• Title/Summary/Keyword: 염화

Search Result 1,974, Processing Time 0.028 seconds

Effects of Calcium Chloride Concentration and Reaction Time on Physical and Sensory Characteristics of Persimmon Calcium Alginate Beads (염화칼슘 농도와 반응시간에 따른 감 칼슘 알지네이트 비드의 물리적 및 관능적 특성)

  • Yong, Dong-Hee;Song, Min-Kyung;Yoon, Hye-Hyun
    • Culinary science and hospitality research
    • /
    • v.18 no.4
    • /
    • pp.209-221
    • /
    • 2012
  • The purpose of this study is to apply molecular gastronomy and its spherification methodology to persimmon desserts. We prepared persimmon calcium alginate beads and investigated physical and sensory characteristics of beads according to the different concentration of calcium chloride(0.5, 0.75, 1.0%) and reaction time(2, 4, 6, 8, 10 min). Lightness and yellowness were decreased significantly as both calcium chloride concentration and reaction time increased. However, redness was increased significantly as the concentration of calcium chloride and reaction time increased. Hardness, springiness, chewiness, cohesiveness, and resilience except for adhesiveness tended to increase as the concentration of calcium chloride and reaction time increased. The thickness of beads also increased as the concentration of calcium chloride and reaction time increased. Quantitative descriptive analysis showed that voluminosity, springiness, hardness, chewiness, and residue tended to increase as the concentration of calcium chloride increased. Overall acceptability reached a peak at the persimmon bead containing 0.5% calcium chloride. The result of this study showed that the concentration of calcium chloride and reaction time influenced the overall characteristics of calcium alginate beads.

  • PDF

Effect of Composition on the pH and Solution Potential of Mixed Solutions of Copper and Iron Chloride (염화(鹽貨)구리와 염화철(鹽貨鐵) 혼합용액(混合溶液)의 조성(組成)이 pH와 용액전위(溶液電位)에 미치는 영향(影響))

  • Lee, Man-Seung;Son, Seong-Ho
    • Resources Recycling
    • /
    • v.17 no.6
    • /
    • pp.17-23
    • /
    • 2008
  • In order to simulate the leaching solution of copper sulfide ore in $FeCl_3$ solutions, synthetic solutions with composition of $FeCl_3$-$FeCl_2$-$CuCl_2$-CuCl-NaCl-HCl-$H_2O$ were prepared. The concentration of iron and copper chloride was varied from 0.1 to 1 m in synthetic solutions. The effect of composition on the mixed solution pH and potential at $25^{\circ}C$ was measured. When HCl concentration was constant, the increase of CuCl concentration increased solution pH. The increase of other solutes excluding HCl and CuCl decreased solution pH owing to the increase of the activity coefficient of hydrogen ion. A high CuCl concentration favored the redox equilibrium in the direction of Cu(I), while $FeCl_3$ had the opposite effect.

Effect of NaCl on Halomonas subglaciescola DH-1 Incapable of Growing at Non-Salinity (Halomonas subglaciescola DH-1의 생장에 미치는 염화나트륨의 영향)

  • Na, Byung-Kwan;Yoo, Young-Sun;Park, Doo-Hyun
    • Microbiology and Biotechnology Letters
    • /
    • v.35 no.4
    • /
    • pp.298-303
    • /
    • 2007
  • A halophilic bacterium, H. subglaciescola DH-1, grew at 2.0 M salinity, but did not grow at 0.8 M salinity when cultivated at higher temperature ($40^{\circ}C$) than optimum ($30^{\circ}C$). When the cell extract of strain DH-1 was heated at $50^{\circ}C$ for 60 min in the absence of NaCl, isocitrate dehydrogenase and malate dehydrogenase lost their activities, but when it was heated in the presence of 2.0 M NaCl, the activity was maintained. Meanwhile, the cell extract of E. coli did not catalyze the reduction of $NAD^+$ to NADH coupled with the oxidation of isocitrate and malate at higher salinities than 1.0 M. The pH range for DH-1 was 7 to 10, and that for E. coli was 5 to 9. DH-1 was not grown in conditions with sodium salts other than NaCl.

Effect of Lithium Chloride on the Borane Reduction of Organic Compound (보란-염화리튬에 의한 유기화합물의 환원반응)

  • Nung Min Yun;Jin Soon Cha
    • Journal of the Korean Chemical Society
    • /
    • v.22 no.1
    • /
    • pp.37-44
    • /
    • 1978
  • The effect of lithium chloride on the borane reduction of organic compounds was studied for three ketones, seven acid derivatives, three epoxides and cyclohexene in tetrahydrofuran at $0^{\circ}$. When compared with borane itself, borane-lithium chloride system enhanced the rates of reductions markedly of 2-heptanone, acetophenone, benzoyl chloride, phthalic anhydride, and three epoxides, whereas the reductions of benzophenone, four esters and cyclohexene showed little or no effect. $BH_3$-LiCl (1 : 0.1) reduced styrene oxide in 2 hr at $0^{\circ}$ to give 94.2 % yield of alcohols, 1-to 2-phenylethanol ratio being 60.8 to 39.2. And in the reduction of cyclohexene oxide, $BH_3$-LiCl (1 : 0.1) gave a quantitative yield of cyclohexanol in 2 hr at $0{\circ}$, however $BH_3$-LiCl (1 : 1) gave 58 % cyclohexanol and 42 % 2-chlorocyclohexanol. In the reduction of cyclohexene oxide, lithium nitrate showed no rate enhancement even when the salt was added in large excess. A formation of lithium chloroborohydride in the$BH_3$-LiCl system is suggested.

  • PDF

Development of Maintenance Simulation System and Prediction of Chloride Ion Permeation for Marine Concrete Structures (해양콘크리트 구조물의 염해 예측 및 유지보수 시뮬레이션시스템 개발)

  • Lee, Chang Su;Kim, Meyong Won
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.17 no.1
    • /
    • pp.64-75
    • /
    • 2013
  • As both laboratory accelerated experiment and field exposure experiment were performed, at recent, the fifth field test at five year exposures was proceeded according to long period experimental plan. Field experiment, for the adoption of the developed evaluation model, which is consisted of the analysis of chloride penetration profile at gate bridges of sea-dike completed 30 years ago was carried out during upgrading the basic evaluation model with analyzing the annual field test data. The surface concentration of chlorides was replaced to the concentration of chloride of inner concrete near the surface chlorides among his research results at basic model. Maage's suggestion function was accepted too as a diffusion coefficient of chloride after verifying the change of diffusion coefficient by analysis of annual field test data. The comparison of field data with model predictions and the estimation of remaining life time demonstrates that the proposed updated model and maintenance simulation system can be used to predict the chloride penetration profile in the marine tidal zone and appropriate repair period and cost.

Effect of Initial Flexural Crack on Resistance to Chloride Penetration into Reinforced Concrete Members (초기 휨균열이 철근콘크리트 부재의 염화물침투저항성에 미치는 영향)

  • Yang, Eun Ik;Jin, Sang Ho;Kim, Myung Yu;Choi, Yoon Suk;Han, Sang Hun
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.15 no.2
    • /
    • pp.79-87
    • /
    • 2011
  • In this study, the chloride penetration tests were performed for the initially cracked reinforced concrete members. The chloride diffusion characteristics and the critical crack width are compared, and the properties of self-healing are investigated. According to the test results, the chloride penetration resistance was greatly reduced as the surface crack width increased. When the mineral admixtures are added, the chloride penetration resistance of uncracked specimens were effectively increased, however, in case of the blast furnace slag and fly ash, the cracked specimens showed the more reduced resistance than OPC case, inversely. Also, the critical width was $29{\mu}m$, on average, for immersion test. The crack width with $4{\sim}15{\mu}m$ was restored by self-healing, The parts restored by self-healing were seemed to be visually restored, however, the chloride penetration resistance was not restored, perfectly.

A Study on Prediction Model of Chloride ion Permeation of Cement Mortar by Steel Powder (염해환경에서의 염화물이온 침투 예측에 관한 연구)

  • Kim, Jeong-Jin;Park, Soon-Jeon;Ko, Joo-Hwan;Han, Cheon-Goo
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2008.04a
    • /
    • pp.513-516
    • /
    • 2008
  • In this study the prediction model of Chloride Ion progress rate of concrete using steel powder as an addition is developed, in which the reduction of not only the diffusion rate of $Cl^-$ but also the corrosion rate by replenishment of pore by corrosion products. The model is based on the diffusions of $Cl^-$ and its reaction with $Fe^{2+}$, in chloride attack progression region. The model can also explain the characteristics of chloride ion permeation resistance of concrete that the matrix is densified due to corrosion products. The prediction by the model agreed well the experimental data in which the concrete using steel powder, and it showed the lower rate in long-term age to Chloride Ion progress rate than the concrete without steel powder. Consequently the model can predict Chloride Ion progress rate of concrete exposed in the atmosphere regardless of the water-to-cement raito, the amount of the content of steel powder, etc.

  • PDF

The Diffusion Property of Chloride Ion into Concrete by Electrically Accelerated Method (전기적인 촉진시험에 의한 콘크리트의 염화물이온 확산특성)

  • Bae, Ju-Seong;Park, Gook-Joon
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.14 no.3
    • /
    • pp.138-143
    • /
    • 2010
  • Recently, as many big marine concrete structures increase, it is necessary that chloride ion diffusion coefficient of concrete shall be evaluated but it will take a long time to evaluate chloride ion diffusion coefficient of concrete. Accordingly, many test methods are suggested to evaluate chloride ion diffusion coefficient in a short period time by the promotion in electro chemical ways but the systematic study for this is insufficient. Therefore, this study evaluates chloride ion penetration and diffusion features by three representative electric promotion tests targeting for three different cements whose ingredients are different and analyzes the correlationship between them. As a result, diffusion features of chloride ion varied according to the cement ingredients and three ingredients cement in which blast furnace slag powder and fly ash are mixed in constant ratio, which shows the most excellent cement diffusion properties. For diffusion properties of chloride ion, the correlationship between test methods are good.

경질염화비닐관 매설실험결과

  • Korea Water and Wastewater Works Association
    • 수도
    • /
    • s.2
    • /
    • pp.62-67
    • /
    • 1974
  • PVC 파이프는 상수도용 배수관을 비롯하여 하수도, 공업용 및 농업용수도 등에서의 수요가 급증하고 있는데 일본 "염화비닐과 포리마" 5월호에 게재된 "경질염화비닐관 매설 실험결과"에 의하면 매설관으로서의 안전성, 타공사에 의한 측토압에 대한 내력, 접합부의 강도, 내충격강도 등이 우수한 것으로 판명되고 있어 참고에 공한다.

  • PDF

염화철처리 활성탄에 의한 합성지하수 중의 질산성 질소 제거

  • 정경훈;정오진;최형일;김우항;박상일;강민석
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 2004.05a
    • /
    • pp.324-328
    • /
    • 2004
  • 본 연구에서는 활성탄을 염화철로 표면 처리한 염화철처리 활성탄을 사용하여 지하수중의 ${NO_3}^{-}$-/-N 제거 가능성과 그 제거에 미치는 영향을 검토하고자 한 것으로 다음과 같은 결론을 얻었다. 1) 조제된 염화철 코팅 활성탄의 표면을 SEM으로 분석한 결과를 보면 활성탄의 표면에 염화철이 코팅되어 있는 것을 확인할 수 있었다. 2) 통수유속이 0.5~4 BV $hr^{-1}$/로 낮을 경우는 질산성 질소 파과시점이 비슷하였으며, 통수유속이 커질수록 활성탄의 비표면적에 접하는 시간이 짧아져서 파과시점이 짧아진 것으로 사료된다. 3) 연속컬럼 실험(3.1 L)에서 통수량 약 82 L까지는 ${NO_3}^{-}$/-N의 파과시점이 나타나지 않았으며 재생액의 농도가 0.5 M-KCl에서는 약 9 L, 1 M-KCl에서는 약 7 L의 재생액이 사용되었고, 재생 후 각각의 파과시점은 약 53 L, 59 L로 유지되었다. 1 M-KCl의 재생액을 사용하여 재생하였을 경우 두번째 재사용과 재생부터 총 질산성 질소 제거량은 약 1,531~l,357 mg/kg, 탈착량은 약 1,526~1,306 mg/kg으로 일정하였다.

  • PDF