• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.184-188
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• 2008

This study presented simple and efficient fabrication of chemical sensors for the detection of acidic gas using 1,3-bisdicyanovinylindane as an indicator because it can be promising materials having property of the rapid color change according to the variation of pH. The dissociation of proton and dye in acidic condition as changing of ion pairs give rise to dramatically change the absorbance intensity of 1,3-bisdicyanovinylindane, which can be easily applied to the development of chemical sensors. In addition, indicator dyes having negatively charge in aqueous phase can be easily fabricated using layer-by-layer (LBL) methods by way of electrostatic interaction. For the proof of concept, we demonstrated the abrupt presentation of skeleton symbol on the chemical sensor, which could be resulted from the reaction of 1,3-bisdicyanovinylindane as background color with acidic gas. Thus, the rapid appearance of symbol will induce user's caution under the emergency condition. The presented chemical gas sensor using 1,3-bisdicyanovinylindane have strong advantages. First, the fabrication process of gas sensor was very simple and low-cost. Secondly, sensors reacted by acidic gas could be reused for several times. Finally, the chemical gas sensor would be environmentally friend, which can be a basic tool for the realization of eco-organic sensor device.

• Journal of Conservation Science
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• v.26 no.4
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• pp.429-436
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• 2010

Dyestuffs extracted from fifteen kinds of natural dyeing materials were researched on their antimicrobial performance against 3 kinds of bacteria and 2 kinds of fungi in order to develop conservation/storage materials of traditional and natural dyed papers. The three types of mordants were evaluated by using the same method and then mixed with the dyestuffs to research their antimicrobial performance. With those results, dyed paper was made by mixing mordants with 9 kinds of dyestuffs with excellent antimicrobial performance. Among the dyed papers, Cotinus coggygria, Coptis chinensis, Phellodendri amurense, Rhus javanica and Acer ginnala multiple mordant papers were found to have an antibacterial quality against fungi, while, in the insect repellent experiment using termites, Coptis chinensis and Phellodendri amurense dyed papers were found to have insect repellent qualities. Also, with regard to the research result about the affect of dyeing paper on other materials like metal, Coptis chinensis have relatively stable qualities. Also, the three types of dyeed paper by Cotinus coggygria, Coptis chinensis and Phellodendri amurense, were found to have a tendency to remove harmful gases. Not only can these dyed papers be used for making storage box for cultural properties to prevent various organic artifacts from bio-damaging, but they can also be utilized as functional finishing materials in various spaces.

• Clean Technology
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• v.24 no.1
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• pp.1-8
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• 2018

As the social demands for environmental pollution increase and regulations on the dyeing process wastewater are strengthened, supercritical dyeing process has been attracting attention as an alternative technology to reduce wastewater and energy consumption. In the supercritical dyeing process where carbon dioxide is used as a solvent instead of water as a solvent, there is no wastewater generated. The unfixed dyes can be reused later which makes the process environment-friendly. Also, after dyeing process, dried textiles can be obtained without additional drying process, which makes the process energy efficient. In this article, we have summarized the development of the supercritical dyeing process along with the research in Korea today and compared the principle of supercritical dyeing process with conventional dyeing process. To further explain the principle, studies of the distribution factor and mass transfer of dyes in supercritical carbon dioxide and fibers, as well as solubility between supercritical $CO_2$ and dyes are discussed. The dynamic behavior of dyes in supercritical dyeing apparatus and summary of the supercritical dyeing facilities developed around the world are also discussed. Finally, we suggest the direction of research and development for optimization of supercritical dyeing process and application to synthetic fibers and natural fibers except for polyester.

• Korean Journal of Heritage: History & Science
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• v.56 no.1
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• pp.80-97
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• 2023

By taking wallpaper specimens from Gyeongbokgung Palace, Changdeokgung Palace, and Chilgung Palace preserved from the late Joseon Dynasty to the present, we planned in this study to determine the types and characteristics of the paper used as wallpaper in the Joseon royal family. First, we confirmed the features of paper hanging in the palaces with old literature on the wallpaper used by the royal family based on archival research. Second, we conducted a field survey targeting the royal palaces whose construction period was relatively clear, and analyzed the first layer of wallpaper directly attached to the wall structure after sampling the specimens. Therefore, we confirmed that the main raw material was hanji, which was used as a wallpaper by the royal family, and grasped the types of substances(dyes and pigments) used to produce a blue color in spaces that must have formality by analyzing the blue-colored paper. Based on the results confirmed through the analysis, we checked documents and the existing wallpaper by comparing the old literature related to wallpaper records of the Joseon Dynasty palaces. We also built a database for the restoration of cultural properties when conserving the wallpaper in the royal palaces. We examined the changes in wallpaper types by century and the content according to the place of use by extracting wallpaper-related contents recorded in 36 cases of Uigwe from the 17th to 20th centuries. As a result, it was found that the names used for document paper and wallpaper were not different, thus document paper and wallpaper were used without distinction during the Joseon Dynasty. And though there are differences in the types of wallpaper depending on the period, it was confirmed that the foundation of wallpaper continued until the late Joseon Dynasty, with Baekji(white hanji), Hubaekji(thick white paper), jeojuji(common hanji used to write documents), chojuji(hanji used as a draft for writing documents) and Gakjang(a wide and thick hanji used as a pad). As a result of fiber identification by the morphological characteristics of fibers and the normal color reaction(KS M ISO 9184-4: Graph "C" staining test) for the first layer of paper directly attached to the palace wall, the main materials of hanji used by the royal family were confirmed and the raw materials used to make hanii in buildings of palaces based on the construction period were determined. Also, as a result of analyzing the coloring materials of the blue decorative paper with an optical microscope, ultraviolet-visible spectroscopic analysis(UV-Vis), and X-ray diffraction analysis(XRD), we determined that the type of blue decorative paper dyes and pigments used in the palaces must have formality and identified that the raw materials used to produce the blue color were natural indigo, lazurite and cobalt blue.

• Korean Journal of Microbiology
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• v.48 no.3
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• pp.225-227
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• 2012

Lignin degrading enzymes from white rot fungi show broad substrate specificities, and therefore they can degrade variety of recalcitrant compounds. We have used three different protocols for the generation of immobilized laccase and manganese peroxidase crude enzymes from the genetically transformed strains of Merulius tremellosus Fr. These immobilized enzymes were used in the decolorization of Remazol Brilliant Blue R (RBBR), and they showed about 75% decolorization rates during the 48 h reactions. Although the decolorization efficiency decreased by 10-15% after a repeated use of the immobilized enzymes, these can be reused in various degrading reactions.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.1
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• pp.176-181
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• 2009

In this work, a new type of DSCs based on nanoporous FTO structure is being developed for research aimed at low-cost high-efficiency solar cell application. The nanoporous FTO materials have been prepared through the sol-gel combustion method followed by thermal treatment at $450{\sim}850[^{\circ}C]$. The properties of the nanoporous FTO materials were investigated by IR spectra, BET and TEM analyses, and the photovoltaic performance of the prepared DSCs were examined. It can be seen from the result that the nanoporous FTO exhibited good transparent conductive properties, well suited for DSCs application.

• Journal of Conservation Science
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• v.30 no.1
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• pp.13-25
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• 2014

This study interpreted the chemicals of the pigments and the coloring techniques employed on Youngsan Ritual Ceremony Buddhist Painting through a nondestructive analysis method and a microscopic observation. Based on the interpretation, this study closely examined the chemical properties of the names of the coloring materials specified on the ceremonial writing of the Buddhist painting. It is estimated that lead white was used for the white pigments, orpiment and organic pigment for the yellow pigment, cinnabar/vermilion, minium, red ochre, and red dyes for the red pigments, malachite or atacamite for the green pigments, azurite and indigo for the blue pigments, and ink stick for the black pigments. The pigment names specified on the ceremonial writing are juhong, jungcheong, hayeop, whangdan, and whanggeum, and it was verified that juhong is cinnabar or vermilion, jungcheong is azurite, hayeop is malachite or atacamite, whangdan is minium, and whanggeum is a gold foil.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.91-91
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• 2011

폴리프로필렌(PP)은 고결정성 범용수지로서 염색성, 내열성, 촉감 등의 문제로 의류용 소재로는 부적합하여 초기에는 카펫용 섬유로서 가염형 폴리프로필렌 섬유가 상업화 되었지만 성공하지는 못하였다. 그 후, 섬유 산업도 의류용 외의 산업자재, 생활 자재 분야 등이 성장함에 따라, 폴리프로필렌 섬유의 수요가 확대되었다. 최근들어 스포츠 액티브 의류가 일반의류 트렌드로 들어오면서 기능성 섬유가 요구되고 이 분위기에 맞춰 다시 한번 폴리프로필렌 섬유의 의류화가 요구되는 시점이 되었으며 섬유중 에너지 소비량이 가장 적고, 쉽게 재용해할 수 있으며 소각시 유해 가스발생량이 매우 적은 특징등이 있기 때문에 지구 환경보호의 입장에서 폴리프로필렌 섬유가 재검토되고 있다. 이번 실험은 분산염료를 이용하여 농도별, 온도별, 시간별, 후처리시 시간과 온도의 변화로 가염 PP/PET 섬유의 염색특성을 알아보기 위해 실험 진행하였다. 실험에 사용되는 시약은 1급으로, $CH_3COOH$, NaOH, $Na_2S_2O_4$이며, 조제는 분산제, 정련제를 사용하였다. 먼저 온도별 실험에서 $40^{\circ}C$에서 승온하여 각각 $100^{\circ}C$, $110^{\circ}C$, $120^{\circ}C$, $130^{\circ}C$에서 온도에 따라 염색되는 정도를 알아보았다. 가장 높은 흡진을 보이는 온도에서 각각 40min, 50min, 60min, 70min 염색 유지시간 실험을 하여 염색이 안정되는 시간을 측정하였다. 위의 실험 결과 최적의 조건으로 염색농도에 따른 Build up 실험을 진행하였다. 가염 PP/PET 섬유는 일반 Polyester처럼 $120{\sim}130^{\circ}C$에서 가장 높은 염색농도 값(K/S)을 보인다. 또한 $130^{\circ}C$에서의 유지시간에서는 50 min 이상 진행시 더 이상의 흡진이 없거나, 염료의 탈락이 있음을 알수 있다. Build up 실험에서는 8.0%까지 실험하였지만, 결과는 그 이상농도를 사용하여도 염색은 가능함을 알 수 있었다. 후처리에 대한 실험에서 염료에 따라 차이가 있지만 크게 영향을 받지 않는 것으로 보이며, 제품성 평가 결과를 보면 후처리를 했을 경우 견뢰도가 우수한 것을 알 수 있었다.

• Journal of Conservation Science
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• v.37 no.2
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• pp.120-134
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• 2021

A Woolen carpet from the late Joseon Dynasty was unearthed in the process of repairing Seongjeonggak in Changdeokgung. Since relics are rarer than documentary records, the woolen carpet is highly valued as a relics. It is presumed to have been woven in the late 19th or early 20th century because there is a record of repairing Seongjeonggak in 1907. In the carpet, a pattern is made by inserting colored yarn dyed yellow and red onto a reddish-purple ground weave. The selvage of the woolen carpet used cotton thread, and jute is used for the warp and weft of the ground weave. The colored patterns is made of wool in the form of loop pile. Cut piles may appear occasionally when the colored yarn changes, but are almost invisible from the surface because they are pressed tightly with a shuttered weft. Making carpets with jute and wool is thought to be influenced by the Brussels carpets of the mid-18th century. Furthermore, the woolen carpet is torn and the pattern is completely unclear; however, it is understandable that the pattern is partially repeated. Microscopic and Fourier transform-Infrared spectrometer(FT-IR) analyses were performed for the above investigation. To identify the dyes used in relics, we compared them with natural dyed fabric samples based on chromaticity measurements and Ultraviolet/Visible spectrophotometer(UV-Vis) analysis. These analyses revealed that the woolen carpet's dyed green yarn did not use indigo, and reddish-purple ground weave is estimated to have used Caesalpinia sappan.

• Clean Technology
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• v.21 no.3
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• pp.164-170
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• 2015

In this study, polysulfone-Escherichia coli biomass composite fiber (PSBF) was prepared by spinning the suspension of PS and E. coli biomass and amine-methylated PSBF (AM-PSBF) was fabricated through the methylation of amine groups in PSBF. As comparing the adsorption characteristics of basic dye, Basic Blue 3 (BB3) by the PSBF and AM-PSBF, the effect of the methylation of amine groups on BB3 adsorption was confirmed. pH edge experiments showed that the BB3 uptake of PSBF and AM-PSBF increased as pH was increased and the BB3 uptake of AM-PSBF was higher than that of PSBF at the same pH. Both of PSBF and AM-PSBF was reached at equilibrium within 5 h and kinetic experimental data were well fitted by the pseudo-first-order kinetic model. By the Langmuir model, the maximum adsorption capacities of PSBF and AM-PSBF at pH 8 were evaluated to be 28.9 and 20.7 mg/g, respectively. The maximum adsorption capacity of AM-PSBF was enhanced 1.4 times comparing that of PSBF. These results indicate that the methylation of amine groups in PSBF leads to the improvement of BB3 adsorption capacity. In addition, the results of desorption experiments revealed that AM-PSBF was repeatedly reusable.