• Polymer(Korea)
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• v.27 no.4
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• pp.313-322
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• 2003

The morphology of poly(ethylene terephthalate) (PET)/poly(m-xylene adipamide) (MXD-6) blends, which was prepared by adding compatibilizer and interchange reaction agent, was investigated. The morphological change in the stretched blend films was also studied. The stretched film showed a dispersed MXD-6 fibril. This fibril became finer with increasing draw ratio (DR). The addition of compatibilizer and interchange reaction agent had no effect on the improvement of interfacial adhesion but caused a defect between the continuous phase and the dispersed phase, leading to the formation of irregular fibril. The change in the superstructure of blends with composition and draw ratio was examined with light scattering (LS). The H$\sub$v/ LS patterns showed a double-cross type pattern consisting of a broad rod-like pattern and a sharp cross streak. On the basis of the model calculation of the H$\sub$v/ pattern, it was found that the appearance of the double-cross type pattern was attributed to the stacking of crystals oriented along the draw direction. The crystals were gradually oriented to the stretching direction with draw ratio. As a result, the high level of orientation was obtained fur the sample of draw ratio is 6.0.

• 대한공업교육학회지
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• v.34 no.2
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• pp.321-330
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• 2009

This study presents the blow molding of injection stretch-blow molding process for PET bottle. The numerical analysis of the blow molding of PET bottle is considered in this paper using CAE with a view to minimize the thickness difference. In order to determine the design parameters and processing conditions in blow molding, it is very important to establish the numerical model with physical phenomenon. In this study, a shell model with thickness has been introduced for the purpose and blow simulations with 3-type blow process condition are carried out. The simulations resulted in the thickness distribution in good agreement with the physical phenomenon. Also, from the result of numerical analysis, we appropriately predicted the thickness distribution along the PET bottle wall and Using the result of numerical analysis we apply the preform design and blow molding process condition for optimization.

• Polymer(Korea)
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• v.27 no.5
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• pp.477-483
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• 2003

The structure development of drawn poly(trimethylene terephthalate) PTT as a function of draw down ratio and drawing temperature was studied. The special effort was made to find out the effect of structural development on thermal properties and crystallinity in drawn PTT. The changes in shrinkage ratio and mechanical properties were understood base on the level of crystallinity and orientation of the drawn PTT. The stress induced crystallization caused the increase in glass transition temperature and the decrease in cold crystallization temperature and enthalpy. The crystallinity and orientation were dependent upon the level of applied stress level as well as chain flexibility at high drawing temperature. The drawing resulted in the increase of shrinkage ratio but it was minimized by increasing of crystallinity. The development of orientation resulted in increasing modulus and tensile strength while decreasing elongation at break.

• Polymer(Korea)
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• v.24 no.6
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• pp.820-828
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• 2000

In this study, biaxially oriented film process was used to improve barrier property of polypropylene (PP)/ethylene-vinyl alcohol copolymer (EVOH) blends by inducing a laminar morphology of the dispersed phase in the matrix phase. In order to examine the extent of deformation during melt extrusion process, the rheological properties of the resins were measured and the viscosity ratio of the dispersed phase to the continuous phase was determined. The effects of compatibilizer content, draw ratio, and draw temperature on the oxygen permeability and morphology of biaxially drawn blend films were studied. The laminar morphology of the EVOH phase with a larger area of thinner layer induced by biaxial orientation was found to result in a significant increase in oxygen barrier property of PP/EVOH (85/15) blends by about 10 times relative to the pure PP When both PP-g-MAH and ionomer were used as the compatibilizers, there existed an optimum level of compatibilizer content for obtaining improved barrier properties with a well developed laminar structure. In addition, higher draw ratio and draw temperature were found to be more favorable processing conditions in obtaining higher barrier blends.

• Polymer(Korea)
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• v.30 no.2
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• pp.175-181
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• 2006

Hybrid process of thermally-induced phase separation and stretching was developed for the preparation of microporous polypropylene hollow fiber membranes. Precursor for stretching was prepared by using soybean oil as a diluent and benzoic acid as a nucleating agent far the sphenlite control and it was stretched far the micrporous hollow fiber membrane. The effects of stretching ratio and deformation rate for stretching process were investigated. Increase of stretching ratio resulted in the greater pore size with nonuniform size distribution. Higher deformation rate also increaser the pore size with uniform size distribution. Stretching ratio was closely related with the orientation of polymer chain and increased the mechanical strength of the fiber. Increase of deformation rate had little effects on the orientation of crystalline phase, and decreased the orientation of amorphous phase which caused the decrease of tensile strength of the fiber and broke the micro-fibrils connecting spherulites to form a circular pore shape.

• Electrical & Electronic Materials
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• v.6 no.1
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• pp.34-39
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• 1993

본 논문에서는 폴리프로필렌 박막에 대하여 연신이 그 시편의 미세적 구조변화와 물성에 미치는 영향이 조사되었다. 이축연신으로 인해, 이축연신폴리프로필렌의 절연내역은 결정화도의 증가와 미세구조의 변화때문에 증가하는 것이 관찰되었다.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.131-134
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• 2001

합성섬유의 방사공정 중 하나인 연신 공정은 섬유의 성질을 향상시키기 위해 고화된 상태의 섬유를 신장하는 공정이다. 연신할 때 변형이 국부적으로 일어나는 네킹이 일반적으로 관찰되는데, 이 현상은 방사 공정 후에 일어나는, 합성섬유의 역학적 성질과 미세구조에 큰 영향을 미친다[1]. 본 논문에서는 네킹을 분자 구조의 변화에 대한고려 없이 거시적인 관점에서 해석하였다. (중략)

• Electrical & Electronic Materials
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• v.3 no.1
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• pp.45-51
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• 1990

무배향 미연신 폴리에틸렌 테레프탈레이트 필름을 수중에서 일축연신 시킨후 연신된 시료의 열자극전류를 측정하여 검토 고찰하였다. 연신에 따른 측정결과 결정화도가 대체로 증가하는 경향이 있으나 연신비 150% 부근에서는 반대로 결정화도가 감소함을 알수가 있었는데 이는 초기인장에 따른 일시적 분자배향의 불안정한 형태로 인한 자유체적의 증가와 더불어 배위 엔트로피가 증가 하기 때문이라고 생각되며 인장된 시료의 밀도측정 및 적외선 스펙트럼분석으로 부터 확인하였다. 그리고 인장비의 변화에 따른 열자극전류의 피이크를 105(.deg.C)부근에서 얻었으며 인장비에 따른 열자극전류의 활성화 에너지를 구한 결과 150%에서 가장 큰 값을 얻었다.

• Proceedings of the Korean Society for Emotion and Sensibility Conference
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• 2003.05a
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• pp.14-18
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• 2003

국내 소모방 업체는 원료를 외국에서 수입하고 있기 때문에 wool 원료를 이용한 고감성 고기능성 제품 개발이 요구되고 있다. 또한 기존 제품은 국제 가격 경쟁력을 상실한 상태이므로 물성개전과 기능성을 향상시킨 획기적인 소재 개발이 요구되고 있는 실정이다. 최근 호주의 CSIRO 연구소에서 개발된 $\ulcorner$Optim$\lrcorner$$^{(R)}$ 은 광택이 뛰어난 모섬유 소재로서 국내에서 수입되어 고감성 의류용 직물로서 상품화가 되고 있다. 그러나 원료가격이 고가인 관계로 원료수금이 원활치 못한 실적이다. 본 연구에서는 생산원가가 저렴하며 50%까지 연신함으로써 광택은 물론 물세탁이 가능한 기능성을 부여할 수 있는 방적 소모사 상태에서 연신하는 기술을 개발하기 위한 최적 공정 조건을 결정하기 위한 실험을 실시하였고 이들 소모사를 이용한 직물의 의류물성을 분석하여 소모사 상태에서 연신기술을 응용한 광택이 우수한 고감성 직물을 개발하기 위해 연구를 수행하였다.

• Journal of the Korea Concrete Institute
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• v.23 no.5
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• pp.559-567
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• 2011

Recently, many researches on high strength reinforcing steel have been conducted to construct optimum reinforced concrete structures. However, the studies have shown that high strength steel shows less elongation capacity than normal strength steel. Therefore, high strength reinforcing steel may not satisfy the minimum elongation requirement of current standards. Moreover, elongation measurements may be not standardized ones since each standard has its own requirements for minimum elongation and gage length. Therefore, the standards for reinforcing steel testing must be investigated to verify the validity of Korean Standard D 3504. This research aimed to compare the requirements for minimum elongation and gage length of the Korean, American, Japanese, European, and ISO Standards. Then, the study further investigated accuracy of the standards by tensile test of reinforcing steel. The study results showed that the Korean Standard has the strictest requirement. Based on the study results, the authors proposed modified minimum elongation requirements for general reinforcing steel and new requirements for seismic reinforcing steel.