• Title/Summary/Keyword: 열구조 안정성

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Thermal and Optical Properties of Cellobiose Octa(cholesteryloxycarbonyl)alkanoates (셀로비오스 옥타(콜레스테릴옥시카보닐)알카노에이트의 열 및 광학 특성)

  • Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.230-238
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    • 2008
  • The thermal and optical properties of cellobiose octa(cholestryloxycarbonyl)alkanoates CCCBn, $n=2{\sim}8$,10, the number of methylene units in the spacer) were investigated. All the samples formed monotropic cholesteric phases with left-handed helical structures. CCBn with n=2 or 10, in contrast with CCBn with $3{\leq}n{\leq}8$, did not display reflection colors over the full cholesteric range, suggesting that the helical twisting power of the cholesteryl group highly depends on the length of the spacer connecting the cholesteryl group to the cellobiose chain. The isotropic-cholestropic transition ($T_{ic}$) and glass transition temperatures decreased with increasing n and showed no odd-even effect. The transition entropy at $T_{ic}$ increased with increasing n from 2 up 6, but at n=7 it drops significantly and then increased again with increasing n from 8 to 10. The sharp change at n=7 may be attributed to a difference in arrangement of the side groups. The thermal stability and degree of order in the mesophase and the temperature dependence of the optical pitch observed for CCBn were significantly different from those reported for the cellulose tri(cholesteryloxycarbonyl)alkanoates and glucose penta(cholesteryloxycarbonyl)alkanoates. The results were discussed in terms of the differences in the degree of polymerization, the number of the mesogenic units per mole-glucose unit, and the conformation of the molecules.

A Timeseries Study on the Determinants Behind the Changes of Korean Welfare State (한국 복지국가 지출변화 결정요인 분석)

  • Ahn, Sang-hoon;Baek, Seung-ho
    • Korean Journal of Social Welfare Studies
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    • no.37
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    • pp.117-144
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    • 2008
  • This is a timeseries study on the riving forces behind the changes of Korean welfare state. There are a few previous studies on the determinants of korean welfare state. These previous studies have some limitations in terms of reliability of the data source and validity of the statistical method used. Using the Comparative Social Policy Data-set(CSPD), we try to overcome the limitation of these previous studies. And adapting the time series regression, we examine the hypotheses about the changes of korean welfare state. In this study, four dependent variables are examined: the ratio of public social welfare expenditure to the GDP(WELGDP), the ratio of public social welfare expenditure to the government budget(WELGOV), the ratio of social expenditure to the GDP(SOCX), social welfare expenditure per capita. And independent variables were selected based on the theoretical background on the changes of welfare state. The results of this study as follows: First, the variables based on structural functionalism (industrialization) are the major driving forces behind the changes of korean welfare state since 1960s. Second, the effect of unemployment variable may be reasonably interpreted as reflecting the residual characteristics of korean welfare state. Third, the politics of the left based on power resource theory should be restrictedly interpreted. Ultimately, korean welfare state is still at rudimentary stage where the theory of industrialization is well applied as a driving forces behind the changes of welfare state.

Evaluation of Physical Properties according to Mixing Ratio and the Survey of the Current Situation for Epoxy Resin used in Conservation (문화재 보존처리에 사용되는 에폭시수지의 사용현황과 배합비율에 따른 물성 변화 연구)

  • Lee, Eun Ji;Jang, Sung Yoon
    • Journal of Conservation Science
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    • v.32 no.2
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    • pp.223-234
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    • 2016
  • Two-component epoxy resin is widely used in the cultural heritage restoration field. However according to mixing ratio of resin and hardener, curing property, mechanical strength and chemical structure differ which have possibility to effect the stability of cultural heritage. Result of questionnaire survey shows hands-on workers in the conservation field tend to mix the epoxy resin with his or her eye measurement when the using amount is small or mix additional hardener to shorten the pot life of epoxy resin. This research aims to analyze the curing property, mechanical strength and chemical structure of rapid curing type epoxy resin and medium curing type one depending on relative ratio of 0.25~4 of hardener to resin. When the amount of hardener was 0.5~2 times more than the resin, exothermic heat and curing speed were both increased. In case of included hardener to resin was lower than official ratio, mechanical strength (tensile shear strength, tensile strength and compressive strength) became higher along with active cross-linking bonding of the epoxy resin. Medium curing type epoxy relatively had lower exothermic heat and slower reaction during curing process. It was observed to be put to definite point of mechanical strength under lower content of hardener than official ratio. While, hardener ratio more than twice the resin slowed down the curing greatly and lowered the adhesion strength also. In conclusion, under the lower mixing rate of hardener than official ratio would show relatively fast reaction with similar mechanical strength. Over the official ratio on the other hand, material property drops rapidly. Accordingly, mixing ratio of epoxy resin is expected to be influential to the stability of cultural heritage.

A study on the flow induced vibration on a heat exchanger circular cylinder (열교환 단일 원관의 유동 유발 진동 특성에 관한 연구)

  • Ha, Ji Soo;Lee, Boo Youn;Shim, Sung Hun
    • Journal of Energy Engineering
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    • v.24 no.3
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    • pp.109-114
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    • 2015
  • Heat exchanger tube array in a heat recovery steam generator is exposed to the hot exhaust gas flow and it could cause the flow induced vibration, which could damage the heat exchanger tube array. It is needed for the structural safe operation of the heat exchanger to establish the characteristics of flow induced vibration in the tube array. The researches for the flow induced vibration of typical heat exchangers have been conducted and the nondimensional PSD(Power Spectral Density) function with the Strouhal number, fD/U, had been derived by experimental method. The present study examined the results of the previous experimental researches for the nondimensional PSD characteristics by CFD analysis and the basis for the application of flow induced vibration to the heat recovery steam generator tube array would be prepared from the present CFD analysis. For the previous mentioned purpose, the present CFD analysis introduced a single circular cylinder and calculated with the unsteady laminar flow over the cylinder. The characteristics of vortex shedding and lift fluctuation over the cylinder was investigated. The derived nondimensional PSD was compared with the results of the previous experimental researches and the characteristics of lift PSD over a single circular cylinder was established from the present CFD study.

An Antifungal Subatance, 2,4-Diacetylphloroglucinol Produced from Antagonistic Bacterium Pseudo-monas fluorescens 2112 Against Phytophthora capsici (Phytophthora capsici를 길항하는 Pseudononas fluorescens 2112가 생산하는 항진균 항생물질 2,4-diacetylphloroglucinol)

  • 이은탁;김상달
    • Microbiology and Biotechnology Letters
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    • v.29 no.1
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    • pp.37-42
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    • 2001
  • An antifungal substance was purified from culture broth of Pseudomonas flulorescens 2112 that showed a broad-spectrum antagonistic activity against various phytopathogenic fungi including capsici. The substance was identified as 2,4-diacetylphloro-glucinol basd on NMR analysis. The 2,4-diacetylphloroglcinol showed antibiotic activity in broad acidic range from pH 1.0 to pH 9.0. About 83% of initial activity was remained after incubation for 30min ar $60^{\circ}C$, however, the activity was dropped up to 50% after 30 min incubation in $80^{\circ}C$. When the nucleotides of P. capsici treated with 2,4-diacetylphloroglucinol were labeled with[$^{3}$ H]-Adenin, the newly synthesized and radioactive-labeled RNA was significantly reduced than those of untreated P. capsici. indicating that the 2,4-diacetylphloroglucinol inhibits RNA synthesis.

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Comparison of insertion torque regarding changes in shape, diameter, and length of orthodontic miniscrews (교정용 미니스크류의 형상에 따른 식립 토오크의 비교)

  • Lim, Seon-A;Cha, Jung-Yul;Hwang, Chung-Ju
    • The korean journal of orthodontics
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    • v.37 no.2 s.121
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    • pp.89-97
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    • 2007
  • Objective: The purpose of this study was to measure the insertion torque of orthodontic miniscrews regarding changes in their shape, diameter, and length. Methods: Torque values were measured during continuous insertion of the miniscrews into solid rigid polyurethane foam, using a torque tester of driving motor type with a regular speed of 3 rpm. Orthodontic miniscrews (Biomaterials Korea, Seoul, Korea) of cylindrical type and taper type were used. Results: Increasing the length and diameter of the miniscrews increased the maximum insertion torque value in both cylindrical and taper type screws. Insertion torque was increased at the incomplete head of the cylindrical type screw, and at the tapered part of the taper type screw. The insertion torque value of miniscrews was influenced most by diameter, then shape and length. As a result, it was shown that the diameter of the screw had the most influence on insertion torque, and the taper type screw had a higher torque value than the cylindrical type screw. Conclusion: Therefore, a large diameter or taper type screw are adequate for areas of thin cortical bone with a large interdental space, and a small diameter or cylindrical type screw are adequate in the mandibular molar area or the midpalatal area having thick cortical bone.

A Study on the Next VWorld System Architecture: New Technology Analysis for the Optimal Architecture Design (차세대 브이월드 시스템 아키텍처 구성에 관한 연구: 최적의 아키텍처 설계를 위한 신기술 분석)

  • Go, Jun Hee;Lim, Yong Hwa;Kim, Min Soo;Jang, In Sung
    • Spatial Information Research
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    • v.23 no.4
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    • pp.13-22
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    • 2015
  • There has been much interest in the VWorld open platform with the addition of a variety of contents or services such as 2D map, 3D terrain, 3D buildings, and thematic map since 2012. However, the VWorld system architecture was not stable for the system overload. For example, the system was stopped due to the rapidly increasing user accesses when the 3D terrain service of the North Korea and the Baekdu mountain was launched at September 2012 and September 2013, respectively. It was because the system architect has just extended the server system and the network bandwidth whenever the rapid increase of user accesses occurs or new service starts. Therefore, this study proposes a new VWorld system architecture that can reliably serve the huge volume of National Spatial Data by applying the new technologies such as CDN, visualization and clustering. Finally, it is expected that the results of this study can be used as a basis for the next VWorld system architecture being capable of a huge volume of spatial data and users.

Characterization and Evolutionary Relationship of Lactate Dehydrogenase in Liver of Lampetra japonica and Liver-specific C4 Isozyme in Gadus macrocephdus. (칠성장어(Lampetra japnica) 간조직 젖산탈수소효소와 대구(Gadus macrocephalus) liver-Specific C4동위효소의 특성 및 진화적 관계)

  • 박선영;조성규;염정주
    • Journal of Life Science
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    • v.14 no.4
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    • pp.708-715
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    • 2004
  • The lactate dehydrogenase (EC 1.1.1.27, LDH) in liver of Lempetra japonica was purified in buffer of affinity chromatography. The liver-specific $C_4$ isozyme of Gadus macrocephalus was purified by heat treatment, affinity chromatography, and DEAE-Sephacel chromatography. The liver-specific $C_4$ isozyme was eluted in a buffer containing NAD+ and was coeluted with $B_4$isozyme in plain buffer of affinity chromagraphy. Liver-specific $C_4$ isozyme in G. macrocephalus was the most thermostable, and$B_4$isozyme was more stable than $A_4$. The LDH in the fraction of pH 7.45 purified from the liver of L. iaponica by chromatofocusing was more inhibited by pyruvate than purified LDH. The optimum pH of the LDH isozyme in the liver of L. japonica was 7.5 and that of liver-specific$C_4$ isozyme was 8.5. The LDH in liver of L. japonica made complexes more with antibody against Coreoperca herzi$A_4$ and liver-specific $C_4$ than with that against eye-specific $C_4$. Therefore, the structure of the LDH in liver of L. japonica might be similarly evolved to that of subunit A and liver-specific $C_4$ isozyme in liver tissue of G. macrocephalus. The evolution rate of subunit C is faster than that of subunit A. LDH in liver of L. japonica has not one isozyme but isozymes and it was also found out to have not only subunit A and B but also subunit C.

The Power Spectral Density Characteristics of Lift and Drag Fluctuation on a Heat Exchanger Circular Tube (열교환 단일 원관의 양력과 항력 변동에 따른 PSD 특성 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.19 no.4
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    • pp.35-40
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    • 2015
  • Heat exchanger tube array in a heat recovery steam generator is exposed to the hot exhaust gas flow and it could cause the flow induced vibration, which could damage the heat exchanger tube array. It is needed for the structural safe operation of the heat exchanger to establish the characteristics of flow induced vibration in the tube array. The researches for the flow induced vibration of typical heat exchangers have been conducted and the nondimensional PSD(Power Spectral Density) function with the Strouhal number, fD/U, had been derived by experimental method. The present study examined the results of the previous experimental researches for the nondimensional PSD characteristics by CFD analysis and the basis for the application of flow induced vibration to the heat recovery steam generator tube array would be prepared from the present CFD analysis. For the previous mentioned purpose, the present CFD analysis introduced a single circular cylinder and calculated with the unsteady laminar flow over the cylinder. The characteristics of vortex shedding and lift and drag fluctuation over the cylinder was investigated. The derived nondimensional PSD was compared with the results of the previous experimental researches and the characteristics of lift and drag PSD over a single circular cylinder was established from the present CFD study.

Effect of Chemical Foaming Process on the Cellular Structure Development and Correlation with the Mechanical and Physical Property of PBAT (화학적 발포 공정이 PBAT 발포 셀 구조 발달에 미치는 영향과 기계적, 물리적 특성과의 상관관계 연구)

  • Yeong ho Ji;Tae Hyeong Park;Ji Eun Choo;Sung Wook Hwang
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.30 no.1
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    • pp.63-72
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    • 2024
  • Poly (butylene adipate-co-terephthalate) (PBAT) is one of the representative biodegradable polymers with high ductility and processability to replace petroleum-based polymers. Many investigations have been conducted to broaden the applications of PBAT in a variety of industries, including the food packaging, agricultural mulching film, and logistics and distribution fields. Foaming process is widely known technique to generate the cell structure within the polymer matrix, offering the insulation and light weight properties. However, there was no commercially feasible foam product based on biodegradable polymers, especially PBAT, and maintaining a proper melt viscosity of the polymer would be a key parameter for the foaming process. In this study, chemical foaming agent and cross-linking agent were introduced to PBAT, and a compression molding process was applied to prepare a foam sheet. The correlation between cell morphological structures and mechanical and physical properties was evaluated. It was found that PBAT with foam structures effectively reduced the density and thermal conductivity, allowing them to be suitable for applications such as insulation and lightweight packaging or cushion materials.