• Journal of the Korean Society of Propulsion Engineers
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• v.12 no.5
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• pp.51-59
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• 2008

DLN-2.6 combustion tuning was carried out for the maintenance of GE 7FA+e gas turbine at Seo-Incheon combined cycle power plant. DLN-2.6 combustion system has the higher level of yellow plume and combustion vibration problem in the initial operating mode than that of the base mode($100{\sim}160MW$). The objectives of this study are to investigate the causes of yellow plume and combustion vibration problems at the starting mode and to suggest the best operating condition for the reliable working of the real combustors. By the analysis of tuning data, we could conclude that a yellow plume is caused by the rich mixture(${\phi}{\sim}1$) in a PM 1 nozzle at mode 3($20{\sim}30MW$). In addition, the combustion vibration($120{\sim}140Hz$) might be related to the cold flow characteristics of PM 3 nozzles at mode 6B($40{\sim}45MW$).

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.88.1-88.1
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• 2011

SOFC는 사용되는 셀의 디자인에 따라 튜브형, 평판형으로 구분되어진다. 평판형의 경우에는 전해질 지지형(ESC), Anode 지지형(ASC) 및 금속 지지형(MSC)로 크게 나눌 수 있다. SOFC 스택은 이와 같은 셀과 밀봉재, 집전체, 분리판의 구성요소를 여러 장으로 적층하여 이루어진다. SOFC 발전시스템은 SOFC 스택과 EBOP, MBOP로 구성되는데, SOFC 발전시스템의 상용화를 위해 선행되어야 할 것은 스택의 안정적 출력 및 신뢰성 확보이다. 즉, 셀, 밀봉재, 분리판 및 집전체로 대변되는 구성요소들이 스택에 장착되었을 때 그 기능을 최대한 발휘하면서도 점진적 또는 급격한 품질저하가 발생되지 말아야 한다. 특히, 밀봉재의 경우 SOFC에 사용되는 연료와 공기의 혼합(Cross-over)을 방지하는 중요한 기능을 담당하고 있으며 여러 장 적층된 분리판의 전기적 단락을 방지해야 한다. 또한 SOFC의 특성상 $700^{\circ}C$ 이상의 고온에서 다른 구성요소와 화학적 반응이 없어야하고 열싸이클(Thermal cycle)을 견딜 수 있도록 충분한 기계적 강도가 보장되어야 하는 등 요구되는 품질기준이 엄격하다. SOFC의 밀봉재는 접합형(Brazing), 압착형(Compressive), 용융-고정형(Glass-ceramic)이 대표적으로 적용되고 있다. 이 중에서 Brazing 물질과 방법은 현재 활발히 연구가 수행 중에 있지만 범용적으로 사용되고 있지는 않은 상태이고 Compressive 밀봉재와 Glass-ceramic 밀봉재가 대면적 SOFC 스택에 사용되어 적용 가능성을 평가받고 있다. 본 연구에서는 SOFC 구성요소의 국산화를 추진하는 지경부과제의 결과물 중 (주)써모텍에서 개발한 Glass-ceramic 밀봉재(RC1) 단품에 대한 특성평가와 실제 단전지 평가를 통해 SOFC 스택 적용 가능성을 평가하였다. 밀봉재 단품에 대한 특성평가는 용융특성, 상분석, 열팽창계수 등의 물리적, 화학적 평가 외에 가스 누설 정도를 평가하는 기밀도 평가와 SOFC의 작동 온도인 $700^{\circ}C$와 상온 분위기를 주기적으로 인가하는 Thermal cycle 특성을 평가하였다. 셀을 한 장 사용하는 단전지(Unit cell) 평가는 RIST에서 자체 제작한 $100{\times}100mm^2$ 평판형 ASC 셀을 사용하여 수행하였으며, 밀봉재는 Dispensing 공정을 통해 구성되었다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.1
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• pp.75-81
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• 2012

Autoignited lifted flames in laminar jets with hydrogen-enriched methane fuels have been investigated experimentally in heated coflow air. The results showed that the autoignited lifted flame of the methane/hydrogen mixture, which had an initial temperature over 920 K, the threshold temperature for autoignition in methane jets, exhibited features typical of either a tribrachial edge or mild combustion depending on fuel mole fraction and the liftoff height increased with jet velocity. The liftoff height in the hydrogen-assisted autoignition regime was dependent on the square of the adiabatic ignition delay time for the addition of small amounts of hydrogen, as was the case for pure methane jets. When the initial temperature was below 920 K, where the methane fuel did not show autoignition behavior, the flame was autoignited by the addition of hydrogen, which is an ignition improver. The liftoff height demonstrated a unique feature in that it decreased nonlinearly as the jet velocity increased. The differential diffusion of hydrogen is expected to play a crucial role in the decrease in the liftoff height with increasing jet velocity.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.4
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• pp.106-112
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• 2013

Compression ratio is an important factor affecting engine performance and emission characteristics since thermal efficiency of spark ignition engine can be theoretically improved by increasing compression ratio. In order to evaluate the effect of compression ratio change in HCNG engine, natural gas engine was employed using HCNG30 (CNG 70 vol%, hydrogen 30 vol%). Combustion and emission characteristics of CNG and HCNG fuel was analyzed with respect to the change of compression ratio at each operating condition. The results showed that thermal efficiency improved and $CH_4$, $CO_2$ emission decreased with the increase in compression ratio while $NO_x$ emissions were decreased at a certain excess air ratio condition. Higher thermal efficiency and further reduction of exhaust emissions can be achieved by the increase of compression ratio and the retard of spark timing.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.33.2-33.2
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• 2011

고온형 SOFC의 개발에 있어 스택의 신뢰성을 확보하는데 가장 중요한 핵심기술은 스택 구성요소 사이를 접합하는데 필요한 고온형 밀봉재의 개발이다. SOFC 스택에서의 밀봉재는 고체전해질과 접속자 사이에서 음극에 공급되는 연료가스와 양극에 공급되는 공기가 서로 혼합되는 것을 방지하는 역할은 물론 기계적으로 취약한 단전지의 보호 및 스택전체 구조물의 구조적 일체성(Structural integrity)을 부여하는데 주목적이 있다. 현재 기체 기밀성을 유지하기 위한 밀봉재는 크게 유리 및 결정화 유리계, mica및 mica/유리복합재료, 유리/충전재 복합재료 등이 사용되고 있으나 다수의 단위전지로 구성되는 스택 구성에서 스택의 열기계적 안정성 및 장기수명을 보장하기 위해서는 본 연구에서 개발하고자 하는 복합밀봉재가 가장 적합할 것으로 예상되고 있다. 본 연구에서는 $SiO_2-B_2O_3-RO$계에 BaO, SrO를 일정비율로 첨가하여 제작된 유리 frit을 열처리하여 물리화학적 물성변화를 검토하였으며, $700^{\circ}C$ 이하의 연화점을 갖는 유리를 기지상으로 하고 세라믹 보강재를 첨가한 고온형 복합밀봉재를 개발하고 그 물리화학적 안정성, 열기계적 안정성 및 밀봉 특성을 평가하였다.

• Journal of the Korean Ceramic Society
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• v.41 no.3
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• pp.242-246
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• 2004

Nano-sized a-alumina with a narrow distribution was prepared by using Flame Spray Pyrolysis (FSP). The microemulsion of water in oil (W/O) was prepared to make ultrafine droplets for FSP process. Kerosene (fuel) as a continuos phase and Al(NO$_3$)$_3$$.$9$H_2O$ (oxidizer) aqueous solution as a dispersed phase were prepared for microemulsification. The microemulsion with dispersion stability was obtained by adjusting the composition of 80 vol% kerosene, 10 vol% aqueous solution, and 10 vol% emulsifying agent. Microemulsion was sprayed onto the flame by using two-fluid nozzle spray gun under the condition of 0.03 ㎫ air pressure. The synthesized products were $\alpha$-alumina phase with the size of 20 to 30 nm.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.5
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• pp.334-342
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• 2009

Trends in the automotive market require the application of new engine technologies, which allows for the use of different types of fuel. Since ethanol is a renewable source of energy and has lower $CO_2$ emissions than gasoline, ethanol produced from biomass is expected to be used more frequently as an alternative fuel. It is recognized that for spark ignition (SI) engines, ethanol has the advantages of high octane number and high combustion speed. Due to the disadvantages of ethanol, it may cause extra wear and corrosion of electric fuel pumps. On-board hydrogen production out of ethanol is an alternative plan. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency and emissions. The combustion characteristics with hydrogen-enriched gaseous fuel from ethanol are also examined. As a result, thermal efficiency increase compared to gasoline. Also, reductions in $CO_2$, NOx, and THC combustion products for ethanol vs. gasoline are described.

• Korean Journal of Optics and Photonics
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• v.9 no.4
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• pp.264-269
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• 1998

The Measurement of concentration patterns for $C_2$, CH and OH radicals in the premixed propane-air flame could be managed through an image processing technique. This technique was applied to the three kinds of flames on a bunsen burner-mixtures of fuel to be lean, optimum and excessive respectively. The image processing system was complished by treating single wavelength flame images around the eac radical luminescence band, which was obtained by using a set of narrow band pass filters, an image intensifier, CCD and PC. It was possible to observe and predict the reaction zone and the concentration distribution of the radicals, Spatial distribution of each radicals in the raaction zone gave us enough informations to analyze the reaction mechanisms in $C_mH_n$ combustion process. According to this informations, the image of $C_2$ radical exists at front zone, following the images of CH and OH radicals at downstream.

• Journal of the Korean Society of Propulsion Engineers
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• v.11 no.5
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• pp.1-13
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• 2007

Scramjet engine is one of the most promising propulsion systems for future transport. For the ground test with T4 shock tunnel, model scramjet engine is designed. Design flight Mach number is 7.6 and flight altitude is 30km. Engine intake is designed by Levenberg-Marquardt optimization method and Korkegi relation. Furthermore, cowl cut out region is installed by the rule of Kantrowitz limit. Inside the combustor, cavity type flame holder is installed. Cavity is designed by Rayleigh line relation and PSR model. Numerical analysis is performed for the design confirm.

• Journal of the Korean Institute of Gas
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• v.8 no.2 s.23
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• pp.42-47
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• 2004

The axisymmetric methane-air counterflow flame in microgravity was simulated to investigate effects of the global strain rate on the flame structure. The flame shapes and profiles of temperature and the axial velocity for the mole fraction of methane in the methane-nitrogen fuel stream, Xm= 20, 50, $80\%$, and the global strain rate, ag= 20, 60, 90 $s^{-1}$ each mole fraction were compared. The profiles of the temperature and axial velocity of the axisymmetric simulations were in good agreement with those of OPPDIF, an one-dimensional flamelet code. It was confirmed that the flame is stretched more and the flame radius increases and the flame thickness decreases as the global strain rate increases.