• Journal of Adhesion and Interface
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• v.4 no.3
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• pp.33-40
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• 2003

In this work, diglycidyl ether of bisphenol A (DGEBA)/polyetherimide (PEI) blends were cured using 4,4-diaminodiphenyl methane (DDM). And the effects of addition of different PEI contents to neat DGEBA were investigated in the thermal properties and fracture toughness of the blends. The contents of contents of containing PEI were varied in 0, 2.5, 5, 7.5, and 10 phr. The cure activation energies ($E_a$) of the cured specimens were determined by Kissinger equation and the mechanical interfacial properties of the specimens were performed by critical stress intensity factor ($K_{IC}$). Also their surfaces were examined by using a scanning electron microscope (SEM) and the surface energetics of blends was determined by contact angles. As a result, $E_a$ and $K_{IC}$ showed maximum values in the 7.5 phr PEI. This result was interpreted in the increment of the network structure of DGEBA/PEI blends. Also, the surface energetics of the DGEBA/PEI blends showed a similar behavior with the results of $K_{IC}$. This was probably due to the improving of specific or polor component of the surface free energy of DGEBA/PEI blends, resulting in increasing the hydrogen bonding of the hydroxyl and imide groups of the blends.

• Applied Chemistry for Engineering
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• v.17 no.3
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• pp.243-249
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• 2006

Porous polymer gel electrolytes (PGEs) based on poly(vinylidenefluoride-co-hexafluoropropylene) (P(VdF-co-HFP)) as a polymer matrix and polyvinylpyrolidone (PVP) as a pore-forming agent were prepared and electrochemical properties were investigated for an electric double layer capacitor (EDLC) in order to increase a permeability of an electrolyte into the PGE. Propylene carbonate (PC) and ethylene carbonate (EC) as plasticizers, and tetraethylammonium tetrafluoroborate ($TEABF_4$) as a supporting salt for the PGE were used. EDLC unit cells were assembled with the PGE and electrode comprising BP-20 and MSP-20 as activated carbon powders, Super P as a conducting agent, and P(VdF-co-HFP)/PVP as a mixed binder. Ion conductivity of PGEs increased with an increased PVP content and was the best at 7 wt% PVP, whereas electrochemical characteristics such as AC-ESR of unit cell were better in 3 wt%. And electrochemical characteristics of the unit cell with PGE were the best at a 33 : 33 weight ratio of PC to EC. Specific capacitance of a mixed plasticizer system of PE and EC was higher than that of pure PC. Ion conductivity of PGEs with a film thickness of $20{\mu}m$ was higher, but electrochemical characteristics of unit cells were higher for a $50{\mu}m$ membrane thickness. Also, the unit cell has shown the highest capacitance of 31.41 F/g and more stable electrochemical performance when PGE and electrode were hot pressed. Consequently, the optimum composition ratio of PGE for EDLCs was 23 : 66 : 11 wt% such as P(VdF-co-HFP) : PVP = 20 : 3 wt% and PC : EC = 44 : 22 wt%. In this case, $3.17{\times}10^{-3}S/cm$ of ion conductivity was achieved at the $50{\mu}m$ thickness of PGE for EDLCs. And the electrochemical characteristics of unit cells were $2.69{\Omega}$ of DC-ESR, 28 F/g of specific capacitance, and 100% of coulombic efficiency.

• Korean Journal of Optics and Photonics
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• v.35 no.3
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• pp.115-120
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• 2024

Magneto-optical (MO) materials have attracted much attention, since they can be utilized for various optical applications, such as magnetic field sensors, optical current sensors, optical isolators, and optical circulators. In this study, alumino-borosilicate (ABS) glasses with high concentrations of Dy³⁺ ions were fabricated by a conventional melt-quenching technique, and the dependence of their thermal, optical, and magneto-optical properties on Dy³⁺ ion concentration was investigated. The MO property of the glasses was investigated by measurement of Faraday rotation at 1550 nm. The Faraday rotation angle increased linearly with the increase of Dy³⁺ ion concentration in the glasses. A very high Verdet constant of -6.86 rad/(T·m) was obtained for glass with a Dy³⁺ ion concentration of 30 mol%. In addition, the ABS-Dy glasses showed good thermal stability of greater than 128 ℃ against crystallization, and high optical transmission of 70% in the visible to near-infrared windows of 480-720, 1390-1560, and 1800-2400 nm. Due to the high Verdet constant and good thermal stability, the ABS-Dy glasses in this study could be candidate optical materials for MO device applications at 1550 nm.

• Fire Science and Engineering
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• v.33 no.6
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• pp.9-19
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• 2019

In fire simulations for building fire safety evaluation, changes in the fire area and grid size can significantly influence the prediction results. Therefore, the effects of area changes of the fire source with identical maximum heat release rates on the prediction results of a compartment fire were investigated. The dependence of the prediction results on the grid size using the identical fire area was also examined. No significant changes were observed in the thermal and chemical characteristics of the fires with variable grid sizes, even though the fire area was changed when six or more grids were set based on the fire diameter. In addition, changes in the fire area caused significant differences in the prediction of major physical quantities associated with available safety egress time (ASET) within a compartment. However, the fire area changes did not considerably influence the overall fire characteristics outside the compartment after reaching a certain distance from the opening.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.2
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• pp.85-91
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• 2016

The Positive Temperature Coefficient (PTC) is used for cabin air heating of a battery electric vehicle, which is different from conventional vehicles. Since the PTC heater consumes a large quantity of power in a parasitic manner, many valuable studies have been reported in the field of alternative heat pumps. In this study, a model for an R134a heat pump taking into account the thermal environment of the cabin was developed for a MATLAB/SIMULINK(R) platform. Component and cabin models are validated with reference values. Results show that the heat pump is more competitive for parasitic power consumption over all ambient temperature conditions. Additionally, the method of waste heat recovery to overcome disadvantages when temperatures are below zero is applied to efficiently operate the heat pump.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.666-673
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• 2015

In this paper the selective reduction catalyst (SCR) for controlling the NOx at high temperature range was studied. XRD and FT-IR BET analysis was also performed to determine the structural properties and adsorption/desorption characteristics of the catalyst. In the case of anatase $TiO_2$ support, a negligible NOx conversion was observed, but the $W/TiO_2$ catalyst made using W as a active metal showed an excellent ability to remove NOx. In particular, the $W/TiO_2$ exhibited a rapid increase in the catalytic activity due to the presence of W for the NOx conversion compared to that of using the pure $TiO_2$ at a high temperature range over $400^{\circ}C$. In addition, the phenomenon of reduced reaction activity due to the heat shock for a long time was found to be suppressed.

• Journal of the Korean Magnetics Society
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• v.17 no.3
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• pp.128-132
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• 2007

The thermal and magnetic properties of amorphous (FeCo)SiBNb ribbon alloys with high glass forming ability have been investigated. The glass forming ability was enhanced by Co substitution in amorphous ($Fe_{1-X}Co_X)_{72}Si_4B_{20}Nb_4$ alloys with the thickness of about $40{\mu}m$. With the increase in Co content, the temperature range of supercooled liquid phase increased indicating the high glass forming ability of the Co-added alloys. Further the ac permeability increased, and the core loss decreased considerably by Co substitution, while small change in $B_8$ (magnetic flux density at 800 A/m) was observed. The frequency characteristics of permeability deteriorated as compared to conventional amorphous ribbon alloys with the thickness of about $20\;{\mu}m$ due to the increased skin effect.

• Journal of the Korea Convergence Society
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• v.12 no.2
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• pp.185-191
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• 2021

The characteristics of the foundry sand were analyzed for water jacket core required to prevent structural deformation from the heat generated in the cylinder bore during the casting of the cylinder block of an automobile. The sand core tensile strength tester, AFS-GFN, and optical microscope were used to evaluate the its properties. If the SiO2 content is high in the foundry sand, the dimensional defects and veining defects occur due to high temperature expansion. Also, if it is too low, the core breakage, porosities, chemical burn-on defects occur. The particle size index and grain shape influenced the core strength and resin consumption, resulting in fluctuations in defect types. The higher the alkalinity of the dried sand, the lower the core strength. And the more basic, the lower the core strength. At the resin content of 1.6~1.8%, the increase in core strength after 1 hour curing was approximately at its maximum.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.271-271
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• 2023

수문학적 기준지점(HRS, Reference Hydrological Station)은 유량의 변동성의 장기적인 추세를 파악하기 위해 고품질의 자료를 생산하는 관측소를 의미한다. 선진외국의 경우 운영목적과 수문학적 기준지점의 정의는 조금씩 다르지만 유사한 개념의 관측소를 운영하고 있다. 호주의 경우 기후변화에 따른 장기간의 수자원 부존량의 변화를 예측하기 위한 모니터링 지점으로 정의하며, 미국의 경우 시간에 따른 수문학적 특성의 자연적인 변화 및 인간의 활동에 따른 수문환경의 변화에 대한 연구를 위한 기준값을 제공하기 위해 참조지점(HBN, Hydrological Benchmark Network)의 자료를 제공하기 위해 운영한다. 영국은 기후변화에 따른 유역의 수문학적 응답을 조사할 목적으로 참조지점(RHN, Reference Hydrological Network)을 운영하고 있으며, 주로 자연유역에 설치하여 운영하고 있다. WMO는 2006년 '기후연구를 위한 적절한 유량관측소'를 선정해 줄 것을 회원국에 요청하고, 관련 자료의 데이터베이스를 독일의 GRDC(Global Runoff Data Centre)에 수집하고 있다. 국외의 경우 '자연에 가까운 유역특성을 갖는 하천 유량관측망 중 양질의 자료를 보유하고 있는 관측소'를 고려하여 수문학적 기준지점을 선정한다. 하지만 우리나라의 경우 장기간의 유량자료를 보유하고 있는 관측소가 상대적으로 부족하고, 장기간의 유량자료를 보유한 지점 또한 홍수예보, 댐 운영 등 물관리 업무에 직접 활용하기 위해 대하천의 본류 중심으로 자료를 생산하고 있다. 따라서 현재를 기준으로 국제적으로 통용되는 기준에 부합하는 기준관측소를 선정하는 것은 곤란한 상황으로 미래에 수문학적 기준지점이 될 수 있는 관측소를 선정하여 장기간 모니터링을 통해 기준관측소를 확대해 나갈 필요가 있다. 본 연구에서는 국외의 수문학적 기준관측소 선정기준을 비교 검토하여 우리나라 실정에 맞는 기준관측소 선정기준을 개발하였다. 선정 기준은 ① 유역의 개발정도, ② 댐·저수지 등 인위적인 조절 정도, ③ 취수량 또는 방류량 등 유역간의 물 이동, ④ 유량자료의 보유기간 및 정확도 등을 고려하여 기준을 설정하였다. 또한 기준지점의 선정을 위한 절차를 ① 수위관측소 사전목록의 작성, ② 관측소 정보 분석(유역특성, 시계열자료 등), ③ 수문학적 기준관측소 후보 선정, ④ 유관기관 및 전문가 검토를 통한 우선순위 선정 등 4단계로 구분하여 제시하였다.

• Journal of Korea Water Resources Association
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• v.50 no.2
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• pp.75-87
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• 2017

In recent decades, extreme events have been significantly increased over the Korean Peninsula due to climate variability and climate change. The potential changes in hydrologic cycle associated with the extreme events increase uncertainty in water resources planning and designing. For these reasons, a reliable changing point analysis is generally required to better understand regime changes in hydrologic time series at watershed scale. In this study, a hierarchical changing point analysis approach that can apply in a watershed scale is developed by combining the existing changing point analysis method and hierarchical Bayesian method. The proposed model was applied to the selected stations that have annual rainfall data longer than 40 years. The results showed that the proposed model can quantitatively detect the shift in precipitation in the middle of 1990s and identify the increase in annual precipitation compared to the several decades prior to the 1990s. Finally, we explored the changes in precipitation and sea level pressure in the context of large-scale climate anomalies using reanalysis data, for a given change point. It was concluded that the identified large-scale patterns were substantially different from each other.