• Title/Summary/Keyword: 열확산비

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Evaluation of Moisture Sorption Characteristics in Polymer Material (고분자 소재에서 흡습 특성의 평가)

  • Park, Hee-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.11
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    • pp.1297-1303
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    • 2012
  • In this paper, the standard procedures for measuring the moisture sorption properties of thin polymeric materials such as polyethylene terephthalate (PET) by using the thermo-gravimetric method to characterize the moisture diffusion in the polymer are presented, and the sorption properties are quantified. The moisture diffusivity and solubility are characterized to investigate the effect of temperature and humidity on the moisture sorption properties according to the Arrhenius equation. The validation of the obtained sorption properties using thermogravimetry is discussed with the measured permeability based on Fickian diffusion. The nonlinear behavior of the concentration dependent moisture diffusion is investigated experimentally, and the nonlinearity is characterized numerically for the case of having an interface with an inorganic material such as a metal. The Fickian/Non-Fickian model based on the obtained moisture sorption properties is compared and discussed.

Performance Analysis of Hybrid DS/SFH Spread Spectrum System using BFSK Modulations over Nakagami-m Fading Channel with Multitone Jamming (다중톤 재밍이 존재하는 나카가미-­m 페이딩 환경에서 BFSK 변조방식을 이용한 Hybrid DS/SFH 확산대역 시스템의 성능분석)

  • 정근열;박진수
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.8
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    • pp.1629-1637
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    • 2003
  • In this paper, we analyzed the performance of a hybird DS/SFH(Direct­Sequency­Slow Frequency­Hopping) Spread Spectrum system with BFSK modulation over Nakagami­m fading channel with multitone jamming. The performance of the system was improved when a frequency bowing rate increased. In case that process gain of hybrid DS/SFH Spread Spectrum system to be fixed, the hybrid DS/SFH Spread Spectrum takes the low bit error probability than a DS Spread Spectrum system. Also, when the fading index m increases, the fading effect decrease, when the JSR(jamming to signal power ratio) increases ,the performance of a hybrid DS/SFH Spread Spectrum system improved than DS Spread Spectrum system. The result, we have been proved that performance of a hybrid DS/SFH Spread Spectrum was superior to DS Spend Spectrum system over Nakagami­m fading with tome jamming.

A Study on Dependence of Smoke Emission in Diesel Engines Upon Diffusion Combustion (디젤기관의 스모크배출의 확산연소 의존성에 관한 연구)

  • 한성빈;문성수;이성열
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.2
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    • pp.397-404
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    • 1994
  • Smoke is emitted in diesel engines because fuel injected into the high-temperatured and high-pressured combustion chamber burns with its mixture with insufficient oxygeny. In consideration of air pollution, above all, it is necessary to illuminate the cause of smoke emission in diesel engines. The smoke emission, which is characteristic of diffusion combustion in diesel engines, results from pyrolysis of fuel not mixed with air. Therefore the smoke emission is dependent on diffusion combustion quantity, which is in turn controlled by engine parameter. The study aims at making clear and interpreting the interdependence of smoke emission in diesel engines with heat released within combustion chamber, camparing diffusion combustion quantity according to each engine parameter (air fuel ratio, injection timing, and engine speed), and showing the relation between smoke emission and fraction of diffusion combustion through experiment.

Heat Transfer by Heat Generation in Electrochemical Reaction of PEMFC (고분자 전해질 연료전지에서 전기화학반응 열생성에 의한 열전달특성)

  • Han, Sang-Seok;Lee, Pil-Hyong;Lee, Jae-Young;Park, Chang-Soo;Hwang, Sang-Soon
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.273-283
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    • 2008
  • GDL(Gas Diffusion Layer) is one of the main components of PEM fuel cell. It transports reactants from the channel to the catalyst and removes reaction products from the catalyst to the channels in the flow filed plate. It is known that higher permeability of GDL can make it possible to enhance the gas transport through GDL, leading to better performance. And MEA's temperature is determined by gas and heat transport. In this paper, three dimensional numerical simulation of PEM fuel cell of parallel channel and serpentine channel by the permeability of GDL is presented to analysis heat and mass transfer characteristics using a FLUENT modified to include the electrochemical behavior. Results show that in the case of parallel channel, performance variation with change of permeability of GDL was not so much. This is thought because mass transfer is carried out by diffusion mechanism in parallel channel. Also, in the case of serpentine channel, higher GDL permeability resulted in better performance of PEM fuel cell because of convection flow though GDL. And mass transfer process is changed from convection to diffusion when the permeability becomes low.

Step Coverge of Tantalum Oxide Thin Film Grown by Metal-Organic Chemical Vapor Deposition (유기금속 화학증착법을 이용한 탄탈륨 산화 박막의 층덮힘 특성 연구)

  • Park, Sang-Gyu;Yun, Jong-Ho;Nam, Gap-Jin
    • Korean Journal of Materials Research
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    • v.6 no.1
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    • pp.106-115
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    • 1996
  • 본 연구에서는 PET(PentaEthoxy Tanatalum:Ta(OC2H5)5) 유기금속 화합물 전구체를 사용하여 차세대 초고집적회로 제조시 고유전체 물질로 유망한 Ta2O5 박막을 열화학증착 방법에 의하여 증착하였다. 본 증착실험을 통하여 여러 가지 운속기체, 기판온도, 반응압력 등의 공정변수가 층덮힘에 미치는 영향을 고찰하였으며 Monte Carlo 전산모사 결과와 기판온도 변화에 따른 층덮힘 패턴의 변화에 대한 실험결과를 비교하여 부착계수를 산출하였다. 운송기체로는 N2, Ar, He을 바꿔가며 실험하였으며 He>N2>Artns으로 층덮힘이 양호한 것으로 나타났다. 이는 운송기체의 종류에 따라 운동량 확산도, 열 확산도, 물질 확산도 등의 이동현상 특성값들이 다르기 때문이라 생각된다. 기판온도의 증가는 운송기체의 종류에 관계없이 층덮힘을 악화시켰으며 도랑내부에서의 Knudsen 확산과 표면반응물의 탈착에 비해 표면반응이 보다 지배적인 역할을 담당함을 알 수 있었다. 또한 질소를 운송기체로 사용한 경우에 부착계수의 겉보기 활성화 에너지는 15.9Kcal/mol로 나타났다. 그리고 3Torr 이하에서 반응압력이 증가하는 반응압력이 증가하는 경우에는 물질 확산도의 감소 효과 때문에 층덮힘이 악화되었다. 본 연구결과 3Torr, 35$0^{\circ}C$에서 He 운송기체를 이용한 경우가 가장 우수한 층덮힘을 얻을 수 있는 최적 공정 조건임을 알 수 있었다.

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A Study on the Burning Characteristics of N-5 Propellant Embedded with Metal Wires (금속선을 삽입한 N-5복기 추진제의 연소 특성)

  • 유지창;박영규;김인철
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.1
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    • pp.78-85
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    • 1999
  • Burning characteristics of solid propellants embedded with four kinds of metal wires(Ag, Cu, Al, Ni-Cr wire) were studied with varying wire diameters(O.10.8 mm) lot N-5 propellant. It was found that the order of the burning rate increment ratio($r_w$/$r_sb$) was Ag wire > Cu wire > Al wire> Ni-Cr wire which was the same as the order of the magnitude of thermal diffusivity. The burning rate increment ratio($r_w$/$r_sb$) of N-5 propellant was less than that of composite Propellant because of the difference of adiabatic flame temperature and flame structure. When Ag, Cu and Al wire having high thermal diffusivity were embedded in N-5 propellant, the plateau and mesa characteristics of the double base propellant were disappeared, but not disappeared in the case of propellant embedded with Ni-Cr wire due to its poor thermal conductivity.

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The Hazard Assessment of Release and Dispersion of CNG Service Station (CNG 충전소의 누출$\cdot$확산에 대한 위험성 평가)

  • Choi Jong-Woon;Lee Su-Kyung
    • Journal of the Korean Institute of Gas
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    • v.4 no.3 s.11
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    • pp.53-58
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    • 2000
  • It was carried out consequence analysis(CA) of CNG (compressed natural gas) service station and we compared the results of CA of CNG service station with LPG service station which was installed by high Pressure gas law. The results of CA were that distance of CNG LFL was 1.5 times than the length of LPG LFL. Thermal radiation effect about CNG may not be showed damage of process facilities, but in the case of LPG, it was enough to have an large damage effect on a downtown. The thermal radiation of 37.5 $kw/m^2$ extended 12.6 m. Also, in the case of 12.5 $kw/m^2$ which was able to burn wood, the radiation effect of LPG is 3 times than CNG.

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Thermal Properties of Granite from the Central Part of Korea (한국 중부 지역의 화강암 열물성)

  • Kim, Jongchan;Lee, Youngmin;Koo, Min-Ho
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.441-453
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    • 2014
  • Thermal and physical properties were measured on 206 Jurassic granite samples obtained from three boreholes in the central part of Korea. Thermal conductivity(${\lambda}$), thermal diffusivity(${\alpha}$), and specific heat(Cp) were measured in a laboratory; the average values are ${\lambda}$=2.813 W/mK, ${\alpha}=1.296mm^2/sec$, and Cp=0.816 J/gK, respectively. In addition, porosity(${\phi}$), and dry and saturated density(${\rho}$) were measured in the laboratory; the average values are ${\phi}$=0.01, ${\rho}(dry)=2.662g/cm^3$ and ${\rho}(saturated)=2.67g/cm^3$, respectively. Thermal diffusivity of 10 granite samples were measured with increasing temperature from $25^{\circ}C$ to $200^{\circ}C$. In this study, we found that thermal diffusivity at $200^{\circ}C$ is about 30% lower than thermal diffusivity at $25^{\circ}C$. In correlation analysis, thermal conductivity increases with increasing thermal diffusivity. However, thermal conductivity does not show good correlation with porosity and density. Consequently, we know that thermal conductivity of granite would be more influenced by mineral composition than by porosity. We also derived ${\rho}=-2.393{\times}{\phi}+2.705$ from density and porosity data. XRD and XRF analysis were performed to investigate effects of mineral and chemical composition on thermal conductivity. From those results, we found that thermal conductivity increases with increasing quartz and $SiO_2$, and decreases with increasing albite and $Al_2O_3$. Regression analysis using those mineral and chemical composition were carried out ; we found $K=0.0294V_{Quartz}+1.93$ for quartz, $K=0.237W_{SiO_2}-14.09$ for $SiO_2$, and $K=0.053W_{SiO_2}-0.476W_{Al_2O_3}+6.52$ for $SiO_2$ and $Al_2O_3$. Specific gravities were measured on 10 granite samples in the laboratory. The measured specific gravity depends on chemical compositions of granite. Therefore, specific gravity can be estimated by the felsic-mafic index(F) that is calculated from chemical composition. The estimated specific gravity ranges from 2.643 to 2.658. The average relative error between measured and estimated specific gravities is 0.677%.

Experimental Study of the Evaporation of Spreading Liquid Nitrogen (확산하는 액체질소의 증발에 관한 실험적 연구)

  • KIM, MYUNGBAE;CHOI, BYUNGIL;KIM, TAE-HOON;DO, KYHYUNG;HAN, YONGSHIK;CHUNG, KYUNGYUL
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.5
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    • pp.466-472
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    • 2018
  • The investigation of cryogenic liquid pool spreading is an essential procedure to assess the hazard of cryogenic liquid usage. In this experimental study, to measure the evaporation velocity when the pool is spreading, liquid nitrogen was continuously released onto unconfined concrete ground. Almost all of the reported results are based on a non-spreading pool in which cryogenic liquid is instantaneously poured onto bounded ground for a very short period of time. A simultaneous measurement of the pool location using thermocouples and of the pool mass using a digital balance was carried out to measure the evaporation velocity and the pool radius. A greater release flow rate was found to result in a greater average evaporation velocity, and the evaporation velocity decreased with the spreading time and the pool radius.

Heat of Combustion Experiment Based on the Ratio of Moisture Content of Infected and Non-Infected Bursaphelenchus Xylophilus (재선충 감염 소나무와 비 감염 소나무의 수분함유율에 따른 연소열 실험)

  • Kwon, Hyuk;Kong, Ha-Sung
    • The Journal of the Convergence on Culture Technology
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    • v.7 no.2
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    • pp.443-451
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    • 2021
  • This study compared and analyzed the thermal characteristics based on the ratio of moisture content of infected and non-infected Bursaphelenchus Xylophilus by heat of combustion experiment. The experiment results are as follows. The analysisresult of the ratio of water content shows that 19.92% on average for infected Bursaphelenchus Xylophilus and 26.27% for non-infected which decreases water content as the size of conduction, convection, and radiant heat increases in case of fire. As the vaporization of the moisture content accelerates, the average moisture content is reached, and the result is contrary to the thermal characteristics of the wood that the moisture content is not ignited by a heat source when the moisture content is under 15%. The combustion heat analysis result showed that infected and non-infected Bursaphelenchus Xylophilus had no significant difference in combustion heat at about 3%. However, it shows that combustion heat is higher than other species. In conclusion, decreasing in moisture content based on the increasing conduction, convection, and radiant heat is one of the direct causes of ignition, and the lower the moisture content, the faster the fire spreads.