• Title/Summary/Keyword: 열분석적 특성

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Na3PO4 Flame Retardant Treatment on Lyocell Fiber for Thermal Stability and Anti-oxidation Properties (라이오셀의 열 안정 및 내산화 특성 향상을 위한 Na3PO4 내염화 처리)

  • Kim, Hyeong Gi;Kim, Eun Ae;Lee, Young-Seak;In, Se Jin
    • Fire Science and Engineering
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    • v.29 no.2
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    • pp.25-32
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    • 2015
  • The improved thermal stability and anti-oxidation properties of lyocell fiber were studied based on flame retardant treatment by using $Na_3PO_4$ solution. The optimized conditions of flame retardant treatment were studied on various concentrations of $Na_3PO_4$ and the mechanism was proposed through experimental results of thermal stability and anti-oxidation. The integral procedural decomposition temperature (IPDT), limiting oxygen index (LOI) and activation energy ($E_a$) increased 30, 160% respectively via flame retardant treatment. It is noted that thermal stability and anti-oxidation improved based on char and carbon layer formation by dehydrogenation and dissociation of C-C bond resulting the hindrance of oxygen and heat energy into polymer resin. The optimized conditions for efficient flame retardant property of lyocell fiber were provided using $Na_3PO_4$ solution and the mechanism was also studied based on experimental results such as initial decomposition temperature (IDT), IPDT, LOI and $E_a$.

A Study of Physicochemical Characteristics and Adsorption properties of Cs and Sr of Natural Zeolite from Kuryongpo in Korea (한국 구룡포산 천연 제올라이트의 이화학적 특성 및 Cs과 Sr 흡착 특성 연구)

  • Bayarsaikhan Battsetseg;Hu Sik Kim;Hyeon Uk Choo;Jong Sam Park;Woo Taik Lim
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.2
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    • pp.117-124
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    • 2023
  • X-ray diffraction analysis, X-ray fluorescence analysis, thermal differential and thermos gravimetric analysis, cation exchange capacity analysis, and Cesium (Cs), Strontium (Sr) adsorption experiments were performed to investigate the physical and chemical properties of natural zeolite from Guryongpo in Korea. As a result of X-ray diffraction analysis, minerals such as mordenite, heulandite, clinoptilolite, and illite are contained, and as a result of X-ray fluorescence analysis, elements such as SiO2, Al2O3, CaO, K2O, MgO, Fe2O3 and Na2O are contained, and the cation exchange capacity was 148.6 meq/100 g. As a result of thermal differential and thermos gravimetric analysis, it was confirmed that the thermal stability was excellent up to 600 ℃. As a result of the adsorption equilibrium experiment over time, the equilibrium was reached within 30 min. for Cesium (Cs) and within 8 hr. for Strontium (Sr), and the adsorption rates of Cesium (Cs) and Strontium (Sr) were 80% and 18%, respectively. As a result of the single-component isothermal adsorption experiment, in conformed to the Langmuir model, and the maximum Cesium (Cs) adsorption amount was 131.5 mg/g, which was high, while the Strontium (Sr) maximum adsorption amount was 29.5 mg/g, which was low. In the case of the natural zeolite used in this study, the content of minerals including 8-rings such as clinoptilolite, heulandite, and mordenite is high, showing high selectivity for Cesium (Cs).

Analysis on the Surface Hydrophilicity & Hydrophobicity Mechanism of Polymer Composites (고분자 복합재료의 표면 친수화 및 소수화 메커니즘 해석)

  • Lim, Kyung-Bum;Roh, Tae-Ho;Lee, Jae-Oy
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.7
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    • pp.3437-3443
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    • 2013
  • The polymer insulators have been extensively used as an alternate material of ceramic insulators. However, when they are used in practical conditions, there are many problems of decreasing performance and shortening lifetime due to the exposures of degradation factors applied from the outdoor situations. Accordingly, the analysis of polymer degradations has been getting influential too late as one of important subjects for improvements of safety and reliability. Heat, water treatments are arbitrary simulated for finding out the initiations and processes of surface degradation on the polymer surface. Especially, this study is focused on the chemical changes properties. From the analysis of hydrophilic and hydrophobic molecular structures, final modeling of surface degradation is accomplished. We checked the contact angle depending on heat and moisturized accelerated degradation and ran an XPS analysis to check the mechanism change of the surface of the PCB polymer composite. The surface that had a tendency to attract moisture showed a decrease in the contact angle and generated a large amount of carboxyl($-COO^*$) radicals. The hydrophobized surface showed an increase in the contact angle and had a stable chemical composition constituted of the breakaway of oxygen radicals and the formation of double bond by carburization.

Evaluation on Spectral Analysis in ALOS-2 PALSAR-2 Stripmap-ScanSAR Interferometry (ALOS-2 Stripmap-ScanSAR 위상간섭기법에서의 스펙트럼 분석 평가)

  • Park, Seo-Woo;Jung, Seong-Woo;Hong, Sang-Hoon
    • Korean Journal of Remote Sensing
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    • v.36 no.2_2
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    • pp.351-363
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    • 2020
  • It is well known that alluvial sediment located in coastal region has been easily affected by geohazard like ground subsidence, marine or meteorological disasters which threaten invaluable lives and properties. The subsidence is a sinking of the ground due to underground material movement that mostly related to soil compaction by water extraction. Thus, continuous monitoring is essential to protect possible damage from the ground subsidence in the coastal region. Radar interferometric application has been widely used to estimate surface displacement from phase information of synthetic aperture radar (SAR). Thanks to advanced SAR technique like the Small BAseline Subset (SBAS), a time-series of surface displacement could be successfully calculated with a large amount of SAR observations (>20). Because the ALOS-2 PALSAR-2 L-band observations maintain higher coherence compared with other shorter wavelength like X- or C-band, it has been regarded as one of the best resources for Earth science. However, the number of ALOS-2 PALSAR-2 observations might be not enough for the SBAS application due to its global monitoring observation scenario. Unfortunately, the number of the ALOS-2 PALSAR-2 Stripmap images in area of our interest, Busan which located in the Southeastern Korea, is only 11 which is insufficient to apply the SBAS time-series analysis. Although it is common that the radar interferometry utilizes multiple SAR images collected from same acquisition mode, it has been reported that the ALOS-2 PALSAR-2 Stripmap-ScanSAR interferometric application could be possible under specific acquisition mode. In case that we can apply the Stripmap-ScanSAR interferometry with the other 18 ScanSAR observations over Busan, an enhanced time-series surface displacement with better temporal resolution could be estimated. In this study, we evaluated feasibility of the ALOS-2 PALSAR-2 Stripmap-ScanSAR interferometric application using Gamma software considering differences of chirp bandwidth and pulse repetition frequency (PRF) between two acquisition modes. In addition, we analyzed the interferograms with respect to spectral shift of radar carrier frequency and common band filtering. Even though it shows similar level of coherence regardless of spectral shift in the radar carrier frequency, we found periodic spectral noises in azimuth direction and significant degradation of coherence in azimuth direction after common band filtering. Therefore, the characteristics of spectral bandwidth in the range and azimuth direction should be considered cautiously for the ALOS-2 PALSAR-2 Stripmap-ScanSAR interferometry.

A Study on the Purchasing Intention of Paid Items in Mobile Social Game-Focusing on game and personal characteristics (모바일 소셜 게임 기반으로 유료아이템의 구매의도에 미치는 영향 - 게임특성 및 개인특성 중심으로 -)

  • Cao, Long-Fei;Kyung, Byung-Pyo;Lee, Dong-lyeor
    • Journal of Digital Convergence
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    • v.18 no.2
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    • pp.385-393
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    • 2020
  • Focusing on the Chinese market of MSNG (Mobile Social Network Game), perceived flow and satisfaction were designed as parameters, purchasing intention was set up as dependent variables, the purpose of present research is to analyze the factors influencing purchase intention of the paid items in mobile social games by studying the game and personal characteristics in terms of interoperability, accessibility, interesting, operability, innovativeness and challenge. Data was collected by questionnaires, Amos was employed to analyze the relationship between purchase intention and target influencing factors. Results showed that characteristics of game and consumers of MSNG have positive effects on the flow and satisfaction of paid items. Moreover, the flow of paid items in MSNG has a positive effect on satisfaction; the flow and satisfaction of paid items in MSNG have a positive effect on purchase intention. more samples and references should be involved in the further study in order to acheive an comprehensive result on comparative study of the social and cultural characteristics between Chinese MSNG and Korean counterpart.

Optimize TOD Time-Division with Dynamic Time Warping Distance-based Non-Hierarchical Cluster Analysis (동적 타임 워핑 거리 기반 비 계층적 군집분석을 활용한 TOD 시간분할 최적화)

  • Hwang, Jae-Yeon;Park, Minju;Kim, Yongho;Kang, Woojin
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.20 no.5
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    • pp.113-129
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    • 2021
  • Recently, traffic congestion in the city is continuously increasing due to the expansion of the living area centered in the metropolitan area and the concentration of population in large cities. New road construction has become impossible due to the increase in land prices in downtown areas and limited sites, and the importance of efficient data-based road operation is increasingly emerging. For efficient road operation, it is essential to classify appropriate scenarios according to changes in traffic conditions and to operate optimal signals for each scenario. In this study, the Dynamic Time Warping model for cluster analysis of time series data was applied to traffic volume and speed data collected at continuous intersections for optimal scenario classification. We propose a methodology for composing an optimal signal operation scenario by analyzing the characteristics of the scenarios for each data used for classification.

Experimental Study on Geometry of a Microlayer During Single-Bubble Nucleate Boiling (단일기포 핵비등 시 미세액막층 구조에 대한 실험적 연구)

  • Jeong, Seunghyuck;Jung, Satbyoul;Kim, Hyungdae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.519-526
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    • 2015
  • To measure the physical parameters of the simple microlayer model for the prediction of the heat flux and heat transfer rate due to the evaporation of the microlayer during nucleate boiling, the microlayer geometry was experimentally examined. The parameters, including initial thickness, moving velocity and microlayer radius, were measured by total reflection and interferometry techniques using a laser. Single-bubble nucleate boiling experiments were conducted using saturated water on a horizontal surface under atmospheric pressure. The geometric characteristics of the microlayer underneath the bubbles periodically nucleating at a nucleation site at an average heat flux of $200kW/m^2$ were analyzed. The experimental results in the present study show that the maximum initial thickness of the microlayer and the horizontal moving velocity are $5.4{\mu}m$ and 0.12 m/s, respectively.

Characterization of Selenium (Se) Distribution in Soils and Crops at Moi-san, Haenam (해남 모이산 인근 토양 및 농작물의 셀레늄(Se) 분포 특성)

  • Kim, Seon-Ok;Cheon, Se Weon;Park, Gyu-Ryeong;Wang, Sookyun
    • Economic and Environmental Geology
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    • v.48 no.3
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    • pp.213-219
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    • 2015
  • Samples from soils and crops were collected and analyzed in order to investigate the interactions of selenium among rocks, soils, and crops by hydrothermal alteration near epithermal mines in the region of Mio-san, Haenam. Soil samples included 6 samples each from mountain and farm area and compositional minerals and their contents were analyzed by water content, pH, ICP, XRD, XRF. Crop samples from onion and scallion were analyzed for chemical composition to elucidate the relationship with soils. Results from XRD analysis for soil samples showed that major compositional minerals are qualtz and feldspar, and illite, chlorite, hematite formed by hydrothermal alteration were included on a small scale. The pH ranges of soil samples from mountain and farm were measured at 4.6~4.9 and 5.2~6.7, respectively. The higher pH in farm soils may result from fertilization during agricultural activities. Results from ICP analysis showed that, compared to soil samples from mountain area with no potassium and calcium, significant amount of K and Ca were detected in soil samples from farms which is affected by fertilization. In a similar manner, potassium and calcium were absorbed and detected in crop samples at relatively high concentrations (116.89~169.79 ppm for K and 20.18~32.29 ppm for Ca). While the selenium contents in soil samples ranged from 18.35 ppb to 70.31 ppb which showed no significant difference, high concentrations of selenium were detected in onion (119.48~179.50 ppb) and scallion (146.65 ppb). These difference in enrichment for each element may result from the distinctive adsorption characteristics depending on crops.

Characterization of Area Installing Combined Geothermal Systems : Hydrogeological Properties of Aquifer (복합지열시스템에 대한 부지특성화: 대수층의 수리지질학적 특성)

  • Mok, Jong-Koo;Park, Yu-Chul;Park, Youngyun;Kim, Seung-Kyum;Oh, Jeong-Seok;Seonwoo, Eun-Mi
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.293-304
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    • 2017
  • This study was performed in order to hydrogeological analysis of aquifer, which is a necessary part for evaluating the efficiency of the combined well and open-closed loops geothermal (CWG) systems. CWG systems have been proposed for the effective utilization of geothermal energy by combining open loop geothermal systems and closed loop geothermal systems. Small aperture CWG systems and large aperture CWG systems were installed at a green house land with water curtain facilities in Chungju City. Aquifer tests include pumping tests and step-drawdown tests were conducted to analyse hydrogeological characteristics of aquifer in the study area. The transmissivity was estimated in the range of $13.49{\sim}58.99cm^2/sec$, and the storativity was estimated in the range of $1.13{\times}10^{-5}{\sim}5.20{\times}10^{-3}$. The geochemical analysis showed $Ca^{2+}$ ion and ${HCO_3}^-$ ion were dominant in groundwater. The Langelier Saturation Index and the Ryznar Stability Index showed low scaling potential of groundwater. In the analysis of vertical water temperature change, the geothermal gradient was estimated as $2.1^{\circ}C/100m$, which indicated the aquifer was enough for geothermal systems. In conclusion, groundwater is rich, can stably use geothermal heat, and it is less likely to cause deterioration of thermal energy efficiency by precipitation of carbonate minerals in study area. Therefore, the study area is suitable for installation of the combined geothermal system.

Fabrication and analysis of luminous properties of phosphor ceramic for laser headlamp in automotive application (자동차용 레이저 헤드램프를 위한 형광체 세라믹 제조 및 발광 특성 분석)

  • Choi, Seung Hee;Kwon, Seok Bin;Yoo, Jung Hyeon;Kim, Jae Pil;Kim, Wan Ho;Jeong, Ho-Jung;Kim, Bo Young;Yoon, Dae Ho;Song, Young Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.73-77
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    • 2020
  • In this study, phosphor ceramics were fabricated, and optical properties were analyzed for application to nextgeneration automotive laser headlamps by using a spherical YAG : Ce phosphor with a garnet structure synthesized based on the spray drying method. The thickness of phosphor ceramic using spherical YAG : Ce phosphor was obtained with 100 ㎛, 150 ㎛, and 200 ㎛ to investigate the effect of thickness on optical properties such as light conversion efficiency, heat dissipation, luminance and color temperature. The results of this study are expected to play a significant role in the manufacturing process for the fabrication of phosphor ceramic by solving issues such as the high cost and low yield in the conventional liquid method to manufacture YAG : Ce nano fluorescent materials.