• Nuclear Engineering and Technology
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• v.25 no.2
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• pp.265-275
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• 1993

A vapor explosion has been a concern in nuclear reactor safety due to its potential for a destructive mechanical energy release. In order to properly assess the hazard of a vapor explosion, it is necessary to accurately estimate the conversion efficiency of the thermal energy to mechanical energy. In the absence of a complete model to determine the explosive energy yield, one may have to rely on a simpler upper bound estimate such as a thermodynamic model. This paper discusses various thermodynamic models and presents a clarification of each model in their mathematical formulation and the thermodynamic work conversion. It is shown that the work release in the shock adiabatic model of Board and Hall is essentially equal to that of Hicks-Menzies thermodynamic model. The effect of coolant void fraction on the explosion efficiency is also predicted based on these thermodynamic models. Finally, the Hicks-Menzies model is modified to account for the chemical reaction between a metallic fuel and water and the resultant effects on the explosion expansion work are discussed.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.202.1-202.1
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• 2015

탄소의 $sp^2$ 혼성으로 이루어진 2차원 단일시트(two-dimensional single sheet)인 그래핀은 기계적, 열역학적, 전기적 특성이 매우 우수하며 특히 고유연성과 투명성을 가진다는 장점 때문에 오랜 기간 주목 받으며 다양한 분야에서 연구되어 왔다. 이러한 그래핀을 만드는 방법에는 화학적 증기 증착법 및 흑연으로부터의 물리적, 화학적 박리 방법이 있다. 양질의 그래핀을 대면적에서 획득 할 수 있는 화학적 증기 증착법의 경우 높은 공정 비용과 함께 수반되어야 하는 전사과정의 어려움으로 인하여 실제 상용화에 어려움이 있다. 이러한 단점의 극복을 위해 대량의 그래핀을 저렴하게 확보 할 수 있는 화학적 박리 방법이 주목을 받고 있다. 화학적 박리 방법의 경우 박리 과정에서 수반되는 산화 그래핀의 환원과정이 필요하였으며, 이를 위해 강력한 환원제를 이용한 화학적 환원 방법, 고온에서의 열처리를 이용한 열역학적 환원 방법, 및 빛을 노광시켜 산화 그래핀을 환원시키는 광학적 방법이 시도되었다. 화학적 및 열역학적 환원방법의 경우 고품질의 환원된 산화 그래핀을 획득 할 수 있으나, 강한 환원제 및 높은 열처리 온도로 인하여 유연 기판의 사용이 제한되는 단점이 있다. 이러한 단점을 극복하기 위해 빛을 이용한 광학적 방법이 제시되었으나, 환원과정에 사용되는 단파장의 자외선 광원의 높은 가격으로 인하여 경제성의 확보가 제한된다. 본 논문에서는 우수한 광학적 특성을 보이는 란타넘족 이온을 사용하여 선택적 파장 대에서 높은 광흡수도를 가지는 산화 그래핀-란타넘 이온 혼합용액을 만들었으며, 가시광선대역의 파장을 가지는 레이저를 사용하여 우수한 품질을 가지는 환원된 산화 그래핀을 제작하였다. 구체적으로 산화 그래핀은 modified hummer's method를 이용하여 만들어졌으며, 자외선 대역을 흡수하는 $Gd_{3+}$, 녹색 레이저를 흡수하는 $Tb_{3+}$, 적색 레이저를 흡수하는 $Eu^{3+}$를 1 mM 섞어주었다. 그 후, 300~800 nm의 파장을 가지는 레이저를 $1mW/cm^2$를 노광시켜 산화 그래핀을 환원시켰다. 환원된 산화 그래핀의 특성은 FT-IR, UV-Vis, 저온 PL, SEM, XPS 및 전기측정을 이용해 측정하여 재현성 및 반복성을 확인하였다.

• Aerospace Engineering and Technology
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• v.4 no.1
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• pp.18-24
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• 2005

Wet compression means the injection of water droplets into the compressor of gas turbines. This method decreases the compression work and increases the turbine output by decreasing the compressor exit temperature through the evaporation of water droplets inside the compressor. This paper provides thermodynamic and aerodynamic analysis on wet compression in a centrifugal compressor for a microturbine. The meanline performance analysis of centrifugal compressor is coupled with the thermodynamic equation of wet compression to get the meanline performance of wet compression. The most influencing parameter in the analysis is the evaporative rate of water droplets. It is found that the impeller exit flow temperature and compression work decreases as the evaporative rate increases. And the exit flow angle decreases as the evaporative rate increases.

• Journal of Industrial Technology
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• v.17
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• pp.51-72
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• 1997

The sound velocity measurements can permit much higher precision than that obtainable in the direct PVT experiments in addition to producing static and dynamic properties simultaneously, and thus the study on the sound velocity has been considered as another important approach to a fundamental understanding and description of the structure of fluids. This review deals with what have been done on studies of the sound velocity for evaluating thermodynamic properties with an emphasis on the development of the methods to extract the thermodynamic properties from the experimental data on sound velocity.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.2189-2205
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• 1991

Thermodynamic properties of binary nonazeotropic refrigerant mixtures are estimated by using a modified Carnhan-Starling equation of state. In this study, pure component refrigerants such as R14, R23, R13, R13 B1, R22, R12, R134a, R152a, R142b, RC318, R114, R11, R123 and R113 are chosen and the thermodynamic properties of enthalpy and entropy are calculated in terms of relevant variables. The modified Carnahan-Starling equation of state is compared with the carnahan-Staring-De Santis equation of sate. Results show that the relative errors become slightly smaller with the equation of state proposed in this study. Correlations are obtained for the mixtures of which the vapor liquid equilibruim data are available to us in the literature. Those mixtures are R14/R23, R23/R12, R13/R12, R13/R11, R13B1/R22, R13B1/RC318, R12/RC138, R12/R114 and R12/R11. The binary interaction coefficients are found under the condition of minimizing the pressure deviations at the vapor liquid equiblibrium state and the estimation of the vapor liquid equilibrium for the refrigerant mixtures is done. Pressure-enthalpy and temperature-entropy diagrams are plotted for the refrigerant mixtures of specific composition.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.3
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• pp.267-272
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• 2012

Carbon emission generated by energy issues is one of the major problems which all countries concern. The International Energy Agency recommends to improve 15-30[%] of energy efficiency than now. Government has pushed the domestic energy saving policies and incentives and penalties were also given in that direction. Pumps are widely used to transfer fluids and they consume at least 20[%] power of each nation. Their loss of energy is huge if they have been operated at low efficiency for long time. Low efficiency of these pumps is often due to incorrect design or degradation. Pump efficiency can be measured to estimate energy loss. If it is low, the pump may be repaired or replaced with new one. This paper introduces thermodynamic method to measure pump efficiency using only two kinds of sensors for temperature and pressure. It can calculate best efficiency point(BEP) of actual systems easily and fast. Its values were compared with the real performance curve provided by pump maker and we got almost similar performance curves from the repeated experiment.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.6
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• pp.476-483
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• 2016

An organic Rankine cycle for ocean thermal energy conversion system is a generating cycle using the temperature difference between surface water and deep water of the ocean. The working fluid is an important factor in the thermodynamic performance of an organic Rankine cycle. There is pinch point analysis as thermodynamic analysis of an organic Rankine cycle. This study performed a thermodynamic performance analysis according to variation in the pinch point temperature difference in heat exchangers and variation of outlet temperature of heat source and heat sink. It analyzed the thermodynamic performance by applying seven types of simple working fluids in a simple Rankine cycle for ocean thermal energy conversion that was designed according to pinch point analysis. As a result of the performance analysis, cycle irreversibility and total exergy destruction factor more decreased, and second law efficiency more increased in the lower pinch point temperature difference and temperature variation of heat source and heat sink in heat exchangers. In addition, the irreversibility changed greatly at a point that occurred in the thermodynamic variation. Among the selected working fluids, RE245fa2 showed the best thermodynamic performance, and the performance of all working fluids was observed to be similar. It needs a strict theoretical basis about diverse factors with thermodynamic performances in selecting heat exchangers and working fluids.

• Proceedings of the Materials Research Society of Korea Conference
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• 1997.10a
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• pp.32-32
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• 1997

• Microbiology and Biotechnology Letters
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• v.17 no.4
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• pp.365-369
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• 1989

Thermal inactivation of Tyichoderma viride cellobiohydrolase was investigated by immunoassay and residual enzyme assay such as carboxymethyl cellulase (CMCase) and filter paper degradation activity (FPase). Arrhenius plots of cellobiohydrolase were appeared as straight line. The Z-values of cellobiohydrolase calculated by CMCase, FPase and immunoassay were 5.2$^{\circ}C$, 6.4$^{\circ}C$ and 5.8$^{\circ}C$, respectively. The thermodynamic parameters obtained from FPase were better agreement with those of immunoassay than CMCase assay.

• Journal of Ocean Engineering and Technology
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• v.13 no.4 s.35
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• pp.159-168
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• 1999

부유식 파랑에너지 변환시스템(Oscillating Water Column)에 대한 해석은 입력파와 챔버, 챔버내 공기의 상호작용으로 인하여 어려움이 많다. 이 논문은 이와 같은 요소를 고려하면서도 쉽고 간편한 해석법을 제시한다. 파랑에너지에 의한 자가발전은 파랑에너지를 기계적 운동으로 변환하고 이를 전기에너지로 변환함으로써 가능하다. 본 논문은 파랑에너지에서 기계적 에너지로 변환하는 과정에 집중하여 그 부분의 성능을 해석한다. 단일 진동수 규칙파가 입력되었을 때에 파에 의하여 챔버의 상하운동이 선형적으로 발생하는 것으로 보며, 이 상하운동에 챔버내의 압력 영향을 고려하였다. 상하운동과 챔버내로 투과한 파, 그리고 챔버내 압력에 의해 발생되는 파에 의해 챔버내의 상대운동을 정하고, 그 상대 운동에 의한 공기의 압축 팽창과 온도상승을 근사적 열역학적 방정식으로 해석하였고 오리피스를 통한 유량을 결정하였다. 얻어진 식은 간단하면서도 관련요소의 영향을 전반적으로 표현한다. 결과에 따르면 고정식의 에너지 변환식은 부유식의 특별한 경우로서 파악되었다. 또한 고정식의 시스템을 그대로 부유식으로 바꿨을 때 그 변환효율은 적어지는 것으로 나타났다. 본 해석법은 계산이 간편하므로 설계단계에서 유용하게 활용될 수 있을 것으로 기대된다.