• Title/Summary/Keyword: 염화물 이온 침투성

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Durability of VA/E/MMA-Modified Mortars with Nitrite-Type Hydrocalumite (VA/E/MMA 터폴리머 분말수지와 아질산형 hydrocalumite를 병용한 폴리머 시멘트 모르타르의 내구성)

  • Hong, Sun-Hee;Lee, Jae-Hwa;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05a
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    • pp.41-42
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    • 2011
  • In this study, VA/E/MMA-modified mortars with nitrite-type hydrocalumite were prepared with various calumite contents and polymer binder-ratios, and tested for chloride ion penetration, carbonation and drying shrinkage. As a result, the chloride ion penetration and carbonation depths were somewhat increased with calumite contents, but those were remarkably decreased depending on the polymer-binder ratios. The 28-d drying shrinkage showed a tendency to increase with polymer-binder ratios and calumite contents. VA/E/MMA-Modified mortars with a calumite of 10 % were dissatisfied with KS requirements. Accordingly, a calumite content of 5 % for the VA/E/MMA-modified mortars with calumite is recommended.

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A Study on Repair Method of Concrete Structures using the Solution of Removing Chloride (염분제거용 약액을 이용한 콘크리트 구조물의 보수공법에 관한 연구)

  • Kim, Woonhak;Hwang, Sungwoon;Kang, Seokwon
    • Journal of the Society of Disaster Information
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    • v.13 no.4
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    • pp.562-569
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    • 2017
  • Reinforced concrete is used for bridges and large structures that are constructed with social overhead capital because they are economically and semi-permanently integrated with reinforcing bar and concrete. However, when the chloride ion in the concrete destroys the passive film of the reinforcing bar by the marine exposure environment and the snow remover used in the winter season, and the reinforcing bar is corroded by various chemical and physical actions, the durability is deteriorated in a short period, and the life span is shortened. In this study, a repair method to recover the durability of the initial structure by effectively removing chloride ion from the damage caused by salting of the above mentioned reinforced concrete was conducted.

Property Analysis of Waterproofing and Corrosion-Resistant Performance in Concrete Water Supply Facilities (상수도시설 콘크리트 수조구조물에서의 염화이온 침투저항 특성분석)

  • Kwak, Kyu-Sung;Ma, Seung-Jae;Choi, Sung-Min;Oh, Sang-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.2
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    • pp.122-131
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    • 2015
  • The purpose of this study is to understand the necessity for waterproofing and corrosion-resistant technique application on concrete water tank used in water supply. Relevant research materials and regulation were collected, reviewing for the case studies of sample structures aged over 20 years, and experimental studies on chloride conduction for the high performance concrete and penetration properties of water repellency of liquid type materials. The result is that the concrete water tank in the water supply is needed for waterproofing and corrosion-resistant material coating to maintain long term durability due to the constant environmentally induced degradation deterioration often caused by chloride attack.

Influences of Slag Replacement on the Properties of Shotcrete Using a Slurry-Type Set Accelerator (슬래그 혼입량이 슬러리형 급결제를 활용한 숏크리트 몰탈의 물성에 미치는 영향)

  • Kim, Hyunwook;Moon, Hoon;Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.389-396
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    • 2014
  • The set accelerator used for shotcrete at high pH environment often causes the dusting problem in practice. In this research, a slurry-type set accelerator was developed to avoid this problem and its effectiveness was investigated by applying it to shotcrete mortars. Set time, stiffening, compressive strength, and chloride ion penetration resistance were examined with different amounts of slag, used as partial replacement of cement. According to the experimental results, it was found that the earlier responses such as set time, stiffening, and 1-day compressive strength were probably affected by the amount of ettringite, formulated by the hydration between C12A7 and calcium sulfate polymorphs present in blast furnace slag. Whereas, it is believed that the result of compressive strength after 3 days was attributed to the hydration of tricalcium silicates. As for the results of a chloride ion penetration test, the partial replacement of cement with slag significantly reduced the total charge passed through the shotcrete mortar.

Mechanical Properties And Chlorde Penetration Resistance of Shotcrete according to Mineral Admixture Types and Supplemental Ratio (광물성 혼화재료의 종류 및 혼입율에 따른 숏크리트의 역학적 특성 및 염해 저항성)

  • Han, Seung-Yeon;Yun, Kyong-Ku;Nam, Kyeong-Gung;Lee, Kyeo-Re;Eum, Young-Do
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4960-4968
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    • 2015
  • In this study to improve the chloride durability of the shotcrete structure depending on types and contents of mineral admixture chloride resistance was evaluated by NT BUILD 492 of european test standards. It was also evaluated with the mechanical properties such as static strength and chloride penetration resistance. For shotcrete mixed crushed stone aggregate of the maximum size 10mm of coarse aggregates was produced. Based on 28days compression strength the variable mixed with 15% silica fume showed the highest strength in 67.55MPa. As the content of fly ash and blast furnace slag increased, the strength lowered. In the chloride penetration resistance test, OPC showed "high grade" and In the case of admixture, the penetration resistance tended to increase in all variables except the fly ash. In order to evaluate the service life, the accelerated chloride penetration test was conducted by the standards of KCL, ACI, FIB. Test results were obtained with the lowest spreading factor in a variable mixed with silica fume of 15%. At the KCI standards, It was found to have a service life of about 65 years and at the FIB standards, It was found to have a service life of 131 years. Among standards, the service life of KCI standard in all of the variables was evaluated as the lowest.

Evaluation of Durability of Slag Concrete by Marine Environment Exposure (해양환경 폭로에 의한 슬래그 콘크리트의 내구성 평가)

  • Kim, Hyun-Jin;Kim, Gyu-Yong;Choe, Gyeong-Cheol;Kim, Hong-Seop;Lee, Bo-Kyeong;Kim, Rae-Hwan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.111-112
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    • 2015
  • There is high possibility of steel corrosion on the reinforced concrete exposed to marine environment by chloride ion penetration. And it show a big difference of concrete durability under conditions of splash zone, tidal zone, and immersion zone. Therefore, in this paper, half-cell potential and chloride ion penetration depth was measured to evaluate the durability of slag concrete by marine exposure experiment. As a result, SC70 specimen showed no steel corrosion, regardless of the marine exposed conditions. Also, a deterrent effect on chloride ion penetration by replacement of slag in tidal zone and immersion zone could be confirmed.

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Strength, Carbonation Resistance, and Chloride-Ion Penetrability of Cement Mortars Containing Catechol-Functionalized Chitosan Polymer (생체모방 폴리머의 구조 분석 및 폴리머 혼입율에 따른 시멘트 모르타르의 특성 변화)

  • Bang, Eun Ji;Choi, Se-Jin;Ko, Haye-Min
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.253-254
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    • 2022
  • In this study, catechol-functionalized chitosan (Cat-Chit), a well-known bioinspired polymer that imitates the basic structures and functions of living organisms and biological materials in nature, was synthesized and combined with cement mortar in various proportions. The compressive strength, tensile strength, drying shrinkage, accelerated carbonation depth, and chloride-ion penetrability of these mixes were then evaluated. In the ultraviolet-visible spectra, a maximum absorption peak appeared at 280 nm, corresponding to catechol conjugation. The sample containing 7.5% Cat-Chit polymer in water (CPW) exhibited the highest compressive strength, and its 28-day compressive strength was ~20.2% higher than that of a control sample with no added polymer. The tensile strength of the samples containing 5% or more CPW was ~2.3-11.5% higher than that of the control sample. Additionally, all the Cat-Chit polymer mixtures exhibited lower carbonation depths than compared to the control sample. The total charge passing through the samples decreased as the amount of CPW increased. Thus, incorporating this polymer effectively improved the mechanical properties, carbonation resistance, and chloride-ion penetration resistance of cement mortar.

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An Experimental Study on the Improvement of Early Strength and Chloride Attack Resistance for Marine Concrete (해양용콘크리트의 초기강도 및 내염해 저항성 향상에 관한 실험적 연구)

  • Lee, Keon-Ho;Kim, Jong-Back;Bae, Jun-Young;Seo, Shin-Seok;Jo, Sung-Hyun;Roh, Hyeon-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.661-664
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    • 2008
  • The structure which is located in special surroundings like ocean-environment is physically and chemically eroded by seawater or salt damage, and then concrete-structure becomes deteriorated by iron corrosion and swelling pressure which leads to remarkably decline durability due to cracks and exploitation. As a measure against salt damage, it is actively being examined to use the blended cement that controls salt damage and fix chloride in the process of hydration. In this study, therefore, to examine the property of marine concrete added admixture, marine concrete is manufactured by adding high-strength admixture(omega2000) by 0, 5, 10, and 15% to low heat-blended cement. Then it shows that the compressive strength of manufactured marine cement tends to increase and chloride penetration resistance improves.

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Characteristics of OCP of Reinforced Concrete Using Socket-type Electrodes during Periodic Salt Damage Test (주기적 염해 시험에 따른 소켓 타입 전극을 활용한 철근 콘크리트의 OCP 특성)

  • Lee, Sang-Seok;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.4
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    • pp.28-36
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    • 2021
  • It is known that buried rebars inside concrete structures are protected from corrosion due to passive layer. It is very important to delay the timing of corrosion or evaluate a detection of corrosion initiation for the purpose of cost-beneficiary service life of a structure. In this study, corrosion monitoring was performed on concrete specimens considering 3 levels of cover depth(60 mm, 45 mm, and 30 mm), W/C(water to cement) ratio(40.0%, 50.0%, and 60.0%) and chloride concentration(0.0%, 3.5%, and 7.0%). OCP(Open Circuit Potential) was measured using agar-based socket type sensors. The OCP measurement showed the consistent behavior where the potential was reduced in wet conditions and it was partially recovered in dry conditions. In the case of 30 mm of cover depth for most W/C ratio cases, the lowest OCP value was measured and rapid OCP recovery was evaluated in increasing cover depth from 30 mm to 45 mm, since cover depth was an effective protection against chloride ion ingress. As the chloride concentration increased, the effect on the cover depth tended to be more dominant than the that of W/C ratio. After additional monitoring and physical evaluation of chloride concentration after specimen dismantling, the proposed system can be improved with increasing reliability of the corrosion monitoring.

Durability Evaluation of Cement Concrete Using Ferrosilicon Industrial Byproduct (페로실리콘 산업부산물 활용 시멘트 콘크리트의 내구성능 평가)

  • Chang-Young Kim;Ki Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.89-96
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    • 2023
  • In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO2 content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.