• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.78-78
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• 2000

다결정 실리콘-게르마늄 (poly-SiGe)은 태양전지 개발에 있어서 중요한 물질이다. 우리는 소량의 Ge(x=0.05)으로부터 다량의 Ge(x=0.67)을 함유한 수소화된 비정질 실리콘-게르마늄 (a-SiGe:H) 박막의 고상결정화 과정을 ESR (electron spin resonance)방법으로 조사해보았다. 먼저 PECVD 방법으로 Corning 1737 glass 위에 a-Si1-xGex:H 박막을 증착시켰다. 증착가스는 SiH4, GeH4 가스를 썼으며, 기판온도는 20$0^{\circ}C$, r.f. 전력은 3W, 증착시 가스압력은 0.6 Torr 정도이었다. 증착된 a-SiGe:H 박막은 $600^{\circ}C$ N2 분위기에서 다시 가열되어 고상결정화 되었고, 결정화 정도는 XRD (111) peak의 세기로부터 구해졌다. ESR 측정은 상온 x-band 영역에서 수행되었다. 측정된 ESR스팩트럼은 두 개의 Gaussian 함수로써 Si dangling-bond와 Ge dangling-bond 신호로 분리되었다. 가열 초기의 a-SiGe:H 박막 결함들의 스핀밀도의 증가는 수소 이탈에 기인하고, 또 고상결정화 과정에서 결정화된 정도와 Ge-db 스핀밀도의 변화는 서로 깊은 상관관계가 있음을 알 수 있었다. 특히 Ge 함유량이 큰 박막 (x=0.21, 0.67)에서 뿐만 아니라 소량의 Ge이 함유된 박막(x=0.05)에서도 Ge dangling-bond가 Si dangliong-bond 보다 고상결정화 과정에서 더 중요한 역할을 한다는 것을 알수 있었다. 또한 초기 열처리시 Si-H, Ge-H 결합에서 H의 이탈로 인하여 나타나는 Si-dangling bond, Ge-dangling bond 스핀밀도의 최대 증가 시간은 x 값에 의존하였는데 이러한 결과는 x값에 의존하는 Si-H, Ge-H 해리에너리지로 설명되어 질 수 있다. 층의 두께가 500 미만인 커패시터의 경우에 TiN과 Si3N4 의 계면에서 형성되는 슬릿형 공동(slit-like void)에 의해 커패시터의 유전특성이 파괴된다는 사실을 알게 되었으며, 이러한 슬릿형 공동은 제조 공정 중 재료에 따른 열팽창 계수와 탄성 계수 등의 차이에 의해 형성된 잔류응력 상태가 유전막을 기준으로 압축응력에서 인장 응력으로 바뀌는 분포에 기인하였다는 사실을 확인하였다.SiO2 막을 약화시켜 절연막의 두께가 두꺼워졌음에도 기존의 SiO2 절연막의 절연 파괴 전압 및 누설 전류오 비교되는 특성을 가졌다. 이중막을 구성하고 있는 안티퓨즈의 ON-저항이 단일막과 비교해 비슷한 것을 볼 수 잇는데, 그 이유는 TiO2에 포함된 Ti가 필라멘트에 포함되어 있어 필라멘트의 저항을 감소시켰기 때문으로 사료된다. 결국 이중막을 구성시 ON-저항 증가에 의한 속도 저하 요인은 없다고 할 수 있다. 5V의 절연파괴 시간을 측정한느 TDDB 테스트 결과 1.1$\times$103 year로 기대수치인 수십 년보다 높아 제안된 안티퓨즈의 신뢰성을 확보 할 수 있었다. 제안된 안티퓨즈의 이중 절연막의 두께는 250 이고 프로그래밍 전압은 9.0V이고, 약 65$\Omega$의 on 저항을 얻을수 있었다.보았다.다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품 개발에 따른 새로운 수요 창출과 수익률 향상, 기존의 기능성 안료를 나노(nano)화하여 나노 입자를 제조, 기존의 기능성 안료에 대한 비용 절감 효과등을 유도 할 수 있다. 역시 기술적인 측면에서도 특수소재 개발에 있어 최적의 나노 입자 제어기술 개발 및 나노입자를 기능성 소재로 사용하여 새로운 제품의 제조와 고압 기상 분사기술의 최적화에 의한 기능성 나노 입자 제조 기술을 확립하고 2차 오염 발생원인 유기계 항균제를 무기계 항균제로 대체할 수 있다. 이와 더불

• The Journal of the Korea Contents Association
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• v.21 no.9
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• pp.299-311
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• 2021

The purpose of this study is to analyze the ripple effect of the Chinese education industry on the national economy by using the industry-related table of 2017 by the China Statistical Office to use it as policy data for revitalization of the Chinese education industry in the future. To achieve this purpose, 149 industries in the basic classification of the industry-related table were classified into 32 industries. Based on these classifications, by analyzing the production induction coefficient, sensitivity coefficient, influence coefficient, yield inducement coefficient, production tax induction coefficient, and labor induction coefficient, etc. The purpose of this study is to understand the relationship between different industries and to find out the economic impact of the Chinese education industry. The analysis results show that in 2017, the total production induction coefficient of China's education industry was 1.7188, the row total was 1.0626, the sensitivity coefficient was 0.01211, the influence coefficient was 0.01958, the income induction coefficient was 0.6667, the production tax induction coefficient was 0.035, and the final demand was 1 billion yuan. When this occurs, the labor induction coefficient shows a total of 31,254 persons (indirect 15,541 persons, direct 15,713 persons). Based on the analysis results, this study suggested the implications that government support, technology introduction and application of new operating models, policy regulations, and efficient supervision of the system and president are required for further development of the Chinese education industry.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.63 no.4
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• pp.378-383
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• 2018

The goal of this study was to examine the growth and yield according to planting density in wide-row drill seeding cultivation suitable for mechanized harvesting. We evaluated effects depending on planting densities [row spacing (30, 40, 50, and 60 cm) and plant spacing (10, 15, and 20 cm)] and cultivars ('Hongeon' and 'Arari') on growth and yield of Adzuki Beans (Vigna angularis (Willd.) Ohwi Ohashi). When row spacing decreased, the stem length increased in 'Arari' but decreased in 'Hongeon.' The stem diameter and number of branches in both the cultivars decreased with a decrease in row spacing. The pod height increased with lower planting densities. The greatest height values recorded in 'Hongeon' and 'Arari' were 5.0 cm and 8.8 cm in $30{\times}10cm$ and $50{\times}10cm$ treatments, respectively. The number of pods and number of seeds in both cultivars tended to increase with a decrease in planting density. On the other hand, in 100-seed weight, there was a difference in planting density in 'Hongeon', but no difference in 'Arari'. The highest yield was at the planting density of $40{\times}15cm$ in both 'Hongeon' and 'Arari', $285kg{\cdot}10a^{-1}$ and $374kg{\cdot}10a^{-1}$.

• Journal of Navigation and Port Research
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• v.42 no.6
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• pp.539-545
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• 2018

In recent years, research on shipping market forecasting with the employment of non-linear AI models has attracted significant interest. In previous studies, input variables were selected with reference to past papers or by relying on the intuitions of the researchers. This paper attempts to address this issue by applying the stepwise regression model and the random forest model to the Cape-size bulk carrier market. The Cape market was selected due to the simplicity of its supply and demand structure. The preliminary selection of the determinants resulted in 16 variables. In the next stage, 8 features from the stepwise regression model and 10 features from the random forest model were screened as important determinants. The chosen variables were used to test both models. Based on the analysis of the models, it was observed that the random forest model outperforms the stepwise regression model. This research is significant because it provides a scientific basis which can be used to find the determinants in shipping market forecasting, and utilize a machine-learning model in the process. The results of this research can be used to enhance the decisions of chartering desks by offering a guideline for market analysis.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.64 no.1
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• pp.33-39
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• 2019

The goal of this study was to investigate how the characteristics of growth and yield are affected by various planting densities in wide-row drill seeding cultivation suitable for mechanized harvesting. Two cultivars ('Hwanggeum' and 'Leebackchal') of proso millet (Panicum miliaceum L.) were planted at varying planting densities [row spacing (20, 30, and 50 cm) and plant spacing (3, 5, 10, and 15 cm)]. The culm length was highest at the planting density of $50{\times}3cm$ and $50{\times}5cm$ for 'Hwanggeum' and $20{\times}3cm$ for 'Leebackchal'. The culm diameter became thinner as the planting density increased. The number of tillering and panicle length showed the same tendency to increase in quantity or length as planting density decreased and was highest at $50{\times}15cm$ when the planting density was lowest. The number of seeds per individual increased as planting density decreased. The thousand grain weight showed no significant differences among treatment plots. The greatest yield of 'Hwanggeum' was obtained at a planting density of $50{\times}3cm$ ($314.9kg{\cdot}10a^{-1}$) and that of 'Leebackchal' was obtained at $50{\times}3cm$ and $50{\times}5cm$ ($358-356kg{\cdot}10a^{-1}$).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.2
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• pp.33-39
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• 2021

As the interest and demand in the recycled yarn field has increased rapidly worldwide, domestic companies are also promoting research and development and business on recycled yarn. The chemical and thermal properties of four types of virgin and recycled PET samples from A and B company, which are the leading domestic companies in the recycled polyester yarn business, were confirmed through infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC). Virgin and recycled PET from two companies were compared. FT-IR spectroscopy revealed the typical spectra of PET for both companies and a different peak at 872 cm-1. DSC confirmed that the melting point and crystallization temperature of recycled PET were lower than those of virgin PET. These results indicate that small amounts of contaminants are an important parameter affecting the thermal properties of recycled PET. In the DSC results after seven repeats of the heating and cooling processes, all four samples showed that a lower melting point, crystallization temperature, and low heat flow intensity increased with increasing number of cycles. The results of melting and crystallization enthalpy also showed similar patterns.

• Korean Chemical Engineering Research
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• v.60 no.2
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• pp.175-183
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• 2022

With the expansion of the automobile market, the demand for Nd as an essential rare earth material for automobile motors is rapidly increasing. Research on the calcio-thermic reduction process between Nd₂O₃ and calcium-based alloys has been extensively studied in order to manufacture Nd. In this study, Ca-Cu, as a reducing for Nd₂O₃, was prepared by electrolysis in CaCl₂ molten salt. Cu wire and graphite were employed as a working electrode and a counter electrode for electrolysis reaction, respectively. The reference electrode was manufactured by putting Ag wire in a mixture of AgCl and CaCl₂ at a ratio of 1:99 mol%. The cyclic voltammetry results showed that the deposition of Ca²⁺ on the surface of working electrode was observed from a potential of -1.8 V, and the reduction potential of Ca²⁺ decreased as the reaction temperature increased. The diffusion coefficient of Ca²⁺ calculated by the chronoamperometry experiment was found to be 5.4(±6.8)×10^-6 cm²/s. In addition, Ca-Cu liquid alloy was prepared by applying a constant potential to Cu electrodes. The element ratio of Ca-Cu alloy formed by applying a potential of -2.0 V was found to Ca:Cu=1:4.

• Journal of Mushroom
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• v.20 no.3
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• pp.153-162
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• 2022

The purpose of this study was to breed a variety of stable productivity and high storage characteristics of white Hypsizygus marmoreus, which has high demand at domestic and global market due to a low bitter taste and the preference for white species. Accordingly, 'Baekmaru' was bred by hybridizing brown and white cap color species and backcrossing with white species. The 'Baekmaru' variety was bred by crossbreeding the brown and white species and backcrossing the white species. Through repeated cultivation of 'Baekmaru', a variety with a low contamination rate was selected when culturing the spawn for stable cultivation. As a results of demonstration test, the yield of 'Baekmaru' was 14% higher than that of the commercial variety. In addition, among the fruiting body characteristics of 'Baekmaru', diameter and thickness of the pileus were 16.43±15.27mm and 6.46±0.58mm, which were slightly higher than the commercial variety, and the hardness was 2.69±0.89N for the pileus and 3.09±0.89N for the stipe. The shelf life showed less change in thickness and color of pileus compared to commercial variety. The hardness of pileus of 'Baekmaru' was maintained in the range of 3.5 to 4.0N in the 4℃ and 4℃ and 20℃ mixed treatment until 30 days of storage, and was higher than that of the commercial variety. Therefore, it was suggested to be excellent in storability.

• The Journal of Engineering Geology
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• v.32 no.4
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• pp.627-642
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• 2022

The world's long reliance on fossil fuels (e.g., oil, coal, and natural gas) is severely changing its environment and climate. Energy research has focused on developing hydrogen as the most promising energy carrier and a key technology for sustainable energy development. Hydrogen can be classified as gray, blue, green, and otherwise according to the raw materials and methods used for production and processing. For the development of hydrogen energy, geologists are attempting to identify the mechanism of abiotic hydrogen generation by serpentinization or hydrothermal alteration. Teams in the United States, France, and Australia have researched laboratory-scale hydrogen production through water-rock interactions under various conditions, whereas there has been almost no research on abiotic hydrogen in South Korea. This paper reviews the current state of international research on hydrothermal alteration and offers suggestions for future investigations of abiotic hydrogen production in South Korea.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.468-468
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• 2023

최근 급격한 기후변화에 의한 이상가뭄 발생 등을 대비하기 위한 비상용수 또는 대체 수자원으로서의 지하수 개발수요가 증가함에 따라 기저유량 확보 및 수질개선 방안을 수립하는 것은 지속가능한 수자원 이용 관리 측면에 있어서 매우 중요하다. 국내 지하수 사용에 따른 하천유량의 변동에 관한 연구는 활발히 진행되었으나, 실질적으로 적용가능한 지하수 저감 방안 및 지하 수질개선방안에 대한 연구는 미비한 실정이다. 이에 본 연구에서는 바이오차를 이용하여 시험포를 설계 및 시공하였으며, 실내 인공강우 실험을 통해 지하 침투수 확보 능력 및 수질개선 효과를 평가하였다. 대조구는 폭 1 m × 길이 1 m × 깊이 0.60 m로 시공하였으며, 바이오차 시험포는 폭 1 m × 길이 1 m, 시험포 상단과 하단 각 0.10 m씩 대조구와 동일한 흙으로 채웠으며, 그 사이 0.40 m만큼은 바이오차를 채워서 시공하였다. 시험의 정밀도를 높이기 위해 동일한 조건으로 대조구와 바이오차 시험포 각 2개씩, 총 4개의 시험포를 시공하여 실내 인공강우 실험을 진행하였으며, 시험포에서 발생한 직접유출수와 기저유출수를 이용하여 바이오차의 지하 침투량 확보 및 수질개선효과를 분석하였다. 시험포 완공 후 총 2번의 실내인공강우 실험 결과 대조구에서 발생한 직접유출량은 총 0.214 m³, 바이오차 시험포에서는 총 0.194 m³로 대조구 대비 총 직접유출량 저감효과는 9.4%로 나타났다. 기저유출의 경우 바이오차 시험포(0.036 m³)에서 대조구(0.003 m³) 대비 약13배 많은 양의 기저유출수가 발생한 것으로 나타났다. 각 시험포에서 발생한 유출수의 오염부하를 산정해 대조구 시험포 대비 바이오차 시험포에서 발생한 직접유출수의 오염부하 저감효과를 분석한 결과 BOD₅ 항목과 COD_Mn 항목, 그리고 TOC 항목의 경우 26.3%과 22.0%, 그리고 27.6%로 저감 된 것으로 나타났으나, SS 항목과 T-N 항목, 그리고 T-P 항목의 경우 저감효과가 없는 것으로 나타났다. 이와 같이 바이오차는 지하 침투수 확보 능력은 효과적인 것으로 나타났으나, 직접유출수의 수질개선 효과는 미비한 것으로 나타났다. 그러나 바이오차의 지하 침투량 및 수질개선 효과는 바이오차 생산 시 사용된 열분해 방식, 사용된 바이오차의 양 등에 따라 편차가 클것으로 판단되며, 바이오차의 생산 방법, 토양 흡착 기간, 바이오차의 양 등 다양한 조건에서의 모니터링을 통해 정량화 되어야 할 것으로 판단된다.