• Journal of the Korean Chemical Society
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• v.12 no.4
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• pp.160-162
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• 1968

Rate constants and activation parameters have been petermined for the chloride exchanges of benzyl chloride in 60, 70, 80 and 90 vol.% ethanol-water solutions. Results showed a good linearity when appiled to our general equation. The significance of this linear fit has been discussed in conjunction with the Dewar's relation which was derived from the PMO method.

• Journal of Korea Water Resources Association
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• v.32 no.6
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• pp.731-740
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• 1999

Autocorrelation function is widely used as a tool measuring linear dependence of hydrologic time series. However, it may not be appropriate for choosing decorrelation time or delay time ${\tau}_d$ which is essential in nonlinear dynamics domain and the mutual information have recommended for measuring nonlinear dependence of time series. Furthermore, some researchers have suggested that one should not choose a fixed delay time ${\tau}_d$ but, rather, one should choose an appropriate value for the delay time window ${\tau}_d={\tau}(m-1)$, which is the total time spanned by the components of each embedded point for the analysis of chaotic dynamics. Unfortunately, the delay time window cannot be estimated using the autocorrelation function or the mutual information. Basically, the delay time window is the optimal time for independence of time series and the delay time is the first locally optimal time. In this study, we estimate general dependence of hydrologic time series using the C-C method which can estimate both the delay time and the delay time window and the results may give us whether hydrologic time series depends on its linear or nonlinear characteristics which are very important for modeling and forecasting of underlying system.

• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.267-272
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• 2007

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at $25^{\circ}C$ in water and in aqueous solutions of n-butanol (0.1 M, 0.2 M, and 0.3 M) were determined as a function of ${\alpha}_1$ (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters ($X_i$, ${\gamma}_i$, $C_i$, ${a_i}^M$, ${\beta}$, and ${\Delta}H_{mix}$) were calculated by means of the equations derived from the nonideal mixed micellar model. The effects of n-butanol on the micellization of TTAB/Brij 35 mixtures have been also studied by analyzing the measured and calculated thermodynamic parameters.

• Journal of the Korean Chemical Society
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• v.50 no.5
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• pp.355-361
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• 2006

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

• Journal of the Korean Chemical Society
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• v.9 no.4
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• pp.215-221
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• 1965

The significant liquid structure theory is extended to binary mixture, benzene-ethylenechloride system. The partition function, applicable throughout the temperature range in which Raoult's law is satisfied is derived. The thermodynamic quantities such as total and partial pressures, molar volumes and mixing entropies are calculated from the partition function at the temperatures $293.15^{\circ},\;323.14^{\circ}\;and\;357.15^{\circ}K.$ The theoretical values, thus calculated, are found to agree with the experimental data in the literatures.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.12 no.1
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• pp.37-44
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• 1999

비등방성으로 적층된 복합판 및 쉘구조물에서 온도와 습도의 급격한 변화는 구조물의 강도와 성능을 저하시키는 중요한 원인이 된다. 더욱이 하중에 의한 역학적 변위와 조합될 때에는 좌굴, 대변형 혹은 고응력 상태를 유발하게 된다. 본 연구에서는 이중 퓨리에급수를 이용하여 3차의 전단변형함수로 가정된 평형방정석을 전개하고 폭-두께비, 형상비의 변화 그리고 재료의 성질에 따른 결과에 대하여 고찰하였다.

• Journal of the Korean Geosynthetics Society
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• v.16 no.2
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• pp.159-164
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• 2017

This paper presents the results of an investigation into the thermo-hydromechanical response of weathered granite soil. The effect of forced change temperature and relative humidity at the soil layer boundaries were monitored during heating. A series of load settlement test were performed on layers of compacted, unsatureated weathered granite soil with geosynthetic embedded at mid height before and after application of heat exchanger to the base of the soil layers. The results from this study indicated the potential for using embedded heat exchangers for the mechanical improvement of geotechnical systems incorporating weathered granite soil.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.942-944
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• 2017

High-speed vehicles are subjected to complex loads, such as acoustic pressure from the engine at launch and aerodynamic heating and aerodynamic pressure during flight. A thermal protection system panel is required to protect internal systems such as the fuel tank of the vehicle from the external environment. This study defines analytical models for heat transfer and thermal structure characteristics of the thermal protection system panel. Furthermore, the study performed parameters analysis to achieve the thermal structural integrity and to make it lighter.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.12
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• pp.1167-1173
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• 2013

This study aimed to calculate the CFFs (critical flow functions) of a sonic nozzle bank with a 12-nozzle package within 1 s. Toward this end, the Helmholtz free energy of natural gas was formulated by using the AGA8-dc equation of state in a form without integral terms, and thereafter, thermodynamic properties such as the enthalpy, entropy, speed of sound, and heat capacity, which are used in CFF calculation, were derived in analytical form. As a result, the calculation time of CFFs was improved from 6.7 s in a previous study to 0.6 s per 12-nozzle package and kept almost constant regardless of the number of components in natural gas. Furthermore, it was confirmed that the calculated CFF values were in agreement with the results of a CFF international comparison test carried out under ISO management in 1998-1999.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.2
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• pp.101-107
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• 2009

Investigation of resaturation and thermal-hydro-mechanical behavior for the buffer of a repository requires measuring the water content of compacted bentonite. This study investigated the relative humidity of compacted bentonites using a humidity sensor (Vaisala HMT 334) applicable under high temperature and pressure, and then conducted a multi-regression analysis based on the measured results to determine relationships among the water content, relative humidity, and temperature. The relationships for the compacted bentonites with the dry densities of 1,500 $kg/m^3$ and 1,600 $kg/m^3$ were expressed as ${\omega}=0.196RH-0.029T+1.391({r^2=0.96)}$ and ${\omega}=0.199RH-0.029T+2.596({r^2=0.98)}$, respectively. These were then used to interpret the resaturation of bentonite blocks in the KENTEX test.