Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Linear Relationships between Thermodynamic Parameters. Part 6 Solvent Effect on Chloride Exchanges in Benzyl Chloride

열역학함수간의 직선관계 (제6보) 염화벤질의 염소교환에 미치는 용매효과

  • Lee, Ik-Choon (Department of Applied Chemistry, College of Engineering, Seoul National University) ;
  • Park, Yong-Ja (Department of Applied Chemistry, College of Engineering, Seoul National University)
  • 이익춘 (서울대학교 공과대학 응용화학과) ;
  • 박용자 (서울대학교 공과대학 응용화학과)
  • Published : 19681200
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Abstract

Rate constants and activation parameters have been petermined for the chloride exchanges of benzyl chloride in 60, 70, 80 and 90 vol.% ethanol-water solutions. Results showed a good linearity when appiled to our general equation. The significance of this linear fit has been discussed in conjunction with the Dewar's relation which was derived from the PMO method.

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References

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