• Title/Summary/Keyword: 염화물 응력부식균열

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Review of Research on Chloride-Induced Stress Corrosion Cracking of Dry Storage Canisters in the United States (미국의 건식저장 캐니스터에서의 CISCC 연구에 대한 검토)

  • Park, Hyoung-Gyu;Park, Kwang-Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.455-472
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    • 2018
  • It is important to study how to manage dry storage casks of spent nuclear fuels (SNF), because wet storage spaces for SNF will shortly be at full capacity in the Republic of Korea. The US has operated a dry storage cask system for several decades, and has carried out significant studies into how to successfully manage dry storage cask for SNF. This type of expertise and experience is currently lacking in the Republic of Korea. The degradation of dry casks is an important issue that must be considered. In particular, chloride-induced stress corrosion cracking (CISCC) is known to lead to the release of radioisotopes from canisters. The U.S. Department of Energy, U.S. Nuclear Regulatory Commission, and the Electric Power Research Institute have undertaken research into the CISCC mechanism. In addition, Sandia National Laboratories (SNL) has extensively researched CISCC and how to manage it in dry storage canisters. In this review paper, the probabilistic model proposed by the SNL is analyzed and, based on this model, US-based CISCC research is reviewed in detail. This paper will inform the management of dry cask storage of SNF from light water reactors in austenite stainless steel canisters in the Republic of Korea.

Development of New Code Case "Mitigation of PWSCC and CISCC in ASME Code Section III Components by the Advanced Surface Stress Improvement Technology (일차수응력부식균열(PWSCC) 및 염화이온부식균열(CISCC) 저감용 표면개질기술 적용을 위한 코드케이스 개발)

  • Cho, Sungwoo;Pyun, Youngsik;Mohr, Nick;Tatman, Jon;Broussard, John;Collin, Jean;Yi, Wongeun;Oh, Eunjong;Jang, Donghyun;Koo, Gyeong Hoi;Hwang, Seong Sik;Choi, Sun Woong;Hong, Hyun UK
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.15 no.1
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    • pp.28-32
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    • 2019
  • In nuclear power plant operation and spent fuel canisters, it is necessary to provide a sound technical basis for the safety and security of long-term operation and storage respectively. Recently, the peening technology is being discussed and the technology will be adopted to ASME Section III, Division 1, Subsection NX (2019 Edition). The peening is prohibited in current edition, but it will be approved in 2019 Edition and adopted. However, Surface stress improvement techniques such as the peening is used to mitigate SCC susceptible in operating nuclear plants. Although the peening will be approved to ASME CODE, there are no performance criteria listed in the 2019 edition. The Korean International Working Group (KIWG) formed a new Task Group named "Advanced Surface Stress Improved Technology". The task group will develop a CODE CASE to address PWSCC(Primary Water Stress Corrosion Cracking) and CISCC(Chloride Induced Stress Corrosion Cracking) for new ASME Section III components. TG-ASSIT was started to make peening performance criteria for ASME Section III (new fabrication) applications. The objective of TG-ASSIT is to gain consensus among the relevant Code groups that requirements/mitigation have been met.

Evaluation of corrosion resistance by electrochemical methode of welded Al 5083-H321 alloy (Al 5083-H321 합금 용접부의 내식성 평가를 위한 전기화학적 특성 분석)

  • Yang, Ye-Jin;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.137-137
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    • 2017
  • Al-Mg 합금은 비중이 적고 강도가 우수하기 때문에 해양 환경에서 구조용 재료로 많이 사용되고 있으며, 특히 선박용 재료로 사용될 경우 선체의 중량을 줄일 수 있어 연료비가 절감되며 선속의 고속화가 가능하다. 그러나 해양환경에서의 재료 특성에 관한 지식 및 관련 기술 부족으로 알루미늄 선박 건조는 활성화 되지 못하고 있는 실정이다. 알루미늄 합금은 공기 중에서는 우수한 내식성을 지니는 것으로 알려져 있으나 해수환경에서는 염소이온에 의한 부동태 피막 파괴로 인해 내식성이 저하되며 공식 및 응력부식균열 등에 의한 손상이 발생할 수 있다. 특히 용접부의 경우, 모재에 비해 부식손상에 취약하며 기공과 같은 용접 결함을 포함하고 있어 구조물 파괴의 시발점이 될 수 있으므로 선박 및 구조물 건조시 대비가 필요하다. 그러나 이에 관한 충분한 연구가 이루어지지 않아 국내 중소형 조선소의 경우 알루미늄 선박 건조에 어려움을 겪는 경우가 많다. 따라서 본 연구에서는 선박 건조 및 해양 구조물에 널리 사용되는 Al 5083-H321 합금 용접부에 대하여 해수 내 부식 특성을 연구하고자 한다. 부식특성 파악을 위한 전기화학적 실험에 앞서 화학적 에칭을 통해 미세부위별 실험을 수행하였다. 기준전극은 은/염화은 전극을 대극은 백금전극을 사용하였으며, 타펠 분석을 위한 분극실험은 OCP를 기준으로 -0.25 ~ +0.25 V까지 실시하였고 양극분극실험은 OCP ~ +3.0 V까지 실시하였다. 양극분극 실험 후 부식된 표면은 주사전자현미경과 3D 분석을 통해 용접부 조직에 따른 전기화학적 특성을 관찰하였다.

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Corrosion-bond Strength Evaluation in OPC and Slag Concrete using Accelerated Corrosion Test (촉진부식실험을 이용한 OPC 및 슬래그 콘크리트의 부식-부착강도 평가)

  • Sang-Jin Oh;Hyeon-Woo Lee;Seung-Jun Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.1-7
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    • 2024
  • Concrete, as a porous construction material, permits chloride penetration from outside, which yields corrosion in embedded steel. In the study, an accelerated corrosion technique (ICM: Impressed current method) was adopted for rapid corrosion formation with 10 Volt of potential, and corrosion amou nt was controlled u p to 10.0 %. Corrosion amou nt had a linear relationship with cumulative corrosion current and increased with a quadratic function of accelerating period due to cracking. Regarding bond strength test, OPC concrete showed rapid drop of bond strength over 3.0 % of corrosion weight ratio, however slag concrete with 30 % replacement ratio showed a level of 51.4~71.6 % of corrosion ratio to OPC concrete with keeping residual bond strength.

Evaluation of Shrinkage Cracking Characteristics and Degree of Restraint for Ultra-High-Strength Concrete (초고강도 콘크리트의 수축 균열 특성 및 구속도 평가)

  • Yoo, Doo-Yeol;Min, Kyung-Hwan;Yang, Jun-Mo;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.22 no.5
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    • pp.641-650
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    • 2010
  • The concrete cracking from the restrained stress caused by the shrinkage may play significant cause of deterioration of concrete structures by allowing the permeation of sulphate and chloride ions which in turn triggers corrosion of steel reinforcement. In particular, the cracking becomes more critical as water binder ratio (W/B) is reduced and concrete strength increases. Therefore, it needs to evaluate correctly the comprehensive shrinkage behavior of concrete with high strength: high-strength concrete (HSC), ultra-highstrength concrete (UHSC). The unrestrained shrinkage tests, however, cannot estimate the net shrinkage effectively which affects cracking after full development of strength and stiffness because it does not consider the degree of restraint, strength development, stress relaxation, and so on. Therefore, in this study, both free and restrained shrinkage tests with variables of W/B (W/B of 30, 25 and 16%) and admixtures (fly ash (FA) and granulated blast-furnace slag (BFS)) for HSC, very-high-strength concrete (VHSC) and UHSC were performed. The test results indicated that the autogenous shrinkage and total shrinkage at drying condition were reduced as W/B increased and FA, BFS were added, and the cracking behavior was suppressed as W/B increased and FA was added.