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Structure-activity relationships on the herbicidal activity of the 2,3-dihydro-2-ethyl-2,4,6,7-tetramethylbenzofuran-5-yl substituents in 5-benzofuryl-2-[1-(alkoxyimino)alkyl]-3-hydroxycyclohex-2-en-1-one derivatives (5-Benzofuryl-2-[1-(alkoxyimino)alkyl]-3-hydroxycyclohex-2-en-1-one 유도체 중 2,3-dihydro-2-ethyl-2,4,6,7-tetramethylbenzofuran-5-yl 치환체들의 제초활성에 관한 구조-활성관계)

  • Sung, Nack-Do;Song, Jong-Hwan;Kim, Kyoung-Mahn
    • The Korean Journal of Pesticide Science
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    • v.4 no.3
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    • pp.34-39
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    • 2000
  • A new fifteen 2,3-dihydro-2-ethyl-2,4,6,7-tetramethylbenzofuran-5-yl substituents in 5-benzofuryl-2-[1-(alkoxyimino)alkyl]-3-hydroxycyclohex-2-en-1-one derivatives as substrate were synthesized and their herbicidal activities against rice plant (Oryza sativa L.) and barnyard grass (Echinochloa crus-galli) with post emergence were measured under submerged conditions. The $R_{1}$=methyl substituents, $1{\sim}8$ showed the higher herbicidal activity to the rice plant and barnyard grass. The structure-activity relationships (SARs) on tile herbicidal activity of $R_{1}$ and $OR_{2}$ groups on the azomethine bond in substrates were analysized. From tile results of dicussed SAR, the herbicide activities against rice plant would depend largely on the steric factor, Whereas, in case of barnyard grass, the activities were governed by the hydrophobicity factor. The conditions of selective herbicide activity between the two plant species are assumed that the substrates should nave optimal hydrophobicity ( $(logP)_{opt.}=6.0$), a $R_{1}$ groups of small and a long $OR_{2}$ groups.

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Herbicidal Activity and Persistency in Aqueous Solution of Ortho Disubstituted Benzenesulfonyl Urea Derivatives (새로운 Ortho 이치환 Benzenesulfonyl Urea 유도체의 제초활성과 수용액중의 잔류성)

  • Kim, Yong-Jip;Chang, Hae-Sung;Kim, Dae-Whang;Sung, Nack-Do
    • Applied Biological Chemistry
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    • v.38 no.6
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    • pp.570-576
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    • 1995
  • The new sixteen herbicidal N-2-(1-hydroxy-2-fluoroethyl)-6-substituted(X)-benzenesulfonyl-N'-4,6-dimethoxypyrimidinyl-2-yl urea derivatives(S) were synthesized and thier herbicidal activities$(pI_{50})$ in vivo against rice(Orysa Sativa L.), Barnyard grass(Echninochloa orizicola) and Bulrush(Scirpus juncoides) were measured by the pot test under paddy conditions. The structure activity relationship(SAR) were studied using the physicochemical parameters of ortho-substituents(X) and hydrolysis rate constant(logk) and herbicidal activities by the multiple regression technique. The SAR suggested that the herbicidal activities were more dependant on the hydrolysis rate constant(logk>0) than the steric constants $(Es, small width($B_4$) and length($L_1$). Among them, halogens(2 & 5), methyl(15) and non(H) substituent(1) showed higher herbicidal activity for weeds which was not tolerent to rise and weeds. The herbicidal activity was increased and the persistency in aqueous solution was decreased by electron donating(${\sigma}0<0$) groups as ortho-substituent(X). From the relationship equation between herbicidal activity and hydrolysis rate constant, it was assumed that the both reactions would be proceeds with similar process. And the conditions on the ortho substituents to show higher herbicidal activity and the persistency in aqueous solution were also discussed.

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Agronomic Characteristics and Anti-oxidant Capacity of Mulberry Genetic Resources conserved by Jeollabuk-Do (전라북도 뽕나무 유전자원의 재배생태적 특성 및 항산화능 분석)

  • Kim, Hyun-Bok;Koh, Seong-Hyouk;Oh, Nam-Ki;Jeong, Jong-Seong;Sung, Gyoo-Byung;Hong, In-Pyo;Chung, In-Mo;Lee, Kwang-Gill
    • Journal of Sericultural and Entomological Science
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    • v.49 no.2
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    • pp.60-66
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    • 2007
  • This study was carried out to develop the utilization of mulberry resources conserved by Jeollabuk-Do Agricultural Research & Extension Services. Mulberry accessions were tested for agronomic characteristics and antioxidant capacity according to varieties. From that result, three suitable varieties such as 'Sinilppong', 'Suwonsang 2' and 'Ilbongeum' were selected for the production of mulberry leaves. They have strong agronomic characteristics like size, yield and resistance against damages by blight and harmful insects. Whereas, 'Gumunyoung' showed the lowest freezing resistance. In the antioxidant capacity analysis of mulberry leaves, autumn's mulberry leaves showed higher antioxidant capacity (ascorbic acid equivalent) than that of spring's it. According to collection time, antioxidant capacity were 2,109.8 nmol (August), 2,617.8 nmol (September) and 3,311.5 nmol (October), respectively.

Characteristics of Newly Bred Mulberry Cultivar "Daesungppong" (Morus Lhou(Ser.) Koidz.) for Mulberry Fruit Production (새로 육성한 오디 생산용 뽕품종 "대성뽕"의 특성)

  • Sung, Gyoo-Byung;Kim, Hyun-Bok;Hong, In-Pyo;Nam, Sung-Hee;Chung, In-Mo
    • Journal of Sericultural and Entomological Science
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    • v.49 no.2
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    • pp.56-59
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    • 2007
  • We bred new mulberry cultivar through local adaptability test, which was registered as a new cultivar for fruit production. Local adaptability test had been carried out at three places(Suwon, Konju and Cheongju) for three years since 2002. This is tetraploidy variety belonging to (Morus Lhou(Ser.) Koidz.) made by colchicine treatment on growing point of winter buds. Daeseongppong was high yielding in productivity by 48% compared to control cultivar "Chungilppong" for two years. Although Daesungppong was a little lower in sugar content of mulberry fruits, it contains more bioactive materials like C3G, rutin and amino acids than Chungilppong. It is adaptable to every where except the places where cold damage and sclerotial disease happen frequently.

Characteristics of mulberry cultivar 'palchung' (Morus Lhou(Ser.) Koidz.) for mulberry breeding as pollen parent (오디 생산용 뽕 품종 육성을 위한 교배모본 '팔청'의 특성)

  • Sung, Gyoo Byung;Kim, Yong Soon;Kim, Kee Young;Kim, Hyun-Bok;Ji, Sang;Kang, Pil Don
    • Journal of Sericultural and Entomological Science
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    • v.52 no.2
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    • pp.147-154
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    • 2014
  • We bred a mulberry cultivar named Palcheong, through local adaptability test, which is under registration as a new cultivar for fruit production. Local adaptability test had been carried out at four places (Suwon, Kongju, Wanju, and Jinju) for seven years from 2007. This is belonging to (Morus Lhou(Ser.) Koidz.) selected among mulberry genetic resources preserved in Suwon. Its sex expression was hermaphrodite, which can be used for the production of seedling for fruit production by artificial crossing as pollen parent Palchung showed lower yielding in fruit productivity by 16% compared to control cultivar 'Chungil (Morus alba L.)' for five years. Although Palchung was higher in sugar content of mulberry fruits, it was bigger than that of 'Chungil'. It is adaptable to every where except the places where cold damage and sclerotic disease happen frequently.

Quantitative analysis of rutin with mulberry leaves (II) (뽕나무 유전자원의 rutin 함량 변이(II))

  • Kim, Hyun-Bok;Kim, Sun-Lim;Lee, Sun-Ho;Sung, Gyoo Byung;Seok, Young-Seek;Kim, Yong Soon;Ju, Wan-Taek;Kim, Sung-Kuk;Chung, Da Eun;Jo, You-Young;Kweon, HaeYong;Lee, Kwang-Gill
    • Journal of Sericultural and Entomological Science
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    • v.52 no.2
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    • pp.129-133
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    • 2014
  • We analyzed rutin content using mulberry genetic resources. They were grown under the same environment and conditions. Mulberry leaves were collected and then freeze-dried and powdered for rutin test. As a result, mean content of mulberry strains was $0.38{\pm}0.17%$, and the coefficient of variation (CV) was 45.7%. The variation was greatly severe. Among the tested strains, 'Jangloe' was showed the highest content of 0.97%, whereas 'Sungsu 3' was showed the lowest content of 0.01% respectively. Finally we selected rutin high-containing 6 strains. They are as follows. 'Jangloe', 'Pumbo 6', 'Youjin', 'Kaeryangjeonjeon', 'Baekhak', and 'Pumbo 32' which are more than twice of the overall average content.

Antagonistic Mode of Action of Fenoxaprop-P-ethyl Phytotoxicity with Bentazon (Fenoxaprop-P-ethyl의 제초활성에 대한 Bentazon의 길항작용기구)

  • Ma, S.Y.;Kim, S.W.;Chun, J.C.
    • Korean Journal of Weed Science
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    • v.18 no.2
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    • pp.161-170
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    • 1998
  • Antagonistic mode of action of fenoxaprop-P-ethyl [ethyl(R)2-4-{(6-chloro-2-benzoxazolyloxy) phenoxy}propionate] with bentazon was investigated with respect to absorption, translocation, metabolism, and change in target site response of fenoxaprop-P-ethyl using four-leaf stage of rice(Oryza sativa L.) and barnyardgrass [Echinochloa eras-galli (L.) P. Beauv.]. Shoots of rice and barnyardgrass was more sensitive to fenoxaprop-P-ethyl than the roots. More than 90% of fenoxaprop-P-ethyl was absorbed within 6 hours after treatment and 30% of the absorbed was acropetally and basipetally translocated at 24 hours after treatment. Fenoxaprop-P-ethyl was rapidly transformed to its acid form, fenoxaprop(2-[4-(6-chloro-2-benzoxazolyloxy)phenoxy]propionic acid), which was subsequently metabolized to polar conjugates. However, changes in absorption, translocation, and metabolism of fenoxaprop-P-ethyl by bentazon treatment were not found in both species. Background activity of acetyl-CoA carboxylase(ACCase) in rice and barnyardgrass was 26.5 and 23.2nmol/min/mg, respectively. Concentration required to inhibit fifty percent enzyme activity$(I_{50})$ in vitro was 6.5~7.4${\mu}M$ of fenoxaprop-P-ethyl and more than 500${\mu}M$ of bentazon. There were no significant differences in $I_{50}$ value between two treatments of fenoxaprop-P-ethyl alone and its bentazon mixture. However, bentazon reduced ACCase activity in vivo and inhibited electron transport in chloroplast thylakoid. Based on the results obtained, it is concluded that the antagonistic effect of bentazon occurs due not to direct effect on target site of fenoxaprop-P-ethyl, but to indirect involvement in reducing herbicidal activity of fenoxaprop-P-ethyl through physiological disturbances caused by bentazone at whole chloroplast level.

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Tank-mix Feasibility Reducing the Application Rate of Quinclorac (Quinclorac 함량감소(含量減少)를 위한 혼합처방(混合處方)의 가능성(可能性) 연구(硏究))

  • Guh, J.O.;Han, S.U.;Chon, S.U.
    • Korean Journal of Weed Science
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    • v.13 no.1
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    • pp.14-18
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    • 1993
  • Greenhouse study was undertaken to find tank-mix feasibility of quinclorac with molinate and propanil, selective post-emergence herbicides in controlling barnyardgrass, for reducing the application rate of quinclorac. Following foliar application in combination of quinclorac at 0.038, 0.075, 0.150, and 0.300kg ai/ha with molinate at 0.190, 0.380, 0.750 and 1.500kg ai/ha, and propanil at 0.263, 0.525, 1.050, and 2.100kg ai/ha at 3.5-leaf stage of barnyardgrass, fresh weight and weeding efficacy and their interaction by Colby's efficacy method were evaluated. Percent inhibition of barnyardgrass growth by quinclorac, molinate and propanil at recommended rate were 78.1, 26.1, and 61.7%, respectively. The dose combination shown above 85% in weeding efficacy were from 0.300kg of quinclorac with 0.75kg of molinate and 0.150kg of quinclorac with all rates of propanil. Therefore, combination of quinclorac with molinate tended to additive interaction and that of quinclorac with propanil appeared partially synergistic interaction. Conclusively, for reducing the application rate of quinclorac, the combination of quinclorac with propanil was more synergistic than that of quinclorac with molinate.

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Study for Sequential Application of Herbicide to Establish an Efficient Weed Control in Red Pepper Field (고추 밭 잡초 관리를 위한 제초제 체계 처리법 개발)

  • Min, Yi-Gi;So, Yoon-Sup
    • Weed & Turfgrass Science
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    • v.5 no.4
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    • pp.213-218
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    • 2016
  • Timely application and the choice of herbicides are crucial for red pepper production since the yield is significantly reduced by weed occurrence. Experiments were conducted to provide efficient weed control methods in red-pepper fields. The results suggest the followings: 1) in the field of prevalent grass weeds, application of pendimethalin EC as pre-emergence herbicide after transplanting followed by tank-mix with pendimethalin and fluazipfop-P-butyl EC as post-emergence at 3-5 leaf stage of Digitalia species gave a good control for 80 days without crop injury, 2) as for grass and other weeds occurrence, sequential application of tank-mix with glufosinate-ammonium SL and pendimethalin at 30 days after transplanting (DAT) followed by glufosinate-ammonium. at < 20 cm of weed height with 30 days' interval provided better weed control than 2-time application of glufosinate-ammonium. single application for 80 days in this trial. 3) To prevent from drifting of non-selective herbicide spray mist into red-pepper at furrow application, glufosinate-ammonium. should be applied at 15 cm of spray nozzle height at 20 DAT (18 cm tall of red pepper), and the spray nozzle should be placed below 30 cm above ground to keep spray drift minimum to red pepper with > 40 cm plant height at 40 DAT.

Physiological Response of Chinese Cabbage to Salt Stress (염 스트레스에 대한 배추의 생리학적 반응)

  • Kim, Ju-Sung;Shim, Ie-Sung;Kim, Myong-Jo
    • Horticultural Science & Technology
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    • v.28 no.3
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    • pp.343-352
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    • 2010
  • In order to understand the plant responses to salt stress (0, 50, and 100 mM NaCl), Chinese cabbage seedlings grown up to two leaf stages by hydroponic culture were used. Fresh and dry weight, chlorophyll (Chl), antioxidant materials, polyamine content, antioxidant enzyme activities, and inorganic ion level were evaluated. Fresh and dry weights of Chinese cabbage increased with the increase in salinity while the optimal growth occurred at 50 mM NaCl. The Chl a, total Chl, carotenoid content, and Chl a/b ratio increased by the 6 days after treatment with 100 mM NaCI; however, the Chl b content decreased. Glutathione increased in the root of Chinese cabbage for 6 days. Dehydroascorbate increased remarkably by day 6 caused by the salt stress in both leaf and the root. While ascorbate peroxidase increased, the activity of catalase and glutathione reductase decreased gradually in the first leaf for 6 days. The $Na^+$ content increased by 12.5-fold in the 3 days after treatment with 100 mM NaCI in the shoot, whereas the $Ca^{2+}$, $K^+$, and $Mg^{2+}$ content measured in the same treatment decreased by 43 to 57%. Spermidine content decreased as salinity increased, but spermine content increased. The growth promotion, glutathione and ascorbic acid content in Chinese cabbage were increased by low salt stress, and shortening of the cultivation period for growth increase of Chinese cabbage is expected.