• Title/Summary/Keyword: 염소 이온 확산계수

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Time Dependent Chloride Transport Evaluation of Concrete Structures Exposed to Marine Environment (해안 환경 하에 있는 콘크리트 구조물의 시간의존적 염화물침투 평가)

  • Song, Ha-Won;Pack, Seung-Woo;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.585-593
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    • 2007
  • This paper presents a model for durability evaluation of concrete structures exposed to marine environment, considering mainly a build-up of surface chloride $(C_s)$ as well as diffusion coefficient (D) and chloride threshold level $(C_{lim})$. In this study, time dependency of $C_s$ and D were extensively studied for more accurate evaluation of service life of concrete structures. An analytical solution to the Fick's second law was presented for prediction of chloride ingress for time varying $C_s$. For the time varying $C_s$, a refined model using a logarithm function for time dependent $C_s$ was proposed by the regression analysis, and averaging integrated values of the D with time over exposed duration were calculated and then used for prediction of the chloride ingress to consider time dependency of D. Durability design was also carried out for railway concrete structures exposed to marine environment to ensure 100 years of service life by using the proposed models along with the standard specification on durability in Korea. The proposed model was verified by the so-called performance-based durability design, which is widely used in Europe. Results show that the standard specification underestimates durability performances of concrete structures exposed to marine environment, so the cover depth design using current durability evaluation in the standard specifications is very much conservative. Therefore, it is found that utilizing proposed models considering time dependent characteristics of $C_s$ and D can evaluate service lift of concrete structures in marine environment more accurately.

Material Characteristics of High-Strength Concrete Incorporating High Replacement Level of Blast-Furnace Slag (고로슬래그를 다량 함유한 고강도 콘크리트의 재료적 특성)

  • Lee, Hoi-Keun;Jung, Jae-Hong;Kim, Han-Joon;Lee, Seung-Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.291-292
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    • 2010
  • In this study, high-strength concrete mixtures were made with blast-furnace slag of 50% and 70% replacement level to evaluate material properties including compressive strength development, adiabatic temperature rise, autogenous shrinkage and chloride-ion migration coefficient. Test results showed that the use of high percentage blast-furnace slag in high-strength concrete can reduce heat of hydration and chloride-ion migration coefficient, result in control thermal cracking and improve durability performance especially under high corrosive environment.

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Characteristics for Reinforcement Corrosion and Chloride Ion Diffusion of High Volume Fly Ash Concrete (하이볼륨 플라이애시 콘크리트의 철근부식 및 염소이온 확산 특성)

  • Kwon, Soon-Oh;Bae, Su-Ho;Lee, Hyun-Jin;Jung, Sang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.34-39
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    • 2014
  • The purpose of this experimental research is to evaluate the resistance of reinforcement corrosion and chloride ion penetration of high volume fly ash (HVFA) concrete. For this purpose, concrete test specimens were made for various strength level and replacement ratio of fly ash, and then compressive strength and diffusion coefficient for chloride ion of them were measured for 28, 91 and 182 days, respectively. Also, corrosion monitoring by half cell potential method was carried out for the made lollypop concrete test specimens to detect the time of corrosion initiation for reinforcement in concrete. As a result, it was observed from the test results that compressive strength of HVFA concrete was decreased with increasing replacement ratio of fly ash but long-term resistance against reinforcement corrosion and chloride ion penetration of that was increased.

Chloride Diffusion Coefficient Model Considering the Initiation Time of Exposure to Chloride Environment (염소이온 노출개시시기를 고려한 기존 확산계수 모델 수정제안)

  • Kim, Ki-Hyun;Cha, Soo-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.377-386
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    • 2009
  • A reference diffusion coefficient model from ACI life-365 is drawn from test results by NT build 443. This test method gives a time-averaged diffusion coefficient during immersion period, thus the ACI model uses the time-averaged diffusion coefficient as a reference value. ACI model needs to be revised, considering the difference between the time-average value and reference value at specified time. In this study, firstly the analytic solutions of diffusion equation are derived considering the initiation time and period of exposure to chloride, and secondly the time-averaged diffusion coefficient from NT build 443 is converted into the diffusion coefficient at reference time. From this study, the reference diffusion coefficient of ACI model should be modified to be about 10% larger values than those of present ACI model. For convenient design of service life, previous relationship between the chloride diffusion coefficient from NT build 443 and that from NT build 492 is also modified. To compare the chloride diffusion coefficients of ACI and JCI models, the reference chloride diffusion coefficient with respect to the JCI model is drawn in the similar form of ACI model's, and service life prediction by ACI life-365 method is confirmed to give a conservative result.

A Study on Moisture Diffusion in Young Concrete (양생초기 콘크리트내의 수분확산에 관한 연구)

  • 한만엽
    • Magazine of the Korea Concrete Institute
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    • v.5 no.3
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    • pp.152-160
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    • 1993
  • 양생 초기에 있어서 콘크리트의 투수계수는 콘크리트의 건조수축에 영향을 미치는 요인으로서 콘크리트내의 물의 이동과 관련된 중요한 변수이다. 콘크리트의 특수성에 관한 연구는 주로 콘크리트의 건조수축이나, 동결융해에 대한 내구성 등과 연관되어 있다. 이들 대부분의 측정결과는 염소 이온등을 이용한 간접 측정방법이거나 충분히 양생된 안정한 콘크리트를 대상으로 하는 것이 대부분이므로 양생초기의 콘크리트의 투수계수에 관한 연구는 거의 없다고 할 수 있다. 본 연구에서는 싸이크로미터라는 수리에너지를 측정하는 쎈서를 이용하여 콘크리트의 투수계수의 측정을 시도하였다. 콘크리트의 투수계수와 확산계수를 측정하기 위한 세가지의 방법을 제시하였으며, 이를 적용하는 실험도 실시하였다. 또한 투수계수와 확산계수간의 변환을 위한 등온 흡수선을 개발, 적용하였다.

Diffusivity of Chloride Ion of Composite Slag Aggregate Replacement Concrete (복합슬래그 골재 치환 콘크리트 염소이온 확산 특성)

  • Park, Dong-Cheon;Lee, Jun-Hae;Kim, Yong-Ro;Song, Yong-Chan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.147-148
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    • 2019
  • Lack of fine aggregate is adversely affecting the quality of concrete. Due to lack of land sand, EZZ sea sand has been used. However, the use of sea sand is also difficult because of the opposition of fishermen. The purpose of this study was to analysis the effect of slag fine aggregate to durability and compressive strength of concrete. The concrete compressive strength and durability were assessed to derive a proper mix ratio of fine aggregate.

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Performance of cement concrete pavement incorporating mineral admixtures (광물질혼화재를 적용한 시멘트콘크리트 포장의 성능 평가)

  • Lee, Seung-Tae;Lee, Da-Hyun;Lee, Jae-Jun
    • International Journal of Highway Engineering
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    • v.12 no.3
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    • pp.113-119
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    • 2010
  • This study presents experimental findings on the performance of cement concrete pavement incorporating mineral admixtures such as ground granulated blastfurnace slag and silica fume. Flexural strength, compressive strength, charge passed, diffusion coefficient of chloride ions and initial surface absorption of cement concrete pavement incorporating mineral admixtures were periodically measured and the corresponding results were compared to those of plain concrete pavement. As a result, strength behaviors of concrete pavement were dependent on the types of mineral admixtures. However, it was true that incorporation of silica fume had a beneficial effect on compressive strength development. Furthermore, the application of mineral admixtures led to a lower diffusion coefficient of chloride ions compared to plain concrete pavement. Based on the experimental results, the present study would be helpful to design high-performance cement concrete pavement.

A Method on the Rapid Assessment of Resistance to Chloride Ion Penetration for Mortar and Concrete with Mineral Admixtures (혼화재를 사용한 모르타르 및 콘크리트의 염소이온 침투 저항성 평가)

  • Park Jung-Jun;Kim Sung-Wook;Koh Kyung-Taek;Lee Jong-Suk;Lee Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.485-492
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    • 2004
  • In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

Chloride Ion Diffusion Coefficient and Compressive Strength of the Concrete Produced by Ready Mixed Concrete Company in Busan (부산지역 레미콘사의 콘크리트의 압축강도와 염소이온 확산계수)

  • Park, Dong-Cheon;Bang, Jung-Suk;Kim, Yong-Ro;Lee, Tae-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.11-12
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    • 2017
  • The properties of concrete produced by ready mixed concrete company in Busan were tested. Because the concrete was mixed with blast furnace slag and fly ash, the compressive strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design.

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The Sensitivity Evaluation of Probability Variables to Durability Design of the RC Structures (철근콘크리트 구조물 염해 내구설계에 있어서 설계확률변수의 민감도 평가)

  • Park, Dong-Cheon;Oh, Sang-Gyun
    • Journal of Navigation and Port Research
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    • v.33 no.3
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    • pp.235-240
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    • 2009
  • Simulation method based on probability was developed to evaluate the durability of reinforced concrete structures about chloride attack. The effects of the probability parameters(surface chloride ion concentration, initial combined chloride ion concentration, the depth of cover thickness of concrete, and the chloride ion diffusion coefficient), probability distribution function and it's variation were calculated using the Monte Carlo method and Fick's 2nd law. From the durability design method proposed in this study, the following results were obtained. 1) The effects of the distance from the coast and the chloride ion diffusion coefficient to the corrosion probability were quite high. 2) The effect of the variation of each parameters was relatively low.