• Clean Technology
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• v.27 no.1
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• pp.93-103
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• 2021

As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.373-380
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• 2022

In this study, Chung's equations 1, 2, and 3 were extended to standardize smoke safety rating evaluation in case of fire, and Chung's equations-V, smoke performance index-V, and smoke growth index-V were calculated. Five types of wood were selected and their smoke indices were measured using the cone calorimeter method according to ISO 5660-1. The smoke risk was graded by the smoke risk index-VI according to Chung's equation-VI. Smoke risk index-VI increased in the order of PMMA (1) ≈ maple (1.01) < ash (1.57) < needle fir (4.98) < paulownia (46.15) < western red cedar (106.26). It was predicted that maple and ash had the lowest smoke risk, and paulownia and western red cedar had the highest. The five samples' CO mean production rate (COP_mean) was 0.0009~0.0024 g/s, indicating that these woods were incompletely burned than the polymethyl methacrylate (PMMA) reference material. Regarding the smoke properties of the chosen woods, the smoke performance index-V (SPI-V) increased as the bulk density increased, and the smoke risk index-VI (SRI-VI) decreased.

• Polymer(Korea)
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• v.31 no.5
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• pp.404-409
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• 2007

Polyurethane nanocomposites with inorganic nano fillers for the improvement thermal stability were prepared by the urethane reaction. Fire retardation properties of polyurethane nanocomposites were investigated by cone calorimeter and limited oxygen index (LOI). Maximum heat release rate of MMT-PU and $Bi_2O_3-PU$ polyurethane nanocomposites were decreased as 50% than polyurethane matrix and fire retardation properties of $MMT/Bi_2O_3-PU$ nanocomposte had the best improvement. The LOI of polyurethane nanocomposites also were improved as filling fillers in the nanocomposites over 20. The maximum heat release rates of MMT-PU, $Bi_2O_3-PU\;and\;MMT/Bi_2O_3-PU$ polyurethane nanocomposites were 764, 707, $635kW/m^2$, respectively and $MMT/Bi_2O_3-PU$ polyurethane nanocomposite exhibited the highest value of fire-retardant. We confirmed that polyurethane nanocomposites improved the fire retardation properties.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.241-246
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• 2003

Numerical simulations are performed at atmospheric pressure in order to understand the effect of additives on flame speed and the NOx formation in freely propagating $H_{2}/O_{2}/N_{2}$ flames with oxygen enrichments. A chemical kinetic mechanism is developed, which involves 26 gas-phase species and 99 reactions. Under several equivalence ratios and oxygen enrichments, flame speeds are calculated and compared with those obtained from the experiments, the results of which is in good agreement. As hydrogen chloride as additive is added into $H_{2}/O_{2}/N_{2}$ flames with low oxygen enrichments, its chemical effect causes the decrease of flame speed, radical concentration, and the NO production rate. It is found that the chemical effect of additive has much more influence on the reduction of EINO than its physical effect. However, in flames with very high flame temperature the physical effect rather than the chemical effect becomes more important on the reduction of EINO.

• Journal of Energy Engineering
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• v.14 no.1
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• pp.1-10
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• 2005

The combustion reactivity of char depending on the pyrolysis pressure was investigated with Pressurized Thermogravimetric Analyser. The amounts of volatiles released at pyrolysis pressure of 1, 8 and 15 atm were, first, measured with Alaska, Adaro and Denisovsky coals. Reactivities of chars produced at var-ious pyrolysis pressure were evaluated at atmospheric pressure and 500℃, and analysed in terms of char crystal structure, surface area, pore characteristics and chemical composition of char. Finally, the combustion reactivities of three chars were examined at pressure of 1 atm, 8 atm and 15 atm. From this study, it was recognized that the amount of volatiles released decreases with increase in pyrolysis pressure, and reaction rate of char produced at higher pyrolysis pressure was lower than that at lower pyrolysis pressure. It might be resulted from the difference in char surface area and pore characteristics rather than char crystal structure and chemical characteristics. At 15 atm, kinetic parameters of Alaska char were obtained with the grain model, and these were 56.8 KJ/mole for activation energy and 222.34 (1/min) for frequency factor.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.696-701
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• 2018

The nitrogen oxides generated during combustion reactions have a great influence on the generation of acid rain and fine dust. As an NOx reduction method, exhaust gas recirculation combustion using Coanda nozzles capable of recirculating a large amount of exhaust gas with a small amount of air has recently been utilized. In this study, for the burner outlet with dual end opening, the use of a recirculation burner was investigated for the distribution of the pressure, streamline, temperature, combustion reaction rate and nitrogen oxides using computational fluid analysis. The gas mixed with the combustion air and the recirculated exhaust gas flow in the tangential direction of the circular cylinder burner, so that there is a region with low pressure in the vicinity of the fuel nozzle exit. As a result, a reverse flow is formed in the central portion of the burner near the center of the circular cylinder burner and the exhaust gas is discharged to the outside region of the circular cylinder burner. The combustion reaction occurs on the right side of the burner and the temperature and NOx distribution are relatively higher than those on the left side of the burner. It was found that the average NOx production decreased from an air flow ratio of 1.0 to 1.5. When the air flow ratio is 1.8, the NOx production increases abruptly. It is considered that the NOx production reaction increases exponentially with temperature when the air ratio is more than 1.5 and the NOx production reaction rate increases rapidly on the right-hand side of the burner.

• Journal of the Korean Society of Propulsion Engineers
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• v.9 no.4
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• pp.31-38
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• 2005

In this paper, the combustion characteristics of a hybrid propulsion system were studied with various L/D(length vs diameter) ratio of the single po.1 type solid fuel. Experiments were performed for 2 cases with the fixed grain port diameter and fuel length respectively. For the first case, results show that there are no large variations for regression rates as the L/D ratio changes. And as the L/D ratio increases, the O/F ratio decreases and thrust, characteristic velocity tends to increase. For the second case, there is no large change for O/F ratio, thrust and characteristic velocity as L/D ratio changes. On the other hand, as the L/D ratio decreases, only the regression rate tends to increase. Experimentally, exponent n in $\dot{r}=a{G_0}^n$ was found about 0.5 and then the O/F ratio was shown nearly constant. In the experiment, PE and gas oxygen were used as a fuel and an oxidizer.

• Journal of the Korean Society of Propulsion Engineers
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• v.18 no.5
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• pp.12-18
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• 2014

A study of gas generator Fuel-Rich propellant for air-breathing propulsion system was performed in this paper. General solid propellant comprises a mean of 60% or more oxidizing agents. but, to develop the fuel-rich solid propellant increased the content of the metal fuel and reduced the content of the oxidizing agents by approximately 30%. Very high amount of heat per volume of fuel into the metal having the Boron was used. Amorphous Boron Powder was applied to propellant as beads type and it allowed to design more amount of metal fuel in the fuel-rich propellant. And the Combustion characteristics and properties of fuel-rich solid propellant according to the Boron-bead sizes were confirmed.

• Journal of Energy Engineering
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• v.9 no.4
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• pp.348-357
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• 2000

본 연구에서는 동해화력 순환유동층 보일러와 유사한 3개의 사이클론을 갖는 직사각형 구조의 순환유동층 반응기를 이용하여 동해화력 운전조건 -연소로 공기 속도, 일-이차 공기비, 전체 고체량(inventory), 입도 및 입도분포 등- 에 따른 축방향 고체 체류량 및 순환량 등의 수력학적 특성을 고찰하였다. 상승관에서의 공기유속(U$_{0}$)이 증가함에 따라, 또는 PA/[PA+SA]비가 증가함에 따라, 그리고 전체 고체량(inventory)이 증가함에 따라 고채 채류량 및 순환량은 증가하는 것으로 나타났다. 또한 넓은 입도 분포를 갖는 석탄 회재의 경우는 균일한 입도 분포의 입자들에 비해 입자 비산량 및 고체 순환량이 작을 것으로 나타났다. 한편, 층내에서의 고체 체루량 분포를 감소지수 a 및 K를 사용하여 나타낼 수 있었으며, a 및 K와 유속 및 입자간의 상관 특성치를 도출하여 유동 및 순환특성을 고찰하였다. 상기의 상관수는 균일한 입도의 모래에 비해 석탄회재가 비교적 큰 값을 나타내었으며, 상관수가 클수록 희박상 영역에서의 비산 및 고체 순환량이 작은 것으로 나타났다.다.

• Elastomers and Composites
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• v.37 no.3
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• pp.159-169
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• 2002

The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).