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Applicability of Natural Zeolite with Different Cation Exchange Capacity as In-situ Capping Materials for Adsorbing Heavy Metals (중금속 흡착을 위한 원위치 피복소재로서 천연제올라이트의 양이온교환용량에 따른 적용성 평가)

  • Kang, Ku;Shin, Weon-Ho;Hong, Seong-Gu;Kim, Young-Kee;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.2
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    • pp.51-58
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    • 2017
  • We investigated the efficiency of natural zeolite with different cation exchange capacity (CEC) as capping material for the remediation of marine sediments contaminated with heavy metals. Three different zeolite with high CEC (HCzeo, 163.74 cmolc/kg), medium CEC (MCzeo, 127.20 cmolc/kg), and low CEC (LCzeo, 70.62 cmolc/kg) were used. The surface area of the zeolite was in decreasing order: HCzeo ($59.43m^2/g$) > MCzeo ($52.10m^2/g$) > LCzeo ($10.12m^2/g$). The results of mineralogical composition obtained from X-ray diffraction (XRD) show that LCzeo was mainly composed of quartz and albite. In the XRD result of MCzeo and HCzeo, the peaks of clinoptilolite, heulandite, and mordenite were also observed along with that of quartz and albite. Sorption equilibrium onto the HCzeo, MCzeo, and LCzeo was reached in 6 h at initial concentration of 10 mg/L and 100 mg/L. Higher adsorption of Cd and Zn onto the zeolite with higher CEC were achieved but adsorption of Cu and Ni were not dependent on the CEC of zeolite. It can be concluded that the zeolite with high cation exchange ability is recommended for the contaminated sediments with Cd and Zn but the inexpensive zeolite with low CEC for Cu and Ni.

Sea Water Intrusion in the Coastal Area of Cheju Volcanic Island, Korea (제주도(濟州島) 임해지역(臨海地域)에서의 해수침입(海水侵入))

  • Choi, Soon Hak;Kim, Young Ki;Lee, Dong Young
    • Economic and Environmental Geology
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    • v.24 no.3
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    • pp.319-327
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    • 1991
  • Cheju is the biggest island in Korean peninsula, consisted entirely of volcanic rocks and pyroclastic sediments. The topography is characterized by wide basalt plain in the low altitude but at the center of island, basalt volcano rises 1,950m above sea-level. Surface drainage is very poor, therefore water supply has been dependent on ground water and natural springs. There are about 1,650 production wells and most of them yield $1,000{\sim}2,000mm^3/day$. According to increase of ground water use, saline water is intruded in the low altitude of coastal area. Specially in the eastern coastal area, the topography is extensively flat and the level of ground water is very close to sea-level, at which overuse of ground water has brought saline intrusion up to maximum 6km far from the coast. Hydrochemical monitoring on this salt water intrusion is now undertaken on long term base.

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A Geochemical Study on Ulsan Granite in Relation to Iron Ore Deposits in the Gyeongsang Basin (경상분지내 철광상 관련 울산화강암에 대한 지화학적 연구)

  • Lee, Jae Yeong;Kim, Sang Wook;Kim, Young Ki
    • Economic and Environmental Geology
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    • v.25 no.2
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    • pp.133-143
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    • 1992
  • Ulsan granite is plotted mainly in the region of syeno-granite of the Streckeisen diagram, which consists with those of iron related granites in the area of Kimhae-Mulgum, while Chindong granites and Yucheon-Eonyang granites are plotted in the regions of granodiorite-diorite and monzo-granite, respectively. These granites show a differentiation trend of calc-alkaline magma, and their magmatic evolution from intermediate to acidic rocks is consistant with the general crystallization path of the Cretaceous granitic rocks in the Gyeongsang basin. The difference index (D.I.) is 70~90 for Ulsan granite, which lies between 35~80 of Chindong granites and 85~95 of Yucheon-Eonyang granites. These granites are distinguishable from each other by variation patterns of chemical elements. For instance, there is clear difference in content of some major and trace elements between Ulsan granite and Cu-related Chindong granites: Ulsan granite has high content of K (2.68%) and Ba (636 ppm), and low content of Ca (1.07%), Mg (0.50%) and Sr (185 ppm), whereas Chindong granites has less content of K (1.62%) and Ba (382 ppm), and higher content of Ca (3.75%), Mg (1.42%) and Sr (405 ppm). However, the content of Ulsan granite overlaps partly those of Yucheon-Eonyang granites, which are apparently dividable from Chindong granites. There is an usual trend that Cu content is high in Chindong granites of Cu province and Zn content is higher in Yucheon-Eonyang granites of Pb-Zn province. But it is unusual that Cu and Zn are higher in Ulsan granite (34 ppm, 74 ppm) than in Chindong granites (15 ppm, 22 ppm) and Yucheon-Eonyang granites (14 ppm, 43 ppm). This may be due to the reason that Ulsan granite is productive and Cu-Zn minerals are associated with iron ores. Productive Chindong granites in Haman-Gunbug area and Yuchon-Eonyang granites near ore deposits have higher content of Cu and Zn than Ulsang granite. Therefore, it is expected that chemical variation patterns of granites are applicable to distinguish mineral commodity of ore deposits (iron, copper, or lead-zinc) related with the granites in the Gyeongsasng basin.

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Ligament Reconstruction for Subluxation of the Trapeziometacarpal Joint of the Thumb (무지의 대능형중수간 관절의 아탈구에 대한 인대 재건술)

  • Park Jin Soo;Chung Yung Khee;Yoo Jung Han;Na Kyong Soo
    • Journal of Korean Orthopaedic Sports Medicine
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    • v.3 no.2
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    • pp.134-140
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    • 2004
  • Purpose: The reconstructive surgery of the anterior oblique ligament has been recommended for patients with unstable carpometacarpal joints. We reviewed retrospectively the functional results of two patients who had been treated by6 using a harvested portion of the tendon of flexor carpi radialis as a substitute for the anterior oblique ligament. Materials and Methods: In two patients with a instability of the trapeziometacarpal joint because of a rupture of the anterior oblique ligament, reconstruction was carried out using a slip of the tendon of flexor carpi radialis and the patients had been followed up for two years. Results: The results after a follow-up of two years that both of them had significant relief from pain and symptoms. The mean grip strength recovered to 90$\%$ of the controlateral side. patients felt that they had subjective improvement and would have undergone the operation again. Conclusion: Increased awareness of this lesion can lead to an early and clear diagnosis, so that the patient may be advised adequately.

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Study on Local Wireless Network Data Structure for Sludge Multimeter (슬러지 멀티미터를 위한 근거리무선네트워크 데이터구조 설계 연구)

  • Jung, Soonho;Kim, Younggi;Lee, Sijin;Lee, Sunghwa;Park, Taejun;Byun, Doogyoon;Cha, Jaesang
    • Journal of Satellite, Information and Communications
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    • v.9 no.2
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    • pp.96-100
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    • 2014
  • Recently, the management system of wastewater treatment facility has magnified due to the stringent regulations for the protection of the environment, and a sewage treatment plant efficiency and research of the car development are activated in large facilities or industrial park. however, the existing sewerage disposal system and specific water quality monitoring network reliability for real-time transmission of this building is insufficient. In this paper, we proposed a local wireless network design for sludge multi meter data collection and control for measuring the concentration of the sludge efficiently. Also, the collected data over the local wireless network to transmitted to the central monitoring system and accumulate the data in real time to calculate statistics is possible to monitor the status of the sewage treatment facilities. The proposed system uses a short-range wireless networks of IEEE 802.15.4 and configures an IEEE 802.11 network which can monitor real-time status in central system. Also, we install a sludge multimeter and communication network in sewage treatment facilities and confirm the usefulness of the proposed technique by demonstrating its effectiveness.

Hemolytic Properties of Tolaasin Causing the Brown Blotch Disease on Oyster Mushroom (느타리버섯 갈반병 원인독소 Tolaasin의 용혈특성)

  • Cho, Kwang-Hyun;Park, Kyoung-Sun;Kim, Young-Kee
    • Applied Biological Chemistry
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    • v.43 no.3
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    • pp.190-195
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    • 2000
  • Tolaasin is a peptide toxin produced by Pseudomonas tolaasii and causes a brown blotch disease forming brown, slightly sunken spots and blotches on the cultivated mushrooms. It is a lipodepsipeptide consisting of 18 amino acids and its molecular mass is 1,985 Da. It forms a pore in plasma membranes, resulting in the disruption of membranes of fungal, bacterial, plant, and animal cells as well as mushroom tissue. In order to measure the toxicity of tolaasin, erythrocytes of blood were used to evaluate the tolaasin-induced hemolysis. Hemolytic activity of tolaasin was measured by observing the absorbance change either at 420 nm, representing the release of hemoglobins from red blood cells(RBCs), or at 600 nm, representing the density of residual cells. The hemolytic activity of culture-extract of P. tolaasii increased at early-stationary phase of growth and was maximal at late stationary phase. The hemolytic activity of tolaasin appeared high in the RBCs of dog and rat. The RBCs of rabbit and hen were less susceptible to tolaasin. The effects of various cations were also measured. $Cd^{2+}$ and $La^{3+}$. as well as $Zn^{2+}$ appeared inhibitory to the tolaasin-induced hemolysis. The effects of various anions on tolaasin-induced hemolysis were measured and carbonate showed the greatest inhibition to the hemolysis. However, phosphate stimulated the tolaasin-induced hemolysis and no effects were observed by chloride and nitrate.

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Isolation of Protoplasts from Tomato Root by Two-step Osmotic Treatment (토마토 뿌리조직으로부터 두 단계 삼투압 처리에 의한 원형질체의 분리)

  • Shin, Dae-Seop;Han, Min-Woo;Kim, Young-Kee
    • Applied Biological Chemistry
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    • v.47 no.2
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    • pp.192-196
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    • 2004
  • In order to measure cellular physiological activity including ion channel activity, protoplasts were isolated from the root tissue of tomato plant. The general methods recommended were not efficient enough to make protoplasts from the root tissue. Among various conditions tested, we found that a two-step treatment of osmosis is very efficient for the isolation of protoplasts. In this procedure, root tissues were preincubated in a solution containing 300 mM sorbitol for 30 min. Then, they moved to the reaction solution containing 700 mM sorbitol as well as cell wall-digesting enzymes. The formation of protoplast was greatly increased by this method. In order to find the optimal condition of the two-step method, various conditions of pH, osmotic pressure, incubation time, and the concentrations of cell wall-digesting enzymes were tested. The yield of protoplast isolation was maximal at pH 5.0 after 2 hr incubation. Mixed enzymes of 3% cellulase, 1 % macerozyme, and 0.1 % pectolyase showed maximal protoplast isolation. The physiological activity of isolated protoplast evaluated by measuring the cellular ATPase activity was as high as that measured from the preparation of root tissue. The protoplasts isolated by this method were remained healthy up to 4 hrs which is enough time to measure the cellular physiological activity. These results show that the two-step treatment of osmotic pressure was successful to obtain high yield of healthy protoplast from tomato root tissue.

A Statistical Study Evaporation tn DAEGU Area (대구지방의 증발량에 대한 통계학적 연구)

  • 김영기
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.15 no.4
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    • pp.3160-3169
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    • 1973
  • Rainfall, evaporation, and permeability of water are the most important factors in determining the demand of water. The Daegu area has only a meteorologi observatory and there is not sufficient data for adapting the advanced method for derivation of the estimated of evaporation in the Daegu area. However, by using available data, the writer devoted his great effort in deriving the most reasonable formula applicable to the Daegu area and it is adaptable for various purposes such as industry and estimation of groundwater etc. The data used in this study was the monthly amount of evaporation of the Daegu area for the past 13 years(1960 to 1970). A year can be divided into two groups by relative degrees of evaporation in this area: the first group (less evaporation) is January, February, March, October, November, and December, and the second (more evaporation) is April, May, June, July, August, and September. The amount of evaporation of the two groups were statistically treated by the theory of probability for derivation of estimated formula of evaporation. The formula derved is believed to fully consider. The characteristic hydrological environment of this area as the following shows: log(x+3)=0.8963+0.1125$\xi$..........(4, 5, 6, 7, 8, 9 month) log(x-0.7)=0.2051+0.3023$\xi$..........(1, 2, 3, 10, 11, 12 month) This study obtained the above formula of probability of the monthly evaporation of this area by using the relation: $F_(x)=\frac{1}{{\surd}{\pi}}\int\limits_{-\infty}^{\xi}e^{-\xi2}d{\xi}\;{\xi}=alog_{\alpha}({\frac{x_0+b'}{x_0+b})\;(-b<x<{\infty})$ $$log(x_0+b)=0.80961$ $$\frac{1}{a}=\sqrt{\frac{2N}{N-1}}\;Sx=0.1125$$ $$b=\frac{1}{m}\sum\limits_{i-I}^{m}b_s=3.14$$ $$S_x=\sqrt{\frac{1}{N}\sum\limits_{i-I}^{N}\{log(x_i+b)\}^2-\{log(x_i+b)\}^2}=0.0791$$ (4, 5, 6, 7, 8, 9 month) This formula may be advantageously applied to estimation of evaporation in the Daegu area. Notation for general terms has been denoted by following: $W_(x)$: probability of occurance. $$W_(x)=\int_x^{\infty}f(x)dx$$ P : probability $$P=\frac{N!}{t!(N-t)}{F_i^{N-{\pi}}(1-F_i)^l$$ $$F_{\eta}:\; Thomas\;plot\;F_{\eta}=(1-\frac{n}{N+1})$$ $X_l\;X_i$: maximun, minimum value of total number of sample size(other notation for general terms was used as needed)

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Enhanced Nitrate Uptake by Enterobacter amnigenus GG0461 at Alkaline pH (염기성 pH에서 Enterobacter amnigenus GG0461의 질산이온 흡수증가)

  • Choi, Tae-Keun;Kim, Sung-Tae;Han, Min-Woo;Kim, Young-Kee
    • Applied Biological Chemistry
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    • v.51 no.1
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    • pp.1-5
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    • 2008
  • Salt accumulation in soils of greenhouse due to the massive application of nitrogen fertilizers causes salt stress on the various crops, a serious problem in domestic agriculture. Since the majority of the salinity is nitrate, the excess nitrate should be removed; therefore, a bacterial strain having high capacity of nitrate uptake and identified as Enterobacter amnigenus GG0461 was isolated from the soils of greenhouse. Optimum conditions for the bacterial growth and nitrate uptake were investigated. GG0461 was able to grow without nitrate; however, nitrate facilitated the growth. The rate of nitrate uptake increased at alkaline pH and both growth and nitrate uptake were maximal at pH 8-9. When the initial pH of culture medium was increased to pH 8 or 9, it was decreased to neutral upon bacterial growth and nitrate uptake. These results imply that the major factor mediating bacterial nitrate uptake is a nitrate/proton antiporter. The fact was supported by the effect of nitrate addition in the absence of nitrate, since the addition of nitrate greatly increased the nitrate uptake and rapidly decreased pH of media.

Characterization of Fusarium solani Causing Fusarium Root Rot of Lisianthus in Korea (꽃도라지 뿌리썩음병을 일으키는 Fusarium solani 의 특성)

  • Choi, Hyo-Won;Hong, Sung Kee;Lee, Young Kee;Kim, Jeomsoon;Lee, Jae Guem;Kim, Hyo Won;Kang, Eun Hye;Lee, Eun Hyeong
    • The Korean Journal of Mycology
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    • v.45 no.1
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    • pp.74-82
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    • 2017
  • Lisianthus (Eustoma grandiflorum) is a flowering ornamental plant used widely in Korea. In 2015, wilting, damping-off, stunting, and root rot symptoms were observed in lisianthus plants of Yeoju and Gimhae, Korea. Affected seedlings appeared yellow and showed poor development of root systems in the field and in nursery boxes. Furthermore, affected plants were yellow, stunted, and died at approximately 2-3 months after transplanting. Fusarium species were consistently isolated from the basal stems of diseased plants. Nine isolates were identified as Fusarium solani based on morphological characteristics. Macroconidia of isolates were relatively wide, straight-to-slightly curved, and microconidia formed in false heads on long monophialides. Abundant chlamydospores were produced at the middle or tips of hyphae. To confirm this identification, a molecular analysis of the translation elongation factor 1 alpha (TEF) and RNA polymerase II subunit (RPB2) genes was conducted. The sequences of TEF and RPB2 showed 99.2-99.9% and 98.0-98.1% similarity, respectively, to those of reference F. solani strains in NCBI GenBank. Pathogenicity was tested using root dipping inoculation of healthy lisianthus seedlings. Symptoms were observed within 7 days of inoculation only in inoculated plants. This is the first report of F. solani causing Fusarium root rot on lisianthus in Korea.