• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.1
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• pp.57-68
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• 2023

In this study, coffee waste was recycled into nitrogen-doped porous carbon fibers as an active material for high-energy EDLC (Electric Double Layer Capacitors). The coffee waste was mixed with polyvinylpyrrolidone and dissolved into dimethylformamide. The mixture was then electrospun to fabricate coffee waste-derived nanofibers (Bare-CWNF), and carbonization process was followed under a nitrogen atmosphere at 900℃. Similar to Bare-CWNF, the as-synthesized carbonized coffee waste-derived nanofibers (Carbonized-CWNF) maintained its fibrous form while preserving the composition of nitrogen. The electrochemical performance was analyzed for carbonized coffee waste (Carbonized-CW)-, carbonized PAN-derived nanofibers (Carbonized-PNF)-, and Carbonized-CWNF-based electrodes in the operating voltage window of -1.0-0.0V, Among the electrodes, Carbonized-CWNF-based electrodes exhibited the highest specific capacitance of 123.8F g^-1 at 1A g^-1 owing to presence of nitrogen and porous structure. As a result, nitrogen-contained porous carbon fibers synthesized from coffee waste showed excellent electrochemical performance as electrodes for high-energy EDLC. The experimental designed in this study successfully demonstrated the recycling of the coffee waste, one of the plant-based biomass that causes the environmental pollution into high-energy materials, also, attaining the ecofriendliness.

• Analytical Science and Technology
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• v.21 no.3
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• pp.191-200
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• 2008

Pharmaceuticals and personal care products (PPCPs) are emerging contaminants in aquatic environmental samples. Therefore, it required rapidly and certainly analytical method for pharmaceuticals which are existed in environment. In this study, Liquid chromatography/tandem mass spectrometry (LC-MS/MS) with electrospray ionization (ESI) was used to measure the concentrations of 7 pharmaceuticals (quinoxaline-2-carboxylic acid, acetylsalicylic acid, diclofenac-Na, naproxen, ibuprofen, mefenamic acid, talniflumate) from environmental water or aquatic samples simultaneously. Effective sample clean-up by solid-phase extraction (SPE) prior to LC-MS/MS analysis is necessary. For further purification, Mixed Cation eXchange (MCX) and Hydrophilic-Lipophilic Balance (HLB) solid-phase extraction (SPE) cartridges were used to eliminate the remaining interferences. LODs (Limits of Detection) and MDLs (Method Detection Limits) for the spiked sample in fresh water were in the range of 0.05~1.50 pg/mL and 0.17~4.90 pg/mL, respectively. The absolute recovery in the concentration of 1.0 ng/mL were between 81.9 and 116.3%. The acidic pharmaceuticals were detected in concentrations of 0.018~16.925 ng/mL in aquatic environmental samples.

• Analytical Science and Technology
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• v.21 no.5
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• pp.364-374
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• 2008

Antarctic Environmental Monitoring Handbook' was published by COMNAP/SCAR in 2000. The standardized method described in this handbook is recommended for monitoring of antarctic environment. High pressure bomb technique in this guide was used to decompose soil samples. In compliance with this guide book, high pressure bomb technique was applied to decompose the antarctic soil sampled at the King Sejong Station. An Isotope Dilution-Inductively Coupled Plasma-Mass Spectrometry (ID-ICP-MS) was applied to determine mass concentrations of Pb, Cu and Zn in the soil. The accuracy in this method was verified by the analysis of certified reference materials (CRM) of NIST 2702 (marine sediment). The analytical results agreed with certified value within the range from 99.5~100.8%. Matrix separation was necessitated for the determination of Cu and Zn by Chelex 100 ion exchange resin. As a result, the average mass concentrations of Pb, Cu and Zn which are suspected to be caused by anthropogenic pollution were 332.9 mg/kg, 95.6 mg/kg and 115.3 mg/kg, respectively. Those for the metals sampled in the soils of the remote regions from the station were 28.1 mg/kg, 101.8 mg/kg and 115.6 mg/kg, respectively.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.476-476
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• 2022

농업용수는 전통적 기능으로 농업용수 그 자체로서의 기능과 시대적 요구에 따른 지역용수로서의 기능을 가진다. 농업용수 그 자체의 기능으로 가장 중요한 것은 관개용수이며, 논, 밭관개, 하우스 시설농업에의 용수공급이다. 농업용수의 실 수요량 측면에서는 논용수가 전체용수 수요량의 60.1%로 가장 많은 양을 차지하고 있으며, 다음으로는 밭용수가 18.6%, 그 외 생활용수, 공업용수, 환경용수, 축산용수 등으로 이용되고 있다. 농업용수 수요 측면에서 논용수의 비중이 가장 높게 나타나기 때문에 본 연구에서는 농업용수 공급에 따라 농업용저수지-관개수로-논에 이르는 공급단계별 수질변화를 분석하였다. 본 연구는 경기, 충남 권역의 오염도가 높은 3개 농업용저수지를 대상으로 하였으며, 농업용수를 본격적으로 공급하는 5월부터 관개가 종료되는 10월까지 농업용저수지와 관개수로, 논을 대상으로 수온, TOC, Chl-a 등 10개 항목을 분석하여 나타내었다. 연구기간동안 수온의 변화는 18.6~34.6 ℃로서 관개수로에 가장 낮고, 논에서 가장 높은 값을 보여 주었으며, 공급단계별 평균 수온은 저수지(R) 27.6 ℃, 관개수로(C) 26.4 ℃, 논(P) 28.4 ℃로 논에서 수온증가가 나타났다. pH는 7.4~9.7의 범위로 저수지에서 최고값, 논에서 최저값을 보였으며, 공급단계별 평균값은 R 9.1, C 8.3, P 8.0으로 저수지, 수로, 논으로 이동하면서 감소하였다. 전기전도도(EC)는 저수지 수질오염도에 따라 다양하게 나타났으며, 공급단계별 평균값은 R 706.3 uS/cm, C 585.5 uS/cm, P 771.2 uS/cm로 논에서 가장 높은 값으로 보였으며, 이는 논에서 추가적인 영양분 공급에 의한 것으로 보였다. 평균 용존산소량(DO)은 R 6.3, C 4.0, P 4.5로 저수지에서 가장 높고, 수로에서 가장 낮게 나타났다. 유기물 지표인 COD와 TOC의 변화를 보면 평균 COD R 21.7 mg/L, C 14.5 mg/L, P 22.7 mg/L, 평균 TOC R 11.2 mg/L, C 8.5 mg/L, P 12.3 mg/L로 두 항목 모두 논에서 가장 높은 값을, 수로에서 가장 낮은 값을 나타내었다. 반면 엽록소 a 평균 농도는 R 128.4 mg/m³, C 54.3 mg/m³, P 31.7 mg/m³로 저수지의 내부생산으로 다량 발생한 조류가 수로와 논으로 이동하면서 급격하게 감소하여 나타났다. 이는 저수지와 논의 유기물 성상이 다름을 보여준다. 영양염류인 총인(TP)의 평균값 변화를 보면 R 0.302 mg/L, C 0.374 mg/L, P 0.384 mg/L로, 저수지에서 수로, 논으로 이동하면서 점차 증가하여 나타났다. 이는 농업용저수지에서 수로, 논으로 관개용수가 이동하면서 오염수 유입 또는 비료 등의 투입이 이루어진 결과로 판단된다. 이와 같이, 농업용저수지의 수질이 논에 그대로 유지되어 유입되지 않고 공급단계에 따라 변화하고 있으므로 항목별 수질 변화 특성을 이해한 후 농업용수 수질관리가 이루어 져야 할 것이다.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2022.11a
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• pp.158-159
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• 2022

Due to the climate crisis, various environmental regulations including greenhouse gas reduction are in effect. This is not limited to any specific industry sector, but is affecting the entire industry worldwide. For this reason, the IMO and governments of each country are announcing strategies and policies related to the shipbuilding and shipping industries. The current regulations can be partially resolved through additional facilities such as scrubbers while using existing fossil fuels, but ultimately, the emission of greenhouse gases such as CO2 from the exhaust gases generated by ships must be restricted through energy conversion. To this end, it is necessary to develop fuels that can replace traditional fuels such as oil and natural gas. Among them, hydrogen is attracting attention as a clean energy that does not emit pollutants when used as a fuel. However, hydrogen has a wide explosive range and a fast dispersion speed, so research on this is necessary. Therefore, in this paper, when hydrogen leakage occurs in the fuel preparation room of a hydrogen-powered ship, the trend was analyzed and the ventilation characteristics were investigated.

• Journal of Advanced Navigation Technology
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• v.28 no.1
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• pp.149-154
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• 2024

Research on particulate matter is advancing in real-time, and various methods are being studied to improve the accuracy of prediction models. Furthermore, studies that take into account various factors to understand the precise causes and impacts of particulate matter are actively being pursued. This paper trains an LSTM model using seasonal data and another LSTM model using concentration-based data. It compares and analyzes the PM_2.5 prediction performance of the two models. To train the model, weather data and air pollutant data were collected. The collected data was then used to confirm the correlation with PM_2.5. Based on the results of the correlation analysis, the data was structured for training and evaluation. The seasonal prediction model and the concentration-specific prediction model were designed using the LSTM algorithm. The performance of the prediction model was evaluated using accuracy, RMSE, and MAPE. As a result of the performance evaluation, the prediction model learned by concentration had an accuracy of 91.02% in the "bad" range of AQI. And overall, it performed better than the prediction model trained by season.

• The Journal of the Convergence on Culture Technology
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• v.10 no.1
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• pp.379-386
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• 2024

The purpose of this study was to pay attention to the increase in the frequency of expression of butterflies and insects, whose decrease in the number of individuals is symbolized as a measure of environmental pollution, among the various motifs of nature as we go through the COVID-19, when we realized the importance of nature. The scope of this study was limited to fashion collection fashion show photos and interview articles of online for fashion collections from 2019 to 2023. As a result of the study, 185 butterfly motivation fashion design appeared, and digital printing techniques were the most used as a type of plane expression method. Along with this, techniques such as quilting, embroidery, and beading have appeared a lot as techniques to express the planar motif of butterflies. As for the three-dimensional expression types, 3D printing, laser cutting, corsage techniques, and draping techniques showed similar proportion. It can be seen that the expressed butterfly motif had more realistic description the shape of the butterfly as it was than abstract expressions. In conclusion, it can be seen that the butterfly motif fashion design over the past five years contains a stronger message about the environment than the butterfly motif fashion in the past. It was confirmed that it is a motif with a great symbolic meaning that can convey an eco-friendly message beyond just the morphological beauty and colorful design elements of the butterfly.

• Journal of Applied Biological Chemistry
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• v.66
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• pp.258-265
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• 2023

After application of veterinary antibiotics, they may be partially metabolized before they are excreted by feces or urine either as unaltered form or as metabolites. Residual antibiotics enter the adjacent agricultural environments by spraying manure-based compost and liquid fertilizer on farmlands and lead to secondary pollution. The objective of this study was to compare the residual concentrations of 6 veterinary antibiotics by different production stages of liquid fertilizer from livestock manure recycling facilities. The relationship between concentration change of the residual antibiotics and the amount of liquid fertilizer component was also assessed. Pre-treatment showed the recovery of 63.4-106.7% at ppb level and the limit of quantification of 0.009-0.037 ㎍/L.As the result of analyzing the relationship between the residual concentrations of antibiotics and the amount of N component in liquid fertilizer by different production stages, the residual concentrations of antibiotics and N tended to decrease as the stabilization period elapsed during the liquid fertilization process. Average concentrations of sulfamethazine in raw materials, middle and final products of liquid fertilizer were 40.85, 26.17, 3.54 ㎍/L, respectively. Those of chlortetracycline decreased from 2.32 to 1.25 ㎍/L. The other 4 antibiotics also showed a decreasing trend by different production stages of liquid fertilizer. The amount of liquid fertilizer component N decreased from 0.21 to 0.096% by production stages of liquid fertilizer. It is considered that the correlation between residual antibiotic concentrations and N content can be applied as basic data for setting antibiotic reduction indicators.

• Journal of Applied Biological Chemistry
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• v.57 no.3
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• pp.267-277
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• 2014

Objective of this paper is to assess the available data on the pesticide uses and regulations in the golf courses, and provide the nationwide systematic management options. Numbers of golf courses in Korea are rapidly increasing from 2000s and reached at 421 sites by the end of 2011. Accordingly pesticide usage has been increased with years in direct proportion to the increasing number of golf courses. Amounts of pesticide applied in 2011 were 118,669 kg as of an active ingredient and were in the orders of fungicides (54.9%) > insecticides (24.4%) > herbicides (13.3%) > growth regulators (0.1%). Average pesticide usages in 2011 were 280.9 kg per golf course and $5.4kg\;ha^{-1}$. Frequencies of the residual pesticide detections in green and turf were higher than those in fairway and soil, respectively. Residue of highly toxic pesticides was not detected in golf courses. Ministry of Environment in 2010 has developed the 'golf course pesticide monitoring and management system' which is the advanced online registry for kind and amount of pesticides applied in each golf course. This system is intended for monitoring of the pesticide uses and residual levels and protecting the environmental pollution from pesticides in the golf course. In 2009, management of pesticides in the golf courses became the task of Ministry of Environment, being merged from many federal agency and ministries. The protocol for the site-specific best management practices, on which to base results from the risk assessment, should be set for pesticides in the golf to minimize the environmental impacts.

• Korean Journal of Environment and Ecology
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• v.30 no.6
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• pp.986-995
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• 2016

The objective of this study was to analyze the distribution of endangered fish species and elucidate their relations on chemical water quality, physical habitat conditions and ecological stream health. The dominant species in the watershed was Pseudopungtungia nigra (Pn), Gobiobotia macrocephala (Gm), Gobiobotia brevibarba (Gb), Liobagrus obesus (Lo), and Iksookimia choii (Ic) in the order. The species of Pn designated as "critical endangered species (I) (CER)", was most widely distributed species among the endangered species, so the designation of the species should be re-evaluated. The endangered species was most popular (4 species, 384 individuals) in the Cho-River region of eighteen lotic regions. According to the analysis of chemical tolerance limits in the habitats with endangered fish species, biological oxygen demand (BOD) and total phosphorus (TP) was analyzed as "very good" (Ia) and "good condition" in the chemical criteria of the Ministry of Environment, Korea. Also, chemical conditions, based on ammonia-N ($NH_{4+}$), total nitrogen (TN), phosphate-P ($PO_{4^-}P$) were much better in the habitat with endangered species (Hw) than the habitat without endangered species (Ho). In the meantime, the species of Ic showed wide ranges on the chemical tolerance, so physical habitat conditions, such as the size of substrate particles (sand) and hydrological regime, were considered as more important factors than the chemical water quality, if the water quality is not largely degraded. The endangered species were also more distributed in the high-order (4-6) streams than the low-order (1-3) streams. The evaluation of ecological stream health, based on multi-metric model of the Index of Biological Integrity (IBI), showed the large difference between the Hw (21.6, fair condition)and Ho (30.5, good condition), indicating that the habitat maintained well chemically and physically had higher distributions of endangered species. Overall, the designation of CER on the Pn should be re-evaluated due to wide-distributions, and the protections from water pollution and the habitat conservations on the endangered species are necessary in the watershed.