• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.85-92
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• 1999

The complete catalytic oxidation of vinyl chloride was investigated over chromium oxide supported ${\gamma}$-alumina using a fixed bed micro-reactor at temperature between 240 and $300^{\circ}C$ and concentration between 600 and 3500 ppm. The oxidation of vinyl chloride was nonlinear in the concentration of vinyl chloride and zeroth order in the concentration of oxygen. The addition of HCl and $H_2O$ as products to the feed stream didn't influence the conversion of vinyl chloride. Several kinetic rate model were tested to describe the data over the range of condition investigated, and developed a model which provide the best correlation of experimental data. The resulting model of kinetic rate was derived by assuming that the reacting occurred via adsorption and subsequent decomposition of the vinyl chloride onto the oxygen covered chromium oxide surface, with the reaction being inhibited by the adsorption of vinyl chloride. The percent standard deviation between the predicted and experimental was about 5.2%, and the activation energy was 18.9 kcal/mol.

• Journal of the Korean Institute of Gas
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• v.5 no.4 s.16
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• pp.85-91
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• 2001

This paper presents safety analysis of LNG leakage in a prestressed concrete outer tank, which is strongly related on the leak checking effects of the PC structure with and without a residual compression zone based on the BS 7777 codes. The full containment type outer tank which is constructed by a prestressed concrete may be destroyed by leaked cryogenic fluids. The FE calculated results show that the total leak checking time of the PC structure with $10\%$ residual compression zone is about 9 days for $-162^{\circ}C$ liquids. But, three primary pumps in an inner tank may operate to send cryogenic fluids for 6 days, which are stored in an inner tank of $140,000m^3$ capacity This means that the prestressed concrete outer tank may be safe for $-162^{\circ}C$ cryogenic fluids leaked from the demolished inner tank.

• The Korean Journal of Pesticide Science
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• v.18 no.2
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• pp.61-68
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• 2014

Dissipation constants and half-lives of acaricides etoxazole and flufenoxuron in apples were calculated to establish their pre-harvest residue limits (PHRLs). The acaricides were sprayed on apples with single and triple doses based on safe use guidelines, and their residual patterns in the apple were interpreted using first order kinetics equation. The residual amounts of acaricides during the experimental period were below their maximum residue limits (MRL) for apple. The dissipation constants of acaricides in the apples were calculated at 0.0788 for etoxazole and 0.0319 for flufenoxuron corresponding to their biological half-lives; 8.8~21.7 days for etoxazole and 21.7~23.1 days for flufenoxuron. The PHRLs of acaricides in the apple showed the residual amounts of etoxazole and flufenoxuron at the harvesting date would be below their MRLs if their residual amounts were less than 0.87 and 0.88 mg/kg, respectively, at 7 days prior to harvesting the apples.

• Journal of Aerospace System Engineering
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• v.14 no.1
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• pp.36-43
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• 2020

The start of satellite thermal design was to predict the worst operating environment through analysis of the thermal environment of the operation orbit. Because the satellites have different types of operating trajectories for their mission, the exposed thermal environment also varies. Thus, it is necessary to analyze in consideration of the orbital conditions, and a design was performed to guarantee thermal stability for the worst case defined through the analysis. The orbital thermal environmental analysis required an understanding of the basic orbit mechanics and the heat exchange relationship between the space environment and satellite. The purpose of this paper was to provide an understanding of the orbital thermal environment analysis by providing basic data on the space thermal environment in the earth-orbit and describing thermal relations that calculate the amount of space heat inflow into satellites. Additionally, an example of a virtual satellite shows the overall process of analyzing the orbital thermal environment during a mission lifetime.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.5
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• pp.523-531
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• 2012

The performance simulation of a desiccant rotor, which is a core component of a desiccant cooling system, was conducted on the basis of a theoretical solution of the heat and mass transfer process in the rotor. The simulation model was validated by comparing simulation results with experimental data; reasonable agreement was observed. The effect of the rotation speed on the performance of the desiccant rotor was investigated for various operation conditions: temperature (50 to $70^{\circ}C$), humidity ratio (0.01 to 0.02 kg/kg DA), and flow rate of regeneration air. The optimum rotation speed was determined from the maximum moisture removal capacity (MRC) of the desiccant rotor, and it was found to vary with the operation conditions. Further, the correlation for the optimum rotation speed was determined by regression analysis.

• Journal of Energy Engineering
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• v.23 no.4
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• pp.169-175
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• 2014

For the safe handling of ethylbenzene, this study was investigated the explosion limits of ethylbenzene in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of ethylbenzene by using Setaflash closed-cup and Pensky-Martens closed-cup testers were experimented $20^{\circ}C$ and $22^{\circ}C$, respectively. The lower flash points ethylbenzene by using Tag and Cleveland open cup testers were experimented $25^{\circ}C$ and $28^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for ethylbnezene. The experimental AIT of ethylbenzene was $430^{\circ}C$. The calculated LEL and UEL by using the measured lower flash point and upper flash point were 0.93 Vol.% and 7.96 Vol.%, respectively.

• Tunnel and Underground Space
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• v.27 no.5
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• pp.333-342
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• 2017

In this study, the heterogeneity of internal structure of various igneous rocks acquired in Korea was quantified and correlated with the seismic velocity and the point load strength. Three-dimensional X-ray Computed Tomography (CT) was used to obtain information on the internal structure of the rock specimen, and the representative unit length (LR) was calculated by applying a statistical technique to the CT images. We also proposed an estimation equation to predict the mechanical properties of rocks from the relationship between LR, acoustic velocity and point load strength. In the proposed method, it is shown that the characterization of internal structure of rocks could be utilized as an indirect index to account for the mechanical behavior of rocks by substituting physical laboratory testing for non-destructive test.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.11 no.3
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• pp.419-428
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• 2000

Multiconductor transmission line(MTL) equations are solved by FDTD(Finite-Difference Time-Domain) method to predict crosstalk and fields to transmission line coupling on lossy multiconductor transmission lines terminated in arbitrary linear loads. Skin effect losses as well as dc losses are included in the analysis. In order to increase computational efficiency, the convolution integral of internal impedance of conductors and the line currents is computed by using Prony method. For boundary conditions of MTLs terminated in linear loads, state-variable formulation is adopted. The simulated results by FDTD method are compared with the measured ones obtained by using TEM cell. The predictions are in good agreement with the measurements. In addition, it has been found that skin effect losses as well as dc losses of the conductors should be included for accurate predictions on relatively high loss transmission lines such as PCB. It has also been found that dc losses and skin-effect losses affect late-time responses and early-time responses, respectively.

• Polymer(Korea)
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• v.24 no.6
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• pp.837-844
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• 2000

The cure behavior of commercial epoxy molding compounds (EMC) commonly used for IC package was studied at constant cure temperatures as well as at constant heating rates using differential scanning calorimetry (DSC), rheometer, and dielectric analyzer (DEA). The cure kinetics were obtained using autocatalytic reaction model according to the Ryan Dutta method after assuming m+n equal to 2. The prediction of reaction rates by the model equation corresponded well to experimental data at all temperatures except for 10$0^{\circ}C$. The phase transitions such as gelation and vitrification occurred during network formation. At each isothermal cure temperature, $T_{g}$ was measured in accordance with cure time, and the vitrification point was attained when $T_{g}$ was equal to $T_{cure}$. The temperature dependence of gel points and vitrification points showed good agreement with Arrhenius relation. DEA using parallel plate electrode was effective for the monitoring of EMC cure. we knew that if the resin systems are materials of comparable quality, $_{gel}$$T_{g}$ is constant regardless of accelerator concentration in TTT (Time-Temperature-Transformation) diagram.

• Journal of Korean Society for Geospatial Information Science
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• v.19 no.4
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• pp.35-45
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• 2011

The purpose of this study is visualizing climate change contents from Weather Research and Forecasting model and providing useful tool to anyone who want to use them for communication and actual movement. As a results, we have built a process and user interface for publishing Arrow KML, BWS KML, and DI KML. Arrow KML provide wind rose service and wind attribute information for each arrow. BWS KML provide a wind power index and DI KML provide a thermal comfort. All KML contents are more reliable because those are visualized from the scientifically verified climate change prediction model. Further study will focus on searching for climate change contents mining and useful contents design for wide range of climate change mitigation/adaptation activity.