated and even petroleum compounds as free liquid state were observed. Pilot-scale soil flushing and soil vapor extraction process(SVE) were applied to evaluate the effectiveness of pollutants removal. Surfactant solution, Tween 80, was used to enhance the solubility of petroleum compounds and resulted in about 10 times increase on TPH(Total Petroleum Hydrocarbon) concentration. As for SVE method, maximum concentration of TPH and BTEX reached within 24 hours of extraction and then continuously decreased. Considerations on the groundwater level and the kinetic limitation for volatilization of contaminants have to be taken into account for the effective application of SVE process.

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