• Title/Summary/Keyword: 열분석적 특성

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Photoluminescence from silicon nanocrystals in silicon ion implanted SiO2 layers (실리콘 이온주입 SiO2층의 나노결정으로 부터의 광루미네센스)

  • Kim, Kwang-Hee;Oh, Hang-Seok;Jang, Tae-Su;Kwon, Young-Kyu;Lee, Yong-Hyun
    • Journal of Sensor Science and Technology
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    • v.11 no.3
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    • pp.183-190
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    • 2002
  • Photoluminescence(PL) properties of $Si^+$-implanted $SiO_2$ film, which was thermally grown on c-Si substrate, is reported. We have compared room temperature photoluminescence (PL) spectra of the samples which was made in several kinds of implantation, subsequent annealing and $SiO_2$ film thickness. XRD data was correlated with the PL spectra. Silicon nanocrystals in $SiO_2$ film is considered as the origin of the photoluminescence. PL spectra was investigated after wet etching of the $SiO_2$ film by using BOE (Buffered Oxide Etchant) at every one minute. PL peak wavelength was varied as the etching is proceeded. These results indicate that the quantity and the distribution of dominant size of Si nanocrystals in $SiO_2$ film seem to have a direct effect on PL spectrum.

Antibacterial Effects of Leek and Garlic Juice and Powder in a Mixed Strains System (복합균주에 대한 부추와 마늘 생즙 및 가루성분의 항균특성)

  • Lee, Eun-Hee;Jang, Keum-Il;Bae, In-Young;Lee, Hyeon-Gyu
    • Korean Journal of Food Science and Technology
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    • v.43 no.4
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    • pp.518-523
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    • 2011
  • The aim of this study was to evaluate the antimicrobial activities of leek and garlic extract juice and powder against Escherichia coli, Salmonella enteritidis, and Staphylococcus aureus in a single strain and a mixed strains system. Garlic juice and powder showed higher antimicrobial activity against Sta. aureus than that of E. coli or S. enteritidis. The antimicrobial activities of the leek and garlic powders decreased with increasing temperature and time, but stabilized at various pHs. The antimicrobial effects of mixtures of various ratios between the leek and garlic extracts increased with an increase in garlic extract content. No synergistic effects by the leek and garlic mixtures were observed. In a mixed strains system, the antimicrobial effects of leek and garlic powder were similar to those in a single strain system.

Time-resolved Photoluminescence Study of Seven-stacked InAs/InAlGaAs Quantum Dots

  • O, Jae-Won;Gwon, Se-Ra;Ryu, Mi-Lee;Jo, Byeong-Gu;Kim, Jin-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.265-265
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    • 2011
  • 자발형성법으로 InP (001) 기판에 성장한 InAs/InAlGaAs 양자점(QDs: quantum dots)의 광학적 특성을 PL (photoluminescence)와 TRPL (time-resolved PL)을 이용하여 분석하였다. InAs QDs 시료는 single layer InAs QDs (QD1)과 7-stacked InAs QDs (QD2)를 사용하였다. 두 시료 모두 저온 (10 K)에서 1,320 nm에서 PL 피크가 나타나고, 온도가 증가함에 따라 PL 피크는 적색편이 (red-shift)를 보였다. 양자점의 온도를 10 K에서 300 K까지 증가하였을 때 QD1은 178 nm 적색편이 하였으며, PL 스펙트럼 폭은 온도가 증가함에 따라 증가하였다. 그러나 QD2는 264 nm 적색편이를 보였으며 PL 스펙트럼의 폭은 QD1 시료와 반대로 온도가 증가함에 따라 감소하였다. QD2의 아주 넓은 PL 스펙트럼 폭과 매우 큰 적색편이는 InAs 양자점 크기의 변화가 QD1에 비해 훨씬 크기 때문이다. QD2의 경우 InAs 층수(layer number)가 증가함에 따라 InAs QD의 크기가 점차 증가하므로 QD 크기의 변화가 single layer인 QD1 시료보다 훨씬 크다. QD1의 PL 소멸은 파장이 증가함에 따라 점차 느려지다가 PL 피크 근처에서 가장 느린 소멸 곡선을 보이고, 파장이 더 증가하였을 때 PL 소멸은 점차 빠르게 소멸하였다. 그러나 QD2의 PL 소멸곡선은 파장이 증가함에 따라 점차 빠르게 소멸하였다. 이것은 QD2는 양자점 크기의 변화가 매우 크기 때문에 (lateral size=18~29 nm, height=2.8~5.9 nm) 방출파장이 증가함에 따라 양자점 사이의 파동함수의 겹침이 증가하여 캐리어의 이완이 증가하기 때문으로 설명된다. 온도에 따른 TRPL 결과는 두 시료 모두 10 K에서 150 K 까지는 소멸시간이 증가하였고, 150 K 이후부터는 소멸시간이 감소하였다. 온도가 증가함에 따라 소멸시간이 증가하는 것은 양자점에서 장벽과 WL (wetting layer)로 운반자(carrier)의 이동, 양자점들 사이에 열에 의해 유도된 운반자의 재분배 등으로 인한 발광 재결합으로 설명할 수 있다. 150 K 이상에서 소멸시간이 감소하는 것은 열적효과에 의한 비발광 재결합 과정에 의한 운반자의 소멸이 증가하기 때문이다. 온도에 따른 TRPL 결과는 두 시료 모두 150 K까지는 발광재결합이 우세하고, 150 K 이상에서 비발광재겹합이 우세하게 나타났다.

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Analysis of TQM-based HACCP System and Safety Management Performance in Middle and High School Foodservice Operations - Seoul, Gyeonggi, Incheon, Kangwon and Chungcheong Areas in Korea - (중.고등학교 급식 운영특성에 따른 종합적 품질경영(TQM)에 근거한 HACCP 시스템 활동 및 위생관리 수행수준 분석 -서울, 경기, 인천, 강원, 충청지역 중.고등학교를 중심으로-)

  • Kim, Gyoung-Mi;Lee, Sim-Yeol
    • Journal of the Korean Dietetic Association
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    • v.17 no.1
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    • pp.72-90
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    • 2011
  • The following study was taken in the Seoul, Gyeonggi, Incheon, Kangwon, and Chungcheong areas to analyze the performance levels of safety management by characteristics of school foodservice. The following results were obtained from a survey conducted on 2,271 middle and high school dietitians in 808 schools. Out of the 808 schools surveyed, 513 schools (63.5%) were self-operated and 295 schools (36.5%) were managed by a contract. Regarding the performance level of the hygiene duties, contract-managed schools were rated as 4.02 points while self-operated schools were rated relatively higher (4.16 points). The self-operated schools had an average score of 3.60 points for the TQM-based HACCP system, and the areas that scored lower than the average were strategies, human resources, data and analysis. The average score of the contract-managed schools was 3.42 points, and such areas as leadership, human resources, data and analysis, and customer satisfactory level scored below the average. For the analysis of CCP performance level, the contract-managed schools scored 4.28 points while self-operated schools scored 4.34 points. Overall, the hygiene duties, CCP performance level, and TQM-based HACCP system performance of the contracted schools were lower than those of the self-operated schools. Therefore, it is advised that the contract-managed schools consider new measures to strengthen their performance level for improved safety of school foodservice.

Thermal Properties and Flame Retardancy of Poly(amic acid)/organoclay Nanocomposites (Poly(amic acid)/organoclay 나노복합체의 열적특성 및 난연성)

  • Kim, Sun;Yoon, Doo-Soo;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.42 no.3
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    • pp.177-185
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    • 2007
  • Polyamic acid(PAA)/organoclay nanocomposites containing phosphorous were prepared by solution blending of phosphorylated PAA(PPAA) and organically modified montmorillonite(O-MMT) as a type of layered clays. The nanocomposites were characterized by FT-IR, DSC, TGA, PCFC, SEM, and XRD. The preparation of nanocomposites was confirmed by FT-IR and XRD. SEM pictures showed that the organoclay was dispersed well in the PAA matrix relatively. XRD results indicated that the O-MMT layers were intercalated. The thermal stability and flame retardancy of O-MMT/PPAA nanocomposites were higher than those of pure PAA. PCFC results also showed that the heat release capacity and total heat release values of O-MMT 4 wt%/PPAA-0.2, 0.4, 0.6 composites were decreased with increasing the mole ratio of phosphorous. It was found that the nanocomposite films had the potential to be used as a fire safe material.

Barcode Region of Interest Extraction Method Using a Local Pixel Directions in a Multiple Barcode Region Image (다중 바코드 영역을 가지는 영상에서 지역적 픽셀 방향성을 이용한 바코드 관심 영역 추출 방법)

  • Cho, Hosang;Kang, Bongsoon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.9
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    • pp.2121-2128
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    • 2015
  • In this paper presents a method of extracting reliable and regions of interest (ROI) in barcode for the purpose of factory automation. backgrounds are separated based on directional components and the characteristics of detected patterns. post-processing is performed on candidate images with analysis of problems caused by blur, rotation and areas of high similarity. In addition, the resizing factor is used to achieve faster calculations through image resizing. The input images contained multiple product or barcode for application to diverse automation environments; a high extraction success rate is accomplished despite the maximum shooting distance of 80 cm. Simulations involving images with various shooting distances gave an ROI detection rate of 100% and a post-processing success rate of 99.3%.

Development of a PTC Heater for Supplementary Heating in a Diesel Vehicle (디젤 차량의 보조 난방을 위한 PTC 히터 개발)

  • Shin, Yoon Hyuk;Kim, Sung Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.666-671
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    • 2014
  • Using positive temperature coefficient (PTC) heater as supplementary heating for diesel engine vehicles with low heat source is a good method to enhance the heating performance during cold start. In this study, the PTC elements were made by using screen printing process for forming ohmic contact layer, and prototype of PTC heater was designed and made for a diesel engine vehicle. In process of designing the PTC heater, the thermal flow analysis of PTC element modules was conducted for verifying the effect of the shapes of contact surface between each of the components (cooling fin, insulator, ceramic element). We also investigated the performance characteristic (heating capacity, energy efficiency, pressure drop) of the PTC heater through the experiments. Therefore, the experimental results indicated that prototype of PTC heater had satisfactory performance. This study will be basis for improving the manufacturing process and increasing the performance of the PTC element and heater.

Synthesis and Characterization of Transparent Copolyimide Films (I) (투명한 폴리이미드 공중합체 필름의 합성과 특성 연구 (I))

  • Park, Jong-Su;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.580-586
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    • 2008
  • Copolyimides were synthesized from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and 1,3-bis(3-aminophenoxy)benzene (BAPB) with different mole ratios of 2,2-bis[4-(4-aminophenoxy)pheny1]hexafluoropropane (BAPP). The solution cast film of poly(amic acid) (PAA) was heat treated at different temperatures to create copolyimide films. The PI copolymer films were found to exhibit good optical transparencies. The thermomechanical properties, morphology, and optical transparency of PI films were examined using fourier transform infrared spectroscopy (FT-IR), wide-angle X-ray diffraction (XRD), scanning electron microscopes (SEM), differential scanning calorimeter(DSC), thermo-gravimetric analyzer (TGA), universal tensile machine (UTM), and IN - Vis. spectrometer. The glass transition temperature ($T_g$), ultimate strength, and initial modulus linearly increased with increasing BAPP mole fraction. However, thermal stability($T_D{^i}$) of the copolyimide remains constant regardless of BAPP loadings. It was found, however, that the optical transparency decreases slightly upon increasing the BAPP content because of the formation of the charge transfer complexes.

Preparation of Spherical Energetic Composites by Crystallization/Agglomeration and their Thermal Decomposition Characteristics (결정화/응집 기법에 의한 구형 에너지 복합체 제조 및 그 열분해 특성)

  • Lee, Eun-Ae;Shim, Hong-Min;Kim, Jae-Kyeong;Kim, Hyoun-Soo;Koo, Kee-Kahb
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.158-164
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    • 2016
  • Spherical DADNE/AP (1,1-diamino-2,2-dinitroethylen/ammonium perchlorate) energetic composites were produced by drowning-out/agglomeration (D/A). The agglomeration of DADNE with AP particles was found to be affected by the amount of the bridging liquid, stirring velocity and residence time. The composites appeared to grow dramatically with the amount of bridging liquid which triggers agglomeration. As the stirring velocity and the residence time increased, the size of composites increased and then tended to decrease. Thermal gravimetric analysis showed that the addition of DADNE activates the low temperature decomposition (LTD) of AP. For the neat AP, the only about 30 wt% of AP was found to decompose at the LTD. On the other hand, it was found that 70 wt% of AP decomposed when DADNE was added by physical mixing and 90 wt% of AP decomposed when the DADNE/AP composites were prepared by the D/A method.

Study on Flame Height Equation for the Pinus densiflora Surface Fuel Bed (소나무 낙엽층 화염높이 산정식에 관한 연구)

  • Kim, Dong-Hyun
    • Fire Science and Engineering
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    • v.23 no.6
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    • pp.10-15
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    • 2009
  • Flame height calculation in a forest fire is a crucial part of predicting horizontal or vertical flame spread flared by radiation heat transfer. Flame height, which is one of the flame characteristics, can be estimated by the average height of luminous flame. This research relied on flame height observation test on P. densiflora surface fuel bed, which are surface combustibles in a forest, and calorimeter to measure Heat Release Rate, thus produced $H_f=0.027(\dot{Q'})^{2/3}$, flame height calculation equation for surface fuel. The research did not take into consideration such conditions as external velocity, slope and other variables that could affect flame height. According to comparison among experiment results, calculation results of the above formula and those of existing Heskestad formula (1998), it was found that standard error in fallen pine needles between experimental results and calculation results of the above formula amounts to 0.08, whereas standard error in same plant between experimental results and calculation results of existing Heskestad formula amounts to 0.23.